Classifications

• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
  • C01G53/00—Compounds of nickel
  • C01G53/40—Nickelates
  • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
  • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
  • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/052—Li-accumulators
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
  • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/36—Selection of substances as active materials, active masses, active liquids
  • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
  • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
  • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2004/00—Particle morphology
  • C01P2004/60—Particles characterised by their size
  • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2006/00—Physical properties of inorganic compounds
  • C01P2006/11—Powder tap density
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2006/00—Physical properties of inorganic compounds
  • C01P2006/40—Electric properties
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
  • H01M2004/028—Positive electrodes
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
  • Y02E60/10—Energy storage using batteries

Definitions

• the present invention relates to a lithium transition metal composite oxide capable of being used as a positive electrode (cathode) active material in non-aqueous electrolyte lithium secondary batteries. Further, the present invention relates to a method for preparing the lithium transition metal composite oxide, to its use as positive electrode active material and to a non-aqueous electrolyte lithium secondary battery containing the lithium transition metal composite oxide.
• a positive electrode active material in a lithium secondary battery an oxide of a transition metal compound and lithium is used.
• oxides are LiNiO 2 , LiCoO 2 , LiMn 2 O 4 , LiFePO 4 , LiNi x Co 1-x O 2 (0 ⁇ x ⁇ 1), LiNi 1-x-y Co x AlyO 2 (0 ⁇ x ⁇ 0.2, 0 ⁇ y ⁇ 0.1) and LiNi 1-x-y Co x Mn y O 2 (0 ⁇ x ⁇ 0.5, 1 ⁇ y ⁇ 0.5).
• Such positive active materials however have limited electric capacity.
• novel positive electrode active materials having various structures are suggested.
• composite-based oxides are used as an alternative.
• Li 2 MO 3 -LiMeO 2 wherein M and Me are transition metals
• the composite-based oxide having a layered structure enables intercalation/deintercalation of a great amount of Li ions, compared to other positive active materials, and thus, it has high capacity properties.
• a structural change may occur during cycles and an average voltage decreases. This is due to the translocation of transition metal into empty Li ion sites.
• the present application provides for a use of the lithium transition metal composite oxide of the present invention as positive electrode active material and for a non-aqueous electrolyte lithium secondary battery comprising said positive electrode active material.
• an aqueous solution contains nickel (Ni), or contains manganese (Mn), or the like, is understood to mean that nickel, or manganese, or the like, is/are present in the aqueous solution in the form of an ion/cation, which terms are used interchangeably herein.
• the lithium transition metal composite oxide of the present invention may be either a composite with a layered structure or a solid solution. In some cases, the lithium transition metal composite oxide may exist in a combination of a composite with a layered structure or a solid solution.
• the lithium transition metal composite oxide according to the present invention contains a stabilized LiMeO 2 phase, whereby an electrochemically inert rocksalt phase Li 2 Me'O 3 is introduced as a component to the overall electrode structure as defined. That is, the lithium transition metal composite oxide represented by formula 1 contains excess Li in a transition metal layer of LiMeO 2 (wherein Me corresponds to trivalent ions M1, M2 and M3, such as Ni 3+ , Mn 3+ and Co 3+ ), and excess Li is contained in the form of a Li 2 Me'O 3 phase (wherein Me' corresponds to tetravalent ions M3', such as Mn 4+ ), which has high capacity and stability at high voltage and, in LiMeO 2 with the layered structure, and accordingly, the lithium transition metal composite oxide exhibits a high capacity and structural stability as electrode active material.
• LiMeO 2 wherein Me corresponds to trivalent ions M1, M2 and M3, such as Ni 3+ , Mn 3+ and Co 3+
• excess Li is contained
• the rocksalt phase Li 2 Me'O 3 has a layered-type structure in which discrete layers of lithium ions alternate with layers containing Me' and lithium ions (in a 2:1 ratio) between the close-packed oxygen sheets.
• the Me' ions in Li 2 Me'O 3 are tetravalent, they cannot be easily electrochemically oxidized by lithium extraction, whereas the trivalent transition metal cations Me can be electrochemically oxidized. Because there is no energetically favorable interstitial space for additional lithium in Li 2 Me'O 3 having the rocksalt phase, Li 2 Me'O 3 cannot operate as an insertion electrode and cannot be electrochemically reduced.
• the structure of the lithium transition metal composite oxide represented by formula 1 can be regarded essentially as a compound with a common oxygen array for both the LiMeO 2 and Li 2 Me'O 3 components, but in which the cation distribution can vary such that domains of the two components exist side by side. Such a solid solution or domain structure does not rule out the possibility of cation mixing and structural disorder, particularly at domain or grain boundaries.
• one layer contains Me, Me' and Li ions between sheets of close-packed oxygen ions, whereas the alternate layers are occupied essentially by Li ions alone.
• the tetravalent Me' ions can partially occupy the Me positions in the monoclinic layered LiMeO 2 structure, thereby providing increased stability to the overall structure.
• the Ni content of the lithium transition metal composite oxide should be high, i.e., index x has to satisfies the condition 0.7 ⁇ x ⁇ 1 in the composite oxide of formula 1, such that the LiMeO 2 component is essentially LiNiO 2 modified in accordance with the invention.
• index x in formula 1 satisfies the condition 0.75 ⁇ x ⁇ 0.9.
• index x satisfies the condition 0.8 ⁇ x ⁇ 0.9.
• x may be 0.80, 0.81, 0.82, 0.83, 0.84, 0.85, 0.86, 0.87, 0.88, 0.89 or 0.90.
• index x is 0.8 ⁇ x ⁇ 0.85.
• the content of metal M2 on the one side and the content of metals M3 and M3' (optionally including M4) on the other side is substantially identical (that is, the molar ratio M2 : (M3+M3'+optionally M4) is approximately 1).
• M2 the molar ratio M2 : (M3+M3'+optionally M4) is approximately 1.
• the lithium transition metal composite oxide according to the present invention represented by formula 1 above satisfies the condition 0 ⁇ a(1-x-y-z) ⁇ 0.05, which means that the molar ratio of Li and the sum of all metal cations (that is: Li : (M1+M2+M3+M3'+optionally M4)) is in the range of more than 1 to less than or equal to 1.05.
• the excess of Li ions in the lithium transition metal composite oxide if the doping content of the metal cations is too high, i.e. the molar ratio Li : metal cations is 1 or less, the amount of Li ions in the composite oxide is relatively small, leading to a decrease in a charging amount. On the other side, if the molar ratio Li : metal cations is greater than 1.05, a high irreversible capacity loss and a high residual alkali amount on the particle surface is observed.
• M2 in formula 1 is one or more transition metals having an oxidation state of three, which are more preferably selected form V, Fe and Co. Most preferably M2 is Co.
• M3' and M3 in formula 1 are identically one or more transition metals, which are more preferably selected from Mn, Ti, Zr, Ru, Re and Pt, with at least one transition metal being Mn.
• M3 and M3' represent the same transition metal(s), which are however present within the composite oxide of formula 1 in different oxidation states.
• M3 is Mn 3+ and M3' is Mn 4+ . It is preferred that M3 and M3' are Mn.
• M2 represents Co and M3 and M3' represent Mn, each having the valence as defined above.
• the lithium transition metal composite oxide according to the present invention may be doped by an element M4, wherein M4 is one or more selected from Mg, Al and B. Preferably, M4 is one or more selected from Mg and Al.
• Index z in general formula 1 of the lithium transition metal composite oxide satisfies the condition 0 ⁇ z ⁇ 0.05. Further preferably, index z satisfies the condition 0 ⁇ z ⁇ 0.045.
• index z satisfies the condition 0 ⁇ z ⁇ 0.05, more preferably 0 ⁇ z ⁇ 0.045, even more preferably 0.005 ⁇ z ⁇ 0.045
• doping element M4 is present, ions M3 and M3' and the Li ions are partially substituted by minor concentrations of one or more di- or trivalent cations M4, where M4 represents one or more of Mg, Al and B (i.e., cations Mg 2+ , Al 3+ , B 3+ ).
• M4 represents one or more of Mg, Al and B (i.e., cations Mg 2+ , Al 3+ , B 3+ ).
• Such doping of the composite oxide imparts improved structural stability or electronic conductivity to a battery electrode during electrochemical cycling.
• the lithium transition metal composite oxide according to the present invention is in the form of particles.
• the lithium transition metal composite oxide may form a primary particle, or primary particles of the lithium transition metal composite oxide may agglomerate or bind to each other, or may be combined with other active materials to form a secondary particle.
• the average particle size of the primary particles is preferably in the range of about 100 nm to about 800 nm, more preferably in the range of about 200 nm to about 500 nm. When the average particle size of the primary particles is more than 800 nm, the resistance to diffusion of lithium ions tends to be increased, so that the lithium transition metal composite oxide particles tend to be deteriorated in initial discharge capacity.
• the average particle size of the secondary particles is preferably in the range of about 1 ⁇ m to 50 ⁇ m, more preferably of about 1 ⁇ m to about 25 ⁇ m. When the average particle size of the secondary particles is within this range, high electrochemical performance of the lithium secondary battery can be provided.
• the average particle size of the primary and secondary particles, respectively, is determined using a light scattering method using commercially available devices. This method is known per se to a person skilled in the art, wherein reference is also made in particular to the disclosure in JP 2002-151082 and WO 02/083555 .
• the average particle sizes were determined by a laser diffraction measurement apparatus (Mastersizer 2000 APA 5005, Malvern Instruments GmbH,dorfberg, DE) and the manufacturer's software (version 5.40) with a Malvern dry powder feeder Scirocco ADA 2000.
• the lithium transition metal composite oxide of the present invention has an excellent tap density of between 1.0 g/cm 3 to 2.0 g/cm 3 , preferably between 1.6 g/cm 3 to 2.0 g/cm 3 .
• the high tap density positively influences the electrode density and hence the energy density of the battery when the lithium transition metal composite oxide is used as an active electrode material.
• the tap density is measured according to ISO 787 (formerly DIN 53194).
• the 0.1 C discharge capacity is 185 mAh/g or higher, and the initial charge-discharge efficiency is 85% or higher, and that they exhibit excellent lifetime when used as a positive electrode active material in a lithium secondary battery.
• the coprecipitation precursor of the composite oxide is preferably in the form particles and obtained by preparing an aqueous solution containing at least a Ni starting compound, a Mn starting compound and a starting compound of metal cation M2 3+ , and initiating precipitation of the composite oxide precursor in the solution.
• the precipitation may be initiated by any method known to a person skilled in the art, for example by adding a complexing agent to the solution, changing the pH or temperature of the solution, or by reducing the volume of the solvent.
• the precipitation in the aqueous solution is initiated by changing the pH of the solution by addition of an alkali aqueous solution.
• M2 is one or more transition metals, which are more preferably selected form V, Fe and Co.
• M2 represents more than one metal
• M2 is Co.
• M3' and M3 are identically one or more transition metals, which are more preferably selected from Mn, Ti, Zr, Ru, Re and Pt, with at least one transition metal being Mn.
• M3/M3' represent one or more further metals besides Mn, for each further metal a respective starting compound is added to the solution.
• M3 and M3' are Mn.
• M2 represents Co
• M3 and M3' represent Mn, each having the valence as defined above.
• the one or more metals M2 and the one or more metals M3/M3' are preferably used as the starting compounds of M1 (i.e., Ni), the one or more metals M2 and the one or more metals M3/M3', with at least one metal being Mn.
• respective metal salts are preferably used.
• the metal salts are not particularly limited, but preferably are at least one of sulfates, nitrates, carbonates, acetates or chlorides, with sulfate salts being most preferred.
• the starting compounds of at least Ni, Mn and a metal cation M2 3+ i.e., the Ni 3+ source, the Mn 3+ /Mn 4+ source and the source of a metal cation M2 3+
• respective metal salts are used, which are independently selected from sulfates, nitrates, carbonates, acetates or chlorides, with sulfate salts being preferred.
• alkali aqueous solution a sodium hydroxide aqueous solution, an ammonia aqueous solution, or a mixture thereof, is preferably used.
• an aqueous solution which is prepared by dissolving therein at least the Ni starting compound, the Mn starting compound and a M2 3+ starting compound such that a molar ratio of each element in the resulting aqueous solution is adjusted to a predetermined range, is simultaneously fed with a sodium hydroxide/ammonia mixed aqueous solution to a reaction vessel of, for example, a precipitating reactor and mixed, before a predetermined residence time is set.
• the Ni starting compound is added in such an amount that the condition 0.7 ⁇ x ⁇ 1, preferably 0.75 ⁇ x ⁇ 0.9, even more preferably 0.8 ⁇ x ⁇ 0.9, and most preferably 0.8 ⁇ x ⁇ 0.85 is satisfied in the general formula of the lithium transition metal composite oxide prepared by the method according to the invention.
• Feeding the metal salts containing aqueous solution and the sodium hydroxide/ammonia mixed aqueous solution simultaneously to a reaction vessel, mixing and setting a residence time in the reaction vessel has a large and advantageous effect on controlling the secondary particle size and the density of the coprecipitated precursor particle to be produced.
• a preferred residence time is affected by a size of the reaction vessel, stirring conditions, a pH, and a reaction temperature, and the residence time is preferably 0.5 h or more.
• the residence time is more preferably 5 h or more, and most preferably 10 h or more.
• the optional doping with element M4, where M4 is one or more selected from B, Mg and Al, preferably one or more selected from Mg and Al, may be performed by any method know to the person skilled in the art.
• a desired amount of a M4 starting compound is added to the aqueous solution containing at least the Ni starting compound, the Mn starting compound and the M2 3+ starting compound.
• a metal salt is preferably used, which may be a sulfate, a nitrate, a carbonate, a halide, or the like, preferably a sulfate.
• index z satisfies the condition 0 ⁇ z ⁇ 0.045.
• index z satisfies the condition 0 ⁇ z ⁇ 0.05, more preferably 0 ⁇ z ⁇ 0.045, even more preferably 0.005 ⁇ z ⁇ 0.045.
• the coprecipitate that is, the coprecipitation precursor of the composite oxide
• a metal hydroxide coprecipitate is obtained as the coprecipitation precursor of the composite oxide.
• the pH of the aqueous solution in the step of coprecipitating the metal hydroxide coprecipitate is not particularly limited, as long as it is in the alkaline (basic) range, but the pH is preferably set equal to or higher than 10.5 when a coprecipitated metal hydroxide is prepared as the coprecipitation precursor of the composite oxide. It is further preferred to control the pH in order to increase a tap density of the coprecipitated precursor. When the pH is adjusted between 10.5 and 12, a tap density of the coprecipitated precursor of 1.6 g/cm 3 or more can be attained. By producing a lithium metal composite oxide using the coprecipitated precursor having a tap density of 1.6 g/cm 3 or more, the initial charge/discharge efficiency and the high rate discharge performance of the lithium secondary battery can be improved.
• the coprecipitate is preferably obtained in the form of particles which remain in suspension and are then filtered off.
• any commonly used method may be used, for example, a centrifuge or a suction filtration device may be used.
• the filtered crude coprecipitate material may be washed by any commonly used method, as long as the method can remove any impurities, such as residual solvent or excess base or complexing agent, if used, from the material obtained. If coprecipitation is performed in aqueous solution, water washing is preferably used, preferably with pure water in order to reduce the impurity content.
• the step of treating the coprecipitation precursor to remove more than 85 %, preferably more than 90 %, even more preferably more than 95 %, of total water from said coprecipitation precursor is not particularly limited.
• the treating of the coprecipitation precursor comprises heating to a temperature of more than 100 °C, or more than 200 °C, 300 °C, 400 °C or 500 °C, in order to evaporate total water and to obtain a composite oxide precursor.
• total water should be understood to include water of crystallization (also called “water of hydration” or “lattice water”), that is, water molecules that are present in the framework or crystal lattice of the coprecipitation precursor due to its formation from aqueous solution, as well as water molecules attached or adsorbed to the surface of the coprecipitation precursor.
• water of crystallization also called “water of hydration” or “lattice water”
• the temperature is preferably not set higher than 600 °C, as high rate discharge performance may be deteriorated.
• the heating temperature in the step of treating the coprecipitation precursor is preferably more than 100 °C to 600 °C, more preferably in the range of 400 oC to 550 oC.
• the treatment of the coprecipitation precursor to remove total water is preferably performed in an oxidizing gas atmosphere, such as air, and is preferably performed for 1 to 10 hours, more preferably for 2 to 8 hours.
• the coprecipitation precursor is heated to a temperature of more than 100 °C to 600°C, preferably in the range of 400 °C to 550 °C, for 1 to 10 hours in air in order to remove the total water.
• the treatment or heating of the coprecipitation precursor to remove total water may be performed in a kiln, for example a rotary kiln or roller hearth kiln, but is not limited thereto.
• a test specimen is dried at certain conditions (for example at 120°C under air) to a constant mass, and the loss of mass of the test specimen due to drying is considered to be water.
• the water content is calculated using the mass of water and the mass of the dry specimen.
• the Li starting compound (Li + source) for preparing the lithium transition metal composite oxide is selected from anhydrous lithium hydroxide (LiOH), lithium hydroxide monohydrate (LiOH ⁇ H 2 O), lithium carbonate (Li 2 CO 3 ), and any mixtures thereof, which is mixed with the heat-treated coprecipitation precursor (i.e., the composite oxide precursor) to obtain a mixture in which a molar ratio of Li and the sum of all metal components (M1, M2, M3/M3' and optionally M4) is in the desired range as defined above.
• anhydrous LiOH is used, which may contain up to 4 wt.% LiOH ⁇ H 2 O.
• the Li starting compound is added such that the condition 0 ⁇ a(1-x-y-z) ⁇ 0.05, preferably 0 ⁇ a(1-x-y-z) ⁇ 0.03, is satisfied in the general formula of the lithium transition metal composite oxide prepared by the method according to the invention.
• the calcining of the mixture comprising the coprecipitation precursor and the Li + source is performed at a temperature of equal to or more than 700 °C, preferably 700 °C to 1000 °C, more preferably 700 °C to 850 °C, preferably in an oxidizing gas atmosphere, such as air.
• a temperature of equal to or more than 700 °C preferably 700 °C to 1000 °C, more preferably 700 °C to 850 °C, preferably in an oxidizing gas atmosphere, such as air.
• the calcination temperature is too low, i.e., below 700 °C, the reaction between lithium and the metal components tends to hardly proceed to a sufficient extend, so that crystallization of the lithium transition metal composite oxide particles does not adequately proceed.
• the metal cations tend to be reduced, for example Ni 3+ tends to be reduced into Ni 2+ , which is then included in the Li + sites, so that the metal occupancy of the Li + sites in the composite oxide is increased.
• the calcination time is preferably 1 to 20 hours, more preferably 6 to 18 hours.
• the calcination may be performed in a kiln, for example a rotary kiln or a roller hearth kiln, without being limited thereto.
• a lithium transition metal composite oxide that contains Li and at least Ni, Mn 3+ /Mn 4+ and an ion M2 3+ mixed in a molar ratio as defined above.
• a crushing or pulverization step can be performed subsequent to calcination using a pulverizer and a classifier for obtaining the powder in a predetermined shape.
• a mortar, a ball mill, a sand mill, a vibration ball mill, a planetary ball mill, a jet mill, a counter jet mill, a swirling air flow jet mill, a sieve or the like is used.
• a purification step to remove impurities remaining from the preparation process may be conducted by any commonly used method.
• the lithium transition metal composite oxide of the present invention and obtained or obtainable using the preparation method according to the present invention, has superior charge-discharge characteristics and exhibits excellent lifetime.
• the 0.1 C discharge capacity is 185 mAh/g or higher, and the initial charge-discharge efficiency is 85% or higher.
• the tap density is between 1.0 to 2.0 g/cm 3 , preferably between 1.6 to 2.0 g/cm 3 .
• a lithium transition metal composite oxide can be provided which has improved performance and lifetime when used as a positive electrode active material in a non-aqueous electrolyte lithium secondary battery.
• the present invention therefore further provides for the use of the lithium transition metal composite oxide according to the invention as positive electrode active material in a non-aqueous electrolyte secondary lithium battery.
• the object of the invention is further solved by a non-aqueous electrolyte secondary battery including a positive electrode which comprises the lithium transition metal composite oxide according to the invention as a positive electrode active material.
• the non-aqueous electrolyte secondary battery comprises the above-mentioned positive electrode, a negative electrode and an electrolyte.
• a positive electrode mixture prepared by adding and mixing a conducting agent and a binder into the positive electrode active material is applied onto a current collector by an ordinary method followed by a drying treatment, a pressurization treatment, and the like.
• a conducting agent include acetylene black, carbon black and graphite.
• the preferred binder include polytetrafluoroethylene and polyvinylidene fluoride.
• materials for the current collector include aluminum, nickel, and stainless steel.
• an electrode comprising a negative electrode active substance such as metallic lithium, lithium/aluminum alloys, lithium/tin alloys, graphite or black lead, or the like may be used, without being limited thereto.
• a solution prepared by dissolving lithium phosphate hexafluoride as well as at least one lithium salt selected from the group consisting of lithium perchlorate, lithium borate tetrafluoride and the like in a solvent may be used, without being limited thereto.
• a solvent for the electrolyte a combination of ethylene carbonate and diethyl carbonate, as well as an organic solvent comprising at least one compound selected from the group consisting of carbonates, such as propylene carbonate and dimethyl carbonate, and ethers, such as dimethoxyethane, may be used, without being limited thereto.
• the non-aqueous electrolyte secondary battery including the positive electrode comprising the positive electrode active material comprising the lithium transition metal composite oxide according to the present invention has excellent lifetime and such an excellent property that an initial discharge capacity thereof is about 185 to about 220 mAh/g.

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• 2018
  • 2018-10-10 EP EP18199542.4A patent/EP3636597A1/de not_active Withdrawn
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