EP2776597B1 - Pièce d'horlogerie ou de bijouterie en or - Google Patents

Pièce d'horlogerie ou de bijouterie en or Download PDF

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Publication number
EP2776597B1
EP2776597B1 EP12784240.9A EP12784240A EP2776597B1 EP 2776597 B1 EP2776597 B1 EP 2776597B1 EP 12784240 A EP12784240 A EP 12784240A EP 2776597 B1 EP2776597 B1 EP 2776597B1
Authority
EP
European Patent Office
Prior art keywords
alloy
weight
gold
silver
timepiece
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP12784240.9A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2776597A1 (fr
Inventor
Stéphane Lauper
Alban Dubach
Denis Vincent
Edwina KLAY
Bruno NEVEU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Swatch Group Research and Development SA
Original Assignee
Swatch Group Research and Development SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Swatch Group Research and Development SA filed Critical Swatch Group Research and Development SA
Priority to EP12784240.9A priority Critical patent/EP2776597B1/fr
Publication of EP2776597A1 publication Critical patent/EP2776597A1/fr
Application granted granted Critical
Publication of EP2776597B1 publication Critical patent/EP2776597B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C27/00—Making jewellery or other personal adornments
    • A44C27/001—Materials for manufacturing jewellery
    • A44C27/002—Metallic materials
    • A44C27/003—Metallic alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C5/00—Alloys based on noble metals
    • C22C5/02—Alloys based on gold
    • G—PHYSICS
    • G04—HOROLOGY
    • G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
    • G04B37/00—Cases
    • G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases

Definitions

  • the invention relates to a timepiece or jewelery made of a gold alloy.
  • the invention also relates to a gold-based alloy, called 18-carat red gold, and more particularly to such an alloy having improved discoloration characteristics.
  • the invention relates to the field of metallurgy of gold alloys for watchmaking, jewelery and jewelery.
  • the document JP 10 245646 discloses an 18-carat gold alloy comprising between 15.0 and 23.0% copper and between 0.3 and 5.0% palladium.
  • the present invention therefore aims to overcome the drawbacks of the aforementioned prior art by providing a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats with improved fade resistance compared to to red gold alloys, typically 5N gold of the prior art.
  • the invention also aims to provide a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats alloy preparations with lower melting points to facilitate its implementation implemented.
  • the invention also aims to provide a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats with lower alloy costs.
  • the invention relates to a timepiece, jewelery or jewelry according to claim 1 of the patent.
  • the invention also relates to a gold-based alloy, called 18-carat red gold, according to claim 9 of the patent.
  • the gold-based alloy (including that of the timepiece of the invention) comprises 1.4% by weight of palladium.
  • the gold-based alloy (including that of the piece of the invention) further comprises between 0.45 and 2.0% by weight of a member selected from the group consisting of iron, zinc, silver and indium or a combination of these latter.
  • the gold-based alloy (including that of the timepiece of the invention) comprises 0.48% by weight of platinum.
  • the gold-based alloy (including that of the timepiece of the invention) further comprises 1.81% by weight of silver.
  • the gold-based alloy (including that of the timepiece of the invention) further comprises by weight at most 1.0% of any one or a combination of the elements chosen from the set comprising gallium, magnesium, calcium, lithium, aluminum, sodium, titanium, molybdenum, tin, silicon, rhodium, zirconium, potassium, and chromium.
  • the gold-based alloy (including that of the timepiece of the invention) comprises, by weight, at most 0.05% of iridium, rhenium, or ruthenium and, advantageously, The alloy comprises by weight 0.01% iridium.
  • timepieces or jewelery as defined by the appended claims are very interesting from the point of view of their color, their brightness and their price.
  • Table 1 shows examples of alloy compositions in weight according to the invention with the exception of alloys No. 103 and No. 113 which respectively represent 18-carat red gold alloy compositions of the prior art. ⁇ u> Table 1 ⁇ / u> No. At. Pd. Cu. Pt. Ag . Ir. 126 773.9 14.0 212.0 0.1 128 769.1 14.0 212.0 4.8 0.1 129 751.0 14.0 212.0 4.8 18.1 0.1 139 751.0 14.0 216.8 18.1 0.1 103 750.7 204.3 45 113 765 210 25
  • Each pellet was immersed in 200 ml of a solution corresponding to the tests shown in Table 2 for 42 days.
  • Each washer was placed at the bottom of a closed bottle ( ⁇ 65 mm, made of polypropylene). For statistical reasons, 3 slices of each alloy of Table 1 were tested for each of the three tests.
  • ⁇ E i The i * - The 0 * 2 + at i * - at 0 * 2 + b i * - b 0 * 2 .
  • L *, a *, b * are the colorimetric values of the samples measured with a "Varian Cary 1 E" colorimeter with a 70mm integrating sphere.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Adornments (AREA)
EP12784240.9A 2011-11-08 2012-11-07 Pièce d'horlogerie ou de bijouterie en or Active EP2776597B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12784240.9A EP2776597B1 (fr) 2011-11-08 2012-11-07 Pièce d'horlogerie ou de bijouterie en or

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11188305 2011-11-08
PCT/EP2012/071962 WO2013068365A1 (fr) 2011-11-08 2012-11-07 Pièce d'horlogerie ou de bijouterie en or
EP12784240.9A EP2776597B1 (fr) 2011-11-08 2012-11-07 Pièce d'horlogerie ou de bijouterie en or

Publications (2)

Publication Number Publication Date
EP2776597A1 EP2776597A1 (fr) 2014-09-17
EP2776597B1 true EP2776597B1 (fr) 2016-02-24

Family

ID=47172613

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12784240.9A Active EP2776597B1 (fr) 2011-11-08 2012-11-07 Pièce d'horlogerie ou de bijouterie en or

Country Status (10)

Country Link
US (1) US10455908B2 (enrdf_load_stackoverflow)
EP (1) EP2776597B1 (enrdf_load_stackoverflow)
JP (2) JP2014530962A (enrdf_load_stackoverflow)
CN (2) CN104011235A (enrdf_load_stackoverflow)
CH (1) CH705653B1 (enrdf_load_stackoverflow)
DE (1) DE212012000198U1 (enrdf_load_stackoverflow)
HK (1) HK1247967A1 (enrdf_load_stackoverflow)
IN (1) IN2014CN04166A (enrdf_load_stackoverflow)
TW (1) TWI551701B (enrdf_load_stackoverflow)
WO (1) WO2013068365A1 (enrdf_load_stackoverflow)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105087996B (zh) * 2015-08-07 2019-08-16 广州番禺职业技术学院 一种用于烧制高温透明珐琅的黄色金合金及其制备方法
CN105087997B (zh) * 2015-08-07 2019-07-23 广州番禺职业技术学院 一种用于烧制高温透明珐琅的红色金合金及其制备方法
EP3165621A1 (fr) * 2015-11-05 2017-05-10 Nivarox-FAR S.A. Procédé de fabrication d'un fil en alliage d'or
EP3220208A1 (fr) * 2016-03-14 2017-09-20 Nivarox-FAR S.A. Composant d'affichage d'horlogerie economique
EP3220212B1 (fr) * 2016-03-16 2024-05-29 The Swatch Group Research and Development Ltd Procédé de décoration d'un composant horloger
CN107760896B (zh) * 2016-08-16 2019-06-07 金亦丁 用于首饰的紫色k金及其制备方法
EP3315620B1 (fr) * 2016-10-25 2020-06-24 Nivarox-FAR S.A. Alliage précieux amagnétique pour applications horlogères
EP3339455B1 (fr) * 2016-12-20 2020-02-05 Montres Breguet S.A. Alliage d'or gris
WO2018178998A1 (en) * 2017-03-27 2018-10-04 Pethe Subodh Hard gold alloy with zirconium, titanium and magnesium for jewelry manufacture
JP6536916B2 (ja) * 2017-08-22 2019-07-03 国立大学法人東京工業大学 アーチファクトレスな超弾性合金
EP3527678B1 (fr) 2018-02-15 2021-06-02 Richemont International S.A. Alliage a base d'or et de cuivre, son procede de preparation et son utilisation
CH714785B1 (it) * 2018-03-15 2022-05-13 Argor Heraeus Sa Lega d'oro resistente alla decolorazione e metodo di produzione della medesima.
CH714786B1 (it) * 2018-03-15 2022-05-13 Argor Heraeus Sa Lega d'oro con colore compatibile allo standard 5N e metodo di produzione della medesima.
KR102066601B1 (ko) * 2018-04-10 2020-01-15 서울시립대학교 산학협력단 Cd free 18K 레드골드용 땜소재
EP3575421B1 (fr) 2018-06-01 2022-09-14 Omega SA Piece d'horlogerie ou de bijouterie ou de joaillerie en alliage a base d'or
CN109136625A (zh) * 2018-09-14 2019-01-04 深圳市品越珠宝有限公司 一种高硬度合金及其制备方法
CN109234564A (zh) * 2018-10-12 2019-01-18 佛山科学技术学院 一种耐磨玫瑰金镀层及其制备工艺
WO2021148862A1 (en) * 2020-01-24 2021-07-29 Argor - Heraeus Sa Tarnishing resistant quinary gold alloy, with color compatible with the 5n standard
IT202000001432A1 (it) * 2020-01-24 2021-07-24 Argor Heraeus Sa Lega d’oro quinaria, resistente al tarnishing, con colore compatibile allo standard 5n
CN111286641B (zh) * 2020-02-26 2021-11-30 深圳市粤豪珠宝有限公司 一种抗变色玫瑰金用补口合金及其制备方法和应用
IT202000014326A1 (it) * 2020-06-16 2021-12-16 Effegi Brevetti Srl Dispositivo di supporto e di fissaggio di ripiani di mobili
EP4015662A1 (fr) * 2020-12-18 2022-06-22 Omega SA Piece d horlogerie, de bijouterie ou de joaillerie en or

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US2135972A (en) * 1936-01-29 1938-11-08 Garlinger Marshall Thom Joseph Coupling and aligning device
DE1287911B (de) * 1961-08-15 1969-04-30 International Nickel Ltd., London Gold-Kupfer-Hartlot
JP3389361B2 (ja) 1995-01-26 2003-03-24 京セラ株式会社 装飾部材およびその製造方法
JPH08325656A (ja) * 1995-06-01 1996-12-10 Kuwayama Kikinzoku:Kk 装飾用ピンク系金合金
CN1085738C (zh) * 1996-06-12 2002-05-29 小笠和男 高纯度金合金及其制造方法
JPH10245646A (ja) * 1997-03-07 1998-09-14 Seiko Epson Corp 金合金、装飾部材、携帯時計及び装飾部材の製造方法
EP0886195B1 (fr) * 1997-06-20 2002-02-13 Montres Rolex Sa Spiral autocompensateur pour oscillateur mécanique balancier-spiral de mouvement d'horlogerie et procédé de fabrication de ce spiral
JPH11335755A (ja) * 1998-05-27 1999-12-07 Ijima Kingin Kogyo Kk メガネ用合金
US7124875B2 (en) * 2002-01-23 2006-10-24 Mitsubishi Denki Kabushiki Kaisha Escalator with high speed inclined section
EP1512766A1 (fr) 2003-09-04 2005-03-09 Rolex Sa Pièce d'horlogerie, de bijouterie ou de joaillerie résistant à la décoloration
EP1512765B1 (fr) * 2003-09-04 2006-12-20 Rolex Sa Pièce d'horlogerie, de bijouterie ou de joaillerie résistant à la décoloration
JP2005082890A (ja) * 2003-09-08 2005-03-31 Ijima Kingin Kogyo Kk 装身具用金合金
WO2008108181A1 (ja) * 2007-03-02 2008-09-12 Citizen Tohoku Co., Ltd. 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材
JP4058101B1 (ja) 2007-05-15 2008-03-05 株式会社ラーピス 装飾用および歯科用金合金
CN101802250A (zh) 2007-09-19 2010-08-11 西铁城控股株式会社 装饰部件
JP5150311B2 (ja) * 2008-03-10 2013-02-20 シチズンホールディングス株式会社 装飾部品
JP4231092B1 (ja) * 2008-03-25 2009-02-25 株式会社ラーピス 鋳放しで時効硬化する歯科用、装飾用および工業製品金合金。

Also Published As

Publication number Publication date
CH705653B1 (fr) 2013-04-30
DE212012000198U1 (de) 2014-07-17
US20140305164A1 (en) 2014-10-16
JP6280532B2 (ja) 2018-02-14
WO2013068365A1 (fr) 2013-05-16
US10455908B2 (en) 2019-10-29
JP2016033263A (ja) 2016-03-10
TW201335389A (zh) 2013-09-01
JP2014530962A (ja) 2014-11-20
IN2014CN04166A (enrdf_load_stackoverflow) 2015-07-17
EP2776597A1 (fr) 2014-09-17
CN107604195A (zh) 2018-01-19
TWI551701B (zh) 2016-10-01
HK1247967A1 (zh) 2018-10-05
CN104011235A (zh) 2014-08-27

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