GB1124911A - Impact resistant moulding materials - Google Patents
Impact resistant moulding materialsInfo
- Publication number
- GB1124911A GB1124911A GB23766A GB23766A GB1124911A GB 1124911 A GB1124911 A GB 1124911A GB 23766 A GB23766 A GB 23766A GB 23766 A GB23766 A GB 23766A GB 1124911 A GB1124911 A GB 1124911A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- styrene
- acrylonitrile
- copolymer
- moulding materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Moulding materials are made comprising an intimate mixture of: (A) 15 to 50 parts by weight of a graft copolymer of 10 to 50% by weight of a mixture of styrene and acrylonitrile in a ratio of 60:40 to 90:10, which has been polymerized on to 50 to 90% by weight of a copolymer of 2 to 20% by weight of tricyclodecenyl acrylate and 98 to 80% of a C4-C8 alcohol ester of acrylic acid, and (B) 50 to 85 parts by weight of a copolymer of styrene and acrylonitrile in the ratio of 50:50 to 90:10. An example describes copolymerizing n-butyl and tricyclodecenyl acrylates in aqueous dispersion, polymerizing a mixture of styrene and acrylonitrile in the resulting dispersion with the aid of potassium persulphate and lauroyl peroxide, separating the graft copolymer soproduced and blending it with a styrene/acrylonitrile copolymer.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1965B0079984 DE1260135B (en) | 1965-01-05 | 1965-01-05 | Impact-resistant thermoplastic molding compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1124911A true GB1124911A (en) | 1968-08-21 |
Family
ID=6980540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23766A Expired GB1124911A (en) | 1965-01-05 | 1966-01-04 | Impact resistant moulding materials |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE674765A (en) |
DE (1) | DE1260135B (en) |
FR (1) | FR1462788A (en) |
GB (1) | GB1124911A (en) |
NL (1) | NL6600058A (en) |
Cited By (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4224419A (en) | 1978-06-20 | 1980-09-23 | Basf Aktiengesellschaft | Weathering-resistant, high-impact, easily colored thermoplastic compositions |
US4433102A (en) * | 1981-07-25 | 1984-02-21 | Basf Aktiengesellschaft | Thermoplastic molding materials |
US4731413A (en) * | 1985-02-14 | 1988-03-15 | Huels Aktiengesellschaft | Molding compositions based on linear, high-molecular weight polyesters |
US4801646A (en) * | 1987-01-16 | 1989-01-31 | The Dow Chemical Company | Low gloss weather and impact resistant resins |
US4968731A (en) * | 1987-10-07 | 1990-11-06 | Basf Aktiengesellschaft | Glass fiber reinforced thermoplastic molding compositions based on polyesters and graft polymers |
US5120788A (en) * | 1990-02-20 | 1992-06-09 | Basf Aktiengesellschaft | Hermoplastic molding material of improved toughness |
US5219907A (en) * | 1991-09-27 | 1993-06-15 | Basf Aktiengesellschaft | Flameproofed molding composition |
US5342898A (en) * | 1990-04-06 | 1994-08-30 | Basf Aktiengesellschaft | Particulate graft polymer, and thermoplastic molding material produced therefrom having improved toughness |
US5367029A (en) * | 1992-10-24 | 1994-11-22 | Basf Aktiengesellschaft | Thermoplastic molding material |
US5438099A (en) * | 1992-12-16 | 1995-08-01 | Basf Aktiengesellschaft | Particulate graft copolymer and thermoplastic molding materials obtained therefrom |
US5585436A (en) * | 1993-12-09 | 1996-12-17 | Basf Aktiengesellschaft | Three-stage silicone rubber based graft copolymers |
WO1999031154A1 (en) * | 1997-12-16 | 1999-06-24 | Lg Chemical Ltd. | Weather resistant resin composition and preparation method thereof |
US5932655A (en) * | 1997-11-19 | 1999-08-03 | Bayer Corporation | Weatherable resinous composition having improved opacity and impact strength |
US6072002A (en) * | 1997-10-21 | 2000-06-06 | Bayer Corporation | Weatherable resinous composition |
US6103821A (en) * | 1996-08-01 | 2000-08-15 | Basf Aktiengesellschaft | Crosslinking agents for emulsion polymers |
US6174958B1 (en) | 1996-05-30 | 2001-01-16 | Basf Aktiengesellschaft | Thermoplastic moulded materials based on polycarbonates and styrene/acrylonitrile polymers which contain copolymers based on alkyl(meth)acrylate to improve their properties |
US6187862B1 (en) | 1998-05-01 | 2001-02-13 | Bayer Corporation | Weatherable resinous composition having improved opacity and impact strength |
US6476126B1 (en) | 1999-04-07 | 2002-11-05 | Bayer Corporation | Weatherable molding composition having improved surface appearance |
US6774167B1 (en) | 1999-10-27 | 2004-08-10 | Basf Aktiengesellschaft | Method for reducing cold stress whitening |
US8097669B2 (en) | 2007-07-10 | 2012-01-17 | Styrolution GmbH | Flame-retardant elastic block copolymer |
US8129455B2 (en) | 2007-07-10 | 2012-03-06 | Styrolution GmbH | Flame retardant thermoplastic molding compositions |
US8367770B2 (en) | 2006-06-08 | 2013-02-05 | Cheil Industries Inc. | Acrylate-vinyl aromatic-unsaturated nitrile graft copolymer with excellent impact strength, colorability, and weatherability, and thermoplastic resin composition containing the same |
US8440764B2 (en) | 2010-05-07 | 2013-05-14 | Styrolution GmbH | Molding composition with reduced light scattering |
US8748527B2 (en) | 2009-02-26 | 2014-06-10 | Styrolution GmbH | Self-cleaning polymers |
US8889769B2 (en) | 2011-06-27 | 2014-11-18 | Basf Se | Weathering-resistant polyester molding compositions with styrene copolymers |
WO2015000873A1 (en) * | 2013-07-02 | 2015-01-08 | Styrolution Group Gmbh | Process for the manufacturing of abs-molding compositions |
US9018300B2 (en) | 2005-06-14 | 2015-04-28 | Styrolution Europe Gmbh | Reinforced thermoplastic molding compositions, processes for preparing such compositions, molding made with such compositions and uses therefor |
US9546271B2 (en) | 2012-01-11 | 2017-01-17 | Styrolution Europe Gmbh | Weather-proof thermoplastic moulding compounds with improved toughness on the basis of styrene copolymers and polyamides |
US9644090B2 (en) | 2012-08-08 | 2017-05-09 | Ineos Styrolution Europe Gmbh | Polymer mixtures with optimized toughness/stiffness ratio and optical properties |
US9650506B2 (en) | 2010-12-16 | 2017-05-16 | Ineos Styrolution Europe Gmbh | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
US9656408B2 (en) | 2013-07-11 | 2017-05-23 | Ineos Styrolution Group Gmbh | Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto |
US9701813B2 (en) | 2010-07-12 | 2017-07-11 | Ineos Styrolution Europe Gmbh | Weathering-stabilized acrylonitrile copolymer molding compositions |
US9714310B2 (en) | 2013-08-27 | 2017-07-25 | Ineos Styroltion Group Gmbh | Styrene copolymer compositions having an improved gloss |
US9745456B2 (en) | 2013-03-19 | 2017-08-29 | Ineos Styrolution Group Gmbh | Matt weather-resistant molding masses for extrusion methods |
US10072145B2 (en) | 2013-11-26 | 2018-09-11 | Ineos Styrolution Group Gmbh | Thermoplastic moulding compositions with appropriately designed graft shell |
US10351679B2 (en) | 2015-03-25 | 2019-07-16 | Ineos Styrolution Group Gmbh | Process for producing thermoplastic polymer compositions with optimized degree of crosslinking |
US10619061B2 (en) | 2016-03-17 | 2020-04-14 | Ineos Styrolution Group Gmbh | Use of moulding compounds based on blends of san-copolymers and polyamide for 3D printing |
US10654249B2 (en) | 2014-05-19 | 2020-05-19 | Ineos Styrolution Group Gmbh | Styrene copolymer composite film |
US10711126B2 (en) | 2016-04-21 | 2020-07-14 | Ineos Styrolution Group Gmbh | ABS molding composition having improved crack and chemical resistance and its use |
US10815367B2 (en) | 2013-12-18 | 2020-10-27 | Ineos Styrolution Group Gmbh | Moulding compositions based on vinylaromatic copolymers for 3D printing |
US10875995B2 (en) | 2016-05-20 | 2020-12-29 | Ineos Styrolution Group Gmbh | Acrylic ester-styrene-acrylonitrile copolymer molding masses having optimized residual monomer fraction |
US11021602B2 (en) | 2016-04-21 | 2021-06-01 | Ineos Styrolution Group Gmbh | ABS molding composition having improved crack and chemical resistance and its use |
US11059965B2 (en) | 2016-09-27 | 2021-07-13 | Ineos Styrolution Group Gmbh | Process for producing ASA plastics |
US11352490B2 (en) | 2017-12-11 | 2022-06-07 | Ineos Styrolution Group Gmbh | Process for production of impact modified thermoplastic moulding composition with improved processing and impact strength |
US11384189B2 (en) | 2017-12-14 | 2022-07-12 | Lg Chem, Ltd. | Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded article comprising the same |
US11680127B2 (en) | 2018-08-29 | 2023-06-20 | Ineos Styrolution Group Gmbh | Process for the production of graft copolymer powder compositions and thermoplastic resin compositions |
US11707420B2 (en) | 2021-08-31 | 2023-07-25 | L'oreal | Compositions, kits, and methods for altering the color of hair |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3102251A1 (en) * | 1981-01-24 | 1982-09-02 | Basf Ag, 6700 Ludwigshafen | THERMOPLASTIC MOLDS |
DE3102253A1 (en) * | 1981-01-24 | 1982-09-02 | Basf Ag, 6700 Ludwigshafen | THERMOPLASTIC MOLDING |
DE3108424A1 (en) | 1981-03-06 | 1982-09-23 | Basf Ag, 6700 Ludwigshafen | THERMOPLASTIC MOLDS |
DE3129472A1 (en) * | 1981-07-25 | 1983-02-10 | Basf Ag, 6700 Ludwigshafen | THERMOPLASTIC MOLDING |
DE3202370A1 (en) * | 1982-01-26 | 1983-08-04 | Basf Ag, 6700 Ludwigshafen | Thermoplastic moulding compositions |
EP0175161B1 (en) * | 1984-09-15 | 1990-04-04 | Hüls Aktiengesellschaft | Moulding masses based on thermoplasts |
DE3504646A1 (en) | 1985-02-12 | 1986-08-14 | Basf Ag, 6700 Ludwigshafen | HALOGEN-FREE, SELF-EXTINGUISHING THERMOPLASTIC SHAPE |
DE4006643A1 (en) * | 1990-03-03 | 1991-09-05 | Basf Ag | PARTICULATE GRAFT POLYMERIZED WITH IMPROVED LIABILITY BETWEEN THE GRAIN BASE AND THE Graft Shell |
DE4402394B4 (en) * | 1994-01-27 | 2005-02-10 | Basf Ag | Process for dewatering water-moist graft rubber |
DE4439969A1 (en) * | 1994-11-09 | 1996-05-15 | Basf Ag | Matt thermoplastic molding compounds |
DE19637368A1 (en) | 1996-09-13 | 1998-03-19 | Basf Ag | Flame retardant thermoplastic molding compounds |
DE19639592A1 (en) | 1996-09-26 | 1998-04-02 | Basf Ag | Thermoplastic molding compounds |
EP0847852A3 (en) * | 1996-12-10 | 2004-03-03 | Basf Aktiengesellschaft | Laminated films or panels and articles formed therefrom |
US6528583B1 (en) | 2000-03-30 | 2003-03-04 | Bayer Corporation | Thermoplastic molding composition having improved dimensional stability and low gloss |
DE10057165A1 (en) | 2000-11-16 | 2002-05-23 | Basf Ag | A granulate pigment preparation e.g. for automobile body parts comprises at least two different pigments, thermoplastic polymer(s) and optionally a dispersing agent |
KR100426123B1 (en) | 2001-07-04 | 2004-04-08 | 주식회사 엘지화학 | Methods for preparing of weatherability thermoplastic resin |
KR100622808B1 (en) | 2004-10-22 | 2006-09-19 | 주식회사 엘지화학 | Graft Copolymer, Method for Preparing the Same and Thermoplastic Resin Composition Containing The Same |
DE102005022632B4 (en) | 2005-05-11 | 2022-05-25 | Ineos Styrolution Europe Gmbh | Particulate rubber, process for its production and use, and graft copolymer, thermoplastic molding material and process for its production |
EP1752478A1 (en) | 2005-08-08 | 2007-02-14 | Basf Aktiengesellschaft | A process for the production of a graft copolymer having a bimodal particle distribution. |
KR100771355B1 (en) | 2005-08-29 | 2007-10-29 | 주식회사 엘지화학 | Thermoplastic resin composition |
DE102008009735A1 (en) | 2008-02-19 | 2009-08-20 | Basf Se | Device for extruding molding compounds |
US20120220678A1 (en) | 2009-11-03 | 2012-08-30 | Christof Mehler | Thermoplastic compositions having improved flowability |
JP5808394B2 (en) | 2010-05-05 | 2015-11-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Constituent member comprising insert member and plastic jacket, and method for manufacturing the same |
KR101891836B1 (en) | 2010-05-07 | 2018-08-24 | 이네오스 스티롤루션 유럽 게엠베하 | Moulding composition with reduced light scattering |
PL2593512T3 (en) | 2010-07-12 | 2016-10-31 | Stabilized acrylonitrile/styrene/acrylic ester molding compositions | |
WO2012019982A1 (en) | 2010-08-09 | 2012-02-16 | Basf Se | Thermoplastic moulding compositions with improved adhesion of electroplated metal layer |
WO2012022669A2 (en) | 2010-08-19 | 2012-02-23 | Basf Se | Nanocomposite blends with polyesters |
WO2012163822A1 (en) | 2011-06-01 | 2012-12-06 | Basf Se | Polyester with styrene copolymers |
CN103619950B (en) | 2011-06-27 | 2016-01-27 | 巴斯夫欧洲公司 | Weatherable polyether moulding compound containing styrol copolymer |
CN103890071A (en) | 2011-09-29 | 2014-06-25 | 苯领股份公司 | Stabilized polycarbonate/acrylonitrile/styrene/acrylic ester moulding compounds |
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US20180346715A1 (en) | 2015-11-26 | 2018-12-06 | Ineos Styrolution Group Gmbh | Polycarbonate-asa blends with antistatic properties using sulfonated alkanes |
KR102420799B1 (en) | 2017-09-07 | 2022-07-15 | 주식회사 엘지화학 | Method for preparing graft copolymer and graft copolymer |
WO2019117433A1 (en) | 2017-12-14 | 2019-06-20 | 주식회사 엘지화학 | Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded product which comprise same |
US11807752B2 (en) | 2018-07-24 | 2023-11-07 | Ineos Styrolution Group Gmbh | Process for preparing graft rubber compositions with improved dewatering |
EP4294850A1 (en) | 2021-02-16 | 2023-12-27 | INEOS Styrolution Group GmbH | Process for producing a thermoplastic moulding compound comprising a thermoplastic copolymer a and a graft copolymer b |
WO2022268736A1 (en) | 2021-06-23 | 2022-12-29 | Ineos Styrolution Group Gmbh | Weather resistant asa molding composition |
WO2023209004A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate copolymer composition with improved uv resistance |
WO2023209007A1 (en) | 2022-04-29 | 2023-11-02 | Ineos Styrolution Group Gmbh | Acrylonitrile styrene acrylate (asa) copolymer composition having good uv resistance with reduced uv absorber content |
WO2024013294A1 (en) | 2022-07-15 | 2024-01-18 | Ineos Styrolution Group Gmbh | Method for producing asa or abs graft copolymers with reduced discoloration |
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Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1182811B (en) * | 1962-02-01 | 1964-12-03 | Basf Ag | Thermoplastic molding compounds based on styrene and acrylonitrile |
-
1965
- 1965-01-05 DE DE1965B0079984 patent/DE1260135B/en active Pending
-
1966
- 1966-01-04 FR FR44771A patent/FR1462788A/en not_active Expired
- 1966-01-04 GB GB23766A patent/GB1124911A/en not_active Expired
- 1966-01-04 NL NL6600058A patent/NL6600058A/xx unknown
- 1966-01-05 BE BE674765D patent/BE674765A/xx not_active IP Right Cessation
Cited By (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4224419A (en) | 1978-06-20 | 1980-09-23 | Basf Aktiengesellschaft | Weathering-resistant, high-impact, easily colored thermoplastic compositions |
US4433102A (en) * | 1981-07-25 | 1984-02-21 | Basf Aktiengesellschaft | Thermoplastic molding materials |
US4731413A (en) * | 1985-02-14 | 1988-03-15 | Huels Aktiengesellschaft | Molding compositions based on linear, high-molecular weight polyesters |
US4801646A (en) * | 1987-01-16 | 1989-01-31 | The Dow Chemical Company | Low gloss weather and impact resistant resins |
US4968731A (en) * | 1987-10-07 | 1990-11-06 | Basf Aktiengesellschaft | Glass fiber reinforced thermoplastic molding compositions based on polyesters and graft polymers |
US5120788A (en) * | 1990-02-20 | 1992-06-09 | Basf Aktiengesellschaft | Hermoplastic molding material of improved toughness |
US5342898A (en) * | 1990-04-06 | 1994-08-30 | Basf Aktiengesellschaft | Particulate graft polymer, and thermoplastic molding material produced therefrom having improved toughness |
US5219907A (en) * | 1991-09-27 | 1993-06-15 | Basf Aktiengesellschaft | Flameproofed molding composition |
US5367029A (en) * | 1992-10-24 | 1994-11-22 | Basf Aktiengesellschaft | Thermoplastic molding material |
US5438099A (en) * | 1992-12-16 | 1995-08-01 | Basf Aktiengesellschaft | Particulate graft copolymer and thermoplastic molding materials obtained therefrom |
US5585436A (en) * | 1993-12-09 | 1996-12-17 | Basf Aktiengesellschaft | Three-stage silicone rubber based graft copolymers |
US6174958B1 (en) | 1996-05-30 | 2001-01-16 | Basf Aktiengesellschaft | Thermoplastic moulded materials based on polycarbonates and styrene/acrylonitrile polymers which contain copolymers based on alkyl(meth)acrylate to improve their properties |
US6103821A (en) * | 1996-08-01 | 2000-08-15 | Basf Aktiengesellschaft | Crosslinking agents for emulsion polymers |
US6072002A (en) * | 1997-10-21 | 2000-06-06 | Bayer Corporation | Weatherable resinous composition |
US5932655A (en) * | 1997-11-19 | 1999-08-03 | Bayer Corporation | Weatherable resinous composition having improved opacity and impact strength |
WO1999031154A1 (en) * | 1997-12-16 | 1999-06-24 | Lg Chemical Ltd. | Weather resistant resin composition and preparation method thereof |
US6187862B1 (en) | 1998-05-01 | 2001-02-13 | Bayer Corporation | Weatherable resinous composition having improved opacity and impact strength |
US6476126B1 (en) | 1999-04-07 | 2002-11-05 | Bayer Corporation | Weatherable molding composition having improved surface appearance |
US6774167B1 (en) | 1999-10-27 | 2004-08-10 | Basf Aktiengesellschaft | Method for reducing cold stress whitening |
US9018300B2 (en) | 2005-06-14 | 2015-04-28 | Styrolution Europe Gmbh | Reinforced thermoplastic molding compositions, processes for preparing such compositions, molding made with such compositions and uses therefor |
US8367770B2 (en) | 2006-06-08 | 2013-02-05 | Cheil Industries Inc. | Acrylate-vinyl aromatic-unsaturated nitrile graft copolymer with excellent impact strength, colorability, and weatherability, and thermoplastic resin composition containing the same |
US8097669B2 (en) | 2007-07-10 | 2012-01-17 | Styrolution GmbH | Flame-retardant elastic block copolymer |
US8129455B2 (en) | 2007-07-10 | 2012-03-06 | Styrolution GmbH | Flame retardant thermoplastic molding compositions |
US8748527B2 (en) | 2009-02-26 | 2014-06-10 | Styrolution GmbH | Self-cleaning polymers |
US8440764B2 (en) | 2010-05-07 | 2013-05-14 | Styrolution GmbH | Molding composition with reduced light scattering |
US10294348B2 (en) | 2010-07-12 | 2019-05-21 | Ineos Styrolution Europe Gmbh | Stabilized acrylonitrile/styrene/acrylate molding compositions |
US9701813B2 (en) | 2010-07-12 | 2017-07-11 | Ineos Styrolution Europe Gmbh | Weathering-stabilized acrylonitrile copolymer molding compositions |
US9650506B2 (en) | 2010-12-16 | 2017-05-16 | Ineos Styrolution Europe Gmbh | Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact |
US8889769B2 (en) | 2011-06-27 | 2014-11-18 | Basf Se | Weathering-resistant polyester molding compositions with styrene copolymers |
US9546271B2 (en) | 2012-01-11 | 2017-01-17 | Styrolution Europe Gmbh | Weather-proof thermoplastic moulding compounds with improved toughness on the basis of styrene copolymers and polyamides |
US9644090B2 (en) | 2012-08-08 | 2017-05-09 | Ineos Styrolution Europe Gmbh | Polymer mixtures with optimized toughness/stiffness ratio and optical properties |
US9745456B2 (en) | 2013-03-19 | 2017-08-29 | Ineos Styrolution Group Gmbh | Matt weather-resistant molding masses for extrusion methods |
US10047220B2 (en) | 2013-07-02 | 2018-08-14 | Ineos Styrolution Group Gmbh | Process for the manufacturing of ABS-molding compositions |
WO2015000873A1 (en) * | 2013-07-02 | 2015-01-08 | Styrolution Group Gmbh | Process for the manufacturing of abs-molding compositions |
US9656408B2 (en) | 2013-07-11 | 2017-05-23 | Ineos Styrolution Group Gmbh | Method for producing thermoplastic molding compounds, and thermoplastic molding compounds produced according thereto |
US9714310B2 (en) | 2013-08-27 | 2017-07-25 | Ineos Styroltion Group Gmbh | Styrene copolymer compositions having an improved gloss |
US10072145B2 (en) | 2013-11-26 | 2018-09-11 | Ineos Styrolution Group Gmbh | Thermoplastic moulding compositions with appropriately designed graft shell |
US10815367B2 (en) | 2013-12-18 | 2020-10-27 | Ineos Styrolution Group Gmbh | Moulding compositions based on vinylaromatic copolymers for 3D printing |
US10654249B2 (en) | 2014-05-19 | 2020-05-19 | Ineos Styrolution Group Gmbh | Styrene copolymer composite film |
US10351679B2 (en) | 2015-03-25 | 2019-07-16 | Ineos Styrolution Group Gmbh | Process for producing thermoplastic polymer compositions with optimized degree of crosslinking |
US10619061B2 (en) | 2016-03-17 | 2020-04-14 | Ineos Styrolution Group Gmbh | Use of moulding compounds based on blends of san-copolymers and polyamide for 3D printing |
US10711126B2 (en) | 2016-04-21 | 2020-07-14 | Ineos Styrolution Group Gmbh | ABS molding composition having improved crack and chemical resistance and its use |
US11021602B2 (en) | 2016-04-21 | 2021-06-01 | Ineos Styrolution Group Gmbh | ABS molding composition having improved crack and chemical resistance and its use |
US10875995B2 (en) | 2016-05-20 | 2020-12-29 | Ineos Styrolution Group Gmbh | Acrylic ester-styrene-acrylonitrile copolymer molding masses having optimized residual monomer fraction |
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US11352490B2 (en) | 2017-12-11 | 2022-06-07 | Ineos Styrolution Group Gmbh | Process for production of impact modified thermoplastic moulding composition with improved processing and impact strength |
US11384189B2 (en) | 2017-12-14 | 2022-07-12 | Lg Chem, Ltd. | Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded article comprising the same |
US11680127B2 (en) | 2018-08-29 | 2023-06-20 | Ineos Styrolution Group Gmbh | Process for the production of graft copolymer powder compositions and thermoplastic resin compositions |
US11707420B2 (en) | 2021-08-31 | 2023-07-25 | L'oreal | Compositions, kits, and methods for altering the color of hair |
Also Published As
Publication number | Publication date |
---|---|
NL6600058A (en) | 1966-07-06 |
DE1260135B (en) | 1968-02-01 |
BE674765A (en) | 1966-07-05 |
FR1462788A (en) | 1966-12-16 |
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