ES2115868T3 - Procedimiento para la produccion de ciclohexanodimetanol, con preponderancia del isomero trans. - Google Patents

Procedimiento para la produccion de ciclohexanodimetanol, con preponderancia del isomero trans.

Info

Publication number
ES2115868T3
ES2115868T3 ES94300067T ES94300067T ES2115868T3 ES 2115868 T3 ES2115868 T3 ES 2115868T3 ES 94300067 T ES94300067 T ES 94300067T ES 94300067 T ES94300067 T ES 94300067T ES 2115868 T3 ES2115868 T3 ES 2115868T3
Authority
ES
Spain
Prior art keywords
hydrogenation
cyclohexanodimethanol
hydrogenation zone
production
trans
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94300067T
Other languages
English (en)
Inventor
John Scarlett
Michael Anthony Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of ES2115868T3 publication Critical patent/ES2115868T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/27—Polyhydroxylic alcohols containing saturated rings
    • C07C31/272—Monocyclic
    • C07C31/276—Monocyclic with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Glass Compositions (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)

Abstract

SE DESCRIBE UN PROCESO PARA LA PRODUCCION DE CICLOHEXANODIMETANOL QUE TIENE UN RELACION DE TRANS-CIS-ISOMERO MAYOR DE APROXIMADAMENTE 1:1 POR HIDROGENACION DE UN CICLOHEXANODICARBOXILATO DE DIALQUILO (POR EJEMPLO DIMETILO)QUE TIENE UNA RELACION DE TRANS-:CIS-ISOMERO INFERIOR A APROXIMADAMENTE 1:1 QUE CONSISTE EN: OBTENER UNA ZONA DE HIDROGENACION QUE CONTIENE UNA CARGA DE UN CATALIZADOR DE HIDROGENACION DE ESTER HETEROGENEO GRANULAR; B) PROPORCIONAR A LA ZONA DE HIDROGENACION UNA CORRIENTE DE ALIMENTACION VAPOROSA QUE CONTIENE HIDROGENO E UN MATERIAL HIDROGENABLE QUE COMPRENDE UN CICLOHEXANODICARBOXILATO DE DIALQUILO Y UNA TEMPERATURA DE ENTRADA QUE ES SUPERIOR A SU PUNTO DE ROCIO DE LA MEZCLA; C) MANTENER LA ZONA DE HIDROGENACION BAJO CONDICIONES DE TEMPERATURA Y PRESION QUE SEAN PROPICIAS PARA EFECTUAR LA HIDROGENACION DE ESTERES; D) PASAR LA CORRIENTE DE ALIMENTACION VAPOROSA A TRAVES DE LA ZONA DE HIDROGENACION; Y E) RECUPERAR DE LA ZONA DE HIDROGENACION UNA CORRIENTE DE PRODUCTO QUE CONTIENEN CICLOHEXANODIMETANOL QUE TIENE UNA RELACION TRANS-:CIS-ISOMERO MAYOR DE 1:1. EN ESTE PROCESO SE PREFIERE EL USO DE 1,4-CICLOHEXANODICARBOXILADO DE DIMETILO
ES94300067T 1993-12-02 1994-01-06 Procedimiento para la produccion de ciclohexanodimetanol, con preponderancia del isomero trans. Expired - Lifetime ES2115868T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939324784A GB9324784D0 (en) 1993-12-02 1993-12-02 Process

Publications (1)

Publication Number Publication Date
ES2115868T3 true ES2115868T3 (es) 1998-07-01

Family

ID=10746057

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94300067T Expired - Lifetime ES2115868T3 (es) 1993-12-02 1994-01-06 Procedimiento para la produccion de ciclohexanodimetanol, con preponderancia del isomero trans.

Country Status (9)

Country Link
US (1) US5395986A (es)
EP (1) EP0656334B1 (es)
JP (1) JP4184449B2 (es)
KR (1) KR100293393B1 (es)
AT (1) ATE165325T1 (es)
DE (1) DE69409761T2 (es)
ES (1) ES2115868T3 (es)
GB (1) GB9324784D0 (es)
TW (1) TW279849B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19720606A1 (de) 1997-05-16 1998-12-10 Basf Ag Verfahren zur Herstellung von cycloaliphatische Gruppen enthaltenden Alkoholen
WO2000058248A1 (en) * 1999-03-25 2000-10-05 Eastman Chemical Company Process for producing 1,4-cyclohexanedimethanol with enhanced cis-isomer content
US6919489B1 (en) * 2004-03-03 2005-07-19 Eastman Chemical Company Process for a cyclohexanedimethanol using raney metal catalysts
US20090142981A1 (en) 2007-12-03 2009-06-04 Velsicol Chemical Corporation Novel Compositions Comprising Structural Isomers Of 1,4-Cyclohexanedimethanol Dibenzoate and Polymer Compositions Containing Same
JP5243861B2 (ja) * 2008-06-27 2013-07-24 Ｊｘ日鉱日石エネルギー株式会社 水素貯蔵装置および水素貯蔵方法
US9115155B1 (en) 2014-03-20 2015-08-25 Eastman Chemical Company Low-pressure synthesis of cyclohexanedimethanol and derivatives
KR102223388B1 (ko) * 2017-09-29 2021-03-04 한화솔루션 주식회사 사이클로헥산 디카르복실산 수소화 반응용 루테늄-백금-주석 촉매의 제조방법 및 이에 의해 제조된 촉매를 이용한 사이클로헥산 디메탄올 (chdm)의 제조방법
KR102188755B1 (ko) * 2017-12-22 2020-12-08 한화솔루션 주식회사 높은 트랜스 함량을 갖는 사이클로헥산 디메탄올 제조방법 및 이에 의해 제조된 사이클로헥산 디메탄올
CN108993500B (zh) * 2018-07-02 2021-06-15 中国科学院兰州化学物理研究所苏州研究院 手性环己烷二甲醇类化合物的合成催化剂、其制法及应用

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2105664A (en) * 1930-04-17 1938-01-18 Du Pont Catalytic hydrogenation of hydroaromatic carboxylic acids and their esters
US2137407A (en) * 1931-05-11 1938-11-22 Du Pont Catalytic hydrogenation process
US2091800A (en) * 1931-09-15 1937-08-31 Rohm & Haas Method of hydrogenating esters
US2079414A (en) * 1932-08-20 1937-05-04 Du Pont Process for producing alcohols from esters of nonaromatic carboxylic acids
US2040944A (en) * 1933-09-22 1936-05-19 Du Pont Process for producing polyhydroxy alcohols
US2755317A (en) * 1952-11-10 1956-07-17 Universal Oil Prod Co Hydrogenation of benzene to cyclohexane
US2818393A (en) * 1953-05-05 1957-12-31 Kellogg M W Co Method of preparing a catalyst
US2830095A (en) * 1953-05-07 1958-04-08 Olin Mathieson Production of ethylene chlorohydrin
BE592181A (es) * 1955-12-22
US2884450A (en) * 1956-04-20 1959-04-28 Du Pont Hydrogenation of unsaturated dilactones to 1,8-octanedioic acids and 1,8-octanediolswith copper chromite catalysts
US2917549A (en) * 1958-01-07 1959-12-15 Eastman Kodak Co Preparation of trans-1,4-cyclohexanedimethanol
NL260833A (es) * 1960-02-09
GB902372A (en) * 1960-03-24 1962-08-01 Ici Ltd Improvements in and relating to the preparation of trans-1 : 4-cyclohexanedimethanol
DE1144703B (de) * 1960-10-06 1963-03-07 Eastman Kodak Co Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Estern
FR1276722A (fr) * 1960-10-11 1961-11-24 Eastman Kodak Co Procédé de préparation d'un catalyseur en vue de la réduction des esters en alcools
NL292315A (es) * 1962-05-05
CH438269A (it) * 1963-05-10 1967-06-30 Snam Spa Processo di idrogenazione di composti acetilenici miscibili con acqua a composti etilenici
US3334149A (en) * 1964-07-21 1967-08-01 Eastman Kodak Co Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite
US4052467A (en) * 1967-11-08 1977-10-04 Phillips Petroleum Company Catalytic reduction of aldehydes to alcohols
GB1454440A (en) * 1974-10-03 1976-11-03 Ucb Sa Process for the production of butane-1,4-diol from but-2-ene- 1,4-dioic acid
GB1464263A (en) * 1974-12-03 1977-02-09 Ucb Sa Production of butane-1,4-diol
US4172961A (en) * 1975-08-08 1979-10-30 Denka Chemical Corporation Production of 1,4-butanediol
US4032458A (en) * 1975-08-08 1977-06-28 Petro-Tex Chemical Corporation Production of 1,4-butanediol
DE2719867A1 (de) * 1977-05-04 1978-11-09 Bayer Ag Verfahren zur herstellung von butandiol-1,4
DE2845905C3 (de) * 1978-10-21 1983-05-26 Chemische Werke Hüls AG, 4370 Marl Verfahren zur kontinuierlichen Herstellung von Butandiol-1,4
DE3106819A1 (de) * 1981-02-24 1982-09-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von 1,4-butandiol
IT1190783B (it) * 1981-04-29 1988-02-24 Davy Mckee Oil & Chem Processo per l'idrogenolisi di esteri di acidi carbossilici
GB8331793D0 (en) * 1983-11-29 1984-01-04 Davy Mckee Ltd Process
GB8514002D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
BR8507068A (pt) * 1984-11-21 1987-07-14 Davy Mckee London Processo para a producao de butano-1,4-diol
GB8514001D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
DE3610698A1 (de) * 1986-03-29 1987-10-01 Henkel Kgaa Katalysator und verfahren zur katalytischen hydrierung von fettsaeuremethylestern im festbett
JPH01500753A (ja) * 1986-08-01 1989-03-16 デイヴィ　マッキー　（ロンドン）　リミテッド ブタン‐１，４‐ジオールおよびガンマ‐ブチロラクトンの同時製造方法
GB8717989D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Catalyst
US4837368A (en) * 1988-02-01 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
KR970009560B1 (ko) * 1987-08-03 1997-06-14 이스트만 코닥 컴퍼니 카보닐을 함유하는 화합물의 저압 촉매수소화 및 이에 관한 촉매
US4999090A (en) * 1988-04-10 1991-03-12 Towa Chemical Industry Co., Ltd. Process for preparing trans-1,4-cyclohexanedimethanol and powder of the same
US5185476A (en) * 1988-07-15 1993-02-09 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
DE3843956A1 (de) * 1988-12-24 1990-06-28 Huels Chemische Werke Ag Verfahren zur herstellung von aliphatischen und cycloaliphatischen diolen durch katalytische hydrierung von dicarbonsaeureestern
US5124435A (en) * 1988-12-28 1992-06-23 Mitsubishi Rayon Co., Ltd. Polyester copolymer from terephthalic acid glycol and cycloaliphatic diol
JP2781272B2 (ja) * 1989-01-17 1998-07-30 デイヴィ・プロセス・テクノロジー・リミテッド 脂肪族アルコールの製造方法
US4929777A (en) * 1989-02-13 1990-05-29 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
US5142067A (en) * 1989-12-21 1992-08-25 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al-X catalysts
US5191091A (en) * 1989-12-21 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al catalysts
GB9025708D0 (en) * 1990-11-27 1991-01-09 Unilever Plc Fatty ester hydrogenation
DE4141199A1 (de) * 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten

Also Published As

Publication number Publication date
DE69409761T2 (de) 1998-09-24
KR100293393B1 (ko) 2001-09-17
JP4184449B2 (ja) 2008-11-19
US5395986A (en) 1995-03-07
DE69409761D1 (de) 1998-05-28
EP0656334B1 (en) 1998-04-22
TW279849B (es) 1996-07-01
EP0656334A1 (en) 1995-06-07
KR950017895A (ko) 1995-07-20
GB9324784D0 (en) 1994-01-19
ATE165325T1 (de) 1998-05-15
JPH07188078A (ja) 1995-07-25

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