EP3936573B1 - Composition de silicone thermoconductrice non durcissable - Google Patents

Composition de silicone thermoconductrice non durcissable Download PDF

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Publication number
EP3936573B1
EP3936573B1 EP20766349.3A EP20766349A EP3936573B1 EP 3936573 B1 EP3936573 B1 EP 3936573B1 EP 20766349 A EP20766349 A EP 20766349A EP 3936573 B1 EP3936573 B1 EP 3936573B1
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component
heat
viscosity
silicone composition
conductive silicone
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EP3936573A4 (fr
EP3936573A1 (fr
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Keita Kitazawa
Wataru TOYA
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Shin Etsu Chemical Co Ltd
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Shin Etsu Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/28—Nitrogen-containing compounds
    • C08K2003/282—Binary compounds of nitrogen with aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/001—Conductive additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Definitions

  • the present invention relates to a non-curable thermal-conductive silicone composition.
  • Typical heat dissipating techniques include a technique involving disposing a cooling member near a heat-generating part and bringing them into close contact to efficiently remove and dissipate heat from the cooling member.
  • Patent Document 9 discloses a heat conductive silicone grease composition containing an organopolysiloxane having a particular structure, an alkoxysilane having particular substituents, and a heat conductive filler. It is stated that the composition has favorable thermal conductivity, favorable flowability, and excellent workability.
  • Patent Documents 10 and 11 disclose sheets having adhesion property and thermal conductivity, and also disclose thermal conductive compositions in each of which an addition-curable silicone rubber composition is blended with a heat conductive filler and a silicone resin having no aliphatic unsaturated hydrocarbon group.
  • Patent Documents 10 and 11 disclose that heat conductive cured products can be provided which have appropriate adhesion property and favorable thermal conductivity in thin-film form.
  • heat-dissipating greases thinly compressible and capable of attaining low thermal resistance are suitable from the viewpoint of heat-dissipating performance.
  • Heat-dissipating greases can be roughly classified into two: “curable type” which can be cured after compression to desired thickness; and “non-curable type” which keeps grease state without being cured.
  • condensation curable heat-dissipating grease is also one of "curable type" (e.g., Patent Document 13). Since such condensation curable heat-dissipating greases are thickened and cured by the moisture in air, preventing moisture allows the transportation and storage at room temperature, and relatively facilitates the product control. Condensation curable heat-dissipating greases have such an advantage that the curing reaction can proceed without requiring a heating step if a certain amount of moisture is present. Nevertheless, there are large problems to be solved, such as odor and contamination of electronic parts with low-boiling-point components that are separated during the curing reaction.
  • non-curable heat-dissipating greases have such features that these are easy to handle, for example, the transportation and storage at room temperature are generally possible. Nevertheless, there is a problem that pumping out mentioned above is likely to occur. As a measure to reduce the pumping out of "non-curable" heat-dissipating greases, it is effective to increase the viscosity of the greases. In exchange, this brings about a problem of lowered coating workability.
  • non-curable heat-dissipating greases are easy to handle and cause less environmental load, but pumping out is likely to happen.
  • the viscosity needs to be increased, but consequently this causes a problem that the coating workability is sacrificed.
  • An object of the present invention is to provide a thermal-conductive silicone composition which is a "non-curable" heat-dissipating grease containing a large amount of heat conductive filler, but which has excellent coating workability and also favorable pumping-out resistance as a result of keeping appropriate viscosity.
  • the present invention provides a non-curable thermal-conductive silicone composition
  • a non-curable thermal-conductive silicone composition comprising essential components of:
  • the inventive non-curable thermal-conductive silicone composition is a "non-curable" heat-dissipating grease containing a large amount of the heat conductive filler, the viscosity is kept appropriately, so that the inventive non-curable thermal-conductive silicone composition can have both of excellent coating workability and excellent pumping-out resistance.
  • the organopolysiloxane of the component (A) preferably has a kinematic viscosity at 25°C of 10,000,000 mm 2 /s or more.
  • Such a non-curable thermal-conductive silicone composition expands and contracts but hardly causes pumping out in a thermal history in which heat generation and cooling repeat.
  • m in the general formula (1) of the hydrolysable organopolysiloxane compound is preferably in a range from 10 to 60.
  • Such a non-curable thermal-conductive silicone composition can have both of more excellent coating workability and more excellent pumping-out resistance.
  • the heat conductive filler preferably has a heat conductivity of 10 W/m ⁇ K or more.
  • Such a non-curable thermal-conductive silicone composition surely has excellent thermal conductivity.
  • the inventive thermal-conductive silicone composition is a "non-curable" heat-dissipating grease containing a large amount of heat conductive filler but maintains appropriate viscosity, so that both excellent coating workability and excellent pumping-out resistance are achieved.
  • the present invention makes it possible to provide a thermal-conductive silicone composition adaptable to increases in heat generation, size, and structural complexity of recent semiconductor devices.
  • thermal conductive silicone composition which is a "non-curable" heat-dissipating grease containing a large amount of heat conductive filler, but which has excellent coating workability and also favorable pumping-out resistance by maintaining suitable viscosity.
  • the present inventors have earnestly studied to achieve the above object and consequently found that a thermal conductive silicone composition having excellent coating workability and also favorable pumping-out resistance is obtained from a "non-curable" heat-dissipating grease, which contains a large amount of heat conductive filler but appropriately keeps viscosity, by: blending an organopolysiloxane having a kinematic viscosity in a particular range with a hydrolysable organosilane compound; controlling the molecular weight distribution of a mixture of these; and blending a thermal conductivity filler thereto. This finding has led to the completion of the present invention.
  • the present invention is a non-curable thermal-conductive silicone composition
  • a non-curable thermal-conductive silicone composition comprising essential components of:
  • the present invention relates to a non-curable thermal-conductive silicone composition which has a viscosity kept appropriately even with a large amount of heat conductive filler, and which has favorable reliability.
  • the inventive non-curable thermal-conductive silicone composition contains (A) an organopolysiloxane with a kinematic viscosity of 1,000,000 mm 2 /s or more at 25°C, (B) a hydrolysable organopolysiloxane compound, and (C) a heat conductive filler, as essential components.
  • a mixture of the components (A) and (B) has a molecular weight distribution Mw/Mn of 10 or more.
  • non-curable thermal-conductive silicone composition is also simply referred to as “thermal-conductive silicone composition”.
  • the component (A) is an organopolysiloxane having a kinematic viscosity at 25°C of 1,000,000 mm 2 /s or more.
  • the chemical structure is not particularly limited. Examples thereof include unreactive organopolysiloxanes, such as methylpolysiloxane; organopolysiloxanes having two or more aliphatic unsaturated hydrocarbon groups per molecule; organohydrogenpolysiloxanes having two or more hydrogen atoms bonded to silicon atoms per molecule; hydrolysable organopolysiloxanes having two or more hydrolysable groups per molecule; etc. One kind of these may be used alone, or two or more kinds thereof may be used in mixture.
  • the molecular structure is not particularly limited, and examples thereof include linear structure, branched structure, linear structure having partially branched or cyclic structure, etc. Particularly preferable is a linear structure in which the main chain is composed of diorganosiloxane repeating units and both terminals of the molecular chain are blocked with triorganosiloxy groups. Organopolysiloxane having the linear structure may have a partially branched or cyclic structure.
  • the kinematic viscosity of the component (A) at 25°C is 1,000,000 mm 2 /s or more, preferably 10,000,000 mm 2 /s or more, further preferably 15,000,000 mm 2 /s or more. If the kinematic viscosity is less than 1,000,000 mm 2 /s, pumping out may occur due to expansion and contraction according to a thermal history in which heat generation and cooling of a heat-generating part repeat. Additionally, the component (A) may have a kinematic viscosity at 25°C of no more than 100,000,000 mm 2 /s.
  • the component (A) is blended in an amount of 5 to 20 mass%, preferably 10 to 15 mass%, relative to a sum amount of the components (A) and (B). If the blend amount is less than 5 mass% or more than 20 mass%, excellent coating workability and pumping-out resistance cannot be achieved simultaneously; in addition, it becomes difficult to make the thermal-conductive silicone composition have a viscosity in an appropriate range.
  • the kinematic viscosity ⁇ A of the component (A) is determined according to the following.
  • the component (B) is a hydrolysable organopolysiloxane compound shown by the following general formula (1).
  • the hydrolysable organopolysiloxane compound as the component (B) is used to treat the surface of the heat conductive filler, and serves to assist high filling performance of the filler.
  • R 1 's each represent a monovalent hydrocarbon group having 1 to 10 carbon atoms optionally having a substituent, and are identical to or different from one another.
  • "m" represents an integer of 5 to 100.
  • R 1 is a monovalent hydrocarbon group having 1 to 10 carbon atoms optionally having a substituent.
  • Preferable examples thereof include monovalent saturated aliphatic hydrocarbon groups optionally having a substituent; monovalent unsaturated aliphatic hydrocarbon groups optionally having a substituent; and monovalent aromatic hydrocarbon groups (including aromatic hetero rings) optionally having a substituent.
  • R 1 is a monovalent saturated aliphatic hydrocarbon group which may have a substituent; or a monovalent aromatic hydrocarbon group which may have a substituent.
  • R 1 is a monovalent saturated aliphatic hydrocarbon group which may have a substituent.
  • the monovalent saturated aliphatic hydrocarbon groups optionally having a substituent have 1 to 10 carbon atoms, preferably 1 to 8 carbon atoms, further preferably 1 to 6 carbon atoms.
  • Specific examples thereof include linear alkyl groups, such as a methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, and octyl group; branched alkyl groups, such as an isopropyl group, isobutyl group, tert-butyl group, isopentyl group, and neopentyl group; cycloalkyl groups, such as a cyclopentyl group, cyclohexyl group, and cycloheptyl group; halogen-substituted alkyl groups, such as a chloromethyl group, 3-chloropropyl group, 3,3,3-trifluoropropyl group, and bromoprop
  • the monovalent unsaturated aliphatic hydrocarbon groups optionally having a substituent have 2 to 10 carbon atoms, preferably 2 to 8 carbon atoms, further preferably 2 to 6 carbon atoms. Specific examples thereof include alkenyl groups, such as an ethenyl group, 1-methylethenyl group, and 2-propenyl group; alkynyl groups, such as an ethynyl group and 2-propynyl group; etc.
  • the monovalent aromatic hydrocarbon groups optionally having a substituent have 6 to 10 carbon atoms, preferably 6 to 8 carbon atoms, further preferably 6 carbon atoms.
  • aryl groups such as a phenyl group and tolyl group
  • aralkyl groups such as a benzyl group and 2-phenylethyl group
  • halogen-substituted aryl groups such as an ⁇ , ⁇ , ⁇ -trifluorotolyl group and chlorobenzyl group; etc.
  • R 1 is preferably a methyl group, an ethyl group, a 3,3,3-trifluoropropyl group, or a phenyl group, further preferably a methyl group, an ethyl group, or a phenyl group, particularly preferably a methyl group.
  • m is an integer of 5 to 100, preferably an integer of 5 to 80, further preferably an integer of 10 to 60. If the value of "m” is smaller than 5, oil bleeding from the silicone composition may become prominent, and the pumping-out resistance may lower. Meanwhile, if the value of "m” is larger than 100, the wettability to the filler becomes insufficient, so that the viscosity of the composition is increased, and the coating workability may degrade.
  • the component (B) is blended in an amount of 80 to 95 mass%, preferably 85 to 90 mass%, relative to the sum amount of the components (A) and (B). If the blend amount is less than 80 mass% or more than 95 mass%, excellent coating workability and pumping-out resistance cannot be achieved simultaneously; in addition, it becomes difficult to make the thermal-conductive silicone composition have a viscosity in an appropriate range.
  • the mixture of the components (A) and (B) has a molecular weight distribution Mw/Mn of 10 or more, preferably 13 or more, more preferably 15 or more. If the molecular weight distribution Mw/Mn is less than 10, the thermal-conductive silicone composition thereby has a higher viscosity, and the coating workability may lower; moreover, flowing-out is likely to occur according to thermal history in which heat generation and cooling of a heat-generating part repeat, so that the pumping-out resistance may degrade.
  • the mixture of the components (A) and (B) of the present invention can be made to have a molecular weight distribution Mw/Mn of 10 or more by blending an appropriate amount of the organopolysiloxane having a kinematic viscosity at 25°C of 1,000,000 mm 2 /s or more as described in the section of (A) Component. Meanwhile, the upper limit of the Mw/Mn is not particularly limited, and can be 20 or less. Note that, in the present invention, the molecular weight distribution is measured by gel permeation chromatography (GPC) using toluene as a solvent.
  • GPC gel permeation chromatography
  • the component (C) is at least one heat conductive filler selected from the group consisting of metals, metal oxides, metal hydroxides, metal nitrides, metal carbides, and carbon allotropes.
  • heat conductive filler selected from the group consisting of metals, metal oxides, metal hydroxides, metal nitrides, metal carbides, and carbon allotropes.
  • examples thereof include aluminum, silver, copper, metallic silicon, alumina, zinc oxide, magnesium oxide, aluminum oxide, silicon dioxide, cerium oxide, iron oxide, aluminum hydroxide, cerium hydroxide, aluminum nitride, boron nitride, silicon carbide, diamond, graphite, carbon nanotube, graphene, etc.
  • One of these can be used alone, or two or more thereof can be used in appropriate combination.
  • filling performance can be enhanced by combining heat conductive fillers having different particle sizes, such as large particle constituents and small particle constituents.
  • the large particle constituents have an average particle size in a range from preferably 0.1 to 100 pm, more preferably 5 to 50 ⁇ m, particularly preferably 10 to 45 ⁇ m.
  • the average particle size is 0.1 ⁇ m or more, there is no fear that the resulting composition has excessively high viscosity or poor extensibility.
  • the average particle size is 100 ⁇ m or less, there is no fear that the resulting composition is not uniform.
  • the small particle constituents have an average particle size in a range from preferably 0.01 ⁇ m or more and less than 10 pm, more preferably 0.1 to 4 ⁇ m.
  • the average particle size is 0.01 ⁇ m or more, there is no fear that the resulting composition has excessively high viscosity or poor extensibility.
  • the average particle size is 10 ⁇ m or less, there is no fear that the resulting composition is not uniform.
  • the ratio of the large particle constituents and the small particle constituents is not particularly limited, but is preferably in a range from 9:1 to 1:9 (mass ratio). Additionally, the shape of the large particle constituents and the small particle constituents is not particularly limited, and may be spherical, irregular, or needle-shaped, for example.
  • the average particle size can be determined, for example, as an average value (or median diameter) based on volume in particle size distribution measurement by a laser beam diffraction method.
  • the component (C) is blended in an amount of 10 to 95 mass%, preferably 20 to 90 mass%, more preferably 30 to 88 mass%, possibly 50 to 85 mass%, relative to a total amount of the composition. If the blend amount is more than 95 mass%, the composition has poor extensibility. If the blend amount is less than 10 mass%, the thermal conductivity becomes poor.
  • the component (C) heat conductive filler
  • the component (C) having a heat conductivity of 10 W/m ⁇ K or more makes the composition excellent in thermal conductivity.
  • the inventive thermal-conductive silicone composition may contain a conventionally-known antioxidant, as necessary, such as 2,6-di-tert-butyl-4-methylphenol, to prevent deterioration of the composition. Further, a dye, a pigment, a flame retardant, a precipitation-inhibitor, a thixotropy-enhancer, or other additives can be blended as necessary.
  • a conventionally-known antioxidant such as 2,6-di-tert-butyl-4-methylphenol
  • the inventive silicone-composition production method is not particularly limited.
  • An example thereof include a method in which the components (A) to (C) are mixed together using, for example, a mixer, such as Trimix, Twinmix or Planetary Mixer (all registered trademarks for mixers manufactured by Inoue Manufacturing Co., Ltd.), Ultramixer (a registered trademark for a mixer manufactured by Mizuho Industrial Co., Ltd.), and a Hivis Disper Mix (a registered trademark for a mixer manufactured by PRIMIX Corporation).
  • a mixer such as Trimix, Twinmix or Planetary Mixer (all registered trademarks for mixers manufactured by Inoue Manufacturing Co., Ltd.), Ultramixer (a registered trademark for a mixer manufactured by Mizuho Industrial Co., Ltd.), and a Hivis Disper Mix (a registered trademark for a mixer manufactured by PRIMIX Corporation).
  • the inventive thermal-conductive silicone composition may be mixed while being heated.
  • the heating conditions are not particularly limited.
  • the temperature is normally 25 to 220°C, preferably 40 to 200°C, particularly preferably 50 to 200°C.
  • the time is normally 3 minutes to 24 hours, preferably 5 minutes to 12 hours, particularly preferably 10 minutes to 6 hours. Additionally, deaeration may be performed during the heating.
  • the inventive thermal-conductive silicone composition has an absolute viscosity of preferably 100 to 1,000 Pa ⁇ s, more preferably 150 to 800 Pa ⁇ s, further preferably 200 to 600 Pa ⁇ s, when measured at 25°C.
  • the absolute viscosity of 100 Pa ⁇ s or more the heat conductive filler does not precipitate over time during the storage, for example, so that the workability is improved; moreover, the pumping-out resistance is also improved. Meanwhile, with the absolute viscosity of 1,000 Pa ⁇ s or less, there is no fear that the coating workability is degraded.
  • inventive thermal-conductive silicone composition may have a heat conductivity of normally 0.5 to 10 W/m ⁇ K.
  • the absolute viscosity of the thermal-conductive silicone composition is a value measured at 25°C with a rotational viscometer
  • the heat conductivity is a value measure by hot disc method.
  • B-1 a dimethylpolysiloxane shown by the following formula (2) and having one terminal blocked with a trimethoxysilyl group
  • the components (A) to (C) were blended according to the formulations shown in Tables 1 to 2 below by the following method to produce silicone compositions.
  • the components (A), (B), and (C) were introduced into 5-litter Planteary Mixer (manufactured by Inoue Manufacturing Co., Ltd.), and mixed under reduced pressure at 170°C for 1 hour to produce silicone compositions.
  • the absolute viscosity of each silicone composition was measured using a Malcolm viscometer (type: PC-1T) at 25°C (at 10 rpm with Rotor-A, and at a shear rate of 6 [1/s]).
  • each of the silicone compositions of Examples 1 to 7 satisfying the requirements of the present invention had appropriate viscosity and also had small values of ⁇ / ⁇ and ⁇ / ⁇ , which are indicators of pumping-out resistance. This clearly indicates that flowing-out (pumping out) of the silicone compositions due to expansion and contraction in the thermal history hardly occurs.
  • the inventive silicone compositions are capable of achieving both excellent coating workability and excellent pumping-out resistance.
  • the silicone compositions of Comparative Examples 1 to 6 did not have appropriate viscosity, and/or had large values of ⁇ / ⁇ and ⁇ / ⁇ , which are indicators of pumping-out resistance. Hence, both of excellent coating workability and excellent pumping-out resistance cannot be achieved simultaneously.
  • the inventive thermal-conductive silicone compositions are "non-curable" heat-dissipating greases containing a large amount of heat conductive filler but keep appropriate viscosity, so that both of excellent coating workability and excellent pumping-out resistance are achieved.
  • the present invention makes it possible to provide thermal-conductive silicone compositions that are adaptable to increases in generated heat, size, and structural complexity of recent semiconductor devices.

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  • Health & Medical Sciences (AREA)
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Claims (4)

  1. Composition de silicone thermoconductrice non durcissable comprenant des constituants essentiels de :
    (A) un organopolysiloxane ayant une viscosité cinématique, déterminée selon ce qui suit :
    [1] une solution de toluène avec le constituant (A) à 1,0 g/100 ml étant préparée pour déterminer la viscosité spécifique ηsp (25 °C) selon la formule (I) suivante, où η représente la viscosité de la solution de toluène, et η0 représente la viscosité du toluène, et où η et η0 sont des valeurs mesurées à 25 °C avec un viscosimètre Ostwald de type Ubbelohde, η sp = η / η 0 − 1
    Figure imgb0021
    [2] ηsp étant insérée dans la formule (II) suivante pour déterminer la viscosité intrinsèque [η], où K' représente la constante de Huggins, η sp = η + K ′ η 2
    Figure imgb0022
    [3] [η] étant insérée dans la formule (III) suivante pour déterminer la masse moléculaire M, et η = 2,15 × 10 − 4 M 0,65
    Figure imgb0023
    [4] M étant insérée dans la formule (IV) suivante pour déterminer la viscosité cinématique ηA du constituant (A), logη A = 1,00 + 0,0123 M 0,5
    Figure imgb0024
     à 25 °C de 1 000 000 mm2/s ou plus et contenu en une quantité de 5 à 20 % en masse par rapport à la somme du constituant (A) et d'un constituant (B) ;
    (B) un composé organopolysiloxane hydrolysable représenté par la formule générale (1) suivante et contenu en une quantité de 80 à 95 % en masse par rapport à la somme du constituant (A) et du constituant (B),
    Figure imgb0025
     dans laquelle les R1' représentent chacun un groupe hydrocarboné monovalent ayant de 1 à 10 atomes de carbone ayant éventuellement un substituant et sont identiques ou différents les uns des autres, et « m » représente un nombre entier de 5 à 100 ; et
    (C) au moins une charge conductrice de chaleur choisie dans le groupe constitué de métaux, d'oxydes métalliques, d'hydroxydes métalliques, de nitrures métalliques, de carbures métalliques et d'allotropes de carbone, dans laquelle le constituant (C) est contenu en une quantité de 10 à 95 % en masse par rapport à une quantité totale de la composition,
    dans laquelle un mélange du constituant (A) et du constituant (B) a une distribution de poids moléculaire Mw/Mn telle que mesurée par chromatographie par perméation de gel (CPG) en utilisant du toluène comme solvant de 10 ou plus.
  2. Composition de silicone thermoconductrice non durcissable selon la revendication 1, dans laquelle l'organopolysiloxane du constituant (A) a une viscosité cinématique à 25 °C de 10 000 000 mm2/s ou plus.
  3. Composition de silicone thermoconductrice non durcissable selon la revendication 1 ou 2, dans laquelle « m » dans la formule générale (1) du composé organopolysiloxane hydrolysable est compris entre 10 et 60.
  4. Composition de silicone thermoconductrice non durcissable selon l'une quelconque des revendications 1 à 3, dans laquelle la charge conductrice de chaleur a une conductivité thermique telle que mesurée par la méthode du disque chaud de 10 W/m·K ou plus.
EP20766349.3A 2019-03-04 2020-02-04 Composition de silicone thermoconductrice non durcissable Active EP3936573B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019038421A JP6959950B2 (ja) 2019-03-04 2019-03-04 非硬化型熱伝導性シリコーン組成物
PCT/JP2020/004191 WO2020179325A1 (fr) 2019-03-04 2020-02-04 Composition de silicone thermoconductrice non durcissable

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WO2020179325A1 (fr) 2020-09-10
CN113597452B (zh) 2023-03-31
US11912869B2 (en) 2024-02-27
JP2020143178A (ja) 2020-09-10
US20220135799A1 (en) 2022-05-05
EP3936573A4 (fr) 2022-11-30
KR20210135235A (ko) 2021-11-12
TWI818154B (zh) 2023-10-11
EP3936573A1 (fr) 2022-01-12
JP6959950B2 (ja) 2021-11-05
CN113597452A (zh) 2021-11-02

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