ES2034225T3 - Un proceso para la produccion de acido acrilico. - Google Patents
Un proceso para la produccion de acido acrilico.Info
- Publication number
- ES2034225T3 ES2034225T3 ES198888304831T ES88304831T ES2034225T3 ES 2034225 T3 ES2034225 T3 ES 2034225T3 ES 198888304831 T ES198888304831 T ES 198888304831T ES 88304831 T ES88304831 T ES 88304831T ES 2034225 T3 ES2034225 T3 ES 2034225T3
- Authority
- ES
- Spain
- Prior art keywords
- order
- volume
- propylene
- production
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
UN PROCESO PARA LA PRODUCCION DE ACIDO ACRILICO POR MEDIO DE OXIDACION EN FASE VAPOR CON CATALIZADOR EN DOS FASES, DEL PROPILENO CON OXIGENO MOLECULAR, SIENDO LA PRIMERA FASE PARA OXIDAR EL PROPILENO PARA PRODUCIR PRINCIPALMENTEACROLEINA Y LA SEGUNDA PARA PRODUCIR PRINCIPALMENTE ACIDO ACRILICO. EL PROCESO REQUIRE SUMINISTRAR A LA PRIMERA FASE DE REACCION UN GAS CRUDO QUE CONTENGA HIDROCARBURO ALIFATICO SATURADO QUE TENGA DE 1 A 5 ATOMOS DE C EN UNA CANTIDAD DEL ORDEN DE 5 A 70% POR VOLUMEN, DIOXIDO DE CARBONO EN UNA CANTIDAD DEL ORDEN DEL 3 AL 50% POR VOLUMEN, Y EL HIDROCARBURO ALIFATICO Y EL DIOXIDO DE CARBONO EN UNA CANTIDD TOTAL DEL ORDEN DEL 20 AL 80% POR VOLUMEN, CONTENIENDO EL GAS PURO ADEMAS CANTIDAD DEL ORDEN DE 0,5 A 8 MOLES POR MOL DE PROPILENO.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12795887 | 1987-05-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2034225T3 true ES2034225T3 (es) | 1993-04-01 |
Family
ID=14972866
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES198888304831T Expired - Lifetime ES2034225T3 (es) | 1987-05-27 | 1988-05-27 | Un proceso para la produccion de acido acrilico. |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0293224B1 (es) |
KR (1) | KR920010470B1 (es) |
CN (1) | CN1029843C (es) |
AU (1) | AU606160B2 (es) |
DE (1) | DE3874209T2 (es) |
ES (1) | ES2034225T3 (es) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2135120T3 (es) * | 1995-03-10 | 1999-10-16 | Basf Ag | Procedimiento de oxidacion en fase gaseosa de propileno a acroleina, acido acrilico, o su mezcla, realizada continuamente, catalizada por via heterogenea. |
DE19600955A1 (de) * | 1996-01-12 | 1997-07-17 | Basf Ag | Verfahren zur Herstellung von Acrylsäure und deren Ester |
DE19624674A1 (de) | 1996-06-20 | 1998-01-02 | Basf Ag | Verfahren zur Entsorgung von bei der Acrylsäure- oder Methacrylsäure-Herstellung anfallenden Nebenkomponenten |
DE19740252A1 (de) | 1997-09-12 | 1999-03-18 | Basf Ag | Verfahren zur Herstellung von Acrylsäure und Methacrylsäure |
DE19833049A1 (de) | 1998-07-22 | 2000-01-27 | Basf Ag | Verfahren zur Herstellung von Acrylsäure |
US6143928A (en) * | 1998-08-10 | 2000-11-07 | Saudi Basic Industries Corporation | Catalysts for low temperature selective oxidation of propylene, methods of making and using the same |
DE19837517A1 (de) | 1998-08-19 | 2000-02-24 | Basf Ag | Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan |
DE19837518A1 (de) | 1998-08-19 | 2000-02-24 | Basf Ag | Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan |
US6384274B1 (en) * | 1998-09-27 | 2002-05-07 | Rohm And Haas Company | Single reactor process for preparing acrylic acid from propylene having improved capacity |
DE19902562A1 (de) | 1999-01-22 | 2000-07-27 | Basf Ag | Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen |
MY121878A (en) * | 1999-03-10 | 2006-02-28 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrylic acid |
MY119958A (en) * | 1999-03-10 | 2005-08-30 | Basf Ag | Catalytic gas-phase oxidation of propene to acrylic acid |
DE19910508A1 (de) | 1999-03-10 | 2000-09-21 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
MY121141A (en) | 1999-03-10 | 2005-12-30 | Basf Ag | Method for the catalytic gas-phase oxidation of propene into acrolein |
DE19926082A1 (de) | 1999-06-08 | 2000-12-14 | Basf Ag | Verfahren zur Reinigung und Herstellung von Acrylsäure oder Methacrylsäure |
US6639106B1 (en) | 1999-07-23 | 2003-10-28 | Rohm And Haas Company | Process for preparing and purifying acrylic acid from propylene having improved capacity |
DE19955168A1 (de) | 1999-11-16 | 2001-05-17 | Basf Ag | Verfahren der katalytischen Gasphasenoxidation von Propen zu Acrylsäure |
US6620968B1 (en) * | 1999-11-23 | 2003-09-16 | Rohm And Haas Company | High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids |
DE10026407A1 (de) | 2000-05-29 | 2001-12-06 | Basf Ag | Verfahren der diskontinuierlichen kristallisativen Reinigung von Roh-Acrylsäure |
EP1289919B1 (de) | 2000-06-14 | 2006-11-29 | Basf Aktiengesellschaft | Verfahren zur herstellung von acrolein und/oder acrylsäure |
US6441227B1 (en) | 2000-06-23 | 2002-08-27 | Saudi Basic Industries Corporation | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
DE10031518A1 (de) | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein |
DE60133473T2 (de) * | 2001-12-14 | 2009-05-20 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrylsäure |
DE10220494A1 (de) | 2002-05-07 | 2003-11-20 | Basf Ag | Verfahren zur Herstellung einer wässrigen Alkaliacrylat-Lösung |
US7115776B2 (en) | 2002-07-18 | 2006-10-03 | Basf Aktiengesellschaft | Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
US7326802B2 (en) | 2002-09-27 | 2008-02-05 | Basf Aktiengesellschaft | Preparation of at least one partial oxidation and/or ammoxidation product of propylene |
DE10313209A1 (de) | 2003-03-25 | 2004-03-04 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
BRPI0413440A (pt) | 2003-08-14 | 2006-10-17 | Basf Ag | processo para a preparação de (met) acroleìna e/ou de ácido (met) acrìlico por oxidação parcial em fase gasosa catalisada heterogeneamente |
KR100553825B1 (ko) | 2003-09-01 | 2006-02-21 | 주식회사 엘지화학 | 고정층 촉매 부분 산화 반응기에서 개선된 제열 시스템을통한 불포화알데히드 및 불포화산의 제조 방법 |
DE10353954A1 (de) | 2003-11-18 | 2005-06-09 | Basf Ag | Verfahren zur Herstellung von Acrolein durch heterogen katalysierte partielle Gasphasenoxidation von Propen |
EP1697278B1 (en) | 2003-12-24 | 2016-06-01 | LG Chem, Ltd. | Method of producing unsaturated acid in fixed-bed catalytic partial oxidation reactor with enhanced heat control system |
US7592483B2 (en) | 2004-07-01 | 2009-09-22 | Basf Aktiengesellschaft | Preparation of acrolein or acrylic acid or a mixture thereof by heterogeneously catalyzed partial gas phase oxidation of propylene |
FR2881136B1 (fr) * | 2005-01-21 | 2007-03-23 | Arkema Sa | Procede de preparation de l'acide acrylique comprenant une oxydation partielle du propane en propylene |
TWI529181B (zh) * | 2005-02-28 | 2016-04-11 | 贏創德固賽有限責任公司 | 以可更新原料為基之吸水聚合物結構及其生產的方法 |
JP4947917B2 (ja) | 2005-04-18 | 2012-06-06 | 株式会社日本触媒 | 気相接触酸化用の固定床反応器およびアクロレインまたはアクリル酸の製造方法 |
FR2897059B1 (fr) * | 2006-02-07 | 2008-04-18 | Arkema Sa | Procede de preparation d'acide acrylique |
DE102008020688B3 (de) | 2008-04-24 | 2009-11-05 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung und Aufreinigung wässriger Phasen |
FR2958185B1 (fr) | 2010-03-30 | 2012-04-20 | Arkema France | Procede d'oxydation selective de monoxyde de carbone |
DE102010048405A1 (de) | 2010-10-15 | 2011-05-19 | Basf Se | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein |
DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
US9150488B2 (en) * | 2012-06-22 | 2015-10-06 | Enerkem, Inc. | Production of acrylic acid and ethanol from carbonaceous materials |
US9738569B2 (en) | 2013-05-15 | 2017-08-22 | Enerkem, Inc. | Production of acrylic acid and ethanol from carbonaceous materials |
US10029974B2 (en) | 2014-10-07 | 2018-07-24 | Lg Chem, Ltd. | Method and apparatus for manufacturing continuous acrylic acid through propane partial oxidation reaction |
WO2016056851A1 (ko) * | 2014-10-07 | 2016-04-14 | 주식회사 엘지화학 | 프로판 부분산화반응에 의한 연속식 아크릴산 제조방법 및 제조장치 |
EP3768658B1 (en) | 2018-03-21 | 2024-06-26 | Rohm and Haas Company | Method for preparing acrylic acid |
EP3770145A1 (en) | 2019-07-24 | 2021-01-27 | Basf Se | A process for the continuous production of either acrolein or acrylic acid as the target product from propene |
WO2024089252A1 (en) | 2022-10-28 | 2024-05-02 | Basf Se | Process for the manufacture of a propylene-derived chemical of interest, in particular an acrylic ester, from renewably-sourced ethanol |
WO2024133081A1 (en) | 2022-12-20 | 2024-06-27 | Basf Se | Manufacture of an ethylene-derived chemical of interest, in particular acrylic acid, in combination with generation of heated steam |
CN116143606A (zh) * | 2023-02-27 | 2023-05-23 | 山东兴鲁承宏新材料科技有限公司 | 一种减少副产的丙烯酸合成工艺 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB996898A (en) * | 1963-06-27 | 1965-06-30 | Distillers Co Yeast Ltd | Improvements in or relating to the production of acrylic acid |
GB1034914A (en) * | 1964-02-05 | 1966-07-06 | Distillers Co Yeast Ltd | Improvements in or relating to the production of unsaturated aliphatic acids |
GB1036375A (en) * | 1964-03-02 | 1966-07-20 | Nippon Catalytic Chem Ind | Manufacture of unsaturated aliphatic carboxylic acids |
DE1793302A1 (de) * | 1968-08-28 | 1971-07-01 | Knapsack Ag | Verfahren zur Herstellung von Acrylsaeure aus Propylen |
US4182907A (en) * | 1971-02-04 | 1980-01-08 | The Standard Oil Company (Ohio) | Process for the oxidation of olefins to aldehydes and acids |
DE2249922C2 (de) * | 1972-10-12 | 1982-05-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur katalytischen Oxidation von Propylen oder Isobutylen zu Acrolein oder Methacrolein in der Gasphase mit molekularem Sauerstoff |
US4182902A (en) * | 1973-12-27 | 1980-01-08 | Siegfried Aktiengesellschaft | Novel cholesterol-lowering compounds |
DE2436818C3 (de) * | 1974-07-31 | 1985-05-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Acrylsäure durch Oxidation von Propylen mit Sauerstoff enthaltenden Gasen in zwei getrennten Oxidationsstufen |
JPS55102536A (en) * | 1979-01-30 | 1980-08-05 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
CA1299193C (en) * | 1986-07-17 | 1992-04-21 | Gordon Gene Harkreader | Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid |
JPH0813777B2 (ja) * | 1986-12-11 | 1996-02-14 | 三菱化学株式会社 | アクリル酸の製造法 |
-
1988
- 1988-05-26 AU AU16783/88A patent/AU606160B2/en not_active Ceased
- 1988-05-27 EP EP88304831A patent/EP0293224B1/en not_active Expired - Lifetime
- 1988-05-27 ES ES198888304831T patent/ES2034225T3/es not_active Expired - Lifetime
- 1988-05-27 DE DE8888304831T patent/DE3874209T2/de not_active Expired - Lifetime
- 1988-05-27 KR KR1019880006275A patent/KR920010470B1/ko not_active IP Right Cessation
- 1988-05-27 CN CN88104251A patent/CN1029843C/zh not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE3874209T2 (de) | 1993-04-15 |
KR920010470B1 (ko) | 1992-11-28 |
DE3874209D1 (de) | 1992-10-08 |
AU606160B2 (en) | 1991-01-31 |
EP0293224A1 (en) | 1988-11-30 |
CN1029843C (zh) | 1995-09-27 |
CN1030228A (zh) | 1989-01-11 |
EP0293224B1 (en) | 1992-09-02 |
KR880013870A (ko) | 1988-12-22 |
AU1678388A (en) | 1988-12-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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