ES2064793T3 - Masa de moldeo termoplastica. - Google Patents
Masa de moldeo termoplastica.Info
- Publication number
- ES2064793T3 ES2064793T3 ES91104862T ES91104862T ES2064793T3 ES 2064793 T3 ES2064793 T3 ES 2064793T3 ES 91104862 T ES91104862 T ES 91104862T ES 91104862 T ES91104862 T ES 91104862T ES 2064793 T3 ES2064793 T3 ES 2064793T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- graft
- polymerized
- monomer
- average
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Abstract
MATERIALES TERMOPLASTICOS DE MOLDEO, DE INTENSO BRILLO Y BUENA TINCION, QUE CONTIENE UN PRIMER POLIMERIZADO DE INJERTO A, A PARTIR DE 55-75% EN PESO, PREFERENTEMENTE 60-70%, REFERIDO A A, DE UN ELASTOMERO POLIMERIZADO DE ESTER ACRILICO A1, RETICULADO, CON UNA GRANULOMETRIA MEDIA (MEDIA EN PESO) DE 50 A 150 NM, COMO BASE DE INJERTO, Y 45-25% EN PESO, PREFERENTEMENTE 40-35%, REFERIDO A A, DE UN REVESTIMIENTO DE INJERTO A2 FORMADO POR UN MONOMERO VINILAROMATICO Y UN MONOMERO INSATURADO POLAR, COPOLIMERIZABLE, ETILENICO, EN UNA RELACION EN PESO DE 80:20 A 65:35. CONTIENE ADEMAS UN SEGUNDO POLIMERIZADO DE INJERTO B OBTENIDO APARTE, A PARTIR DE 50-80% EN PESO, PREFERENTEMENTE 60-70%, REFERIDO A B, DE UN ELASTOMERO POLIMERIZADO B1, DISTINTO A A1, RETICULADO, CON UNA GRANULOMETRIA MEDIA (MEDIA EN PESO) DEL ORDEN DE 200 A 700 NM, COMO BASE DE INJERTO, CON UN PRIMER REVESTIMIENTO DE INJERTO B2 DE 5-30% EN PESO, PREFERENTEMENTE 10-20%, REFERIDO A B, DE UN MONOMERO VINILAROMATICO Y UN SEGUNDO REVESTIMIENTO DE INJERTO B3 DE 15-40% EN PESO, PREFERENTEMENTE 20-30%, REFERIDO A B, DE UNA MEZCLA DE UN MONOMERO VINILAROMATICO B31 Y UN MONOMERO POLAR INSATURADO, COPOLIMERIZABLE, ETILENICO B32 EN UNA RELACION EN PESO DE B31 A B32 DE 90:10 A 60:40. ASI MISMO CONTIENE TAMBIEN UNA MATRIZ DURA C COMPUESTA POR UNO O MAS COPOLIMERIZADOS DE ESTIRENO, -METILESTIRENO, NITRILO ACRILICO, METACRILATO DE METILO Y/O FENILMALEINIMIDA, DE MODO QUE LA PROPORCION EN PESO A1:B1 DE LAS BASES DE INJERTO, ES DEL ORDEN DE 95:5 A 35:65 Y QUE LA SUMA DE LAS PARTES DE A1 Y B1 BASICAS ES DE 10 A 35% EN PESO, REFERIDO AL PESO DEL MATERIAL DE MOLDEO A, B Y C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4011162A DE4011162A1 (de) | 1990-04-06 | 1990-04-06 | Thermoplastische formmasse |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2064793T3 true ES2064793T3 (es) | 1995-02-01 |
Family
ID=6403900
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES91104862T Expired - Lifetime ES2064793T3 (es) | 1990-04-06 | 1991-03-27 | Masa de moldeo termoplastica. |
Country Status (6)
Country | Link |
---|---|
US (1) | US5196480A (es) |
EP (1) | EP0450485B1 (es) |
JP (1) | JP3043451B2 (es) |
KR (1) | KR100201985B1 (es) |
DE (2) | DE4011162A1 (es) |
ES (1) | ES2064793T3 (es) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4131728A1 (de) * | 1991-09-24 | 1993-03-25 | Basf Ag | Teilchenfoermiges pfropfcopolymerisat mit kern/schale-aufbau |
DE4131985A1 (de) * | 1991-09-26 | 1993-04-01 | Basf Ag | Thermoplastische formmassen |
DE4242974A1 (de) * | 1992-12-18 | 1994-06-23 | Basf Ag | Thermoplastische Formmasse mit erhöhter Kerbschlagzähigkeit |
DE19503545A1 (de) * | 1995-02-03 | 1996-08-08 | Basf Ag | Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit |
ES2176470T3 (es) * | 1995-06-26 | 2002-12-01 | Basf Ag | Composicion polimera nueva para copolimeros de injerto asi como sus mezclas y masas termoplasticas h que los contienen. |
DE19536892A1 (de) * | 1995-10-04 | 1997-04-10 | Basf Ag | Formteile aus thermoplastischen Formmassen |
US5777036A (en) * | 1996-02-01 | 1998-07-07 | Basf Aktiengesellschaft | Particulate graft copolymers and thermoplastic molding materials containing them and having improved colorability |
US5910858A (en) * | 1996-04-01 | 1999-06-08 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting with coated back surface |
US5882796A (en) * | 1996-04-01 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Bonded structured retroreflective sheeting |
US5784197A (en) * | 1996-04-01 | 1998-07-21 | Minnesota Mining And Manufacturing Company | Ultra-flexible retroreflective sheeting with coated back surface |
US5754338A (en) * | 1996-04-01 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Structured retroreflective sheeting having a rivet-like connection |
DE19617068A1 (de) * | 1996-04-29 | 1997-10-30 | Basf Ag | Formteile, hergestellt aus thermoplastischen Formmassen |
ES2191178T3 (es) | 1996-05-30 | 2003-09-01 | Basf Ag | Masas de moldeo termoplasticas a base de policarbonatos y polimeros de estireno/acrilonitrilo, que contienen para la mejora de sus propiedades copolimeros a base de (met)acrilato de alquilo. |
DE19623416A1 (de) * | 1996-06-12 | 1997-12-18 | Basf Ag | Teilchenförmige Pfropfcopolymerisate und diese enthaltende thermoplastische Formmassen mit verbesserter Einfärbbarkeit |
DE19630118A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Flächige Wandelemente |
DE19630143A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Gehäuse und Verkleidungen für medizinische Zwecke |
DE19630061A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Gehäuse für Gartengeräte |
DE19630097A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Vorrichtung zur Haltung oder Versorgung von Kleintieren |
DE19630117A1 (de) * | 1996-07-25 | 1998-01-29 | Basf Ag | Gehäuse für Sicherheitseinrichtungen |
EP0847852A3 (de) * | 1996-12-10 | 2004-03-03 | Basf Aktiengesellschaft | Verbundschichtplatten oder -folien und Formkörper daraus |
DE19846209A1 (de) * | 1998-10-07 | 2000-04-13 | Basf Ag | Sportartikel |
DE10057164A1 (de) * | 2000-11-16 | 2002-05-23 | Basf Ag | Pigmentzubereitungen |
DE10057165A1 (de) * | 2000-11-16 | 2002-05-23 | Basf Ag | Pigmentzubereitungen |
KR20010079049A (ko) * | 2001-06-08 | 2001-08-22 | 권구범 | 윗몸 일으키기 기계 기구의 상체 활용 뱃살 빼는 방법 |
US20030236350A1 (en) * | 2002-06-21 | 2003-12-25 | General Electric Company | Impact-modified compositions |
US8969476B2 (en) * | 2002-06-21 | 2015-03-03 | Sabic Global Technologies B.V. | Impact-modified compositions |
KR100815995B1 (ko) * | 2006-06-08 | 2008-03-21 | 제일모직주식회사 | 저온 및 상온 내충격성과 착색성 및 내후성이 우수한asa 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물 |
WO2008141941A1 (de) * | 2007-05-23 | 2008-11-27 | Basf Se | Isotaktisches polystyrol mit reaktiven gruppen |
WO2009007358A1 (en) | 2007-07-10 | 2009-01-15 | Basf Se | Flame retardant thermoplastic molding compositions |
KR20100081319A (ko) | 2007-09-14 | 2010-07-14 | 바스프 에스이 | 스티렌-부타디엔 블록 공중합체 혼합물을 기재로 하는, 투명하고 인성 및 강성을 갖는 성형 조성물 |
CN101970720B (zh) * | 2008-03-13 | 2014-10-15 | 巴斯夫欧洲公司 | 施加金属层至基质的方法和分散体及可金属化热塑性模塑组合物 |
EP2297240B1 (de) * | 2008-07-07 | 2012-10-24 | Styrolution GmbH | Kautschukmodifizierte flammgeschützte formmassen |
WO2010034778A1 (de) * | 2008-09-29 | 2010-04-01 | Basf Se | Thermoplastische zusammensetzungen mit verarbeitungseigenschaften |
US20120220678A1 (en) | 2009-11-03 | 2012-08-30 | Christof Mehler | Thermoplastic compositions having improved flowability |
KR101891836B1 (ko) * | 2010-05-07 | 2018-08-24 | 이네오스 스티롤루션 유럽 게엠베하 | 광산란이 감소된 성형 조성물 |
US8440764B2 (en) | 2010-05-07 | 2013-05-14 | Styrolution GmbH | Molding composition with reduced light scattering |
CN103080214B (zh) | 2010-07-12 | 2015-07-15 | 巴斯夫股份公司 | 稳定的丙烯腈/苯乙烯/丁二烯成型组合物 |
US9701813B2 (en) | 2010-07-12 | 2017-07-11 | Ineos Styrolution Europe Gmbh | Weathering-stabilized acrylonitrile copolymer molding compositions |
CN102372891B (zh) * | 2010-08-22 | 2013-01-16 | 山东道恩高分子材料股份有限公司 | Asa专用彩色母粒 |
WO2012080388A1 (de) | 2010-12-16 | 2012-06-21 | Basf Se | Kautschukmodifizierte flammgeschützte formmassen und deren herstellung |
BR112013025003B1 (pt) * | 2011-03-29 | 2020-12-01 | Techno-Umg Co., Ltd. | copolímero enxertado à base de borracha acrílica, composição de resina termoplástica, e artigo |
US8889769B2 (en) | 2011-06-27 | 2014-11-18 | Basf Se | Weathering-resistant polyester molding compositions with styrene copolymers |
WO2013000747A1 (de) | 2011-06-27 | 2013-01-03 | Basf Se | Witterungsbeständige polyesterformmassen mit styrolcopolymeren |
JP6070974B2 (ja) * | 2011-09-16 | 2017-02-01 | 三菱レイヨン株式会社 | グラフト共重合体組成物、樹脂組成物及び成形体 |
KR20140096037A (ko) | 2011-09-29 | 2014-08-04 | 스티롤루션 게엠베하 | 폴리아미드 및 asa-공중합체로 이루어진 안정화 성형 화합물 |
KR20140096036A (ko) | 2011-09-29 | 2014-08-04 | 스티롤루션 게엠베하 | 안정화 폴리카르보네이트/아크릴로니트릴/스티렌/아크릴산 에스테르 성형 화합물 |
US10253175B2 (en) | 2011-10-05 | 2019-04-09 | Kaneka Corporation | Acrylic resin film having excellent resistance to whitening on bending and excellent cracking resistance |
WO2014104485A1 (ko) | 2012-12-28 | 2014-07-03 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 포함한 성형품 |
US9745456B2 (en) | 2013-03-19 | 2017-08-29 | Ineos Styrolution Group Gmbh | Matt weather-resistant molding masses for extrusion methods |
KR20150002267A (ko) | 2013-06-28 | 2015-01-07 | 제일모직주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
KR101681212B1 (ko) | 2013-09-03 | 2016-11-30 | 롯데첨단소재(주) | 열가소성 수지 조성물을 이용한 자동차용 성형품 |
US10072145B2 (en) | 2013-11-26 | 2018-09-11 | Ineos Styrolution Group Gmbh | Thermoplastic moulding compositions with appropriately designed graft shell |
WO2015150223A1 (de) | 2014-03-31 | 2015-10-08 | Styrolution Group Gmbh | Verfahren zur herstellung von acrylat-kautschuk mit reduzierter koagulatbildung |
KR101681427B1 (ko) * | 2014-12-05 | 2016-12-01 | 주식회사 엘지화학 | 열가소성 수지 제조방법 |
KR101671297B1 (ko) | 2015-01-07 | 2016-11-02 | 금호석유화학 주식회사 | 내충격성과 착색성이 우수한 아크릴계 그라프트 공중합체의 제조방법 |
WO2017055179A1 (de) * | 2015-09-30 | 2017-04-06 | Ineos Styrolution Group Gmbh | Verfahren zur herstellung von acrylatkautschuk bei reduzierter emulgatorkonzentration |
CN111303334B (zh) | 2015-10-28 | 2022-06-07 | 大科能宇菱通株式会社 | 接枝共聚物、橡胶质聚合物以及它们的制造方法、热塑性树脂组合物和成型品 |
KR101884972B1 (ko) * | 2015-12-04 | 2018-08-02 | 주식회사 엘지화학 | 무광 및 유광이 우수한 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
WO2017198593A1 (de) | 2016-05-20 | 2017-11-23 | Ineos Styrolution Group Gmbh | Acrylester-styrol-acrylnitril-copolymer formmassen mit optimiertem restmonomeren-anteil |
CN109952322B (zh) * | 2016-09-06 | 2021-09-14 | 英力士苯领集团股份公司 | 用于聚合丙烯酸酯的方法和系统 |
CN110023349A (zh) | 2016-09-27 | 2019-07-16 | 英力士苯领集团股份公司 | 制备asa塑料的改进方法 |
KR102171738B1 (ko) * | 2016-12-22 | 2020-10-29 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 사출 성형품 |
EP3649194A1 (en) * | 2017-07-05 | 2020-05-13 | INEOS Styrolution Group GmbH | Thermoplastic resin composition with improved uv resistance |
JP7005990B2 (ja) | 2017-07-28 | 2022-01-24 | テクノUmg株式会社 | ゴム質重合体、グラフト共重合体および熱可塑性樹脂組成物 |
ES2886928T3 (es) | 2017-12-11 | 2021-12-21 | Ineos Styrolution Group Gmbh | Procedimiento para la producción de una composición de moldeo termoplástica modificada al impacto con procesamiento y resistencia al impacto mejorados |
EP3774956A1 (en) | 2018-03-29 | 2021-02-17 | Rohm and Haas Company | Three-stage polymer particle |
ES2923444T3 (es) | 2018-07-24 | 2022-09-27 | Ineos Styrolution Group Gmbh | Copolímero de caucho de injerto de poliacrilato y composición de moldeo termoplástica modificada al impacto |
WO2020020834A1 (en) | 2018-07-24 | 2020-01-30 | Ineos Styrolution Group Gmbh | Polyacrylate graft rubber copolymer and thermoplastic molding composition |
US20240026146A1 (en) * | 2019-10-15 | 2024-01-25 | Ineos Styrolution Group Gmbh | Weathering-resistant styrene copolymer molding compositions with reduced mold deposit formation for high gloss applications |
US20220177692A1 (en) * | 2020-02-03 | 2022-06-09 | Lg Chem, Ltd. | Thermoplastic resin composition |
EP4359477A1 (en) | 2021-06-23 | 2024-05-01 | INEOS Styrolution Group GmbH | Weather resistant asa molding composition |
KR20230172111A (ko) * | 2022-06-15 | 2023-12-22 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이로부터 제조된 성형품 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2826925A1 (de) * | 1978-06-20 | 1980-01-17 | Basf Ag | Witterungsbestaendige, schlagzaehe thermoplastische massen mit guter einfaerbbarkeit |
DE3135252A1 (de) * | 1981-09-05 | 1983-03-17 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
DE3149358A1 (de) * | 1981-12-12 | 1983-06-16 | Basf Ag, 6700 Ludwigshafen | Thermoplastische formmasse |
DE3262827D1 (en) * | 1981-12-12 | 1985-05-02 | Basf Ag | Thermoplastic moulding masses |
-
1990
- 1990-04-06 DE DE4011162A patent/DE4011162A1/de not_active Withdrawn
-
1991
- 1991-03-27 DE DE59103615T patent/DE59103615D1/de not_active Expired - Lifetime
- 1991-03-27 ES ES91104862T patent/ES2064793T3/es not_active Expired - Lifetime
- 1991-03-27 EP EP91104862A patent/EP0450485B1/de not_active Expired - Lifetime
- 1991-04-02 JP JP3069857A patent/JP3043451B2/ja not_active Expired - Lifetime
- 1991-04-04 KR KR1019910005426A patent/KR100201985B1/ko not_active IP Right Cessation
- 1991-04-05 US US07/681,054 patent/US5196480A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5196480A (en) | 1993-03-23 |
EP0450485B1 (de) | 1994-11-30 |
KR100201985B1 (ko) | 1999-06-15 |
DE59103615D1 (de) | 1995-01-12 |
EP0450485A2 (de) | 1991-10-09 |
JP3043451B2 (ja) | 2000-05-22 |
EP0450485A3 (en) | 1992-11-25 |
KR910018467A (ko) | 1991-11-30 |
DE4011162A1 (de) | 1991-10-10 |
JPH04225051A (ja) | 1992-08-14 |
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