EP3855242B1 - Light modulation sheet, and method of manufacturing light modulation sheet - Google Patents

Light modulation sheet, and method of manufacturing light modulation sheet Download PDF

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Publication number
EP3855242B1
EP3855242B1 EP19863196.2A EP19863196A EP3855242B1 EP 3855242 B1 EP3855242 B1 EP 3855242B1 EP 19863196 A EP19863196 A EP 19863196A EP 3855242 B1 EP3855242 B1 EP 3855242B1
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EP
European Patent Office
Prior art keywords
section
light control
layer
insulating
region
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EP19863196.2A
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German (de)
English (en)
French (fr)
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EP3855242A4 (en
EP3855242A1 (en
Inventor
Masayuki Takahashi
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Toppan Inc
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Toppan Printing Co Ltd
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1343—Electrodes
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1345—Conductors connecting electrodes to cell terminals
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
    • E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
    • E06B2009/2464—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds featuring transparency control by applying voltage, e.g. LCD, electrochromic panels

Definitions

  • the present invention relates to a light control sheet that has a light control region having a variable light transmittance, and a method of producing the light control sheet.
  • a light control sheet includes a light control layer that contains a liquid crystal composition and a pair of transparent electrode layers that sandwich the light control layer.
  • a light transmittance of the light control sheet varies (see, for example, PTL 1).
  • An object of the present invention is to provide a light control sheet capable of preventing short circuits due to contact of a conductive material with an edge surface of the light control sheet, and a method of producing the light control sheet.
  • a light control sheet for solving the above problem is defined by claim 1.
  • the electrode section is not exposed on an edge surface of the light control sheet. This can prevent a short circuit due to attachment of a conductive material to the edge surface. Furthermore, when the electrode section is composed of an oxide semiconductor, corrosion of the electrode section due to attachment of water to the edge surface can also be prevented.
  • the first transparent electrode layer may have a conductive section insulated from the electrode section by the insulating section, the insulating section may be sandwiched between the electrode section and the conductive section in plan view, and the conductive section may be exposed on an edge surface of the light control sheet.
  • the insulating section When the insulating section is formed by irradiating a conductive film with a laser so that the electrode section and the conductive section are separated from each other, the insulating section tends to be more brittle than the electrode section and the conductive section. According to the above configuration, as compared with a configuration in which the insulating section is arranged at an edge section of the light control sheet, the layers constituting the light control sheet are prevented from being peeled off from each other at the edge section of the light control sheet.
  • the insulating section may be a laser-processed region.
  • the insulating section is formed by laser irradiation, as compared with, for example, a production method in which the insulating section is formed by etching, it is possible to reduce the number of steps required to produce the light control sheet.
  • the first transparent electrode layer may include a portion composed of a conductive film, and the conductive film may be broken in the insulating section.
  • the insulating section having the above configuration can be suitably formed by laser irradiation.
  • a visible light transmittance of a region in which the insulating section is located in plan view of the light control sheet may be lower than a visible light transmittance of a region in which the electrode section is located in plan view.
  • the insulating section having the above configuration can be suitably formed by laser irradiation.
  • a region in which the insulating section is located may be composed of a strip-shaped region having an outer shape formed of a sequence of a plurality of rounded regions arranged in one direction.
  • the insulating section having the above configuration can be suitably formed by irradiation with a pulsed laser.
  • the use of the pulsed laser allows formation of the insulating section while dissipating heat generated by laser irradiation. This prevents generation of air bubbles in the light control layer.
  • the insulating section has an annular shape that surrounds the entire electrode section, and in a region surrounded by the insulating section in plan view, the light control sheet has a region to which a wiring section for applying a driving voltage to the electrode section is connected.
  • the entire electrode section including the region to which the wiring section is connected is surrounded by the insulating section. Accordingly, the electrode section is not exposed over the entire periphery on the edge surface of the light control sheet; thus, a short circuit of the electrode section is accurately prevented.
  • the second transparent electrode layer may have an electrode section to which a driving voltage is applied and an insulating section that is adjacent to the electrode section in the direction along the surface of the light control sheet and extends along an outer edge of the electrode section in plan view, and the insulating section of the first transparent electrode layer may overlap the insulating section of the second transparent electrode layer in plan view.
  • the electrode section is not exposed on the edge surface of the light control sheet at the portion at which the insulating section of the first transparent electrode layer overlaps the insulating section of the second transparent electrode layer, in both the first transparent electrode layer and the second transparent electrode layer.
  • a short circuit due to attachment of a conductive material to the edge surface is more reliably prevented.
  • the electrode section is composed of an oxide semiconductor, corrosion of the electrode section due to attachment of water to the edge surface can be prevented in both the first transparent electrode layer and the second transparent electrode layer.
  • the insulating sections when the insulating sections are formed by laser irradiation, the insulating sections can be collectively formed; thus, the insulating sections can be formed with high efficiency.
  • a method of producing a light control sheet for solving the above problem is defined by the independent method claim.
  • the electrode section is not exposed on the edge surface of the light control sheet. This can prevent a short circuit due to attachment of a conductive material to the edge surface. Furthermore, when the electrode section is composed of an oxide semiconductor, corrosion of the electrode section due to attachment of water to the edge surface can also be prevented. Furthermore, since the insulating section is formed by laser irradiation, for example, as compared with the production method in which the insulating section is formed by etching, it is possible to reduce the number of steps required to produce the light control sheet. Furthermore, since the insulating section is formed after the multilayer laminate is formed, it is possible to easily cope with design change in the shape of the light control sheet, the shape of the electrode section, and the like.
  • the present invention can prevent a short circuit due to attachment of a conductive material to an edge surface of the light control sheet.
  • a first embodiment of a light control sheet and a method of producing the light control sheet will be described with reference to Figs. 1 to 17 .
  • a light control sheet 10 of the first embodiment has either a normal-type structure or a reverse-type structure.
  • Fig. 1 shows a cross-sectional structure of a normal-type light control sheet 10N.
  • the normal-type light control sheet 10N includes a light control layer 11, a first transparent electrode layer 12A and a second transparent electrode layer 12B which are a pair of transparent electrode layers, and a first transparent support layer 13A and a second transparent support layer 13B which are a pair of transparent support layers.
  • the first transparent electrode layer 12A and the second transparent electrode layer 12B sandwich the light control layer 11, and the first transparent support layer 13A and the second transparent support layer 13B sandwich the light control layer 11 and the transparent electrode layers 12A and 12B.
  • the first transparent support layer 13A supports the first transparent electrode layer 12A, and the second transparent support layer 13B supports the second transparent electrode layer 12B. All the above layers constituting the light control sheet 10N extend to an edge surface 10E of the light control sheet 10N.
  • the light control sheet 10N is attached to a transparent plate 50. Specifically, a back surface of the light control sheet 10N is bonded to a surface of the transparent plate 50 via a transparent adhesive layer 51. The back surface of the light control sheet 10N is a surface of the second transparent support layer 13B facing away from the second transparent electrode layer 12B.
  • the transparent plate 50 is a transparent plate-shaped member composed of glass, resin, or the like.
  • the transparent plate 50 may have a single-layer structure or a multilayer structure.
  • the surface of the transparent plate 50 may be a flat surface or a curved surface.
  • the transparent plate 50 may be, for example, a construction material such as a window glass or a glass wall, or may be a vehicle member such as a window glass for an automobile.
  • the first transparent electrode layer 12A has an electrode section 20A, insulating sections 21A, and outer-peripheral conductive sections 22A.
  • the electrode section 20A is located in a region including a central portion of the first transparent electrode layer 12A in a surface direction.
  • the surface direction is a direction in which the layers extend, in other words, a direction along a surface of the light control sheet 10.
  • Each of the outer-peripheral conductive sections 22A is located at an edge section of the first transparent electrode layer 12A in the surface direction, and each of edge surface of the outer-peripheral conductive sections 22A constitutes a part of the edge surface 10E of the light control sheet 10N.
  • Each of the insulating section 21A is adjacent to the electrode section 20A and each of the outer-peripheral conductive sections 22A and is sandwiched between the electrode section 20A and each of the outer-peripheral conductive sections 22A. That is, each of the outer-peripheral conductive section 22A, the insulating section 21A, and the electrode section 20A is located in this order along the surface direction from the edge surface 10E.
  • the outer-peripheral conductive sections 22A and the insulating sections 21A are arranged to overlap the light control layer 11 as viewed from a position facing the surface of the light control sheet 10N.
  • the second transparent electrode layer 12B has an electrode section 20B, insulating sections 21B, and outer-peripheral conductive sections 22B.
  • the electrode section 20B is located in a region including a central portion of the second transparent electrode layer 12B in the surface direction.
  • Each of the outer-peripheral conductive sections 22B is located at an edge section of the second transparent electrode layer 12B in the surface direction, and each of edge surface of the outer-peripheral conductive sections 22B constitutes a part of the edge surface 10E of the light control sheet 10N.
  • Each of the insulating sections 21B is adjacent to an electrode section 20B and an outer-peripheral conductive section 22B and is sandwiched in the surface direction between an electrode section 20B and an outer-peripheral conductive sections 22B.
  • the electrode sections 20A and 20B When a driving voltage is applied to the electrode sections 20A and 20B, the electrode sections 20A and 20B function as electrodes that sandwich the light control layer 11.
  • the insulating sections 21A and 21B have insulation properties, and the outer-peripheral conductive sections 22A and 22B have conductivity.
  • the outer-peripheral conductive sections 22A are insulated from the electrode section 20A by interposition of the insulating sections 21A, and the outer-peripheral conductive sections 22B are insulated from the electrode section 20B by interposition of the insulating sections 21B. That is, no driving voltage is applied to the outer-peripheral conductive sections 22A and 22B.
  • the electrode section 20A and the electrode section 20B face each other with the light control layer 11 interposed therebetween.
  • the insulating sections 21A and the insulating sections 21B face each other with the light control layer 11 interposed therebetween.
  • the outer-peripheral conductive sections 22A and the outer-peripheral conductive sections 22B face each other with the light control layer 11 interposed therebetween.
  • a region in which the electrode section 20A is located matches a region in which the electrode section 20B is located, except for regions in which the electrode sections 20A and 20B are connected to wiring sections.
  • a region in which the insulating sections 21A are located matches a region in which the insulating sections 21B are located, and a region in which the outer-peripheral conductive sections 22A are located matches a region in which the outer-peripheral conductive sections 22B are located.
  • a region in which the light control layer 11 is sandwiched between the electrode section 20A and the electrode section 20B is a light control region SL that has a variable light transmittance.
  • a driving voltage when a driving voltage is applied to the electrode sections 20A and 20B, liquid crystal molecules contained in the light control layer 11 are aligned, and major axes of the liquid crystal molecules are oriented in the direction of an electric field between the electrode sections 20A and 20B.
  • the light control layer 11 is more likely to transmit light, and thus the light control region SL becomes transparent.
  • the major axes of the liquid crystal molecules are irregularly oriented.
  • light incident on the light control layer 11 is scattered.
  • the light control region SL becomes whitish and opaque.
  • Fig. 2 shows a cross-sectional structure of a reverse-type light control sheet 10R.
  • the reverse-type light control sheet 10R includes a first alignment layer 14A and a second alignment layer 14B which are a pair of alignment layers that sandwich the light control layer 11.
  • the first alignment layer 14A is located between the light control layer 11 and the first transparent electrode layer 12A
  • the second alignment layer 14B is located between the light control layer 11 and the second transparent electrode layer 12B.
  • the first transparent electrode layer 12A and the second transparent electrode layer 12B have the same configurations as in the normal-type light control sheet.
  • the alignment layers 14A and 14B are, for example, vertical alignment films.
  • the alignment layers 14A and 14B align the liquid crystal molecules contained in the light control layer 11 so that the major axes of the liquid crystal molecules are oriented along a normal direction of the alignment layers 14A and 14B.
  • the alignment layers 14A and 14B allow the directions of the major axes of the liquid crystal molecules contained in the light control layer 11 to be changed to directions other than the normal direction.
  • the major axes of the liquid crystal molecules contained in the light control layer 11 are oriented in directions different from the normal direction of the alignment layers 14A and 14B, and thus the light control region SL becomes opaque.
  • the major axes of the liquid crystal molecules are oriented along the normal direction of the alignment layers 14A and 14B, and thus the light control region SL becomes transparent.
  • Fig. 3 is a plan view of the light control sheet 10 attached to the transparent plate 50, and indicates, by dots, a region in which the insulating sections 21A and 21B are located.
  • the region in which the insulating sections 21A and 21B are located is an insulating region SI
  • a region in which the outer-peripheral conductive sections 22A and 22B are located is a conductive region SO.
  • the insulating region SI is located outside the light control region SL and extends along an outer edge of the light control region SL.
  • the conductive region SO is located outside the insulating region SI and extends along an outer edge of the insulating region SI.
  • the insulating region SI has an annular shape that surrounds the entire light control region SL
  • the conductive region SO has an annular shape that surrounds the entire light control region SL and insulating region SI.
  • the insulating sections 21A and 21B are configured such that sections having insulation properties are continuously arranged in the direction in which the insulating region SI extends.
  • the conductive region SO preferably has a width WO of 1 mm or more and 10 mm or less. If the width WO is 1 mm or more, the conductive region SO is not excessively thin, and thus the outer-peripheral conductive sections 22A and 22B are easily formed. Furthermore, the conductive region SO having a width WO of 1 mm or more provides sufficient adhesive force of the outer-peripheral conductive section 22A to the layers adjacent to the transparent electrode layer 12A in a thickness direction and sufficient adhesive force of the outer-peripheral conductive section 22B to the layers adjacent to the transparent electrode layer 12B in the thickness direction. If the width WO is 10 mm or less, the light control region SL is prevented from being small. If a length of the conductive region SO in a width direction is not constant, the width WO is an average length of the conductive region SO in the width direction.
  • the insulating region SI preferably has a width WI that is equal to or less than the width WO of the conductive region SO. If the width WI is equal to or less than the width WO, the light control region SL is prevented from being small.
  • the width WI of the insulating region SI is preferably 5 ⁇ m or more. If a length of the insulating region SI in the width direction is not constant, the width WI is an average length of the insulating region SI in the width direction.
  • the light control sheet 10 has the light control region SL, a first connection region SA for connecting the electrode section 20A of the first transparent electrode layer 12A to a drive circuit, and a second connection region SB for connecting the electrode section 20B of the second transparent electrode layer 12B to the drive circuit.
  • a region other than the connection regions SA and SB is the light control region SL.
  • connection regions SA and SB may be apart from the insulating region SI or may be in contact with the insulating region SI.
  • Fig. 3 shows an example in which the connection regions SA and SB are apart from the insulating region SI.
  • each of the first connection region SA and the second connection region SB is surrounded by the light control region SL.
  • the configuration in which the connection regions SA and SB are apart from the insulating region SI does not require high accuracy in alignment of the connection regions SA and SB with the insulating region SI; thus, the connection regions SA and SB and the insulating region SI are easily formed.
  • a positional relationship between the first connection region SA and the second connection region SB is not particularly limited, and for example, the first connection region SA and the second connection region SB may be arranged in a direction along a side of the light control sheet 10 having a rectangular shape.
  • the first connection region SA is connected to a first wiring section 40A
  • the second connection region SB is connected to a second wiring section 40B.
  • the electrode section 20A of the first transparent electrode layer 12A is connected to the drive circuit through the first wiring section 40A
  • the electrode section 20B of the second transparent electrode layer 12B is connected to the drive circuit through the second wiring section 40B.
  • the drive circuit converts a voltage received from a power supply into a driving voltage, and applies the driving voltage to the electrode sections 20A and 20B through the wiring sections 40A and 40B, respectively.
  • Fig. 4 shows examples of structures of the normal-type light control sheet 10N.
  • a surface of the first transparent electrode layer 12A facing away from the first transparent support layer 13A is exposed from other layers of the light control sheet 10, which include the light control layer 11, the second transparent electrode layer 12B, and the second transparent support layer 13B, and facing to the transparent plate 50.
  • a surface of the first transparent support layer 13A facing away from the first transparent electrode layer 12A is a surface of the light control sheet 10.
  • the first transparent electrode layer 12A is continuous between the light control region SL and the first connection region SA, and the electrode section 20A is located in both the light control region SL and the first connection region SA. In the first connection region SA, the first wiring section 40A is connected to the electrode section 20A.
  • the first wiring section 40A only needs to be configured to allow electrical conduction between the electrode section 20A and the drive circuit.
  • the first wiring section 40A includes a conductive adhesive layer 41A, a lead 42A, and a solder section 43A.
  • the conductive adhesive layer 41A is composed of, for example, a conductive tape such as a copper tape.
  • the conductive adhesive layer 41A is bonded to a surface of the electrode section 20A in the first connection region SA, and the lead 42A is fixed to a surface of the conductive adhesive layer 41A via the solder section 43A.
  • a surface of the second transparent electrode layer 12B facing away the second transparent support layer 13B is exposed from other layers of the light control sheet 10, which include the light control layer 11, the first transparent electrode layer 12A, and the first transparent support layer 13A, and constitutes the outermost surface of the light control sheet 10.
  • a surface of the second transparent support layer 13B facing away from the second transparent electrode layer 12B is in contact with the transparent adhesive layer 51.
  • the second transparent electrode layer 12B is continuous between the light control region SL and the second connection region SB, and the electrode section 20B is located in both the light control region SL and the second connection region SB.
  • the second wiring section 40B is connected to the electrode section 20B.
  • the second wiring section 40B only needs to be configured to allow electrical conduction between the electrode section 20B and the drive circuit.
  • the second wiring section 40B includes a conductive adhesive layer 41B, a lead 42B, and a solder section 43B.
  • the conductive adhesive layer 41B is bonded to a surface of the electrode section 20B in the second connection region SB, and the lead 42B is fixed to a surface of the conductive adhesive layer 41B via the solder section 43B.
  • a method of producing the light control sheet 10 will be described by using an example of the normal type light control sheet 10N.
  • a multilayer laminate 30 that includes the light control layer 11, transparent conductive layers 31A and 31B, and the transparent support layers 13A and 13B is formed.
  • the first transparent conductive layer 31A is supported by the first transparent support layer 13A
  • the second transparent conductive layer 31B is supported by the second transparent support layer 13B.
  • the first transparent conductive layer 31A and the second transparent conductive layer 31B sandwich the light control layer 11.
  • the transparent conductive layer 31A is the transparent electrode layer 12A in which the electrode section 20A, the insulating section 21A, and the outer-peripheral conductive section 22A are not yet formed
  • the transparent conductive layer 31B is the transparent electrode layer 12B in which the electrode section 20B, the insulating section 21B, and the outer-peripheral conductive section 22B are not yet formed.
  • the transparent conductive layers 31A and 31B are a transparent uniform conductive film including no section having insulation properties.
  • the multilayer laminate 30 is, for example, cut out from a large sheet including a laminate of the light control layer 11, the transparent conductive layers 31A and 31B, and the transparent support layers 13A and 13B, and is formed into a desired shape corresponding to an object to which the light control sheet 10 is to be bonded.
  • the light control layer 11 contains a liquid crystal composition.
  • the light control layer 11 is composed of, for example, a polymer network liquid crystal (PNLC), a polymer dispersed liquid crystal (PDLC), a nematic curvilinear aligned phase (NCAP) liquid crystal, or the like.
  • PNLC polymer network liquid crystal
  • PDLC polymer dispersed liquid crystal
  • NCAP nematic curvilinear aligned phase
  • a polymer network liquid crystal has a three-dimensional mesh polymer network, and holds liquid crystal molecules in voids in the polymer network.
  • the liquid crystal molecules contained in the light control layer 11 have, for example, positive dielectric anisotropy, and have a higher dielectric constant in a major axis direction of the liquid crystal molecules than in a minor axis direction of the liquid crystal molecules.
  • liquid crystal molecules are, for example, liquid crystal molecules based on Schiff base, azo, azoxy, biphenyl, terphenyl, benzoic acid ester, tolan, pyrimidine, cyclohexanecarboxylic acid ester, phenylcyclohexane, or dioxane molecules.
  • the light control layer 11 may include a dye that has a predetermined color and does not hinder movement of the liquid crystal molecules according to a magnitude of the voltage applied to the light control layer 11. Such a configuration achieves the light control region SL having a predetermined color.
  • Materials forming the transparent conductive layers 31A and 31B include, for example, polymers including indium tin oxide (ITO), fluorine-doped tin oxide (FTO), tin oxide, zinc oxide, carbon nanotube (CNT), or poly(3,4-ethylenedioxythiophene) (PEDOT), and multilayer films including Ag alloy thin films.
  • ITO indium tin oxide
  • FTO fluorine-doped tin oxide
  • CNT carbon nanotube
  • PEDOT poly(3,4-ethylenedioxythiophene)
  • the first transparent support layer 13A and the second transparent support layer 13B are transparent substrates.
  • Example of the transparent support layers 13A and 13B include a glass substrate, a silicon substrate, or a polymer film made of polyethylene, polystyrene, polyethylene terephthalate, polyvinyl alcohol, polycarbonate, polyvinyl chloride, polyimide, polysulfone, cycloolefin polymer, triacetylcellulose, or the like.
  • the multilayer laminate 30 is irradiated with a laser beam to form the insulating sections 21A and 21B. Subsequently, the transparent electrode layers 12A and 12B are formed.
  • a region of the multilayer laminate 30 that is to be the insulating region SI is irradiated with a laser La from a side on which the first transparent conductive layer 31A is located with respect to the light control layer 11.
  • a laser La By irradiation with the laser La, an insulating region is formed in the two transparent conductive layers 31A and 31B, i.e., in both the first transparent conductive layer 31A which is closer to a light source of the laser device 60 and the second transparent conductive layer 31B which is farther from the light source.
  • the insulating section 21A, and the electrode section 20A and the outer-peripheral conductive section 22A that are divided by the insulating section 21A are formed in the first transparent conductive layer 31A.
  • the first transparent electrode layer 12A is formed.
  • the insulating section 21B, and the electrode section 20B and the outer-peripheral conductive section 22B that are divided by the insulating section 21B are formed in the second transparent conductive layer 31B.
  • the second transparent electrode layer 12B is formed.
  • the laser La is focused on the first transparent conductive layer 31A or a portion in the vicinity of the first transparent conductive layer 31A, and the multilayer laminate 30 is irradiated with the laser La from a position facing the first transparent support layer 13A so that the laser La is transmitted through the first transparent support layer 13A.
  • At least an outer surface of the first transparent support layer 13A is not modified by the laser La, and a portion having insulation properties is formed in the first transparent conductive layer 31A, and thus the insulating section 21A is formed.
  • a portion having insulation properties is formed in the second transparent conductive layer 31B by the laser La transmitted through the first transparent conductive layer 31A and the light control layer 11, and thus the insulating section 21B is formed.
  • the laser La may be focused on the second transparent conductive layer 31B or a portion in the vicinity of the second transparent conductive layer 31B. Furthermore, the insulating sections 21A and 21B may be formed by focusing the laser La on a position beyond the second transparent conductive layer 31B as viewed from the light source of the laser device 60 and setting a wavelength of the laser La to a wavelength at which the laser La is absorbed by the first transparent conductive layer 31A and the second transparent conductive layer 31B.
  • the multilayer laminate 30 may be irradiated with the laser La from a side on which the second transparent conductive layer 31B is located with respect to the light control layer 11.
  • the laser La is focused on the second transparent conductive layer 31B or a portion in the vicinity of the second transparent conductive layer 31B, and the multilayer laminate 30 is irradiated with the laser La from a position facing the second transparent support layer 13B so that the laser La is transmitted through the second transparent support layer 13B.
  • At least an outer surface of the second transparent support layer 13B is not modified by the laser La, and the insulating section 21B is formed in the second transparent conductive layer 31B.
  • the insulating section 21A is formed in the first transparent conductive layer 31A by the laser La transmitted through the second transparent conductive layer 31B and the light control layer 11.
  • the laser La may be focused on the first transparent conductive layer 31A or a portion in the vicinity of the first transparent conductive layer 31A.
  • the insulating sections 21A and 21B may be formed by focusing the laser La on a position beyond the first transparent conductive layer 31A as viewed from the light source of the laser device 60 and setting the wavelength of the laser La to a wavelength at which the laser La is absorbed by the first transparent conductive layer 31A and the second transparent conductive layer 31B.
  • a medium and wavelength of the laser used for laser irradiation are not particularly limited.
  • Examples of a laser that can be used include a Nd:YAG laser, Nd:YVO 4 laser, CO 2 laser, and semiconductor laser.
  • an infrared wavelength may be used for the laser wavelength.
  • the laser may be a continuous-wave laser or a pulsed laser.
  • connection regions SA and SB are formed.
  • the first connection region SA is formed by removing, by cutting or the like, the light control layer 11, the second transparent conductive layer 31B, and the second transparent support layer 13B from a region of the multilayer laminate 30 that is to be the first connection region SA.
  • the second connection region SB is formed by removing, by cutting or the like, the light control layer 11, the first transparent conductive layer 31A, and the first transparent support layer 13A from a region of the multilayer laminate 30 that is to be the second connection region SB.
  • the connection regions SA and SB may be formed before laser irradiation.
  • the multilayer laminate 30 used in production of the reverse-type light control sheet 10R includes the alignment layers 14A and 14B in addition to the light control layer 11, the transparent conductive layers 31A and 31B, and the transparent support layers 13A and 13B.
  • the first alignment layer 14A is located between the light control layer 11 and the first transparent conductive layer 31A
  • the second alignment layer 14B is located between the light control layer 11 and the second transparent conductive layer 31B.
  • Materials for forming the alignment layers 14A and 14B are, for example, polyesters such as polyamide, polyimide, polycarbonate, polystyrene, polysiloxane, polyethylene terephthalate, and polyethylene naphthalate, and polyacrylates such as polymethylmethacrylate.
  • polyesters such as polyamide, polyimide, polycarbonate, polystyrene, polysiloxane, polyethylene terephthalate, and polyethylene naphthalate
  • polyacrylates such as polymethylmethacrylate.
  • Examples of alignment processing for the alignment layers 14A and 14B include rubbing, polarized light irradiation, and microprocessing.
  • the multilayer laminate 30 including the alignment layers 14A and 14B is irradiated with a laser similarly to the case of the normal type described above, and thus the first transparent electrode layer 12A and the second transparent electrode layer 12B are formed.
  • the light control sheet 10 may include one or more additional layers, in addition to the light control layer 11, the transparent electrode layers 12A and 12B, the transparent support layers 13A and 13B, and the alignment layers 14A and 14B.
  • additional layers include layers having a UV barrier function or the like, layers for protecting the light control layer 11 and the transparent electrode layers 12A and 12B, layers contributing to control of optical transparency in the light control region SL, and layers improving strength or characteristics such as heat resistance of the light control sheet 10.
  • laser irradiation is performed on the multilayer laminate 30, having a layer configuration corresponding to the layer configuration of the light control sheet 10, to form the first transparent electrode layer 12A and the second transparent electrode layer 12B.
  • the light control sheet 10 of the present embodiment has flexibility suitable for bonding to a curved surface, and can be applied to a curved surface having any shape such as a developable surface or a three-dimensional curved surface.
  • the light control sheet 10 can be arranged along a curved surface without particular physical processing such as cutting of a part of the light control sheet 10. Thus, even if the light control sheet 10 is bent while being bonded to the curved surface, it is possible to avoid the occurrence of cracks initiated from the processed portion or the like in the light control sheet 10. Therefore, good resistance to bending is obtained.
  • the insulating sections 21A and 21B are a laser-processed region formed by laser irradiation. First, the laser-processed region will be described in detail.
  • Figs. 8 and 9 are enlarged views of a first example of a cross-sectional structure in the vicinity of the insulating section 21A.
  • the insulating section 21A is a section at which the conductive film constituting the first transparent conductive layer 31A is broken into small fragments.
  • the conductive film is fragmented into pieces by laser irradiation, and a part of the first transparent conductive layer 31A is removed from the first transparent support layer 13A. That is, the insulating section 21A is a section at which the conductive film is removed from the first transparent support layer 13A.
  • Fragment Fg of the conductive film removed from the first transparent support layer 13A are located at a section in the vicinity of the insulating section 21A in a functional layer such as the light control layer 11 or the first alignment layer 14A that is in contact with the first transparent electrode layer 12A.
  • a section of the functional layer that is in contact with the insulating section 21A has a higher content of the same element as an element constituting the electrode section 20A than sections of the functional layer that are in contact with the electrode section 20A and the outer-peripheral conductive section 22A.
  • the insulating section 21A may be a portion in which the conductive film is physically disrupted while being in contact with the first transparent support layer 13A as shown in Fig. 9 .
  • a surface of the insulating section 21A is rougher than surfaces of the electrode section 20A and the outer-peripheral conductive section 22A. In this case, the fragment Fg is not dispersed into the functional layer.
  • Figs. 10 and 11 are enlarged views of a second example of the cross-sectional structure in the vicinity of the insulating section 21A.
  • the insulating section 21A is a region chemically modified by laser irradiation.
  • the insulating section 21A is a region in which atoms contributing to electrical conductivity or elements Pc which are parts of molecules contributing to electrical conductivity have flowed into the layer under the first transparent electrode layer 12A, resulting in a change in composition.
  • Such a modification in composition imparts insulating properties to the insulating section 21A.
  • the section in contact with the insulating section 21A has a higher content of the element Pc than the sections of the functional layer in contact with the electrode section 20A and the outer-peripheral conductive section 22A.
  • the electrode section 20A, the insulating section 21A, and the outer-peripheral conductive section 22A constitute a single mutually continuous layer, and the first transparent electrode layer 12A has a flat film shape.
  • the insulating section 21A is more fragile than the electrode section 20A and the outer-peripheral conductive section 22A.
  • the surface of the insulating section 21A is rougher than the surfaces of the electrode section 20A and the outer-peripheral conductive section 22A.
  • the insulating section 21A is a region different from the electrode section 20A and the outer-peripheral conductive section 22A in that the atomic positions in the compound have been displaced or the chemical structure has changed due to breakage of bonds in molecules or the like. Such a change in chemical structure imparts insulating properties to the insulating section 21A. In the insulating section 21A, no change in composition has occurred.
  • the electrode section 20A, the insulating section 21A, and the outer-peripheral conductive section 22A constitute a single mutually continuous layer, and the first transparent electrode layer 12A has a flat film shape.
  • the insulating section 21A has a structure of the first example or the second example depends on the material constituting the first transparent electrode layer 12A, that is, the material constituting the first transparent conductive layer 31A, the power of the laser, and the like. Further, the insulating section 21A may have a structure in which the first example and the second example are combined. For example, the first transparent electrode layer 12A may have a structure in which the element Pc migrates from the insulating section 21A into a layer underlying the first transparent electrode layer 12A while the conductive film is physically damaged. The element Pc is an element included in a plurality of elements constituting the electrode section 20A.
  • the insulating section 21B of the second transparent electrode layer 12B also has the same structure as the insulating section 21A, i.e., a structure in the first example, a structure in the second example, or a structure which is a combination of the first example and the second example.
  • the cross-sectional shape of the insulating section 21A is shown such that a width of the insulating section 21A increases toward the first transparent support layer 13A, and the outer edge of the insulating section 21A has a curve bulging outward.
  • This shape is on the assumption that the insulating section 21A is formed if the laser is focused on a central portion of the first transparent conductive layer 31A in the thickness direction to the surface in contact with the first transparent support layer 13A and the laser is irradiated from a position facing the first transparent support layer 13A.
  • the cross-sectional shape of the insulating section 21A may be different from the shapes shown in Figs. 8 to 11 depending on the laser irradiation direction, the focusing position, power, or the like.
  • Fig. 12 is an enlarged view of an example of a planar structure in the vicinity of the insulating region SI of the light control sheet 10.
  • the insulating region SI When viewed in a direction perpendicular to a surface of the light control sheet 10, that is, in a direction perpendicular to the first transparent support layer 13A, the insulating region SI has a straight strip-shaped region Ss, which is a strip-shaped region having a constant width.
  • the insulating sections 21A and 21B are formed by a continuous-wave laser.
  • Fig. 12 shows an example in which edge sections of the straight strip-shaped region Ss in the width direction are discolored.
  • the degree of discoloration varies in the straight strip-shaped region Ss, since the farther from the center at which the laser is focused, the lower the energy of the laser received by the multilayer laminate 30.
  • a portion where discoloration occurs in the straight strip-shaped region Ss can vary.
  • a central portion of the straight strip-shaped region Ss in the width direction may be discolored, or edge sections in the width direction and a central portion may be discolored.
  • One of the factors of discoloration is, for example, when the transparent support layers 13A and 13B are polyethylene terephthalate films, a portion of the transparent support layer 13A in contact with the insulating section 21A and a portion of the transparent support layer 13B in contact with the insulating section 21B become amorphous due to laser irradiation. Such a change into an amorphous state in the transparent support layer 13A and 13B is particularly likely to occur in a central portion of the straight strip-shaped region Ss in the width direction. Whether a change into an amorphous state occurs or not in the transparent support layer 13A and 13B can be controlled by the power of laser, focus position, and the like.
  • the laser irradiation conditions may be adjusted so that a change to the amorphous state occurs in at least one of the first transparent support layer 13A and the second transparent support layer 13B or that no change to the amorphous state occurs in either of the first transparent support layer 13A or the second transparent support layer 13B.
  • the insulating region SI may be configured such that a plurality of straight strip-shaped regions Ss are arranged in the width direction of the straight strip-shaped regions Ss.
  • the insulating region SI composed of the plurality of straight strip-shaped regions Ss is formed by scanning a laser a plurality of times to a region that is to be the insulating region SI while gradually offsetting the laser irradiation position in the width direction of the region.
  • the configuration in which the insulating region SI is composed of the plurality of straight strip-shaped regions Ss improves the reliability of insulation of the insulating section 21A between the electrode section 20A and the outer-peripheral conductive section 22A and insulation of the insulating section 21B between the electrode section 20B and the outer-peripheral conductive section 22B.
  • Fig. 13 is an enlarged view of another example of the planar structure in the vicinity of the insulating region SI of the light control sheet 10.
  • the insulating section SI is formed as a rounded strip-shaped region Cs having an outer shape formed of a sequence of rounded regions arranged in one direction.
  • the circular strip-shaped region Cs has an outer shape in which a plurality of circles are sequentially connected so that regions in the circles communicate with each other.
  • the insulating sections 21A and 21B are formed by a pulsed laser.
  • Fig. 13 shows an example in which edge sections of the rounded strip-shaped region Cs in the width direction, that is, a circumferential portion of the rounded regions connected to each other is discolored.
  • the degree of discoloration varies in the rounded strip-shaped region Cs, since the farther from the center at which the laser is focused, the lower the laser energy received by the multilayer laminate 30.
  • the discolored section of the circular strip-shaped region Cs may vary according to the power of the laser. For example, a central portion of the rounded regions of the rounded strip-shaped region Cs may be discolored, or a circumferential portion and a central portion of the rounded regions may be discolored.
  • a portion of the transparent support layers 13A and 13B in contact with the insulating sections 21A and 21B becomes amorphous due to laser irradiation.
  • Such a change into an amorphous state in the transparent support layers 13A and 13B is particularly likely to occur in a central portion of the rounded regions of the rounded strip-shaped region Cs.
  • whether a change into an amorphous state occurs or not in the transparent support layers 13A and 13B can be controlled by the power of the laser, focus position, and the like.
  • the multilayer laminate 30 is continuously irradiated with a laser beam, so the heat generated by laser irradiation is not likely to dissipate. As a result, liquid crystals contained in the light control layer 11 may change into gas, generating gas bubbles.
  • the multilayer laminate 30 is intermittently irradiated with a laser beam. Accordingly, the heat generated by laser irradiation is more likely to dissipate compared with a case using a continuous-wave laser. This prevents generation of air bubbles in the light control layer 11.
  • the insulating region SI may be configured such that a plurality of rounded strip-shaped regions Cs are arranged in the width direction of the rounded strip-shaped regions Cs.
  • the insulating region SI composed of the plurality of rounded strip-shaped regions Cs is formed by scanning a laser a plurality of times to a region where the insulating region SI is to be formed while gradually offsetting the laser irradiation position in the width direction of the region.
  • the configuration in which the insulating region SI is composed of the plurality of rounded strip-shaped regions Cs improves the reliability of insulation of the insulating section 21A between the electrode section 20A and the outer-peripheral conductive section 22A and insulation of the insulating section 21B between the electrode section 20B and the outer-peripheral conductive section 22B.
  • the width of the strip-shaped region that is, the width of the insulating portion tends to have an irregular shape compared with a case using a continuous-wave laser. Accordingly, arranging a plurality of rounded strip-shaped regions Cs side by side is advantageous for improved reliability of the insulating properties.
  • the length of the insulating region SI in the width direction is a length between one side of the plurality of strip-shaped regions and the other side of the plurality of strip-shaped regions in the width direction.
  • the transparent support layers 13A and 13B were made of a polyethylene terephthalate film, and the light control layer 11 was made of a polymer network liquid crystal. Polyimide was used as a material of the alignment layers 14A and 14B.
  • the multilayer laminate 30 was irradiated with a laser from a position facing the first transparent support layer 13A, in which the laser wavelength is set to be absorbed by the ITO.
  • a reverse type light control sheet 10R was formed.
  • the light control layer 11 was divided in the thickness direction so that the light control sheet 10R is separated into a first multilayer laminate having the first transparent support layer 13A, the first transparent electrode layer 12A, the first alignment layer 14A, and part of the light control layer 11, and a second multilayer laminate having the second transparent support layer 13B, the second transparent electrode layer 12B, the second alignment layer 14B, and part of the light control layer 11.
  • the first multilayer laminate was observed with a scanning electron microscope (SEM) and analyzed by energy dispersive X-ray spectrometry (EDX).
  • SEM scanning electron microscope
  • EDX energy dispersive X-ray spectrometry
  • JSM-7001F manufactured by JEOL Ltd.
  • measurement was performed in a direction perpendicular to the horizontal plane while a surface of the multilayer laminate was inclined by 30° relative to the horizontal plane in order to ensure the layer thickness of the analysis target.
  • the appearance and composition of the first multilayer laminate and the second multilayer laminate were analyzed according to the above procedure, and it was confirmed that the insulating section 21A formed according to the above laser irradiation conditions had a structure of the first example.
  • the analysis results will be described in detail below.
  • Fig. 14 (a) shows an SEM image of a surface of the first multilayer laminate on a side on which the light control layer 11 is located.
  • Figs. 14 (b) to (d) show the EDX mapping results of a region included in the image in Fig. 14 (a).
  • Fig. 14 (b) shows distribution of indium (In)
  • Fig. 14 (c) shows distribution of carbon (C)
  • Fig. 14 (d) shows distribution of oxygen (O).
  • a region sandwiched by two dotted lines is a region which has been irradiated with the laser, and a region outside the two dotted lines is a region which has not been irradiated with the laser.
  • the surface of the first multilayer laminate was rougher in the laser irradiated region than in the laser non-irradiated region.
  • Figs. 15(a) to (c) show the EDX spectra measured for the points included in the laser irradiated region and the points included in two non-laser irradiated regions located on both sides of the laser irradiated region in the first multilayer laminate after the light control layer 11 and the first alignment layer 14A are wiped off by using methyl ethyl ketone.
  • Fig. 15 (a) shows an EDX spectrum in the laser irradiated region
  • Figs. 15 (b) and (c) show EDX spectra in the non-laser irradiated region.
  • Fig. 15 (a) no In was detected in the laser irradiated region.
  • Figs. 15 (b) and (c) In is detected in the non-laser irradiated region.
  • the ITO film is present in the laser non-irradiated regions, and the ITO film is damaged in the laser irradiated region.
  • the ITO film was fragmented by laser irradiation and the fragments were scattered outside the first transparent electrode layer 12A.
  • the detected Pt is derived from the coating applied to the sample as pretreatment.
  • Fig. 16 is an SEM image of a surface of the first multilayer laminate after the light control layer 11 and the first alignment layer 14A are removed by wiping with methyl ethyl ketone.
  • a region Ra is a region which has been irradiated with a laser
  • a region Rb is a region which has not been irradiated with a laser.
  • Fig. 16 shows that the ITO film is damaged in the laser irradiated region.
  • a region having the damaged ITO film in the first transparent electrode layer 12A has a width of approximately 30 ⁇ m.
  • the insulating section 21A formed under the above laser irradiation conditions has a structure of the first example described above. That is, in the insulating section 21A, a physical structure of the first transparent conductive layer 3 1A is damaged, the conductive film is removed from the first transparent support layer 13A, and the fragments of the conductive film are dispersed into the light control layer 11.
  • Fig. 17 is a stereoscopic microscope image of the reverse type light control sheet 10R formed by laser irradiation in a direction perpendicular to the first transparent support layer 13A based on the above laser irradiation conditions. The image was captured as viewed in a direction perpendicular to the first transparent support layer 13A.
  • the insulating region SI is formed as a rounded strip-shaped region Cs having an outer shape formed of a sequence of rounded regions. Further, the insulating region SI appears dull compared with the light control region SL, suggesting that the visible light transmittance of the insulating region SI is lower than that of the light control region SL.
  • cloudiness due to a change into an amorphous state was observed on a surface in contact with the first transparent electrode layer 12A in the laser irradiated region.
  • the electrode section 20A and each of the outer-peripheral conductive sections 22A are insulated by each of the insulating sections 21A
  • the electrode section 20B and each of the outer-peripheral conductive sections 22B are insulated by each of the insulating sections 21B.
  • the sections of the transparent electrode layers 12A and 12B exposed on the edge surface 10E of the light control sheet 10 are the outer-peripheral conductive sections 22A and 22B, respectively.
  • a high driving voltage is applied, considering the influence of voltage gradient in the light control sheet. Accordingly, the prevention of a short circuit is highly important.
  • the oxide semiconductor When an electrolytic solution contacts an oxide semiconductor such as ITO while a voltage is applied to the oxide semiconductor, the oxide semiconductor is reduced by an electrochemical reaction, resulting in corrosion.
  • Water that can adhere to the light control sheet 10 may be caused by condensation or rain and often contains salt. Accordingly, the water can function as an electrolytic solution.
  • the transparent electrode layers 12A and 12B are formed of an oxide semiconductor, if the electrode sections 20A and 20B are exposed on the edge surface 10E of the light control sheet 10, water may adhere to the edge surface 10E and cause corrosion of the electrode sections 20A and 20B, resulting in an increase in resistance or disconnection.
  • the sections exposed on the edge surface 10E are the outer-peripheral conductive sections 22A and 22B that are insulated from the electrode sections 20A and 20B, respectively. This prevents corrosion of the electrode sections 20A and 20B. Furthermore, no voltage is applied to the outer-peripheral conductive sections 22A and 22B, and this also prevents corrosion of the outer-peripheral conductive sections 22A and 22B. That is, corrosion of the entire transparent electrode layers 12A and 12B is prevented.
  • the insulating sections 21A and 21B formed by laser irradiation are often more fragile than the electrode sections 20A and 20B and the outer-peripheral conductive sections 22A and 22B.
  • the outer-peripheral conductive sections 22A and 22B which are conductive films that are not broken or modified by laser irradiation, are arranged at the edge section of the light control sheet 10
  • the layers constituting the light control sheet 10 are prevented from being removed at the edge section of the light control sheet 10.
  • the attachment of conductive dust to the edge surface 10E of the light control sheet 10 may also be prevented by sealing the edge surface 10E with resin to cover the edge surface 10E.
  • the resin sealing structure does not necessarily have sufficient waterproof properties; thus, water may permeate the resin sealing structure and adhere to the edge surface 10E.
  • a conductive material may enter from a gap due to the cracks or peeling and adhere to the edge surface 10E.
  • the edge surface 10E of the light control sheet 10 in the first embodiment may or may not be sealed with resin.
  • the configuration in which the end surface 10E of the light control sheet 10 is not sealed with resin can reduce the work required to attach the light control sheet 10 to the transparent plate 50.
  • the transparent electrode layers 12A and 12B are exposed on the edge surface 10E of the light control sheet 10.
  • the insulating sections 21A and 21B are formed by irradiating the multilayer laminate 30 with a laser, compared with the case where the insulating sections 21A and 21B are formed by photolithography and etching, it is possible to reduce the number of steps required to produce the light control sheet 10 and also reduce the production time. The production cost can also be reduced. Since the insulating section 21A of the first transparent electrode layer 12A and the insulating section 21B of the second transparent electrode layer 12B are collectively formed, as compared with the case where the insulating section 21A of the first transparent electrode layer 12A and the insulating section 21B of the second transparent electrode layer 12B are separately formed, the insulating sections 21A and 21B can be efficiently produced.
  • the insulating sections 21A and 21B formed by laser irradiation can be less conspicuous.
  • the first embodiment achieves the following effects.
  • a second embodiment of the light control sheet (not covered by the claimed invention) and the method of producing the light control sheet will be described with reference to Figs. 18 and 19 .
  • the second embodiment differs from the first embodiment in the arrangement of the connection regions SA and SB and the insulating sections 21A and 21B.
  • differences between the second embodiment and the first embodiment will mainly be described, and the same components as in the first embodiment are given the same reference numerals and are not described. Either the normal-type structure or the reverse-type structure can be applied to the light control sheet in the second embodiment.
  • a light control sheet 15 in the second embodiment has a rectangular shape in plan view as viewed in a direction perpendicular to a surface of the light control sheet 15, and has the connection regions SA and SB at corner sections of the light control sheet 15.
  • the first connection region SA and the second connection region SB are arranged along one side of the light control sheet 15.
  • the first connection region SA is located at one edge section of the light control sheet 15 in a direction in which the side of the light control sheet 15 extends
  • the second connection region SB is located at another edge section of the light control sheet 15 in the direction in which the side of the light control sheet 15 extends.
  • connection regions SA and SB constitute an outer edge of the light control sheet 15.
  • connection region SA is not surrounded by the insulating section 21A, the outer-peripheral conductive section 22A and the light control region SL.
  • connection region SB is not surrounded by the insulating section 21B, the outer-peripheral conductive section 22B and the light control region SL.
  • the insulating region SI is located outside the light control region SL. However, the insulating region SI does not surround the entire light control region SL. In at least a part in the vicinity of the first connection region SA and at least a part in the vicinity of the second connection region SB, the insulating region SI is not provided.
  • the insulating region SI includes a main insulating region SIa and a sub insulating region SIb.
  • the main insulating region SIa is located outside the light control region SL and extends along an outer edge of the light control region SL, and the sub insulating region SIb extends from an edge section of the main insulating region SIa to the outer edge of the light control sheet 15.
  • the main insulating region SIa is interrupted in the vicinity of the first connection region SA, and at the section at which the main insulating region SIa is interrupted, the light control region SL and the first connection region SA are adjacent to each other.
  • the main insulating region SIa is interrupted in the vicinity of the second connection region SB, and at the section at which the main insulating region SIa is interrupted, the light control region SL and the second connection region SB are adjacent to each other.
  • the sub insulating region SIb extends from the edge section at which the main insulating region SIa is interrupted to the outer edge of the light control sheet 15.
  • the conductive region SO surrounded by the insulating region SI and the outer edge of the light control sheet 15 is formed.
  • the conductive region SO is separated from the light control region SL.
  • the conductive region SO is located outside the light control region SL, but does not surround the entire light control region SL.
  • the light control region SL has a substantially rectangular shape.
  • the light control region SL and the first connection region SA are adjacent to each other at a section along a side of the light control region SL, and the main insulating region SIa is interrupted at this section. From each of the edge sections of the interrupted main insulating region Sia, the sub insulating region SIb extends along the first connection region SA to the outer edge of the light control sheet 15. Furthermore, the light control region SL and the second connection region SB are adjacent to each other at a section along the side of the light control region SL.
  • the main insulating region SIa is also interrupted at this section. From each of the edge sections of the interrupted main insulating region Sia, the sub insulating region SIb extends along the second connection region SB to the outer edge of the light control sheet 15.
  • the shape of the light control region SL and the arrangement of the insulating region SI are not limited to the example shown in Fig. 18 .
  • the light control sheet 15 only needs to be configured such that the insulating region SI is located along the outer edge of the light control region SL, a section is provided at which the insulating region SI is not provided and the light control region SL is adjacent to the connection region SA and a section is provided at which the insulating region SI is not provided and the light control region SL is adjacent to the connection region SB, and the light control region SL and the conductive region SO are separated from each other by the insulating region SI.
  • Fig. 19 shows examples of the normal-type structures.
  • a surface of the first transparent electrode layer 12A facing away from the first transparent support layer 13A is exposed from other layers of the light control sheet 15, and is facing to the transparent plate 50.
  • the electrode section 20A is continuous between the light control region SL and the first connection region SA.
  • the first wiring section 40A is connected to the electrode section 20A in the first connection region SA, and thus a driving voltage is applied to the electrode section 20A in the light control region SL through the first wiring section 40A.
  • a surface of the second transparent electrode layer 12B facing away from the second transparent support layer 13B is exposed from other layers of the light control sheet 15, and constitutes the outermost surface of the light control sheet 15.
  • the electrode section 20B is continuous between the light control region SL and the second connection region SB.
  • the second wiring section 40B is connected to the electrode section 20B in the second connection region SB.
  • the light control sheet 15 of the second embodiment is produced by laser irradiation to the multilayer laminate 30 to form the insulating sections 21A and 21B, and the connection regions SA and SB.
  • connection regions SA and SB are arranged at the corner sections of the light control sheet 15.
  • the connection regions SA and SB are surrounded by other regions, it is easy to form the connection regions SA and SB, and it is easy to connect the wiring sections 40A and 40B to the connection regions SA and SB.
  • the wiring section 40A in order to lead the wiring sections 40A and 40B to an outer peripheral region of the light control sheet 10, the wiring section 40A is required to be extended over the insulating region SI and the conductive region SO that surround the connection region SA, and the wiring section 40B is required to be extended over the insulating region SI and the conductive region SO that surround the connection region SB.
  • the wiring sections 40A and 40B can be directly led to the outer peripheral region from the connection regions SA and SB.
  • a bending force or the like is less likely to be applied to the wiring sections 40A and 40B. This improves the reliability of the electrical conduction between the electrode section 20A and the drive circuit due to the wiring section 40A, and the electrical conduction between the electrode section 20B and the drive circuit due to the wiring section 40B.
  • the wiring sections 40A and 40B are located at the edge sections of the light control sheet 15, it is easy to secure, in the light control region SL, a large region that has, for example, a rectangular shape and allows a user of the light control sheet 15 to visually recognize a situation behind the light control sheet 15 without being blocked by the wiring sections 40A and 40B.
  • the outer-peripheral conductive section 22A insulated from the electrode section 20A and the outer-peripheral conductive section 22B insulated from the electrode section 20B are exposed on the edge surface 10E of the light control sheet 15.
  • the electrode sections 20A and 20B are exposed on the edge surface 10E of the light control sheet 15.
  • the electrode section exposed on the edge surface 10E in each of the connection regions is one of the electrode section 20A in the connection region SA and the electrode section 20B in the connection region SB, even when a conductive material is attached to the edge surface 10E, a short circuit is less likely to occur.
  • the entire light control region SL is surrounded by the insulating sections 21A and 21B and the outer-peripheral conductive sections 22A and 22B, and the electrode sections 20A and 20B are not exposed over the entire periphery on the edge surface 10E of the light control sheet 10. Accordingly, the first embodiment is more effective in preventing a short circuit and corrosion of the electrode sections 20A and 20B than the second embodiment. Thus, if the prevention of a short circuit and corrosion is prioritized, it is preferable to employ the structure in the first embodiment.
  • the second embodiment is less effective in preventing a short circuit and corrosion of the electrode sections 20A and 20B than the first embodiment, as described above, the location of the connection regions SA and SB at the edge sections of the light control sheet 15 achieves various effects. If these effects are prioritized, it is preferable to employ the structure in the second embodiment.
  • the second embodiment achieves the following effects.
  • connection regions SA and SB are located at the edge sections of the light control sheet 15 in plan view, and the insulating sections 21A and 21B are interrupted in the vicinity of the connection regions SA and SB.
  • Such a configuration can improve the ease of forming the connection regions SA and SB and connecting the wiring section 40A to the connection region SA and the wiring section 40B to the connection region SB while preventing a short circuit and corrosion of the electrode sections 20A and 20B.
  • the multilayer laminate 30 may be irradiated with a laser from a position facing the first transparent support layer 13A or may be irradiated with a laser from a position facing the second transparent support layer 13B.
  • the production method in which laser is irradiated in a direction perpendicular to the first transparent support layer 13A since the insulating section is formed in the transparent conductive layer, which is one of the two transparent conductive layers which is located closer to the laser light source, irradiation conditions of laser can be easily set. Adjustment of the power and the focus position of the laser makes it possible to control whether to process by laser irradiation only the first transparent conductive layer 31A or both the first transparent conductive layer 31A and the second transparent conductive layer 31B.
  • the insulating region SI is composed of the straight strip-shaped region Ss or the rounded strip-shaped region Cs.
  • the degree of discoloration in the strip-shaped regions Ss and Cs may vary, but the outer shape does not significantly vary.
  • Fig. 20 shows an SEM image of the surface of the second multilayer laminate after the light control layer 11 and the second alignment layer 14B are wiped off using methyl ethyl ketone.
  • a region Ra indicates a region that has been irradiated with a laser
  • a region Rb indicates a region that has not been irradiated with a laser.
  • region X which is a portion of an ITO film extending from the non-laser irradiated region which remains connected in the laser irradiated region. That is, in the second transparent electrode layer 12B shown in Fig. 20 , portions damaged by laser irradiation are intermittently arranged. In other words, in the second transparent electrode layer 12B shown in Fig. 20 , a strip-shaped section was formed in which sections having insulation properties are intermittently arranged. In Fig. 20 , a region having the damaged ITO film in the second transparent electrode layer 12B has a width of approximately 25 ⁇ m.
  • the first transparent conductive layer 31A is more likely to receive sufficient energy from the laser compared with the case where the insulating portion is formed only in the first transparent conductive layer 31A. Therefore, the insulating section 21A can be suitably formed.
  • a third embodiment of the light control sheet and the method of producing the light control sheet will be described with reference to Figs. 21 to 24 .
  • the third embodiment differs from the first embodiment in the method of forming an insulating section.
  • the following description will be described focusing on differences between the third embodiment and the first embodiment, and configuration that is the same as that of the first embodiment will be referred to by the same reference numbers and the description thereof will be omitted.
  • Either the normal-type structure or the reverse-type structure can be applied to the light control sheet in the third embodiment.
  • Insulating sections 23A and 23B of a light control sheet 16 in the third embodiment are formed by etching the transparent conductive layers 31A and 31B, respectively.
  • the insulating sections 23A and 23B formed by etching are easily formed to have a large width compared with an insulating section formed by laser irradiation.
  • the light control sheet 16 does not have the conductive region SO, and the insulating region SI extends to an outer edge of the light control sheet 16.
  • the insulating region SI surrounds the entire light control region SL.
  • the light control sheet 16 has the light control region SL, the first connection region SA, and the second connection region SB in a region surrounded by the insulating region SI.
  • the connection regions SA and SB may be apart from the insulating region SI or may be in contact with the insulating region SI.
  • Fig. 21 shows an example in which the connection regions SA and SB are in contact with the insulating region SI.
  • FIG. 22 shows a normal-type structure as an example.
  • the first transparent electrode layer 12A does not have the outer-peripheral conductive section 22A, and is composed of the electrode section 20A and the insulating sections 23A.
  • the second transparent electrode layer 12B does not have the outer-peripheral conductive section 22B, and is composed of the electrode section 20B and the insulating sections 23B.
  • Each of the insulating sections 23A is located at an edge section of the first transparent electrode layer 12A in the surface direction
  • each of the insulating sections 23B is located at an edge section of the second transparent electrode layer 12B in the surface direction.
  • the insulating sections 23A and 23B are sections from which a conductive film has been removed by etching.
  • the insulating sections 23A and 23B may be composed of a material having the same composition as a material of the functional layer such as the light control layer 11 or the alignment layers 14A and 14B in contact with the transparent electrode layers 12A and 12B, or may be sections filled with air. That is, the light control layer 11 is composed of a sandwiched section that is sandwiched between the electrode section 20A and the electrode section 20B and a stretched section that is stretched from the sandwiched section in the surface direction and extends to an edge section of the light control sheet 16.
  • the first transparent electrode layer 12A is composed of the electrode section 20A and each of the insulating sections 23A that extends from the electrode section 20A in the surface direction, and each of the insulating sections 23A and the second transparent electrode layer 12B sandwich the stretched section of the light control layer 11.
  • the second transparent electrode layer 12B is composed of the electrode section 20B and each of the insulating sections 23B that extends from the electrode section 20B in the surface direction, and each of the insulating sections 23B and the first transparent electrode layer 12A sandwich the stretched section of the light control layer 11.
  • a method of producing the light control sheet 16 in the third embodiment will be described using an example of the normal-type light control sheet.
  • the first transparent conductive layer 31A formed on the first transparent support layer 13A is subjected to processing such as patterning of a resist mask, and is then etched to remove a section surrounding a region that is to be the electrode section 20A.
  • the second transparent conductive layer 31B formed on the second transparent support layer 13B is etched to remove a section surrounding a region that is to be the electrode section 20B.
  • Materials of the transparent support layers 13A and 13B and the transparent conductive layers 31A and 31B may be the materials described in the first embodiment.
  • the etching may be wet etching or dry etching.
  • the light control layer 11 is formed by coating or the like on the transparent conductive layer of one of laminates, i.e., a first laminate 32A composed of the first transparent support layer 13A and the first transparent conductive layer 31A and a second laminate 32B composed of the second transparent support layer 13B and the second transparent conductive layer 31B. Then, the other laminate is laminated on the light control layer 11 so that the transparent conductive layer is in contact with the light control layer 11.
  • a laminated structure composed of the light control layer 11, the transparent electrode layers 12A and 12B, and the transparent support layers 13A and 13B is formed.
  • the insulating sections 23A and 23B are composed of a material having the same composition as the material of the light control layer 11.
  • connection regions SA and SB may be formed as in the first embodiment after lamination of the first laminate 32A, the light control layer 11, and the second laminate 32B.
  • connection regions SA and SB may be formed together with lamination of the first laminate 32A, the light control layer 11, and the second laminate 32B, for example, by processing in advance to produce the shapes of the transparent support layers 13A and 13B.
  • the insulating sections 23A and 23B also extend along the outer edges of the electrode sections 20A and 20B, respectively.
  • the electrode sections 20A and 20B are not exposed on the edge surface 10E of the light control sheet 16. This can prevent short circuit and corrosion of the electrode sections 20A and 20B due to adhesion of a conductive material to the edge surface 10E.
  • the insulating sections 23A and 23B are formed by etching, the insulating sections 23A and 23B are easily formed to have a large width compared with an insulating section formed by laser irradiation. Furthermore, a high degree of freedom is provided to the shape of the region in which the insulating sections 23A and 23B are arranged. Furthermore, in the configuration in which the insulating sections 23A and 23B are filled with a material having the same composition as the material of the functional layer in contact with the transparent electrode layers 12A and 12B, the insulating sections 23A and 23B are prevented from being fragile as in the case where the insulating sections 23A and 23B are formed by laser irradiation. Thus, without the outer-peripheral conductive sections 22A and 22B, the layers constituting the light control sheet 16 are prevented from being separated from each other at the edge section of the light control sheet 16.
  • the third embodiment achieves the following effects.
  • the insulating sections 23A and 23B are formed by etching, the insulating sections 23A and 23B are easily formed to have a large width, and a high degree of freedom is provided to the shape of the region for the insulating sections 23A and 23B. Furthermore, in the configuration in which the insulating sections 23A and 23B are filled with a material having the same composition as the material of the functional layer in contact with the transparent electrode layers 12A and 12B, even though the outer-peripheral conductive sections 22A and 22B are not provided, the layers constituting the light control sheet 16 are prevented from being removed from each other at the edge section of the light control sheet 16.
  • the third embodiment can be implemented with modifications as described below.
  • the following modifications may be implemented in combination.

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EP19863196.2A 2018-09-19 2019-09-19 Light modulation sheet, and method of manufacturing light modulation sheet Active EP3855242B1 (en)

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PCT/JP2019/036825 WO2020059820A1 (ja) 2018-09-19 2019-09-19 調光シート、および、調光シートの製造方法

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JP7173154B2 (ja) 2022-11-16
CN112585525B (zh) 2024-03-19
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JPWO2020059820A1 (ja) 2021-08-30
WO2020059820A1 (ja) 2020-03-26
EP3855242A1 (en) 2021-07-28
US11828964B2 (en) 2023-11-28
CN112585525A (zh) 2021-03-30
US20210208321A1 (en) 2021-07-08
JP7375280B2 (ja) 2023-11-08

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