ES2103033T3 - Catalizadores inmovilizados de acidos de lewis. - Google Patents

Catalizadores inmovilizados de acidos de lewis.

Info

Publication number
ES2103033T3
ES2103033T3 ES92914043T ES92914043T ES2103033T3 ES 2103033 T3 ES2103033 T3 ES 2103033T3 ES 92914043 T ES92914043 T ES 92914043T ES 92914043 T ES92914043 T ES 92914043T ES 2103033 T3 ES2103033 T3 ES 2103033T3
Authority
ES
Spain
Prior art keywords
approximately
lewis acid
cicloalkilo
group
immobilized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92914043T
Other languages
English (en)
Inventor
Tze-Chiang Chung
Frank Joung-Yei Chen
Jon Edmond Stanat
Alok Kumar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2103033T3 publication Critical patent/ES2103033T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/08—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkali metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Sanitary Device For Flush Toilet (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN CATALIZADOR DE ACIDO DE LEWIS INMOVILIZADO QUE CONTIENE UN POLIMERO QUE TIENE AL MENOS UN ACIDO DE LEWIS INMOVILIZADO DENTRO DE LA ESTRUCTURA QUE LO CONTIENE Y DICHO POLIMERO TIENE UNIDADES MONOMERICAS REPRESENTADAS POR LA FORMULA ESTRUCTURAL: -CION Y 99 MOLES % APROXIMADAMENTE; B REPRESENTA ENTRE 0 APROXIMADAMENTE Y 50 MOLES % APROXIMADAMENTE; C REPRESENTA ENTRE 1 APROXIMADAMENTE Y 99 MOLES % APROXIMADAMENTE; A + B + C ES PREFERENTEMENTE UN 100% APROXIMADAMENTE; A ES ((ALFA); B ES ((BETA)); C SE SELECCIONA DEL GRUPO QUE CONSISTE EN (I), (II) Y (III) COMBINACIONES DE LOS MISMOS, EN DONDE D ES OH, HALOGENURO, OR4, NH2, NHR3, OM'' U OM"; E ES EL RESIDUO DE LA REACCION DE AL MENOS UN ACIDO DE LEWIS CON EL SUSTITUYENTE D DE LA UNIDAD MONOMERICA B; R1 REPRESENTA UN PROTON, UN GRUPO ALKILO C1C24 O CICLOALKILO C3-C24; R2 REPRESENTA UN GRUPO ALKILENO C1-C24, CICLOALKILENO C3-C24, ARILENO C6-C18 O ALKILARILENO C7-C30; R3 REPRESENTA ALKILO C1-C24, CICLOALKILO C3-C24, ARILO C1-C24 O ALKILARILO C7-C30; R4 REPRESENTA ALKILO C1-C24, CICLOALKILO C3-C24, ARILO C1-C24 O ALKILARILO C7-C30; M'' REPRESENTA UN METAL ALCALINO; M" REPRESENTA UN METAL ALCALINO-TERREO. TAMBIEN SE PRESENTAN LOS PROCESOS DE POLIMERIZACION Y ALKILACION EN LOS QUE SE UTILIZAN LOS CATALIZADORES DE ACIDO DE LEWIS INMOVILIZADO. OTRO ASPECTO DE LA INVENCION SE REFIERE A UN METODO PARA LA PRODUCCION DE CATALIZADORES DE ACIDO DE LEWIS INMOVILIZADO.
ES92914043T 1991-06-28 1992-06-26 Catalizadores inmovilizados de acidos de lewis. Expired - Lifetime ES2103033T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/723,130 US5288677A (en) 1991-06-28 1991-06-28 Immobilized Lewis acid catalysts

Publications (1)

Publication Number Publication Date
ES2103033T3 true ES2103033T3 (es) 1997-08-16

Family

ID=24904986

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92914043T Expired - Lifetime ES2103033T3 (es) 1991-06-28 1992-06-26 Catalizadores inmovilizados de acidos de lewis.

Country Status (16)

Country Link
US (7) US5288677A (es)
EP (1) EP0591380B1 (es)
JP (1) JPH06508869A (es)
KR (1) KR100232330B1 (es)
CN (3) CN1032429C (es)
AR (1) AR247574A1 (es)
AT (1) ATE153677T1 (es)
AU (1) AU673331B2 (es)
BR (1) BR9206222A (es)
CA (1) CA2109845A1 (es)
DE (1) DE69220060T2 (es)
ES (1) ES2103033T3 (es)
FI (1) FI935880A7 (es)
MX (1) MX9203432A (es)
NO (1) NO303019B1 (es)
WO (1) WO1993000373A1 (es)

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US5288677A (en) 1994-02-22
US5600055A (en) 1997-02-04
EP0591380A1 (en) 1994-04-13
AU2254992A (en) 1993-01-25
DE69220060D1 (de) 1997-07-03
EP0591380B1 (en) 1997-05-28
US5571885A (en) 1996-11-05
CN1121080A (zh) 1996-04-24
US5409873A (en) 1995-04-25
US5481054A (en) 1996-01-02
KR100232330B1 (ko) 1999-12-01
CN1032429C (zh) 1996-07-31
KR940701412A (ko) 1994-05-28
FI935880A0 (fi) 1993-12-27
MX9203432A (es) 1992-12-01
JPH06508869A (ja) 1994-10-06
CN1117955A (zh) 1996-03-06
US5414177A (en) 1995-05-09
FI935880A7 (fi) 1993-12-27
BR9206222A (pt) 1995-04-25
NO934575L (no) 1993-12-13
WO1993000373A1 (en) 1993-01-07
AU673331B2 (en) 1996-11-07
CA2109845A1 (en) 1993-01-07
CN1049900C (zh) 2000-03-01
CN1048975C (zh) 2000-02-02
NO934575D0 (no) 1993-12-13
CN1069496A (zh) 1993-03-03
US5563313A (en) 1996-10-08
ATE153677T1 (de) 1997-06-15
DE69220060T2 (de) 1997-09-18
AR247574A1 (es) 1995-01-31
NO303019B1 (no) 1998-05-18

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