EP2776597B1 - Golduhr oder schmuckstück - Google Patents
Golduhr oder schmuckstück Download PDFInfo
- Publication number
- EP2776597B1 EP2776597B1 EP12784240.9A EP12784240A EP2776597B1 EP 2776597 B1 EP2776597 B1 EP 2776597B1 EP 12784240 A EP12784240 A EP 12784240A EP 2776597 B1 EP2776597 B1 EP 2776597B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- weight
- gold
- silver
- timepiece
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010931 gold Substances 0.000 title claims description 22
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims description 20
- 229910052737 gold Inorganic materials 0.000 title claims description 20
- 229910045601 alloy Inorganic materials 0.000 claims description 67
- 239000000956 alloy Substances 0.000 claims description 67
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 19
- 229910001112 rose gold Inorganic materials 0.000 claims description 19
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 239000004332 silver Substances 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 229910052741 iridium Inorganic materials 0.000 claims description 8
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 229910052733 gallium Inorganic materials 0.000 claims description 5
- 229910052738 indium Inorganic materials 0.000 claims description 5
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 229910052700 potassium Inorganic materials 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- 229910052702 rhenium Inorganic materials 0.000 claims description 5
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011135 tin Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 4
- ILJUKYMHVYRXLZ-UHFFFAOYSA-N rhodium zirconium Chemical compound [Zr].[Rh] ILJUKYMHVYRXLZ-UHFFFAOYSA-N 0.000 claims 3
- 239000003353 gold alloy Substances 0.000 description 20
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 11
- 238000002845 discoloration Methods 0.000 description 9
- 210000004243 sweat Anatomy 0.000 description 9
- 229910001020 Au alloy Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000003916 acid precipitation Methods 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C27/00—Making jewellery or other personal adornments
- A44C27/001—Materials for manufacturing jewellery
- A44C27/002—Metallic materials
- A44C27/003—Metallic alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/02—Alloys based on gold
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
Definitions
- the invention relates to a timepiece or jewelery made of a gold alloy.
- the invention also relates to a gold-based alloy, called 18-carat red gold, and more particularly to such an alloy having improved discoloration characteristics.
- the invention relates to the field of metallurgy of gold alloys for watchmaking, jewelery and jewelery.
- the document JP 10 245646 discloses an 18-carat gold alloy comprising between 15.0 and 23.0% copper and between 0.3 and 5.0% palladium.
- the present invention therefore aims to overcome the drawbacks of the aforementioned prior art by providing a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats with improved fade resistance compared to to red gold alloys, typically 5N gold of the prior art.
- the invention also aims to provide a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats alloy preparations with lower melting points to facilitate its implementation implemented.
- the invention also aims to provide a timepiece, jewelery or jewelery made in a red gold alloy, 18 carats with lower alloy costs.
- the invention relates to a timepiece, jewelery or jewelry according to claim 1 of the patent.
- the invention also relates to a gold-based alloy, called 18-carat red gold, according to claim 9 of the patent.
- the gold-based alloy (including that of the timepiece of the invention) comprises 1.4% by weight of palladium.
- the gold-based alloy (including that of the piece of the invention) further comprises between 0.45 and 2.0% by weight of a member selected from the group consisting of iron, zinc, silver and indium or a combination of these latter.
- the gold-based alloy (including that of the timepiece of the invention) comprises 0.48% by weight of platinum.
- the gold-based alloy (including that of the timepiece of the invention) further comprises 1.81% by weight of silver.
- the gold-based alloy (including that of the timepiece of the invention) further comprises by weight at most 1.0% of any one or a combination of the elements chosen from the set comprising gallium, magnesium, calcium, lithium, aluminum, sodium, titanium, molybdenum, tin, silicon, rhodium, zirconium, potassium, and chromium.
- the gold-based alloy (including that of the timepiece of the invention) comprises, by weight, at most 0.05% of iridium, rhenium, or ruthenium and, advantageously, The alloy comprises by weight 0.01% iridium.
- timepieces or jewelery as defined by the appended claims are very interesting from the point of view of their color, their brightness and their price.
- Table 1 shows examples of alloy compositions in weight according to the invention with the exception of alloys No. 103 and No. 113 which respectively represent 18-carat red gold alloy compositions of the prior art. ⁇ u> Table 1 ⁇ / u> No. At. Pd. Cu. Pt. Ag . Ir. 126 773.9 14.0 212.0 0.1 128 769.1 14.0 212.0 4.8 0.1 129 751.0 14.0 212.0 4.8 18.1 0.1 139 751.0 14.0 216.8 18.1 0.1 103 750.7 204.3 45 113 765 210 25
- Each pellet was immersed in 200 ml of a solution corresponding to the tests shown in Table 2 for 42 days.
- Each washer was placed at the bottom of a closed bottle ( ⁇ 65 mm, made of polypropylene). For statistical reasons, 3 slices of each alloy of Table 1 were tested for each of the three tests.
- ⁇ E i The i * - The 0 * 2 + at i * - at 0 * 2 + b i * - b 0 * 2 .
- L *, a *, b * are the colorimetric values of the samples measured with a "Varian Cary 1 E" colorimeter with a 70mm integrating sphere.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Adornments (AREA)
Claims (16)
- Zeitmessgerät, Schmuck- oder Juwelierteil, das aus einer Rotgoldlegierung mit 18 Karat ohne Nickel und ohne Kobalt hergestellt ist, deren Zusammensetzung dem Gewicht nach zwischen 75 % und 77,5 % Gold, zwischen 1,35 und 1,45 % Palladium und zwischen 20,1 und 23,8 % Kupfer enthält, wobei die Legierung kein Silber enthält und wobei die Legierung dann, wenn sie Silber enthält, 1,81 Gew.-% Silber enthält, wobei die Legierung außerdem dem Gewicht nach eventuell zwischen 0,45 und 2,0 % eines der Elemente, die unter Eisen, Zink, Silber und Indium oder einer Kombination dieser Letzteren gewählt sind, eventuell 0,48 % Platin, eventuell höchstens 1,0 % irgendeines oder einer Kombination der Elemente, die unter Gallium, Magnesium, Calcium, Lithium, Aluminium, Natrium, Titan, Molybdän, Zinn, Silicium, Rhodium, Zirkonium, Kalium und Chrom gewählt sind, und eventuell dem Gewicht nach höchstens 0,05 % eines der Elemente, die unter Iridium, Rhenium und Ruthenium gewählt sind, enthält.
- Zeitmessgerät oder Schmuck oder Juwelierteil nach Anspruch 1, dadurch gekennzeichnet, dass die Legierung 1,4 Gew.-% Palladium enthält.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach Anspruch 1, dadurch gekennzeichnet, dass die Legierung außerdem zwischen 0,45 und 2,0 Gew.-% eines Elements enthält, das unter Eisen, Zink, Silber und Indium oder einer Kombination dieser Letzteren gewählt ist.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach Anspruch 3, dadurch gekennzeichnet, dass die Legierung 0,48 Gew.-% Platin enthält.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach Anspruch 4, dadurch gekennzeichnet, dass die Legierung 1,81 Gew.-% Silber enthält.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Legierung höchstens 1,0 Gew.-% irgendeines oder einer Kombination der Elemente enthält, die unter Gallium, Magnesium, Calcium, Lithium, Aluminium, Natrium, Titan, Molybdän, Zinn, Silicium, Rhodium, Zirkonium, Kalium und Chrom gewählt sind.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Legierung höchstens 0,05 Gew.-% eines Elements enthält, das unter Iridium, Rhenium und Ruthenium gewählt ist.
- Zeitmessgerät oder Schmuck- oder Juwelierteil nach Anspruch 7, dadurch gekennzeichnet, dass die Legierung 0,01 Gew.-% Iridium enthält.
- Legierung auf der Basis von Rotgold mit 18 Karat ohne Nickel und ohne Kobalt, dadurch gekennzeichnet, dass sie dem Gewicht nach gebildet ist aus:- Gold zwischen 75 % und 77,5 %,- Palladium zwischen 1,35 % und 1,45 %;- Kupfer zwischen 20,1 % und 23,8 %, wobei die Legierung kein Silber enthält und wobei die Legierung dann, wenn sie Silber enthält, 1,81 Gew.-% Silber enthält, wobei die Legierung außerdem eventuell von 0,45 bis 2,0 Gew.-% eines der Elemente, die unter Eisen, Zink, Silber und Indium oder einer Kombination dieser Letzteren gewählt sind, eventuell 0,48 % Platin, eventuell höchstens 1,0 % irgendeines irgendeiner Kombination der Elemente, die unter Gallium, Magnesium, Calcium, Lithium, Aluminium, Natrium, Titan, Molybdän, Zinn, Silicium, Rhodium, Zirkonium, Kalium und Chrom gewählt sind, und eventuell höchstens 0,05 Gew.-% eines der Elemente, die unter Iridium, Rhenium und Ruthenium gewählt sind, enthält.
- Legierung auf Goldbasis nach Anspruch 9, dadurch gekennzeichnet, dass der Gewichtsanteil von Palladium 1,4 % beträgt.
- Legierung auf Goldbasis nach einem der Ansprüche 9 oder 10, dadurch gekennzeichnet, dass sie zwischen 0,45 Gew.-% und 2,0 Gew.-% eines Elements enthält, das aus der Gesamtheit gewählt ist, die Eisen, Zink, Silber und Indium oder eine Kombination dieser Letzteren enthält.
- Legierung auf Goldbasis nach Anspruch 11, dadurch gekennzeichnet, dass sie 0,48 Gew.-% Platin enthält.
- Legierung auf Goldbasis nach Anspruch 12, dadurch gekennzeichnet, dass sie 1,81 Gew.-% Silber enthält.
- Legierung auf Goldbasis nach einem der Ansprüche 9 bis 13, dadurch gekennzeichnet, dass sie höchstens 1,0 Gew.-% irgendeines oder einer Kombination von Elementen enthält, die aus der Gesamtheit, die Gallium, Magnesium, Calcium, Lithium, Aluminium, Natrium, Titan, Molybdän, Zinn, Silicium, Rhodium, Zirkonium, Kalium und Chrom enthält, gewählt sind.
- Legierung auf Goldbasis nach einem der Ansprüche 9 bis 13, dadurch gekennzeichnet, dass sie höchstens 0,05 Gew.-% irgendeines oder einer Kombination von Elementen enthält, die aus der Gesamtheit, die Iridium, Rhenium und Ruthenium enthält, gewählt sind.
- Legierung auf Goldbasis nach Anspruch 15, dadurch gekennzeichnet, dass sie 0,01 Gew.-% Iridium enthält.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12784240.9A EP2776597B1 (de) | 2011-11-08 | 2012-11-07 | Golduhr oder schmuckstück |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11188305 | 2011-11-08 | ||
| EP12784240.9A EP2776597B1 (de) | 2011-11-08 | 2012-11-07 | Golduhr oder schmuckstück |
| PCT/EP2012/071962 WO2013068365A1 (fr) | 2011-11-08 | 2012-11-07 | Pièce d'horlogerie ou de bijouterie en or |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2776597A1 EP2776597A1 (de) | 2014-09-17 |
| EP2776597B1 true EP2776597B1 (de) | 2016-02-24 |
Family
ID=47172613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12784240.9A Active EP2776597B1 (de) | 2011-11-08 | 2012-11-07 | Golduhr oder schmuckstück |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10455908B2 (de) |
| EP (1) | EP2776597B1 (de) |
| JP (2) | JP2014530962A (de) |
| CN (2) | CN104011235A (de) |
| CH (1) | CH705653B1 (de) |
| DE (1) | DE212012000198U1 (de) |
| HK (1) | HK1247967A1 (de) |
| IN (1) | IN2014CN04166A (de) |
| TW (1) | TWI551701B (de) |
| WO (1) | WO2013068365A1 (de) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105087996B (zh) * | 2015-08-07 | 2019-08-16 | 广州番禺职业技术学院 | 一种用于烧制高温透明珐琅的黄色金合金及其制备方法 |
| CN105087997B (zh) * | 2015-08-07 | 2019-07-23 | 广州番禺职业技术学院 | 一种用于烧制高温透明珐琅的红色金合金及其制备方法 |
| EP3165621A1 (de) * | 2015-11-05 | 2017-05-10 | Nivarox-FAR S.A. | Herstellungsverfahren eines drahts aus goldlegierung |
| EP3220208A1 (de) * | 2016-03-14 | 2017-09-20 | Nivarox-FAR S.A. | Preisgünstige komponente für uhrenanzeige |
| EP3220212B1 (de) * | 2016-03-16 | 2024-05-29 | The Swatch Group Research and Development Ltd | Dekorationsverfahren für eine uhrkomponente |
| CN107760896B (zh) * | 2016-08-16 | 2019-06-07 | 金亦丁 | 用于首饰的紫色k金及其制备方法 |
| EP3315620B1 (de) * | 2016-10-25 | 2020-06-24 | Nivarox-FAR S.A. | Nichtmagnetische hochwertige legierung für anwendungen in uhren |
| EP3339455B1 (de) * | 2016-12-20 | 2020-02-05 | Montres Breguet S.A. | Weissgoldlegierung |
| CN110446794B (zh) | 2017-03-27 | 2021-03-26 | 派特·古普塔 | 用于珠宝制造的含锆、钛和镁的硬质金合金 |
| JP6536916B2 (ja) * | 2017-08-22 | 2019-07-03 | 国立大学法人東京工業大学 | アーチファクトレスな超弾性合金 |
| EP3527678B1 (de) | 2018-02-15 | 2021-06-02 | Richemont International S.A. | Legierung auf gold-kupfer-basis, ihr herstellungsverfahren und ihre verwendung |
| CH714785B1 (it) * | 2018-03-15 | 2022-05-13 | Argor Heraeus Sa | Lega d'oro resistente alla decolorazione e metodo di produzione della medesima. |
| CH714786B1 (it) * | 2018-03-15 | 2022-05-13 | Argor Heraeus Sa | Lega d'oro con colore compatibile allo standard 5N e metodo di produzione della medesima. |
| KR102066601B1 (ko) * | 2018-04-10 | 2020-01-15 | 서울시립대학교 산학협력단 | Cd free 18K 레드골드용 땜소재 |
| EP3575421B1 (de) * | 2018-06-01 | 2022-09-14 | Omega SA | Teil einer uhr oder eines schmuckstückes aus einer legierung auf basis von gold |
| CN109136625A (zh) * | 2018-09-14 | 2019-01-04 | 深圳市品越珠宝有限公司 | 一种高硬度合金及其制备方法 |
| CN109234564A (zh) * | 2018-10-12 | 2019-01-18 | 佛山科学技术学院 | 一种耐磨玫瑰金镀层及其制备工艺 |
| IT202000001432A1 (it) * | 2020-01-24 | 2021-07-24 | Argor Heraeus Sa | Lega d’oro quinaria, resistente al tarnishing, con colore compatibile allo standard 5n |
| WO2021148862A1 (en) * | 2020-01-24 | 2021-07-29 | Argor - Heraeus Sa | Tarnishing resistant quinary gold alloy, with color compatible with the 5n standard |
| CN111286641B (zh) * | 2020-02-26 | 2021-11-30 | 深圳市粤豪珠宝有限公司 | 一种抗变色玫瑰金用补口合金及其制备方法和应用 |
| IT202000014326A1 (it) * | 2020-06-16 | 2021-12-16 | Effegi Brevetti Srl | Dispositivo di supporto e di fissaggio di ripiani di mobili |
| EP4015662A1 (de) * | 2020-12-18 | 2022-06-22 | Omega SA | Uhr, schmuck- oder juwelierartikel aus gold |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2135972A (en) * | 1936-01-29 | 1938-11-08 | Garlinger Marshall Thom Joseph | Coupling and aligning device |
| BE621400A (de) * | 1961-08-15 | |||
| JP3389361B2 (ja) * | 1995-01-26 | 2003-03-24 | 京セラ株式会社 | 装飾部材およびその製造方法 |
| JPH08325656A (ja) * | 1995-06-01 | 1996-12-10 | Kuwayama Kikinzoku:Kk | 装飾用ピンク系金合金 |
| ATE224961T1 (de) * | 1996-06-12 | 2002-10-15 | Kazuo Ogasa | Verfahren zur herstellung von einer hochreinen hartgoldlegierung |
| JPH10245646A (ja) * | 1997-03-07 | 1998-09-14 | Seiko Epson Corp | 金合金、装飾部材、携帯時計及び装飾部材の製造方法 |
| ES2171872T3 (es) * | 1997-06-20 | 2002-09-16 | Rolex Montres | Espiral autocompensadora para oscilador mecanico de balancin-espiral para dispositivo de movimiento de relojeria y procedimiento de fabricacion de la espiral. |
| JPH11335755A (ja) * | 1998-05-27 | 1999-12-07 | Ijima Kingin Kogyo Kk | メガネ用合金 |
| US7124875B2 (en) * | 2002-01-23 | 2006-10-24 | Mitsubishi Denki Kabushiki Kaisha | Escalator with high speed inclined section |
| DE03405645T1 (de) * | 2003-09-04 | 2005-09-01 | Rolex Sa | Entfärbungsbeständige Uhr oder Schmuck |
| EP1512766A1 (de) | 2003-09-04 | 2005-03-09 | Rolex Sa | Artikel für Uhren oder Schmuck mit Widerstand gegen Entfärbung |
| JP2005082890A (ja) * | 2003-09-08 | 2005-03-31 | Ijima Kingin Kogyo Kk | 装身具用金合金 |
| JPWO2008108181A1 (ja) * | 2007-03-02 | 2010-06-10 | シチズン東北株式会社 | 金合金被膜、金合金被膜被覆積層体及び金合金被膜被覆部材 |
| JP4058101B1 (ja) * | 2007-05-15 | 2008-03-05 | 株式会社ラーピス | 装飾用および歯科用金合金 |
| US20100255338A1 (en) | 2007-09-19 | 2010-10-07 | Citizen Holdings Co., Ltd. | Decorative part |
| JP5150311B2 (ja) * | 2008-03-10 | 2013-02-20 | シチズンホールディングス株式会社 | 装飾部品 |
| JP4231092B1 (ja) * | 2008-03-25 | 2009-02-25 | 株式会社ラーピス | 鋳放しで時効硬化する歯科用、装飾用および工業製品金合金。 |
-
2012
- 2012-11-07 WO PCT/EP2012/071962 patent/WO2013068365A1/fr active Application Filing
- 2012-11-07 JP JP2014537669A patent/JP2014530962A/ja active Pending
- 2012-11-07 EP EP12784240.9A patent/EP2776597B1/de active Active
- 2012-11-07 TW TW101141368A patent/TWI551701B/zh not_active IP Right Cessation
- 2012-11-07 DE DE212012000198.0U patent/DE212012000198U1/de not_active Expired - Lifetime
- 2012-11-07 CN CN201280054887.1A patent/CN104011235A/zh active Pending
- 2012-11-07 CH CH02281/12A patent/CH705653B1/fr unknown
- 2012-11-07 CN CN201710821015.8A patent/CN107604195A/zh active Pending
- 2012-11-07 IN IN4166CHN2014 patent/IN2014CN04166A/en unknown
- 2012-11-07 US US14/357,053 patent/US10455908B2/en active Active
-
2015
- 2015-11-06 JP JP2015218145A patent/JP6280532B2/ja active Active
-
2018
- 2018-06-07 HK HK18107427.8A patent/HK1247967A1/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW201335389A (zh) | 2013-09-01 |
| US20140305164A1 (en) | 2014-10-16 |
| CN107604195A (zh) | 2018-01-19 |
| JP2016033263A (ja) | 2016-03-10 |
| US10455908B2 (en) | 2019-10-29 |
| CN104011235A (zh) | 2014-08-27 |
| HK1247967A1 (zh) | 2018-10-05 |
| WO2013068365A1 (fr) | 2013-05-16 |
| CH705653B1 (fr) | 2013-04-30 |
| TWI551701B (zh) | 2016-10-01 |
| EP2776597A1 (de) | 2014-09-17 |
| JP6280532B2 (ja) | 2018-02-14 |
| IN2014CN04166A (de) | 2015-07-17 |
| DE212012000198U1 (de) | 2014-07-17 |
| JP2014530962A (ja) | 2014-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2776597B1 (de) | Golduhr oder schmuckstück | |
| EP1512765B1 (de) | Entfärbungsbestängdige Uhr oder Schmuck | |
| EP2954079B1 (de) | Roségold-legierung für uhr | |
| EP1010768B1 (de) | Graue Goldlegierung, ohne Nickel | |
| EP2546371B1 (de) | Weißgold, 18 Karat | |
| KR20240019186A (ko) | 금으로 제조된 타임피스 또는 장신구 또는 보석 장신구의 피스 | |
| CH715061A2 (fr) | Pièce d'horlogerie ou de bijouterie ou de joaillerie en alliage d'or. | |
| EP3527678B1 (de) | Legierung auf gold-kupfer-basis, ihr herstellungsverfahren und ihre verwendung | |
| EP4263890A1 (de) | Uhr, schmuck- oder schmuckstück aus gold | |
| CH717525A2 (fr) | Alliage d'or pour composant horloger, de bijouterie ou de joaillerie. | |
| EP1512766A1 (de) | Artikel für Uhren oder Schmuck mit Widerstand gegen Entfärbung | |
| CH718194A2 (fr) | Pièce d'horlogerie, de bijouterie ou de joaillerie en or. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20140610 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: NEVEU, BRUNO Inventor name: LAUPER, STEPHANE Inventor name: KLAY, EDWINA Inventor name: VINCENT, DENIS Inventor name: DUBACH, ALBAN |
|
| DAX | Request for extension of the european patent (deleted) | ||
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| INTG | Intention to grant announced |
Effective date: 20151026 |
|
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: ICB INGENIEURS CONSEILS EN BREVETS SA, CH Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 776788 Country of ref document: AT Kind code of ref document: T Effective date: 20160315 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602012014987 Country of ref document: DE |
|
| REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20160224 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 776788 Country of ref document: AT Kind code of ref document: T Effective date: 20160224 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160524 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160525 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160624 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 5 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602012014987 Country of ref document: DE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed |
Effective date: 20161125 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161130 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160524 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20161107 |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161130 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 6 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161107 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161107 |
|
| REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20161130 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20121107 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160224 |
|
| P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230615 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20231019 Year of fee payment: 12 Ref country code: DE Payment date: 20231019 Year of fee payment: 12 Ref country code: CH Payment date: 20231201 Year of fee payment: 12 |