ES2103033T3 - Catalizadores inmovilizados de acidos de lewis. - Google Patents
Catalizadores inmovilizados de acidos de lewis.Info
- Publication number
- ES2103033T3 ES2103033T3 ES92914043T ES92914043T ES2103033T3 ES 2103033 T3 ES2103033 T3 ES 2103033T3 ES 92914043 T ES92914043 T ES 92914043T ES 92914043 T ES92914043 T ES 92914043T ES 2103033 T3 ES2103033 T3 ES 2103033T3
- Authority
- ES
- Spain
- Prior art keywords
- approximately
- lewis acid
- cicloalkilo
- group
- immobilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/08—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkali metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
UN CATALIZADOR DE ACIDO DE LEWIS INMOVILIZADO QUE CONTIENE UN POLIMERO QUE TIENE AL MENOS UN ACIDO DE LEWIS INMOVILIZADO DENTRO DE LA ESTRUCTURA QUE LO CONTIENE Y DICHO POLIMERO TIENE UNIDADES MONOMERICAS REPRESENTADAS POR LA FORMULA ESTRUCTURAL: -CION Y 99 MOLES % APROXIMADAMENTE; B REPRESENTA ENTRE 0 APROXIMADAMENTE Y 50 MOLES % APROXIMADAMENTE; C REPRESENTA ENTRE 1 APROXIMADAMENTE Y 99 MOLES % APROXIMADAMENTE; A + B + C ES PREFERENTEMENTE UN 100% APROXIMADAMENTE; A ES ((ALFA); B ES ((BETA)); C SE SELECCIONA DEL GRUPO QUE CONSISTE EN (I), (II) Y (III) COMBINACIONES DE LOS MISMOS, EN DONDE D ES OH, HALOGENURO, OR4, NH2, NHR3, OM'' U OM"; E ES EL RESIDUO DE LA REACCION DE AL MENOS UN ACIDO DE LEWIS CON EL SUSTITUYENTE D DE LA UNIDAD MONOMERICA B; R1 REPRESENTA UN PROTON, UN GRUPO ALKILO C1C24 O CICLOALKILO C3-C24; R2 REPRESENTA UN GRUPO ALKILENO C1-C24, CICLOALKILENO C3-C24, ARILENO C6-C18 O ALKILARILENO C7-C30; R3 REPRESENTA ALKILO C1-C24, CICLOALKILO C3-C24, ARILO C1-C24 O ALKILARILO C7-C30; R4 REPRESENTA ALKILO C1-C24, CICLOALKILO C3-C24, ARILO C1-C24 O ALKILARILO C7-C30; M'' REPRESENTA UN METAL ALCALINO; M" REPRESENTA UN METAL ALCALINO-TERREO. TAMBIEN SE PRESENTAN LOS PROCESOS DE POLIMERIZACION Y ALKILACION EN LOS QUE SE UTILIZAN LOS CATALIZADORES DE ACIDO DE LEWIS INMOVILIZADO. OTRO ASPECTO DE LA INVENCION SE REFIERE A UN METODO PARA LA PRODUCCION DE CATALIZADORES DE ACIDO DE LEWIS INMOVILIZADO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/723,130 US5288677A (en) | 1991-06-28 | 1991-06-28 | Immobilized Lewis acid catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2103033T3 true ES2103033T3 (es) | 1997-08-16 |
Family
ID=24904986
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES92914043T Expired - Lifetime ES2103033T3 (es) | 1991-06-28 | 1992-06-26 | Catalizadores inmovilizados de acidos de lewis. |
Country Status (16)
Country | Link |
---|---|
US (7) | US5288677A (es) |
EP (1) | EP0591380B1 (es) |
JP (1) | JPH06508869A (es) |
KR (1) | KR100232330B1 (es) |
CN (3) | CN1032429C (es) |
AR (1) | AR247574A1 (es) |
AT (1) | ATE153677T1 (es) |
AU (1) | AU673331B2 (es) |
BR (1) | BR9206222A (es) |
CA (1) | CA2109845A1 (es) |
DE (1) | DE69220060T2 (es) |
ES (1) | ES2103033T3 (es) |
FI (1) | FI935880A (es) |
MX (1) | MX9203432A (es) |
NO (1) | NO303019B1 (es) |
WO (1) | WO1993000373A1 (es) |
Families Citing this family (85)
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DE69409512T2 (de) * | 1993-05-20 | 1998-09-24 | Exxon Chemical Patents Inc | Lewis-säure-katalysatoren auf einem porösen polymersubstrat |
PL318432A1 (en) * | 1994-08-03 | 1997-06-09 | Exxon Chemical Patents Inc | Ionic supported catalyst composition |
US6143686A (en) * | 1994-08-03 | 2000-11-07 | Exxon Chemical Patents, Inc. | Supported ionic catalyst compositions |
US5643847A (en) * | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
US6218331B1 (en) | 1995-03-29 | 2001-04-17 | Equistar Chemicals, L.P. | Polymer-supported catalyst for olefin polymerization |
US5945574A (en) * | 1995-12-13 | 1999-08-31 | Bp Amoco Corporation | Olefin oligomerization process and catalysts therefor |
US5811617A (en) * | 1995-12-13 | 1998-09-22 | Amoco Corporation | Olefin oligomerization process |
EP0866784A1 (en) * | 1995-12-13 | 1998-09-30 | Amoco Corporation | Olefin oligomerization process and catalyst |
US5691431A (en) * | 1996-01-18 | 1997-11-25 | Exxon Chemical Patents Inc. | Cationic polymerization catalyzed by lewis acid catalysts supported on porous polymer substrate |
DE19619267A1 (de) * | 1996-05-13 | 1997-11-20 | Basf Ag | Verfahren zur Herstellung von mittelmolekularem, hochreaktivem Polyisobuten |
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US6228795B1 (en) | 1997-06-05 | 2001-05-08 | Exxon Chemical Patents, Inc. | Polymeric supported catalysts |
US6030918A (en) * | 1997-06-25 | 2000-02-29 | The Regents Of The University Of California | Gallium based low-interaction anions |
WO1999064476A1 (en) | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
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US6486088B1 (en) | 1998-10-23 | 2002-11-26 | Exxonmobil Chemical Patents Inc. | High activity carbenium-activated polymerization catalysts |
US6147173A (en) | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
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US6476164B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Carbenium cationic complexes suitable for polymerization catalysts |
BR0015178A (pt) * | 1999-11-05 | 2002-06-18 | Ici Plc | Lìquidos iÈnicos imobilizados |
JP3389176B2 (ja) * | 1999-11-17 | 2003-03-24 | 科学技術振興事業団 | 高分子担持ルイス酸触媒 |
US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
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JPS59212438A (ja) * | 1983-05-17 | 1984-12-01 | Nippon Oil Co Ltd | 高純度ブテン−1の分離回収方法 |
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US4490571A (en) * | 1983-10-05 | 1984-12-25 | Uop Inc. | Oligomerization of olefins |
GB8329082D0 (en) * | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
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US4929800A (en) * | 1986-10-22 | 1990-05-29 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
US4719190A (en) * | 1986-10-22 | 1988-01-12 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
US4798667A (en) * | 1986-10-22 | 1989-01-17 | University Of Florida | Hydrocarbon conversion polymerization catalyst and method of making and using same |
CA1283997C (en) * | 1986-12-12 | 1991-05-07 | Frank Joung-Yei Chen | Fixed bed process for polymerizing liquid butenes |
US4751276A (en) * | 1986-12-24 | 1988-06-14 | Exxon Research And Engineering Company | Method for preparing functional alpha-olefin polymers and copolymers |
US4734472A (en) * | 1986-12-24 | 1988-03-29 | Exxon Research And Engineering Company | Method for preparing functional alpha-olefin polymers and copolymers |
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US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
US4940760A (en) * | 1988-02-16 | 1990-07-10 | E. I. Du Pont De Nemours And Company | Group Transfer Polymerization process employing supported initiators |
BE1001858A3 (nl) * | 1988-06-29 | 1990-03-20 | Schelde Delta Bv Ba | Werkwijze voor het raffineren van olien. |
US4943616A (en) * | 1988-07-26 | 1990-07-24 | Polysar Limited | Living cationic polymerization process |
DK169166B1 (da) * | 1990-05-14 | 1994-09-05 | Roulunds Fabriker As | Måtte af et væsketæt, fleksibelt materiale |
US5026799A (en) * | 1990-05-30 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Living cationic polymerization of vinylic unsaturated compounds |
BE1006694A5 (fr) * | 1991-06-22 | 1994-11-22 | Basf Ag | Procede de preparation de polyisobutenes extremement reactifs. |
US5288677A (en) * | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5376744A (en) * | 1993-11-10 | 1994-12-27 | The University Of Akron | Carbocationic polymerizations in supercritical CO2 |
-
1991
- 1991-06-28 US US07/723,130 patent/US5288677A/en not_active Expired - Fee Related
-
1992
- 1992-06-25 AR AR92322623A patent/AR247574A1/es active
- 1992-06-26 DE DE69220060T patent/DE69220060T2/de not_active Expired - Fee Related
- 1992-06-26 BR BR9206222A patent/BR9206222A/pt not_active Application Discontinuation
- 1992-06-26 WO PCT/US1992/005454 patent/WO1993000373A1/en active IP Right Grant
- 1992-06-26 JP JP5501698A patent/JPH06508869A/ja active Pending
- 1992-06-26 CA CA002109845A patent/CA2109845A1/en not_active Abandoned
- 1992-06-26 EP EP92914043A patent/EP0591380B1/en not_active Expired - Lifetime
- 1992-06-26 US US07/905,582 patent/US5409873A/en not_active Expired - Fee Related
- 1992-06-26 AU AU22549/92A patent/AU673331B2/en not_active Ceased
- 1992-06-26 MX MX9203432A patent/MX9203432A/es not_active Application Discontinuation
- 1992-06-26 ES ES92914043T patent/ES2103033T3/es not_active Expired - Lifetime
- 1992-06-26 AT AT92914043T patent/ATE153677T1/de active
- 1992-06-26 KR KR1019930704069A patent/KR100232330B1/ko not_active IP Right Cessation
- 1992-06-27 CN CN92105127A patent/CN1032429C/zh not_active Expired - Fee Related
-
1993
- 1993-11-18 US US08/154,228 patent/US5414177A/en not_active Expired - Fee Related
- 1993-12-13 NO NO934575A patent/NO303019B1/no not_active IP Right Cessation
- 1993-12-27 FI FI935880A patent/FI935880A/fi unknown
-
1995
- 1995-03-03 US US08/398,635 patent/US5571885A/en not_active Expired - Fee Related
- 1995-03-03 US US08/398,637 patent/US5481054A/en not_active Expired - Fee Related
- 1995-03-03 US US08/398,463 patent/US5563313A/en not_active Expired - Fee Related
- 1995-05-08 US US08/436,508 patent/US5600055A/en not_active Expired - Fee Related
- 1995-05-26 CN CN95105501A patent/CN1049900C/zh not_active Expired - Fee Related
- 1995-05-26 CN CN95105502A patent/CN1048975C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH06508869A (ja) | 1994-10-06 |
AU2254992A (en) | 1993-01-25 |
CN1032429C (zh) | 1996-07-31 |
US5288677A (en) | 1994-02-22 |
US5600055A (en) | 1997-02-04 |
CN1121080A (zh) | 1996-04-24 |
ATE153677T1 (de) | 1997-06-15 |
DE69220060T2 (de) | 1997-09-18 |
US5563313A (en) | 1996-10-08 |
CN1117955A (zh) | 1996-03-06 |
CA2109845A1 (en) | 1993-01-07 |
WO1993000373A1 (en) | 1993-01-07 |
EP0591380A1 (en) | 1994-04-13 |
US5409873A (en) | 1995-04-25 |
EP0591380B1 (en) | 1997-05-28 |
US5481054A (en) | 1996-01-02 |
FI935880A0 (fi) | 1993-12-27 |
US5571885A (en) | 1996-11-05 |
CN1049900C (zh) | 2000-03-01 |
CN1069496A (zh) | 1993-03-03 |
NO934575D0 (no) | 1993-12-13 |
NO303019B1 (no) | 1998-05-18 |
MX9203432A (es) | 1992-12-01 |
AR247574A1 (es) | 1995-01-31 |
KR100232330B1 (ko) | 1999-12-01 |
KR940701412A (ko) | 1994-05-28 |
US5414177A (en) | 1995-05-09 |
BR9206222A (pt) | 1995-04-25 |
DE69220060D1 (de) | 1997-07-03 |
AU673331B2 (en) | 1996-11-07 |
FI935880A (fi) | 1993-12-27 |
CN1048975C (zh) | 2000-02-02 |
NO934575L (no) | 1993-12-13 |
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