GB1124911A - Impact resistant moulding materials - Google Patents

Impact resistant moulding materials

Info

Publication number
GB1124911A
GB1124911A GB23766A GB23766A GB1124911A GB 1124911 A GB1124911 A GB 1124911A GB 23766 A GB23766 A GB 23766A GB 23766 A GB23766 A GB 23766A GB 1124911 A GB1124911 A GB 1124911A
Authority
GB
United Kingdom
Prior art keywords
weight
styrene
acrylonitrile
copolymer
moulding materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23766A
Inventor
Herbert Willersinn
Hans-Werner Otto
Paul Raff
Ludwig Schuster
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1124911A publication Critical patent/GB1124911A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Moulding materials are made comprising an intimate mixture of: (A) 15 to 50 parts by weight of a graft copolymer of 10 to 50% by weight of a mixture of styrene and acrylonitrile in a ratio of 60:40 to 90:10, which has been polymerized on to 50 to 90% by weight of a copolymer of 2 to 20% by weight of tricyclodecenyl acrylate and 98 to 80% of a C4-C8 alcohol ester of acrylic acid, and (B) 50 to 85 parts by weight of a copolymer of styrene and acrylonitrile in the ratio of 50:50 to 90:10. An example describes copolymerizing n-butyl and tricyclodecenyl acrylates in aqueous dispersion, polymerizing a mixture of styrene and acrylonitrile in the resulting dispersion with the aid of potassium persulphate and lauroyl peroxide, separating the graft copolymer soproduced and blending it with a styrene/acrylonitrile copolymer.
GB23766A 1965-01-05 1966-01-04 Impact resistant moulding materials Expired GB1124911A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1965B0079984 DE1260135B (en) 1965-01-05 1965-01-05 Impact-resistant thermoplastic molding compounds

Publications (1)

Publication Number Publication Date
GB1124911A true GB1124911A (en) 1968-08-21

Family

ID=6980540

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23766A Expired GB1124911A (en) 1965-01-05 1966-01-04 Impact resistant moulding materials

Country Status (5)

Country Link
BE (1) BE674765A (en)
DE (1) DE1260135B (en)
FR (1) FR1462788A (en)
GB (1) GB1124911A (en)
NL (1) NL6600058A (en)

Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4224419A (en) 1978-06-20 1980-09-23 Basf Aktiengesellschaft Weathering-resistant, high-impact, easily colored thermoplastic compositions
US4433102A (en) * 1981-07-25 1984-02-21 Basf Aktiengesellschaft Thermoplastic molding materials
US4731413A (en) * 1985-02-14 1988-03-15 Huels Aktiengesellschaft Molding compositions based on linear, high-molecular weight polyesters
US4801646A (en) * 1987-01-16 1989-01-31 The Dow Chemical Company Low gloss weather and impact resistant resins
US4968731A (en) * 1987-10-07 1990-11-06 Basf Aktiengesellschaft Glass fiber reinforced thermoplastic molding compositions based on polyesters and graft polymers
US5120788A (en) * 1990-02-20 1992-06-09 Basf Aktiengesellschaft Hermoplastic molding material of improved toughness
US5219907A (en) * 1991-09-27 1993-06-15 Basf Aktiengesellschaft Flameproofed molding composition
US5342898A (en) * 1990-04-06 1994-08-30 Basf Aktiengesellschaft Particulate graft polymer, and thermoplastic molding material produced therefrom having improved toughness
US5367029A (en) * 1992-10-24 1994-11-22 Basf Aktiengesellschaft Thermoplastic molding material
US5438099A (en) * 1992-12-16 1995-08-01 Basf Aktiengesellschaft Particulate graft copolymer and thermoplastic molding materials obtained therefrom
US5585436A (en) * 1993-12-09 1996-12-17 Basf Aktiengesellschaft Three-stage silicone rubber based graft copolymers
WO1999031154A1 (en) * 1997-12-16 1999-06-24 Lg Chemical Ltd. Weather resistant resin composition and preparation method thereof
US5932655A (en) * 1997-11-19 1999-08-03 Bayer Corporation Weatherable resinous composition having improved opacity and impact strength
US6072002A (en) * 1997-10-21 2000-06-06 Bayer Corporation Weatherable resinous composition
US6103821A (en) * 1996-08-01 2000-08-15 Basf Aktiengesellschaft Crosslinking agents for emulsion polymers
US6174958B1 (en) 1996-05-30 2001-01-16 Basf Aktiengesellschaft Thermoplastic moulded materials based on polycarbonates and styrene/acrylonitrile polymers which contain copolymers based on alkyl(meth)acrylate to improve their properties
US6187862B1 (en) 1998-05-01 2001-02-13 Bayer Corporation Weatherable resinous composition having improved opacity and impact strength
US6476126B1 (en) 1999-04-07 2002-11-05 Bayer Corporation Weatherable molding composition having improved surface appearance
US6774167B1 (en) 1999-10-27 2004-08-10 Basf Aktiengesellschaft Method for reducing cold stress whitening
US8097669B2 (en) 2007-07-10 2012-01-17 Styrolution GmbH Flame-retardant elastic block copolymer
US8129455B2 (en) 2007-07-10 2012-03-06 Styrolution GmbH Flame retardant thermoplastic molding compositions
US8367770B2 (en) 2006-06-08 2013-02-05 Cheil Industries Inc. Acrylate-vinyl aromatic-unsaturated nitrile graft copolymer with excellent impact strength, colorability, and weatherability, and thermoplastic resin composition containing the same
US8440764B2 (en) 2010-05-07 2013-05-14 Styrolution GmbH Molding composition with reduced light scattering
US8748527B2 (en) 2009-02-26 2014-06-10 Styrolution GmbH Self-cleaning polymers
US8889769B2 (en) 2011-06-27 2014-11-18 Basf Se Weathering-resistant polyester molding compositions with styrene copolymers
WO2015000873A1 (en) * 2013-07-02 2015-01-08 Styrolution Group Gmbh Process for the manufacturing of abs-molding compositions
US9018300B2 (en) 2005-06-14 2015-04-28 Styrolution Europe Gmbh Reinforced thermoplastic molding compositions, processes for preparing such compositions, molding made with such compositions and uses therefor
US9546271B2 (en) 2012-01-11 2017-01-17 Styrolution Europe Gmbh Weather-proof thermoplastic moulding compounds with improved toughness on the basis of styrene copolymers and polyamides
US9644090B2 (en) 2012-08-08 2017-05-09 Ineos Styrolution Europe Gmbh Polymer mixtures with optimized toughness/stiffness ratio and optical properties
US9650506B2 (en) 2010-12-16 2017-05-16 Ineos Styrolution Europe Gmbh Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact
US9656408B2 (en) 2013-07-11 2017-05-23 Ineos Styrolution Group Gmbh Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto
US9701813B2 (en) 2010-07-12 2017-07-11 Ineos Styrolution Europe Gmbh Weathering-stabilized acrylonitrile copolymer molding compositions
US9714310B2 (en) 2013-08-27 2017-07-25 Ineos Styroltion Group Gmbh Styrene copolymer compositions having an improved gloss
US9745456B2 (en) 2013-03-19 2017-08-29 Ineos Styrolution Group Gmbh Matt weather-resistant molding masses for extrusion methods
US10072145B2 (en) 2013-11-26 2018-09-11 Ineos Styrolution Group Gmbh Thermoplastic moulding compositions with appropriately designed graft shell
US10351679B2 (en) 2015-03-25 2019-07-16 Ineos Styrolution Group Gmbh Process for producing thermoplastic polymer compositions with optimized degree of crosslinking
US10619061B2 (en) 2016-03-17 2020-04-14 Ineos Styrolution Group Gmbh Use of moulding compounds based on blends of san-copolymers and polyamide for 3D printing
US10654249B2 (en) 2014-05-19 2020-05-19 Ineos Styrolution Group Gmbh Styrene copolymer composite film
US10711126B2 (en) 2016-04-21 2020-07-14 Ineos Styrolution Group Gmbh ABS molding composition having improved crack and chemical resistance and its use
US10815367B2 (en) 2013-12-18 2020-10-27 Ineos Styrolution Group Gmbh Moulding compositions based on vinylaromatic copolymers for 3D printing
US10875995B2 (en) 2016-05-20 2020-12-29 Ineos Styrolution Group Gmbh Acrylic ester-styrene-acrylonitrile copolymer molding masses having optimized residual monomer fraction
US11021602B2 (en) 2016-04-21 2021-06-01 Ineos Styrolution Group Gmbh ABS molding composition having improved crack and chemical resistance and its use
US11059965B2 (en) 2016-09-27 2021-07-13 Ineos Styrolution Group Gmbh Process for producing ASA plastics
US11352490B2 (en) 2017-12-11 2022-06-07 Ineos Styrolution Group Gmbh Process for production of impact modified thermoplastic moulding composition with improved processing and impact strength
US11384189B2 (en) 2017-12-14 2022-07-12 Lg Chem, Ltd. Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded article comprising the same
US11680127B2 (en) 2018-08-29 2023-06-20 Ineos Styrolution Group Gmbh Process for the production of graft copolymer powder compositions and thermoplastic resin compositions
US11707420B2 (en) 2021-08-31 2023-07-25 L'oreal Compositions, kits, and methods for altering the color of hair

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3102251A1 (en) * 1981-01-24 1982-09-02 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDS
DE3102253A1 (en) * 1981-01-24 1982-09-02 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDING
DE3108424A1 (en) 1981-03-06 1982-09-23 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDS
DE3129472A1 (en) * 1981-07-25 1983-02-10 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDING
DE3202370A1 (en) * 1982-01-26 1983-08-04 Basf Ag, 6700 Ludwigshafen Thermoplastic moulding compositions
EP0175161B1 (en) * 1984-09-15 1990-04-04 Hüls Aktiengesellschaft Moulding masses based on thermoplasts
DE3504646A1 (en) 1985-02-12 1986-08-14 Basf Ag, 6700 Ludwigshafen HALOGEN-FREE, SELF-EXTINGUISHING THERMOPLASTIC SHAPE
DE4006643A1 (en) * 1990-03-03 1991-09-05 Basf Ag PARTICULATE GRAFT POLYMERIZED WITH IMPROVED LIABILITY BETWEEN THE GRAIN BASE AND THE Graft Shell
DE4402394B4 (en) * 1994-01-27 2005-02-10 Basf Ag Process for dewatering water-moist graft rubber
DE4439969A1 (en) * 1994-11-09 1996-05-15 Basf Ag Matt thermoplastic molding compounds
DE19637368A1 (en) 1996-09-13 1998-03-19 Basf Ag Flame retardant thermoplastic molding compounds
DE19639592A1 (en) 1996-09-26 1998-04-02 Basf Ag Thermoplastic molding compounds
EP0847852A3 (en) * 1996-12-10 2004-03-03 Basf Aktiengesellschaft Laminated films or panels and articles formed therefrom
US6528583B1 (en) 2000-03-30 2003-03-04 Bayer Corporation Thermoplastic molding composition having improved dimensional stability and low gloss
DE10057165A1 (en) 2000-11-16 2002-05-23 Basf Ag A granulate pigment preparation e.g. for automobile body parts comprises at least two different pigments, thermoplastic polymer(s) and optionally a dispersing agent
KR100426123B1 (en) 2001-07-04 2004-04-08 주식회사 엘지화학 Methods for preparing of weatherability thermoplastic resin
KR100622808B1 (en) 2004-10-22 2006-09-19 주식회사 엘지화학 Graft Copolymer, Method for Preparing the Same and Thermoplastic Resin Composition Containing The Same
DE102005022632B4 (en) 2005-05-11 2022-05-25 Ineos Styrolution Europe Gmbh Particulate rubber, process for its production and use, and graft copolymer, thermoplastic molding material and process for its production
EP1752478A1 (en) 2005-08-08 2007-02-14 Basf Aktiengesellschaft A process for the production of a graft copolymer having a bimodal particle distribution.
KR100771355B1 (en) 2005-08-29 2007-10-29 주식회사 엘지화학 Thermoplastic resin composition
DE102008009735A1 (en) 2008-02-19 2009-08-20 Basf Se Device for extruding molding compounds
US20120220678A1 (en) 2009-11-03 2012-08-30 Christof Mehler Thermoplastic compositions having improved flowability
JP5808394B2 (en) 2010-05-05 2015-11-10 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Constituent member comprising insert member and plastic jacket, and method for manufacturing the same
KR101891836B1 (en) 2010-05-07 2018-08-24 이네오스 스티롤루션 유럽 게엠베하 Moulding composition with reduced light scattering
PL2593512T3 (en) 2010-07-12 2016-10-31 Stabilized acrylonitrile/styrene/acrylic ester molding compositions
WO2012019982A1 (en) 2010-08-09 2012-02-16 Basf Se Thermoplastic moulding compositions with improved adhesion of electroplated metal layer
WO2012022669A2 (en) 2010-08-19 2012-02-23 Basf Se Nanocomposite blends with polyesters
WO2012163822A1 (en) 2011-06-01 2012-12-06 Basf Se Polyester with styrene copolymers
CN103619950B (en) 2011-06-27 2016-01-27 巴斯夫欧洲公司 Weatherable polyether moulding compound containing styrol copolymer
CN103890071A (en) 2011-09-29 2014-06-25 苯领股份公司 Stabilized polycarbonate/acrylonitrile/styrene/acrylic ester moulding compounds
KR20140096037A (en) 2011-09-29 2014-08-04 스티롤루션 게엠베하 Stabilized moulding compounds consisting of polyamide and asa-copolymers
KR20140097156A (en) 2011-10-13 2014-08-06 스티롤루션 게엠베하 Stabilized polyamide/abs molding masses
US9249290B2 (en) 2012-01-13 2016-02-02 Styrolution Europe Gmbh Terpolymer molding compounds with a low yellow index, method for producing same, and use thereof
EP2828334A1 (en) 2012-03-21 2015-01-28 Styrolution GmbH Method for producing thermoplastic molding compounds with a high glass fiber content
KR101425754B1 (en) 2012-08-27 2014-08-05 주식회사 엘지화학 Graft copolymer and thermoplastic resin composition comprising thereof
WO2016131899A1 (en) 2015-02-19 2016-08-25 Ineos Styrolution Group Gmbh Component made of thermoplastic composite material with increased notched bar impact strength
KR101949371B1 (en) 2015-10-07 2019-02-18 주식회사 엘지화학 Weather-resistant thermoplastic resin, thermoplastic resine composition containing the same and methd for preparing the composition
US20180346715A1 (en) 2015-11-26 2018-12-06 Ineos Styrolution Group Gmbh Polycarbonate-asa blends with antistatic properties using sulfonated alkanes
KR102420799B1 (en) 2017-09-07 2022-07-15 주식회사 엘지화학 Method for preparing graft copolymer and graft copolymer
WO2019117433A1 (en) 2017-12-14 2019-06-20 주식회사 엘지화학 Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded product which comprise same
US11807752B2 (en) 2018-07-24 2023-11-07 Ineos Styrolution Group Gmbh Process for preparing graft rubber compositions with improved dewatering
EP4294850A1 (en) 2021-02-16 2023-12-27 INEOS Styrolution Group GmbH Process for producing a thermoplastic moulding compound comprising a thermoplastic copolymer a and a graft copolymer b
WO2022268736A1 (en) 2021-06-23 2022-12-29 Ineos Styrolution Group Gmbh Weather resistant asa molding composition
WO2023209004A1 (en) 2022-04-29 2023-11-02 Ineos Styrolution Group Gmbh Acrylonitrile styrene acrylate copolymer composition with improved uv resistance
WO2023209007A1 (en) 2022-04-29 2023-11-02 Ineos Styrolution Group Gmbh Acrylonitrile styrene acrylate (asa) copolymer composition having good uv resistance with reduced uv absorber content
WO2024013294A1 (en) 2022-07-15 2024-01-18 Ineos Styrolution Group Gmbh Method for producing asa or abs graft copolymers with reduced discoloration
WO2024013297A1 (en) 2022-07-15 2024-01-18 Ineos Styrolution Group Gmbh Method for producing asa or abs graft copolymers with reduced discoloration

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* Cited by examiner, † Cited by third party
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DE1182811B (en) * 1962-02-01 1964-12-03 Basf Ag Thermoplastic molding compounds based on styrene and acrylonitrile

Cited By (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4224419A (en) 1978-06-20 1980-09-23 Basf Aktiengesellschaft Weathering-resistant, high-impact, easily colored thermoplastic compositions
US4433102A (en) * 1981-07-25 1984-02-21 Basf Aktiengesellschaft Thermoplastic molding materials
US4731413A (en) * 1985-02-14 1988-03-15 Huels Aktiengesellschaft Molding compositions based on linear, high-molecular weight polyesters
US4801646A (en) * 1987-01-16 1989-01-31 The Dow Chemical Company Low gloss weather and impact resistant resins
US4968731A (en) * 1987-10-07 1990-11-06 Basf Aktiengesellschaft Glass fiber reinforced thermoplastic molding compositions based on polyesters and graft polymers
US5120788A (en) * 1990-02-20 1992-06-09 Basf Aktiengesellschaft Hermoplastic molding material of improved toughness
US5342898A (en) * 1990-04-06 1994-08-30 Basf Aktiengesellschaft Particulate graft polymer, and thermoplastic molding material produced therefrom having improved toughness
US5219907A (en) * 1991-09-27 1993-06-15 Basf Aktiengesellschaft Flameproofed molding composition
US5367029A (en) * 1992-10-24 1994-11-22 Basf Aktiengesellschaft Thermoplastic molding material
US5438099A (en) * 1992-12-16 1995-08-01 Basf Aktiengesellschaft Particulate graft copolymer and thermoplastic molding materials obtained therefrom
US5585436A (en) * 1993-12-09 1996-12-17 Basf Aktiengesellschaft Three-stage silicone rubber based graft copolymers
US6174958B1 (en) 1996-05-30 2001-01-16 Basf Aktiengesellschaft Thermoplastic moulded materials based on polycarbonates and styrene/acrylonitrile polymers which contain copolymers based on alkyl(meth)acrylate to improve their properties
US6103821A (en) * 1996-08-01 2000-08-15 Basf Aktiengesellschaft Crosslinking agents for emulsion polymers
US6072002A (en) * 1997-10-21 2000-06-06 Bayer Corporation Weatherable resinous composition
US5932655A (en) * 1997-11-19 1999-08-03 Bayer Corporation Weatherable resinous composition having improved opacity and impact strength
WO1999031154A1 (en) * 1997-12-16 1999-06-24 Lg Chemical Ltd. Weather resistant resin composition and preparation method thereof
US6187862B1 (en) 1998-05-01 2001-02-13 Bayer Corporation Weatherable resinous composition having improved opacity and impact strength
US6476126B1 (en) 1999-04-07 2002-11-05 Bayer Corporation Weatherable molding composition having improved surface appearance
US6774167B1 (en) 1999-10-27 2004-08-10 Basf Aktiengesellschaft Method for reducing cold stress whitening
US9018300B2 (en) 2005-06-14 2015-04-28 Styrolution Europe Gmbh Reinforced thermoplastic molding compositions, processes for preparing such compositions, molding made with such compositions and uses therefor
US8367770B2 (en) 2006-06-08 2013-02-05 Cheil Industries Inc. Acrylate-vinyl aromatic-unsaturated nitrile graft copolymer with excellent impact strength, colorability, and weatherability, and thermoplastic resin composition containing the same
US8097669B2 (en) 2007-07-10 2012-01-17 Styrolution GmbH Flame-retardant elastic block copolymer
US8129455B2 (en) 2007-07-10 2012-03-06 Styrolution GmbH Flame retardant thermoplastic molding compositions
US8748527B2 (en) 2009-02-26 2014-06-10 Styrolution GmbH Self-cleaning polymers
US8440764B2 (en) 2010-05-07 2013-05-14 Styrolution GmbH Molding composition with reduced light scattering
US10294348B2 (en) 2010-07-12 2019-05-21 Ineos Styrolution Europe Gmbh Stabilized acrylonitrile/styrene/acrylate molding compositions
US9701813B2 (en) 2010-07-12 2017-07-11 Ineos Styrolution Europe Gmbh Weathering-stabilized acrylonitrile copolymer molding compositions
US9650506B2 (en) 2010-12-16 2017-05-16 Ineos Styrolution Europe Gmbh Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact
US8889769B2 (en) 2011-06-27 2014-11-18 Basf Se Weathering-resistant polyester molding compositions with styrene copolymers
US9546271B2 (en) 2012-01-11 2017-01-17 Styrolution Europe Gmbh Weather-proof thermoplastic moulding compounds with improved toughness on the basis of styrene copolymers and polyamides
US9644090B2 (en) 2012-08-08 2017-05-09 Ineos Styrolution Europe Gmbh Polymer mixtures with optimized toughness/stiffness ratio and optical properties
US9745456B2 (en) 2013-03-19 2017-08-29 Ineos Styrolution Group Gmbh Matt weather-resistant molding masses for extrusion methods
US10047220B2 (en) 2013-07-02 2018-08-14 Ineos Styrolution Group Gmbh Process for the manufacturing of ABS-molding compositions
WO2015000873A1 (en) * 2013-07-02 2015-01-08 Styrolution Group Gmbh Process for the manufacturing of abs-molding compositions
US9656408B2 (en) 2013-07-11 2017-05-23 Ineos Styrolution Group Gmbh Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto
US9714310B2 (en) 2013-08-27 2017-07-25 Ineos Styroltion Group Gmbh Styrene copolymer compositions having an improved gloss
US10072145B2 (en) 2013-11-26 2018-09-11 Ineos Styrolution Group Gmbh Thermoplastic moulding compositions with appropriately designed graft shell
US10815367B2 (en) 2013-12-18 2020-10-27 Ineos Styrolution Group Gmbh Moulding compositions based on vinylaromatic copolymers for 3D printing
US10654249B2 (en) 2014-05-19 2020-05-19 Ineos Styrolution Group Gmbh Styrene copolymer composite film
US10351679B2 (en) 2015-03-25 2019-07-16 Ineos Styrolution Group Gmbh Process for producing thermoplastic polymer compositions with optimized degree of crosslinking
US10619061B2 (en) 2016-03-17 2020-04-14 Ineos Styrolution Group Gmbh Use of moulding compounds based on blends of san-copolymers and polyamide for 3D printing
US10711126B2 (en) 2016-04-21 2020-07-14 Ineos Styrolution Group Gmbh ABS molding composition having improved crack and chemical resistance and its use
US11021602B2 (en) 2016-04-21 2021-06-01 Ineos Styrolution Group Gmbh ABS molding composition having improved crack and chemical resistance and its use
US10875995B2 (en) 2016-05-20 2020-12-29 Ineos Styrolution Group Gmbh Acrylic ester-styrene-acrylonitrile copolymer molding masses having optimized residual monomer fraction
US11059965B2 (en) 2016-09-27 2021-07-13 Ineos Styrolution Group Gmbh Process for producing ASA plastics
US11352490B2 (en) 2017-12-11 2022-06-07 Ineos Styrolution Group Gmbh Process for production of impact modified thermoplastic moulding composition with improved processing and impact strength
US11384189B2 (en) 2017-12-14 2022-07-12 Lg Chem, Ltd. Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded article comprising the same
US11680127B2 (en) 2018-08-29 2023-06-20 Ineos Styrolution Group Gmbh Process for the production of graft copolymer powder compositions and thermoplastic resin compositions
US11707420B2 (en) 2021-08-31 2023-07-25 L'oreal Compositions, kits, and methods for altering the color of hair

Also Published As

Publication number Publication date
NL6600058A (en) 1966-07-06
DE1260135B (en) 1968-02-01
BE674765A (en) 1966-07-05
FR1462788A (en) 1966-12-16

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