ES2070933T3 - Chapa de acero revestida con un material compuesto organico muy susceptible a la electrodeposicion cationica. - Google Patents
Chapa de acero revestida con un material compuesto organico muy susceptible a la electrodeposicion cationica.Info
- Publication number
- ES2070933T3 ES2070933T3 ES90101218T ES90101218T ES2070933T3 ES 2070933 T3 ES2070933 T3 ES 2070933T3 ES 90101218 T ES90101218 T ES 90101218T ES 90101218 T ES90101218 T ES 90101218T ES 2070933 T3 ES2070933 T3 ES 2070933T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- coating composition
- type
- layer
- total solids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/51—One specific pretreatment, e.g. phosphatation, chromatation, in combination with one specific coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4045—Mixtures of compounds of group C08G18/58 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/58—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
- C08G59/4028—Isocyanates; Thioisocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/90—Compositions for anticorrosive coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12542—More than one such component
- Y10T428/12549—Adjacent to each other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12556—Organic component
- Y10T428/12569—Synthetic resin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12611—Oxide-containing component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
- Y10T428/12757—Fe
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
LA PRESENTE INVENCION OFRECE UNA LAMINA DE ACERO CHAPADO ORGANICO COMPUESTO ALTAMENTE SUSCEPTIBLE DE ELECTRODEPOSICION CATIONICA, QUE CONSTA DE UN SUSTRATO DE ACERO CHAPADO CON OTRO SELECCIONADO DEL GRUPO QUE CONTENGA ZINC, ALEACION DE ZINC, ALEACION COMPUESTA DE ZINC O ALUMINIO, Y UNA PRIMERA CAPA CON UNA PELICULA CROMADA MENOS SOLUBLE CON UN CONTENIDO SOLUBLE EN AGUA DEL 5% O MENOS, FORMADA SOBRE EL SUSTRATO CON UNA CANTIDAD DE 10 A 150 MG COMO TOTALIDAD DE CROMO POR METRO CUADRADO, Y UNA SEGUNDA CAPA CON UNA PELICULA FINA DE REVESTIMIENTO SOLIDO DE 0,2 A 2 (MU)M, FORMADA SOBRE LA PRIMERA CAPA; LA SEGUNDA CAPA ESTA FORMADA POR UNA COMPOSICION DE REVESTIMIENTO CON UN PESO DEL 10 A 50% DE SOLIDOS, QUE CONSTA DE: (A) UN 30% O MAS DE PESO DE UNA RESINA EPOXIDICA DEL TIPO A BISFENOL CON UN PESO MOLECULAR MEDIO DE 300 A 100.000 SEGUN LOS SOLIDOS TOTALES EN LA COMPOSICION DE REVESTIMIENTO; (B) UNA RELACION DE PESO DE AL MENOS UN AGENTE DE CURADO SELECCIONADO DEL GRUPO QUE COMPRENDA COMPUESTOS DE POLIISOCIANATO Y COMPUESTOS DE POLIISOCIANATO DE BLOQUE, RESPECTO A UN SOLIDO DE RESINA EPOXIDICA DE 0,1 A 2,0; (C) UN 5 A 50% DE PESO DE SILICE CON UN TAMAÑO MEDIO DE LAS PARTICULAS DE 0,1 A 100 NM SEGUN LOS SOLIDOS TOTALES DE DICHA COMPOSICION DE REVESTIMIENTO; (D) AL MENOS UN PIGMENTO SELECCIONADO DEL GRUPO QUE CONSTE DE PIGMENTOS ORGANICOS DEL TIPO AZO INSOLUBLE, TIPO LACA AZO Y TIPO TALOCIANINA CON UN TAMAÑO MEDIO DE 0,01 A 2 (MU)M CON UN PESO DEL 0,1 A 15% SEGUN LOS SOLIDOS TOTALES DE LA COMPOSICION DE REVESTIMIENTO Y UNA RELACION DE PESO DEL PIGMENTO RESPECTO AL SILICE AHUMADO DEL 0,01 A 1,0; Y (E) EL 40% O MAS DE UN SOLVENTE ORGANICO DEL TIPO CETONA EN LA COMPOSICION DE REVESTIMIENTO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1013342A JPH02194946A (ja) | 1989-01-23 | 1989-01-23 | 高カチオン電着塗装性有機複合めっき鋼板 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2070933T3 true ES2070933T3 (es) | 1995-06-16 |
Family
ID=11830448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90101218T Expired - Lifetime ES2070933T3 (es) | 1989-01-23 | 1990-01-22 | Chapa de acero revestida con un material compuesto organico muy susceptible a la electrodeposicion cationica. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4948678A (es) |
| EP (1) | EP0380024B1 (es) |
| JP (1) | JPH02194946A (es) |
| CA (1) | CA2007905C (es) |
| DE (1) | DE69018657T2 (es) |
| ES (1) | ES2070933T3 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03268939A (ja) * | 1990-03-19 | 1991-11-29 | Sumitomo Metal Ind Ltd | 電着塗装性と耐食性に優れた有機複合被覆鋼板 |
| JP2523204B2 (ja) * | 1990-03-19 | 1996-08-07 | 日本ペイント株式会社 | プレコ―ト金属材料用被覆組成物 |
| JPH0735585B2 (ja) * | 1990-05-18 | 1995-04-19 | 日本鋼管株式会社 | 溶接可能な黒色鋼板 |
| JPH0815584B2 (ja) * | 1990-11-30 | 1996-02-21 | 日本鋼管株式会社 | 溶接可能な着色鋼板 |
| JP2841912B2 (ja) * | 1991-03-29 | 1998-12-24 | 日本鋼管株式会社 | 溶接可能な黒色鋼板 |
| JP2844953B2 (ja) * | 1991-03-29 | 1999-01-13 | 日本鋼管株式会社 | 溶接可能な着色鋼板 |
| JP2502229B2 (ja) * | 1991-11-27 | 1996-05-29 | 川崎製鉄株式会社 | 表裏識別性に優れた有機複合被覆鋼板 |
| JP2502230B2 (ja) * | 1991-11-29 | 1996-05-29 | 川崎製鉄株式会社 | 識別性に優れた有機複合被覆鋼板 |
| US5393605A (en) * | 1991-12-12 | 1995-02-28 | Nkk Corporation | Zinciferous plated steel sheet excellent in press-formability and corrosion resistance |
| US5387473A (en) * | 1992-03-31 | 1995-02-07 | Nkk Corporation | Weldable black steel sheet with low-gloss appearance |
| JP2792324B2 (ja) * | 1992-04-30 | 1998-09-03 | 日本鋼管株式会社 | 複層亜鉛系めっき鋼板 |
| JPH0623319A (ja) * | 1992-07-10 | 1994-02-01 | Dainippon Toryo Co Ltd | 塗装金属板加工品の製造方法 |
| DE4244209A1 (de) * | 1992-12-24 | 1994-06-30 | Basf Lacke & Farben | Elektrotauchlacke und Verfahren zur Beschichtung elektrisch leitfähiger Substrate |
| US5547661A (en) * | 1994-02-22 | 1996-08-20 | Helene Curtis, Inc. | Antiperspirant deodorant compositions |
| DE19748764A1 (de) | 1997-11-05 | 1999-05-06 | Henkel Kgaa | Leitfähige, organische Beschichtungen |
| DE10022075A1 (de) | 2000-05-06 | 2001-11-08 | Henkel Kgaa | Leitfähige, organische Beschichtungen |
| DE102004028764A1 (de) | 2004-06-16 | 2006-01-12 | Henkel Kgaa | Strahlungshärtbares elektrisch leitfähiges Beschichtungsgemisch |
| US20070087201A1 (en) * | 2005-10-13 | 2007-04-19 | Michael Wimmer | Self-bonding coating composition |
| US7829188B2 (en) * | 2006-04-03 | 2010-11-09 | E.I. Du Pont De Nemours And Company | Filled epoxy compositions |
| US20080146470A1 (en) * | 2006-12-18 | 2008-06-19 | Zap-Lok Pipeline Systems, Inc. | Lubricating fast setting epoxy composition |
| FR3053352A1 (fr) | 2016-07-04 | 2018-01-05 | Airbus Safran Launchers Sas | Composition de protection anticorrosion |
| CN113881317B (zh) * | 2017-12-20 | 2022-07-26 | 江苏德威涂料有限公司 | 一种水性环氧富锌底漆及其制备方法和应用 |
| KR102453007B1 (ko) | 2020-12-18 | 2022-10-12 | 주식회사 포스코 | 가공 후 내식성이 우수한 복합 도금강판 및 이의 제조방법 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1235283A (en) * | 1967-06-22 | 1971-06-09 | Ici Ltd | The use of ureas and carbamates containing amino groups in dispersions |
| JPS5551032A (en) * | 1978-10-06 | 1980-04-14 | Neos Co Ltd | Preparation of hexafluoroepoxypropane oligomer |
| JPS55152055A (en) * | 1979-05-16 | 1980-11-27 | Toa Gosei Chem Ind | Resin coated zinc plated steel plate and adhering vessel using said resin coated zinc plated steel plate as blank |
| JPS602186B2 (ja) * | 1980-12-24 | 1985-01-19 | 日本鋼管株式会社 | 塗装下地用表面処理鋼板 |
| JPS59162278A (ja) * | 1983-03-04 | 1984-09-13 | Nisshin Steel Co Ltd | 塗装下地用亜鉛または亜鉛合金めつき鋼板 |
| JPS59166678A (ja) * | 1983-03-08 | 1984-09-20 | Nisshin Steel Co Ltd | Fe−Zn合金めつき鋼板の高耐食表面処理方法 |
| DE3314777A1 (de) * | 1983-04-23 | 1984-10-25 | Herberts Gmbh, 5600 Wuppertal | Verfahren zur lackierung |
| JPS6050181A (ja) * | 1983-08-31 | 1985-03-19 | Nippon Kokan Kk <Nkk> | 高耐食性表面処理鋼板 |
| JPS6086283A (ja) * | 1983-10-18 | 1985-05-15 | Kawasaki Steel Corp | 亜鉛または亜鉛系合金めつき鋼板の塗料密着性改良方法 |
| JPS60149786A (ja) * | 1984-01-17 | 1985-08-07 | Kawasaki Steel Corp | 耐食性に優れた亜鉛系合金電気めつき鋼板の表面処理方法 |
| JPS61584A (ja) * | 1984-06-13 | 1986-01-06 | Kawasaki Steel Corp | 耐食性および塗装性に優れた亜鉛系めつき鋼板の特殊クロメ−ト処理法 |
| JPS6123766A (ja) * | 1984-07-10 | 1986-02-01 | Sumitomo Metal Ind Ltd | 複合被覆めつき鋼板 |
| JPS6167794A (ja) * | 1984-09-10 | 1986-04-07 | Nippon Steel Corp | 耐食性に優れた高鮮映性を有する塗装用鋼板の製造方法 |
| JPS61152444A (ja) * | 1984-12-25 | 1986-07-11 | 川崎製鉄株式会社 | 溶接性、加工性、耐食性の優れた塗装鋼板 |
| JPS61177238A (ja) * | 1985-02-02 | 1986-08-08 | 日新製鋼株式会社 | マフラ−用塗装鋼板およびその製造方法 |
| JPS61177237A (ja) * | 1985-02-02 | 1986-08-08 | 日新製鋼株式会社 | マフラ−用塗装鋼板およびその製造方法 |
| US4707415A (en) * | 1985-03-30 | 1987-11-17 | Sumitomo Metal Industries, Ltd. | Steel strips with corrosion resistant surface layers having good appearance |
| JPS6220024A (ja) * | 1985-07-19 | 1987-01-28 | Fujitsu Ltd | バツフアレジスタにおけるリクエスト信号発生装置 |
| US4775600A (en) * | 1986-03-27 | 1988-10-04 | Nippon Kokan Kabushiki Kaisha | Highly corrosion-resistant surface-treated steel plate |
| ES2033726T3 (es) * | 1986-05-14 | 1993-04-01 | Nippon Steel Corporation | Material de acero tratado en superficie, particularmente chapa de acero con revestimiento electrolitico. |
| JP2521462B2 (ja) * | 1986-08-14 | 1996-08-07 | 日本鋼管株式会社 | 高耐食性複層被覆鋼板 |
| US4889775A (en) * | 1987-03-03 | 1989-12-26 | Nippon Kokan Kabushiki Kaisha | Highly corrosion-resistant surface-treated steel plate |
| JP2719698B2 (ja) * | 1987-04-06 | 1998-02-25 | 臼井国際産業 株式会社 | 耐食性重層被覆金属管 |
| JPS63283935A (ja) * | 1987-05-18 | 1988-11-21 | Nippon Steel Corp | 有機複合鋼板 |
| US4847122A (en) * | 1987-05-27 | 1989-07-11 | Palmer International, Inc. | Cavitation-resistant polymer and coating |
| JPS6411830A (en) * | 1987-07-06 | 1989-01-17 | Nippon Steel Corp | Organic composite plated steel plate excellent in press formability, weldability, electrocoating property and corrosion resistance |
-
1989
- 1989-01-23 JP JP1013342A patent/JPH02194946A/ja active Granted
-
1990
- 1990-01-17 CA CA002007905A patent/CA2007905C/en not_active Expired - Fee Related
- 1990-01-22 US US07/468,296 patent/US4948678A/en not_active Expired - Fee Related
- 1990-01-22 DE DE69018657T patent/DE69018657T2/de not_active Expired - Fee Related
- 1990-01-22 ES ES90101218T patent/ES2070933T3/es not_active Expired - Lifetime
- 1990-01-22 EP EP90101218A patent/EP0380024B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69018657D1 (de) | 1995-05-24 |
| JPH0562585B2 (es) | 1993-09-08 |
| EP0380024A2 (en) | 1990-08-01 |
| CA2007905A1 (en) | 1990-07-23 |
| US4948678A (en) | 1990-08-14 |
| EP0380024A3 (en) | 1991-11-27 |
| CA2007905C (en) | 1993-06-08 |
| JPH02194946A (ja) | 1990-08-01 |
| DE69018657T2 (de) | 1995-08-17 |
| EP0380024B1 (en) | 1995-04-19 |
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