EP2940202B1 - Heat-resistant fabric - Google Patents
Heat-resistant fabric Download PDFInfo
- Publication number
- EP2940202B1 EP2940202B1 EP13869555.6A EP13869555A EP2940202B1 EP 2940202 B1 EP2940202 B1 EP 2940202B1 EP 13869555 A EP13869555 A EP 13869555A EP 2940202 B1 EP2940202 B1 EP 2940202B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- fiber
- resistant fabric
- aromatic polyamide
- meta
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004744 fabric Substances 0.000 title claims description 170
- 239000000835 fiber Substances 0.000 claims description 208
- 239000004760 aramid Substances 0.000 claims description 89
- 229920003235 aromatic polyamide Polymers 0.000 claims description 89
- 238000000034 method Methods 0.000 claims description 55
- 238000005299 abrasion Methods 0.000 claims description 44
- 238000005406 washing Methods 0.000 claims description 41
- 230000014759 maintenance of location Effects 0.000 claims description 29
- 125000003118 aryl group Chemical group 0.000 claims description 23
- 229920000728 polyester Polymers 0.000 claims description 19
- 239000013557 residual solvent Substances 0.000 claims description 16
- 239000006096 absorbing agent Substances 0.000 claims description 14
- -1 aromatic dicarboxylic acid halide Chemical class 0.000 claims description 14
- 238000012360 testing method Methods 0.000 claims description 12
- 229920003043 Cellulose fiber Polymers 0.000 claims description 11
- 239000000975 dye Substances 0.000 claims description 11
- 229920000297 Rayon Polymers 0.000 claims description 9
- 239000002964 rayon Substances 0.000 claims description 9
- 239000004952 Polyamide Substances 0.000 claims description 8
- 229920002647 polyamide Polymers 0.000 claims description 8
- 229920002972 Acrylic fiber Polymers 0.000 claims description 7
- 150000004984 aromatic diamines Chemical class 0.000 claims description 5
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 3
- 125000000524 functional group Chemical group 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000005647 linker group Chemical group 0.000 claims description 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 239000007850 fluorescent dye Substances 0.000 claims description 2
- 125000006157 aromatic diamine group Chemical group 0.000 claims 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 28
- 239000000306 component Substances 0.000 description 20
- 239000002689 soil Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 238000009987 spinning Methods 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000015271 coagulation Effects 0.000 description 11
- 238000005345 coagulation Methods 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
- 150000001408 amides Chemical class 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 229920006231 aramid fiber Polymers 0.000 description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 229920002994 synthetic fiber Polymers 0.000 description 7
- 239000012209 synthetic fiber Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000002085 enols Chemical class 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- YCGKJPVUGMBDDS-UHFFFAOYSA-N 3-(6-azabicyclo[3.1.1]hepta-1(7),2,4-triene-6-carbonyl)benzamide Chemical group NC(=O)C1=CC=CC(C(=O)N2C=3C=C2C=CC=3)=C1 YCGKJPVUGMBDDS-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 238000005562 fading Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000012695 Interfacial polymerization Methods 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000008358 core component Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920006253 high performance fiber Polymers 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- NJMIRMHNYQIHST-UHFFFAOYSA-M 2-dodecylbenzenesulfonate;tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O NJMIRMHNYQIHST-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- WQGNHOQJJZTLIJ-UHFFFAOYSA-M benzyl(tributyl)azanium;2-dodecylbenzenesulfonate Chemical compound CCCC[N+](CCCC)(CCCC)CC1=CC=CC=C1.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O WQGNHOQJJZTLIJ-UHFFFAOYSA-M 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000012770 industrial material Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 238000009970 yarn dyeing Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- YDYSEBSNAKCEQU-UHFFFAOYSA-N 2,3-diamino-n-phenylbenzamide Chemical compound NC1=CC=CC(C(=O)NC=2C=CC=CC=2)=C1N YDYSEBSNAKCEQU-UHFFFAOYSA-N 0.000 description 1
- GOJFAKBEASOYNM-UHFFFAOYSA-N 2-(2-aminophenoxy)aniline Chemical compound NC1=CC=CC=C1OC1=CC=CC=C1N GOJFAKBEASOYNM-UHFFFAOYSA-N 0.000 description 1
- MYEWQUYMRFSJHT-UHFFFAOYSA-N 2-(2-aminophenyl)sulfonylaniline Chemical compound NC1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1N MYEWQUYMRFSJHT-UHFFFAOYSA-N 0.000 description 1
- LNTGGPJSADTYSG-UHFFFAOYSA-N 2-(2-carbonochloridoylphenoxy)benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1OC1=CC=CC=C1C(Cl)=O LNTGGPJSADTYSG-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- FEIVVAUUAPGMES-UHFFFAOYSA-M 2-dodecylbenzenesulfonate;tetraphenylphosphanium Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 FEIVVAUUAPGMES-UHFFFAOYSA-M 0.000 description 1
- UIWFKZBONQGUDI-UHFFFAOYSA-M 2-dodecylbenzenesulfonate;tributyl(tetradecyl)phosphanium Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC UIWFKZBONQGUDI-UHFFFAOYSA-M 0.000 description 1
- ZHTQTFPMOHHUNM-UHFFFAOYSA-M 2-hexylbenzenesulfonate;tetrabutylphosphanium Chemical compound CCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCC[P+](CCCC)(CCCC)CCCC ZHTQTFPMOHHUNM-UHFFFAOYSA-M 0.000 description 1
- WEEOFHJAGVFCFD-UHFFFAOYSA-N 2-n-chlorobenzene-1,2-diamine Chemical compound NC1=CC=CC=C1NCl WEEOFHJAGVFCFD-UHFFFAOYSA-N 0.000 description 1
- RPKCLSMBVQLWIN-UHFFFAOYSA-N 2-n-methylbenzene-1,2-diamine Chemical compound CNC1=CC=CC=C1N RPKCLSMBVQLWIN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- QDBOAKPEXMMQFO-UHFFFAOYSA-N 4-(4-carbonochloridoylphenyl)benzoyl chloride Chemical compound C1=CC(C(=O)Cl)=CC=C1C1=CC=C(C(Cl)=O)C=C1 QDBOAKPEXMMQFO-UHFFFAOYSA-N 0.000 description 1
- LHSXSRQUGCHBPG-UHFFFAOYSA-N 4-(aminomethoxy)aniline Chemical compound NCOC1=CC=C(N)C=C1 LHSXSRQUGCHBPG-UHFFFAOYSA-N 0.000 description 1
- IWRVPXDHSLTIOC-UHFFFAOYSA-N 4-phenyldiazenylbenzene-1,3-diamine Chemical compound NC1=CC(N)=CC=C1N=NC1=CC=CC=C1 IWRVPXDHSLTIOC-UHFFFAOYSA-N 0.000 description 1
- HPFMWXQXAHHFAA-UHFFFAOYSA-N 5-chlorobenzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC(Cl)=CC(C(Cl)=O)=C1 HPFMWXQXAHHFAA-UHFFFAOYSA-N 0.000 description 1
- CGXXBHCRXCEKCP-UHFFFAOYSA-N 5-methoxybenzene-1,3-dicarbonyl chloride Chemical compound COC1=CC(C(Cl)=O)=CC(C(Cl)=O)=C1 CGXXBHCRXCEKCP-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920000561 Twaron Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- ZXKVYIKEMZVNBW-UHFFFAOYSA-M benzyl(tributyl)phosphanium;2-hexylbenzenesulfonate Chemical compound CCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCC[P+](CCCC)(CCCC)CC1=CC=CC=C1 ZXKVYIKEMZVNBW-UHFFFAOYSA-M 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- MPXAYYWSDIKNTP-UHFFFAOYSA-N n-(2-aminophenyl)acetamide Chemical compound CC(=O)NC1=CC=CC=C1N MPXAYYWSDIKNTP-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- VIUHYPPHBQZSPF-UHFFFAOYSA-N naphthalene-1,4-dicarbonyl chloride Chemical compound C1=CC=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1 VIUHYPPHBQZSPF-UHFFFAOYSA-N 0.000 description 1
- NZZGQZMNFCTNAM-UHFFFAOYSA-N naphthalene-2,6-dicarbonyl chloride Chemical compound C1=C(C(Cl)=O)C=CC2=CC(C(=O)Cl)=CC=C21 NZZGQZMNFCTNAM-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000004626 polylactic acid Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
- D01F6/805—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides from aromatic copolyamides
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/0041—Cut or abrasion resistant
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/007—UV radiation protecting
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/04—Heat-responsive characteristics
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/22—Physical properties protective against sunlight or UV radiation
Definitions
- the heat-resistant fabric of the invention is a heat-resistant fabric containing a meta-type wholly aromatic polyamide fiber, characterized in that the abrasion resistance of the heat-resistant fabric in accordance with the JIS L1096 8.19.1 A-1 method (universal type method (plane method), abrasion tester press load: 4.45 N (0.454 kf), paper: #600) is 200 rubs or more, the tear strength of the heat-resistant fabric in accordance with the JIS L1096 8.17.4 D method (pendulum method) is 20 N or more, and the retention of the abrasion resistance and the retention of the tear strength after 100 washes in accordance with JIS L0844 No.
- JIS L1096 8.19.1 A-1 method universal type method (plane method), abrasion tester press load: 4.45 N (0.454 kf), paper: #600
- the tear strength of the heat-resistant fabric in accordance with the JIS L1096 8.17.4 D method pendulum method
- the pilling resistance of the heat-resistant fabric in accordance with the 11. JIS L1096 A method is Level 4 or higher.
- the heat-resistant fabric of the invention it is preferable that the heat-resistant fabric contains cellulose and is dyed with a fluorescent dye.
- the above object can be achieved by using the below-mentioned fiber having improved dyeing affinity and discoloration/fading resistance as a meta-type wholly aromatic polyamide fiber to form the heat-resistant fabric.
- appropriate materials for the heat-resistant fabric are selected, and they are mixed in appropriate proportions.
- the single-fiber toughness of the meta-type wholly aromatic polyamide fiber is 130 or less, more preferably 110 or less, and still more preferably 100 or less.
- the heat-resistant fabric contains at least one member selected from a cellulose fiber, a polyester fiber, an acrylic fiber, and a polyamide fiber in an amount of 2 to 50 mass%, more preferably 2 to 48 mass%, based on the mass of the heat-resistant fabric.
- a specific substituted benzotriazole is preferable.
- Specific examples thereof include 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol, 2-[5-chloro(2H)-benzotriazol-2-yl]-4-methyl-6-(tert-butyl) phenol, 2-[2H-benzotriazol-2-yl]-4-6-bis(1-methyl-1-phenylethyl)ph enol, and 2-[2H-benzotriazol-2-yl]-4-(1,1,3,3-tetramethylbutyl)pheno 1.
- 2-[2H-benzotriazol-2-yl]-4-6-bis(1-methyl-1-phenylethyl)ph enol is particularly preferable because of its high hydrophobicity and low absorption in the visible region.
- a meta-type wholly aromatic aramid fiber was prepared by the following method.
- the spinning dope was discharged and spun from a spinneret (hole diameter: 0.07 mm, the number of holes: 500) into a coagulation bath at a bath temperature of 30°C.
- the spinning dope was discharged and spun into the coagulation bath at a yarn speed of 7 m/min.
- the brightness L was adjusted with a dye so that fabrics after dyeing had an L value of 49 (neutral color) regardless of the foundation fabrics. Redyeing was performed as necessary to accurately control the L value.
- the conditions for dyeing and the conditions for washing a dyed product in a reducing bath (pH 5.5) were as follows.
- Staple fibers of a meta-type wholly aromatic polyamide fiber (MA), a para-type wholly aromatic polyamide fiber (PA), a polyester fiber (PE), and a flame-retardant rayon fiber (RY) were blend-spun in a mass ratio MA/PA/PE/RY of 55/5/15/25 into a spun yarn (36 count, 2-ply yarn), and woven at a weaving density of warp: 100 yarns/25.4 mm and weft: 56 yarns/25.4 mm, thereby giving a twill-woven fabric having an areal weight of 230 g/m 2 .
- the abrasion resistance of the obtained fabric was measured. As a result, the resistance before washing (L0) was 67 rubs, while the resistance after 100 washes (L100) was 41 rubs. Thus, the retention of abrasion resistance (L100/L0 ⁇ 100) was 61%.
- the tear strength of the obtained fabric was measured. As a result, the strength before washing (L0) was 21 N in the longitudinal direction and 10 N in the transverse direction, while the strength after 100 washes (L100) was 11 N in the longitudinal direction and 6 N in the transverse direction. Thus, the retention of tear strength (L100/L0 ⁇ 100) was 52% in the longitudinal direction and 60% in the transverse direction. Further, pilling was Level 3 in the longitudinal direction and Level 3 in the transverse direction.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Woven Fabrics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Coloring (AREA)
- Artificial Filaments (AREA)
- Laminated Bodies (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012287423 | 2012-12-28 | ||
| PCT/JP2013/085353 WO2014104411A1 (ja) | 2012-12-28 | 2013-12-27 | 耐熱布帛 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2940202A1 EP2940202A1 (en) | 2015-11-04 |
| EP2940202A4 EP2940202A4 (en) | 2015-12-23 |
| EP2940202B1 true EP2940202B1 (en) | 2017-02-01 |
Family
ID=51021462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13869555.6A Active EP2940202B1 (en) | 2012-12-28 | 2013-12-27 | Heat-resistant fabric |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20150299905A1 (es) |
| EP (1) | EP2940202B1 (es) |
| JP (1) | JPWO2014104411A1 (es) |
| KR (1) | KR20150103101A (es) |
| CN (1) | CN104903502A (es) |
| BR (1) | BR112015015161A2 (es) |
| CA (1) | CA2895042A1 (es) |
| ES (1) | ES2621358T3 (es) |
| HK (1) | HK1213606A1 (es) |
| MX (1) | MX349902B (es) |
| RU (1) | RU2015131087A (es) |
| TW (1) | TW201504492A (es) |
| WO (1) | WO2014104411A1 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6158602B2 (ja) * | 2013-06-11 | 2017-07-05 | 帝人株式会社 | 伸縮性難燃布帛および繊維製品 |
| CA2960129C (en) * | 2014-09-03 | 2022-07-26 | Teijin Limited | Fabric and fiber product |
| JP6449616B2 (ja) * | 2014-10-23 | 2019-01-09 | 帝人株式会社 | 布帛および繊維製品および布帛の処理方法 |
| EP3585927B1 (en) * | 2017-02-27 | 2023-05-17 | Teijin Aramid GmbH | Textile fabric and workwear manufactured thereof |
| US10612166B1 (en) | 2017-05-03 | 2020-04-07 | Waubridge Specialty Fabrics, Llc | Fire resistant fabric with stitchbonding |
| JP2019014994A (ja) * | 2017-07-06 | 2019-01-31 | 帝人株式会社 | 布帛および繊維製品 |
| WO2020262671A1 (ja) * | 2019-06-28 | 2020-12-30 | 帝人株式会社 | 染色布帛、それを用いた繊維製品、および、布帛の染色方法 |
| WO2021100387A1 (ja) * | 2019-11-18 | 2021-05-27 | 帝人株式会社 | 布帛および防護製品 |
| IT202000005650A1 (it) * | 2020-03-17 | 2021-09-17 | Manteco S P A | Metodo di simulazione dell’invecchiamento di un tessuto |
| JP7448640B2 (ja) * | 2020-04-21 | 2024-03-12 | 帝人フロンティア株式会社 | 撥水性布帛および繊維製品 |
| CN112080812B (zh) * | 2020-08-28 | 2023-11-21 | 泰和新材集团股份有限公司 | 一种舒适性间位芳纶及制备方法 |
| CN113724797B (zh) * | 2021-09-02 | 2024-03-08 | 成都慧成科技有限责任公司 | 一种聚酰胺拉伸成膜稳定性的评价方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1111974A (en) | 1964-06-16 | 1968-05-01 | Certels Ltd | Improvements in or relating to building blocks |
| JP2003147651A (ja) | 2001-11-07 | 2003-05-21 | Toray Ind Inc | 耐熱性複合紡績糸およびそれを用いてなる布帛 |
| JP4447476B2 (ja) * | 2005-01-21 | 2010-04-07 | 一村産業株式会社 | 洗濯耐久性の改善された織編物 |
| CN100343426C (zh) * | 2005-12-29 | 2007-10-17 | 中国人民解放军海军医学研究所 | 一种耐热阻燃织物及其制备方法 |
| CN201074263Y (zh) * | 2006-12-06 | 2008-06-18 | 上海新纺织产业用品有限公司 | 一种高强、复合结构的防护织物 |
| JP5710980B2 (ja) * | 2008-01-04 | 2015-04-30 | サザンミルズ インコーポレイテッドＳｏｕｔｈｅｒｎ Ｍｉｌｌｓ，Ｉｎｃ． | 改善された耐表面磨耗性または耐ピリング性を有する難燃性布地およびそれらを製造する方法 |
| JP5188841B2 (ja) | 2008-03-05 | 2013-04-24 | ユニチカトレーディング株式会社 | 複合紡績糸及び織編物 |
| JP2009249758A (ja) | 2008-04-04 | 2009-10-29 | Toyobo Co Ltd | 被覆性及び耐摩耗性に優れた芯鞘複合糸及び織編物 |
| JP4647680B2 (ja) * | 2008-09-29 | 2011-03-09 | 帝人テクノプロダクツ株式会社 | 易染色性メタ型全芳香族ポリアミド繊維 |
| JP2011202327A (ja) * | 2010-03-26 | 2011-10-13 | Teijin Techno Products Ltd | 易染色性メタ型全芳香族ポリアミド繊維を含む布帛 |
| JP4804590B1 (ja) * | 2010-04-14 | 2011-11-02 | 帝人テクノプロダクツ株式会社 | メタ型全芳香族ポリアミド繊維 |
| JP2012052249A (ja) * | 2010-08-31 | 2012-03-15 | Teijin Techno Products Ltd | 複合紡績糸 |
| CN101967713B (zh) * | 2010-09-13 | 2012-08-29 | 无锡华东创新材料研究院 | 遇热膨胀的阻燃面料及由其制得的防火隔热服装 |
| JP2012154002A (ja) * | 2011-01-27 | 2012-08-16 | Teijin Techno Products Ltd | メタ型全芳香族ポリアミド繊維布帛 |
-
2013
- 2013-12-27 BR BR112015015161A patent/BR112015015161A2/pt not_active Application Discontinuation
- 2013-12-27 TW TW102148758A patent/TW201504492A/zh unknown
- 2013-12-27 CA CA2895042A patent/CA2895042A1/en not_active Abandoned
- 2013-12-27 WO PCT/JP2013/085353 patent/WO2014104411A1/ja active Application Filing
- 2013-12-27 MX MX2015008229A patent/MX349902B/es active IP Right Grant
- 2013-12-27 RU RU2015131087A patent/RU2015131087A/ru not_active Application Discontinuation
- 2013-12-27 US US14/648,769 patent/US20150299905A1/en not_active Abandoned
- 2013-12-27 ES ES13869555.6T patent/ES2621358T3/es active Active
- 2013-12-27 EP EP13869555.6A patent/EP2940202B1/en active Active
- 2013-12-27 KR KR1020157020093A patent/KR20150103101A/ko not_active Application Discontinuation
- 2013-12-27 JP JP2014554635A patent/JPWO2014104411A1/ja active Pending
- 2013-12-27 CN CN201380068177.9A patent/CN104903502A/zh active Pending
-
2016
- 2016-02-16 HK HK16101644.0A patent/HK1213606A1/zh unknown
Non-Patent Citations (1)
| Title |
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| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2940202A1 (en) | 2015-11-04 |
| CA2895042A1 (en) | 2014-07-03 |
| ES2621358T3 (es) | 2017-07-03 |
| WO2014104411A1 (ja) | 2014-07-03 |
| JPWO2014104411A1 (ja) | 2017-01-19 |
| US20150299905A1 (en) | 2015-10-22 |
| TW201504492A (zh) | 2015-02-01 |
| BR112015015161A2 (pt) | 2017-07-11 |
| HK1213606A1 (zh) | 2016-07-08 |
| MX349902B (es) | 2017-08-18 |
| MX2015008229A (es) | 2015-09-29 |
| KR20150103101A (ko) | 2015-09-09 |
| CN104903502A (zh) | 2015-09-09 |
| RU2015131087A (ru) | 2017-02-02 |
| EP2940202A4 (en) | 2015-12-23 |
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