EP2660369B1 - Zusammengesetzte spinndüse und verfahren zur herstellung von verbundfasern - Google Patents

Zusammengesetzte spinndüse und verfahren zur herstellung von verbundfasern Download PDF

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Publication number
EP2660369B1
EP2660369B1 EP11853367.8A EP11853367A EP2660369B1 EP 2660369 B1 EP2660369 B1 EP 2660369B1 EP 11853367 A EP11853367 A EP 11853367A EP 2660369 B1 EP2660369 B1 EP 2660369B1
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Prior art keywords
discharge holes
hole
component discharge
polymer
island component
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English (en)
French (fr)
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EP2660369A1 (de
EP2660369A4 (de
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Joji Funakoshi
Seiji Mizukami
Masato Masuda
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Toray Industries Inc
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Toray Industries Inc
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Priority claimed from JP2010289980A external-priority patent/JP5728936B2/ja
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30—Conjugate filaments; Spinnerette packs therefor
    • D01D5/36—Matrix structure; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00—Spinnerette packs; Cleaning thereof
    • D01D4/06—Distributing spinning solution or melt to spinning nozzles

Definitions

  • the present invention relates to a composite spinneret and a method of manufacturing a composite fiber.
  • Fibers using a thermoplastic polymer such as polyester or polyamide are excellent in mechanical characteristics and dimensional stability, and therefore, the fibers have a variety of uses and many fibers provided with various functionalities are developed.
  • the composite fiber includes a core-sheath type fiber, a side-by-side type fiber and an islands-in-the-sea fiber which are attained by using the composite spinneret, and an alloy type fiber which is attained by melt-kneading polymers with each other.
  • the core-sheath type enables to provide sensitive effects such as textures and bulkiness or mechanical properties such as strength, elastic modulus and abrasion resistance which cannot be achieved by fibers of a single component only since a core component is covered with a sheath component.
  • a side-by-side type enables to exhibit a crimping property which cannot be obtained by fibers of a single component only and provide a stretching property and the like.
  • ultrafine fibers having a yarn diameter of monofilament of nano-order can be obtained by eluting an easy-to-elute component (sea component) after melt spinning.
  • the ultrafine fibers exhibit the soft touch and delicacy unavailable from general fibers, and can be applied to artificial leathers and textiles exhibiting new feelings and senses, and since fiber clearances become compact, the ultrafine fibers can be developed for sports clothing requiring wind-breaking capability and water-repelling capability as high-density woven fabrics.
  • the ultrafine fibers have large specific surface areas and high dust collectability, these can be applied to high performance filters or the like, and since ultrafine fibers enter into fine grooves and wipe out dirt, these can also be applied to wiping cloths and precision polishing cloths for precision apparatuses, etc.
  • the core-sheath type enables to provide sensitive effects such as textures and bulkiness or mechanical properties such as strength, elastic modulus and abrasion resistance which cannot be achieved by fibers of a single component only since a core component is covered with a sheath component.
  • a side-by-side type enables to exhibit a crimping property which cannot be obtained by fibers of a single component only and provide a stretching property and the like.
  • a technique of manufacturing a composite fiber by a composite spinneret is generally referred to as a composite spinning method
  • a technique of manufacturing a composite fiber by melt-kneading polymers with one another is generally referred to as a polymer alloy method.
  • the polymer alloy method can be employed; however, there is a limitation in controlling a fiber diameter, and it is difficult to obtain uniform and homogeneous ultrafine fibers.
  • the composite spinning method is supposed to be superior to the polymer alloy method in that a composite polymer stream is precisely controlled by the composite spinneret, and a highly precise form of a yarn cross section can be uniformly and homogeneously formed in the running direction of a yarn.
  • a composite spinneret technology in the composite spinning method is extremely important in stably determining the form of the yarn cross section, and various proposals are heretofore made.
  • Patent Document 1 discloses a composite spinneret as shown in Fig. 12.
  • Fig. 12 (b) is a plan view of the composite spinneret of Patent Document 1
  • Fig. 12 (a) is a partially enlarged plan view of Fig. 12 (b) .
  • a black circle 1 indicates an island component discharge hole for discharging an island component polymer
  • an open circle 4 indicates a sea component discharge hole for discharging a sea component polymer
  • reference numerals 5 and 8 indicate a lowermost layer distribution plate and a distribution groove, respectively.
  • a description of the drawing may not be given by use of the same reference symbol or numeral.
  • Patent Document 1 describes that a plurality of distribution plates are overlaid, and a lowermost layer distribution plate 5, which is provided with distribution grooves 8, island component discharge holes 1 and sea component discharge holes 4, is disposed at the lowest layer of the distribution plates, and an island component polymer of a hard-to-elute component and a sea component polymer of an easy-to-elute component are previously distributed as many streams to the lowermost layer distribution plate 5 by the distribution plate, and then the polymers of both components are discharged from the island component discharge holes 1 and the sea component discharge holes 4, respectively, of the lowermost layer distribution plate 5 to be combined into one immediately after discharging, and thereby, islands-in-the-sea composite fibers can be manufactured.
  • Patent Document 1 also describes that a composite fiber, in which an island form has a hexagonal cross section (honeycomb form) and 61 pieces are uniformly distributed, can be manufactured by using this composite spinneret.
  • the composite spinneret is generally referred to as a spinneret of a distribution plate system.
  • a denier value of the resulting fiber is 0.06 denier (fiber diameter in a trial calculation: about 2.5 ⁇ m) of a micron size and does not reach a nano-order size.
  • an island form has a hexagon in cross section by disposing the sea component discharge holes 4 so as to form a hexagon around the island component discharge hole 1 as an arrangement pattern of a hole group; however, another arrangement pattern of a hole group is not presented, and islands-in-the-sea composite fibers having a variety of island forms may not be obtained in some cases.
  • Fig. 9 and Fig. 10 are a partially enlarged plan view of the composite spinneret of Patent Document 5
  • Fig. 23 is a partially enlarged plan view of the composite spinneret of Patent Document .8.
  • the lowermost layer distribution plate 5 described in Fig. 9 and Fig. 10 is different in name from an upper layer plate 29 in Fig. 23 ; however, these play the same role.
  • the pattern in Patent Document 5 and Patent Document 8 is a pattern in which three or four sea component discharge holes 4 are equally disposed around the island component discharge hole 1 (zigzag alignment), and it appears that islands-in-the-sea composite fibers in which the island component form is polygonal can be obtained at a glance.
  • the island component polymer streams may join with one another.
  • the problem may not be solved in some cases even when changing spinning conditions such as discharge amounts and a ratio between discharge amounts of the respective component polymers, and in the worst case, the production may become impossible and the productivity may be deteriorate in some cases if not changing the composite spinneret.
  • Patent Document 2 discloses a composite spinneret as shown in Fig. 13.
  • Fig. 13 is a schematic sectional view of the composite spinneret of Patent Document 2.
  • a reference numeral 10 indicates a discharge plate
  • a reference numeral 11 indicates a discharge introduction hole
  • a reference numeral 43 indicates a multilayer plate
  • a reference numeral 44 indicates a dividing plate
  • a reference numeral 45 indicates an arrangement plate, respectively.
  • the composite spinneret is configured by laminating the multilayer plate 43, the dividing plate 44, the arrangement plate 45 and the discharge plate 10 in turn, a sea component polymer and an island component polymer which are flown from an upstream side are layered, the layered polymer is partially divided, aligned in another order, and divided again to be changed to a sea-island composite stream having many island components, and ultimately the sea-island composite stream is discharge from the discharge introduction hole 11, and thereby, islands-in-the-sea composite fiber can be manufactured.
  • ultrafine fibers obtained by dissolving the island component are not changed in an islands-in-the-sea structure even in long term spinning, a shape of island is circular and a thickness thereof is uniform, and a fiber diameter can reach the nano-order size.
  • the shape of island of ultrafine fibers obtained by using the composite spinneret of Patent Document 2 is limited to a circular shape or an elliptical shape similar to the circular shape, the ultrafine fibers having a complicated shape such as a polygonal shape of island may not be obtained in some cases.
  • Patent Document 2 since a variation of the actual number of islands to the theoretical number of islands ((maximum number of islands - minimum number of islands)/average number of islands) x 100 [%]) is in a range of ⁇ 20%, the number of islands may not be controlled with high precision in some cases.
  • types of the sea component polymers which can be used are limited to polyethylene and polystyrene, and a variety of polymers (polymers having different structures such as polyester, polyamide, polyphenylenesulfide, and polyolefin) may not be used in some cases.
  • Patent Documents 3 and Document 7 disclose composite spinnerets each is generally known as a pipe system spinneret which manufactures islands-in-the-sea fibers.
  • Fig. 14 is a schematic sectional view of the composite spinneret of Patent Documents 3 and 7.
  • Fig. 14 is a schematic sectional view of the composite spinneret of Patent Documents 3 and 7.
  • a reference numeral 30 indicates a pipe
  • a reference numeral 31 indicates a sea component polymer introduction flow path
  • a reference numeral 32 indicates an island component polymer introduction flow path
  • a reference numeral 33 indicates an upper spinneret plate
  • a reference numeral 34 indicates a middle spinneret plate
  • a reference numeral 35 indicates a lower spinneret plate
  • a reference numeral 40 indicates a distribution chamber for a sea component polymer
  • a reference numeral 41 indicates a pipe insertion hole
  • a reference numeral 42 indicates a spinneret discharge hole, respectively.
  • the spinneret of Patent Document 3 is generally known as a pipe system spinneret, and it is composed of the upper spinneret plate 33 provided with the sea component polymer introduction flow paths 31, the island component polymer introduction flow paths 32 and the pipes 30; the middle spinneret plate 34 provided with the pipe insertion hole 41 with a diameter equal to or larger than an outer diameter of the pipe 30; and the lower spinneret plate 35 provided with the spinneret discharge holes 42.
  • the sea component polymer of an easy-to-elute component is guided from the sea component polymer introduction flow paths 31 to the distribution chamber 40 for a sea component polymer to fill the outer circumference of the pipe 30, and on the other hand, the island component polymer of a hard-to-elute component is guided from the island component polymer introduction flow paths 32 to the pipes 30, and discharged from the pipe 30, and thereby, polymers of both components join with each other to form a sea-island composite cross section, and then a composite polymer is discharged from the spinneret discharge hole 42 through the pipe insertion hole 41, and thereby, islands-in-the-sea composite fibers can be manufactured.
  • the pipe system spinneret of Patent Document 3 has a large problem that since a pipe thickness is added for manufacturing an island, an area per a pipe is increased. Further, since the pipe 30 is press-fitted in the upper spinneret plate 33 and fixed to the upper spinneret plate 33 by welding for manufacturing a spinneret, a welding clearance is required, and since a hole for insertion of the pipe 30 is disposed, a space between pipes cannot be narrowed because of a problem of strength. Accordingly, the pipes 30 may not be arranged in a close-packed state per a unit area and the hole packing density may not be increased, and thus it may be difficult to manufacture ultrafine fibers with a fiber diameter of nano-order size in some cases.
  • the resulting shape of island is limited to a circular shape or an elliptical shape similar to the circular shape, the islands-in-the-sea composite fibers having a complicated shape such as a polygonal shape of island may not be obtained in some cases. Since this spinneret has a low degree of freedom for an arrangement of the pipes 30 and a controllable fiber cross section form is limited, it may be difficult to manufacture fibers in which complicated cross sections are layered in some cases.
  • the sea component polymer introduction flow path 31 is disposed at the outer circumference of a pipe group where the pipes 30 are arranged in a close-packed state, it is difficult to supply an adequate sea component polymer to the center of the pipe group, and particularly the island component polymer streams discharged from the pipes 30 at the center of the pipe group may join with one another in some cases.
  • the above-mentioned problem becomes more remarkable.
  • the spinneret has a problem that the spinneret has a very complicated structure and facility cost is expensive since for example, in order to dispose the sea component polymer introduction flow path 31 in the group of pipes, it is necessary to dispose the sea component polymer introduction flow path 31 by bending the pipe 30 on the way.
  • Fig. 18 is a schematic sectional view of the composite spinneret of Patent Document 6.
  • a reference numeral 25 indicates a discharge hole
  • a reference numeral 55 indicates an upper plate
  • a reference numeral 56 indicates a projection, respectively.
  • Patent Document 6 describes that the distribution of a polymer can be improved by having the projections 56 around the discharge hole 25 and the island component discharge hole 1 in order to distribute the sea component polymer and the island component polymer uniformly, and narrowing a gap between a bottom surface of the upper spinneret plate 33 and a top surface of the projection 56 formed around the discharge hole 25, and a gap between a bottom surface of the upper plate 29 and a top surface of the projection 56 formed around the island component discharge hole 1 to increase a pressure loss.
  • Fig. 15 is a schematic sectional view of the composite spinneret of Patent Document 4.
  • a reference numeral 27 indicates a radial groove and a reference numeral 28 indicates a groove on a concentric circle.
  • Patent Document 4 describes that by forming the radial grooves 27 around the island component discharge hole 1 and the grooves 28 on a concentric circle around the discharge hole 25, islands-in-the-sea composite fibers can be attained, in which the distribution of the sea component polymer is improved and island component streams are prevented from joining with one another even when a ratio of the sea component polymer is low.
  • JP 2007-039858 A discloses a method for forming multiple aggregates having a uniform extremely fine regularly arranged structure and group of aggregates having the same form or different forms in long axial or longitudinal direction in a conjugated fiber obtained by using at least two kinds of polymeric materials having different physical properties such as refractive index, strength, elasticity, etc.
  • This extremely fine regularly arranged structural fiber in which the dimension of the extremely fine structural body and a pitch distance of the extremely fine structural body are also regulated is formed by supplying one of the components of at least two kinds of molten polymeric materials having different physical properties through penetrated holes communicating with the multiple openings separated as a definite arrangement, also supplying other component through a passage installed between the penetrated holes and also a flowing speed and flowing direction-regulating relaxing groove installed in the surroundings communicating with the passage exit, joining the flows in a state of maintaining a definite arrangement structure, then compressing and making as thin at a funnel-formed passage following in lower direction and covering its outer peripheral part with any of a component and then compressing again, or using a spinneret repeating the above processes as multiple steps to increase compression ratio.
  • US 2010/205926 A1 discloses a spinneret for preparing island-in-the-sea yarns, wherein island ingredient supply channels are partitioned into a plurality of groups in a discharge portion.
  • the island-in-the-sea yarns prepared using the spinneret can prevent aggregation of island portions in the center thereof, although the number of island portions is 500 or more. Accordingly, island-in-the-sea yarns are considerably advantageous for the preparation of microfibers, since 500 or more island portions can be disposed in one island-in-the-sea yarn and fineness of island portions can thus be reduced.
  • the island-in-the-sea yarns have an advantage of considerably reduced production costs, since 500 or more microfibers can be produced from one island-in-the-sea yarn. Furthermore, the island-in-the-sea yarns render a specific color according to the ratio of sea portions to island portions and diameter of fibers, without adding chromogenic compounds such as dyes, and are thus applicable to photochromic fibers
  • a composite spinneret which can prevent the island component polymer streams from joining with one another while increasing the hole packing density of the discharge holes for the island component polymer, and thereby, can form various fiber cross sections, particularly heteromorphic cross sections, with high accuracy while maintaining high dimensional stability of the cross section, and a method of manufacturing composite fibers in which melt spinning is performed by a composite spinning machine using the composite spinneret.
  • a composite spinneret for discharging composite polymer streams composed of an island component polymer and a sea component polymer, which is composed of one or more distribution plates in which distribution holes and distribution grooves for distributing the polymer components are formed; and a lowermost layer distribution plate positioned to the downstream side of the distribution plate in the direction of the polymer spinning path, and having formed therein a plurality of island component discharge holes and a plurality of sea component discharge holes, wherein the sea component discharge holes are arranged on a virtual circular line C1 with a radius R1 centered on the island component discharge hole, the sea component discharge holes are arranged on a virtual circular line C2 with a radius R2 centered on the island component discharge hole, and the island component discharge holes are arranged on a virtual circular line C4 with a radius R4 centered on the island component discharge hole, and R1, R
  • the composite spinneret which has a plurality of the distribution plates, wherein in the distribution plates, the number of the distribution holes increases toward the downstream side in the direction of the polymer spinning path, and the distribution groove is formed so as to communicate the distribution hole positioned to the upstream side in the direction of the polymer spinning path with the distribution hole positioned to the downstream side in the direction of the polymer spinning path, and a plurality of distribution holes communicated with an end part of the distribution groove are configured.
  • the composite spinneret wherein with respect to a plurality of polymer flow through paths composed of the distribution hole and the distribution groove within the distribution plate, a diameter of the distribution hole in a path in which a length of the polymer flow through path from an upper end of the distribution plate to the lowermost layer distribution plate is comparatively long is larger than a diameter of the distribution hole in a path in which a length of the polymer flow through path is comparatively short.
  • the composite spinneret wherein at least a part of the sea component discharge hole is present in a region surrounded with two lines commonly circumscribing the neighboring two island component discharge holes.
  • the composite spinneret wherein at least a part of each of at least two of the sea component discharge holes is present in a region surrounded with two lines commonly circumscribing the neighboring two island component discharge holes, and the two sea component discharge holes are located across a line segment connecting centers of the two island component discharge holes.
  • the composite spinneret wherein a thickness of a distribution plate having a distribution groove configured therein at the upstream side in the direction of the polymer spinning path is larger than that at the downstream side.
  • the composite spinneret wherein a diameter DMIN of a minimum hole formed in the distribution plate or the lowermost layer distribution plate, and a thickness BT of a plate in which the minimum hole is formed satisfy the following expression: BT / DMIN ⁇ 2 wherein DMIN represents a diameter (mm) of a minimum hole formed in the distribution plate or the lowermost layer distribution plate, and BT represents a thickness (mm) of the distribution plate or the lowermost layer distribution plate in which the minimum hole is formed.
  • the composite spinneret wherein a thickness of the distribution plate or the lowermost layer distribution plate is 0.1 to 0.5 mm.
  • the composite spinneret wherein a hole packing density of the island component discharge hole is 0.5 hole/mm 2 or more.
  • melt spinning is performed by a composite spinning machine using the above-mentioned composite spinneret in which flow-path pressure losses at the respective flow paths from the distribution plate to the island component discharge holes of the lowermost layer distribution plate are the same, and flow-path pressure losses at the respective flow paths from the distribution plate to the sea component discharge holes of the lowermost layer distribution plate are the same.
  • melt spinning is performed at a ratio of the island component polymer of 50% or more by a composite spinning machine using the composite spinneret.
  • the distribution hole refers to a hole which is formed by combining a plurality of distribution plates into one and plays a role of distributing a polymer in the direction of the polymer spinning path.
  • the distribution groove refers to a groove which is formed by combining a plurality of distribution plates into one and plays a role of distributing a polymer in the direction perpendicular to the direction of the polymer spinning path.
  • the distribution groove may be a long and thin hole (slit), or a long and thin groove may be cut.
  • the direction of the polymer spinning path refers to a main direction in which the respective polymer components flow from a metering plate to a spinneret discharge hole of a discharge plate.
  • the direction perpendicular to the direction of the polymer spinning path refers a direction perpendicular to the main direction in which the respective polymer components flow from a metering plate to a spinneret discharge hole of a discharge plate.
  • the virtual circular line C1 with a radius R1 refers to a virtual circular line C1 in which a center distance between an island component discharge hole as a reference and a sea component discharge hole closest to the island component discharge hole as a reference is a radius R1.
  • the virtual circular line C2 with a radius R2 refers to a virtual circular line C2 in which a center distance between an island component discharge hole as a reference and a sea component discharge hole second closest to the island component discharge hole as a reference is a radius R2.
  • the virtual circular line C4 with a radius R4" refers to a virtual circular line C4 in which a center distance between an island component discharge hole as a reference and an island component discharge hole closest to the island component discharge hole as a reference is a radius R4.
  • the center angle refers to an angle at which two line segments connecting the center of the island component discharge hole as a reference and centers of two sea component discharge holes adjacent to each other in a circumferential direction, which are arranged on the virtual circular line C1, or C2 intersect, or an angle at which two line segments connecting the center of the island component discharge hole as a reference and centers of two island component discharge holes adjacent to each other in a circumferential direction, which are arranged on the virtual circular line C4 intersect.
  • the phase angle refers to an angle at which a line segment connecting the center of the island component discharge hole as a reference and the center of the sea component discharge hole arranged on the virtual circular line C1, and a line segment connecting the center of the island component discharge hole as a reference and the center of the sea component discharge hole arranged on the virtual circular line C2 intersect, or an angle at which a line segment connecting the center of the island component discharge hole as a reference and the center of the sea component discharge hole arranged on the virtual circular line C1, and a line segment connecting the center of the island component discharge hole as a reference and the center of the island component discharge hole arranged on the virtual circular line C4 intersect.
  • the polymer flow through path refers to a path formed by communicating the distribution hole formed within the distribution plate with the distribution groove formed within the distribution plate.
  • the hole packing density refers to a value determined by dividing the number of island component discharge holes for discharging an island component polymer by a cross section area of the discharge introduction hole.
  • the hole packing density is larger, a composite fiber is obtained which is composed of more island component polymers.
  • the island-component polymer is uniformly distributed and the island component polymer streams are prevented from joining with one another while increasing the hole packing density of the discharge holes for the island component polymer, and thereby, various fiber cross sections, particularly heteromorphic cross sections, are formed with high accuracy while maintaining high dimensional stability of the cross section.
  • FIG. 5 is a schematic sectional view of a composite spinneret used in an embodiment of the present invention
  • Fig. 7 is a view taken in the direction of arrows X-X in Fig. 5
  • Fig. 1 is a partially enlarged plan view of Fig. 7
  • Figs. 2 , 3, 4 and 16 are respectively a partially enlarged plan view of a lowermost layer distribution plate used in another embodiment of the present invention
  • Fig. 6 is a schematic sectional view of a composite spinneret, and surroundings of a spin pack and a cooling apparatus, which are used in an embodiment of the present invention
  • 17 , 20 , 21, 22 , 31 and 38 are respectively a schematic partially sectional view of a distribution plate and a lowermost layer distribution plate used in an embodiment of the present invention.
  • these are conceptual drawings for correctly expressing the essential points of the present invention and are simplified, and the composite spinneret of the present invention is not limited to these, and the number of holes and grooves, and a dimensional ratio of holes and grooves may be changed according to the embodiment.
  • a composite spinneret 18 used in an embodiment of the present invention is fitted in a spin pack 15 and fixed in a spin block 16, and a cooling apparatus 17 is configured immediately below the composite spinneret 18.
  • Two types or more of polymers introduced into the composite spinneret 18 respectively pass through a metering plate 9, a distribution plate 6 and a lowermost layer distribution plate 5, and are discharged from a spinneret discharge hole 42 of a discharge plate 10 and then cooled by an air stream blown out from the cooling apparatus 17 and provided with a spinning oil, and then the polymers are taken up as islands-in-the-sea composite fibers.
  • a metering plate 9 As shown in Fig. 6 , a composite spinneret 18 used in an embodiment of the present invention is fitted in a spin pack 15 and fixed in a spin block 16, and a cooling apparatus 17 is configured immediately below the composite spinneret 18.
  • Two types or more of polymers introduced into the composite spinneret 18 respectively pass through a metering plate 9, a
  • the annular cooling apparatus 17 which blows an air stream annually-inwardly is employed; however, a cooling apparatus which blows an air stream from one direction may be used.
  • a cooling apparatus which blows an air stream from one direction may be used.
  • a flow path or the like used in the existing spin pack 15 may be used, and the member does not need to be exclusive.
  • the composite spinneret 18 used in an embodiment of the present invention is configured by laminating the metering plate 9, at least one distribution plate 6, the lowermost layer distribution plate 5 and the discharge plate 10 in turn, and particularly the distribution plate 6 and the lowermost layer distribution plate 5 are preferably composed of a thin plate.
  • the metering plate 9 and the distribution plate 6, and the lowermost layer distribution plate 5 and the discharge plate 10 are positioned so as to be aligned with a center position (core) of the spin pack 15 by a locating pin, laminated, and then may be fixed by a screw or bolt, or may be metal-joined (diffusion-bonded) by thermocompression bonding.
  • the distribution plates 6, and the distribution plate 6 and the lowermost layer distribution plate 5 are preferably metal-joined (diffusion-bonded) with each other by thermocompression bonding since a thin plate is used for these plates.
  • a thickness of the thin plate is preferably in a range of 0.01 to 1 mm, and further suitably 0.1 to 0.5 mm.
  • the thickness of the thin plate is small, there are advantages that hole diameters, groove widths and hole pitches/groove pitches of processable holes/grooves can be reduced and hence the hole packing density can be increased.
  • the hole packing density can be more increased.
  • the hole packing density can be more increased as with the above-mentioned case.
  • the hole packing density can be more increased; however, further in order to minimize uneven discharge of the island component polymer, the BT and the DMIN more preferably satisfy the expression (3).
  • a type of a polymer capable of being used may be limited in some cases (with a high viscous polymer, a pressure loss is increased and bending occurs). In this case, a whole thickness may be increased by laminating and metal-joining a plurality of thin plates to improve the strength. Further, the strength per a plate is improved by increasing the thickness of the thin plate, and therefore there is an advantage of increasing a type of polymer capable of being used.
  • a thickness of the distribution plate having the great number of holes may be reduced, and a thickness of the distribution plate having the smaller number of holes may be increased.
  • polymers of the respective components supplied from the metering plate 9 pass through the distribution groove 8 and a distribution hole 7 of the distribution plate 6 formed by laminating at least one plate, and then are discharged from the island component discharge hole 1 for discharging an island component polymer and a sea component discharge hole 4 for discharging a sea component polymer of the lowermost layer distribution plate 5, and thereby, the polymers of the respective components join with each other to form a composite polymer stream. Thereafter, the composite polymer stream passes through a discharge introduction hole 11 and a contracting hole 12 of the discharge plate 10, and is discharged from the spinneret discharge hole 42.
  • all of diameters of the island component discharge holes 1 disposed in the lowermost layer distribution plate 5 are preferably the same, and all of diameters of the sea component discharge holes 4 disposed in the lowermost layer distribution plate 5 are preferably the same.
  • the diameters of the island component discharge hole 1 and the sea component discharge hole 4 are preferably in a range of 0.03 to 0.8 mm, and further suitably in a range of 0.05 to 0.5 mm.
  • the island component polymer streams can be prevented from joining with one another while increasing the hole packing density of the composite spinneret 18, and various fiber cross sections, particularly heteromorphic cross sections, can be formed with high accuracy.
  • the island component discharge holes 1 need to be close to one another as much as possible, and in this case, island-component polymer streams join with one another between neighboring island component discharge holes. For example as shown in Fig.
  • joining of the island component polymer streams in the case where a cross section of the island component has a circular shape takes place mainly on a line connecting centers of neighboring island component discharge holes 1; however, joining of the island component polymer streams in the case where a cross section of the island component is a heteromorphic cross section having a plurality of edge (corner) portions takes place not only on the line connecting gravity centers of the island component discharge holes 1, but also between neighboring edge portions.
  • the sea component discharge holes 4 are arranged on the virtual circular line C1 with a radius R1, centered on the island component discharge hole 1, the sea component discharge holes 4 are arranged on the virtual circular line C2 with a radius R2, centered on the island component discharge hole 1, and the island component discharge holes 1 are arranged on the virtual circular line C4 with a radius R4, centered on the island component discharge hole 1, and these discharge holes are arranged to satisfy the expression (1) and according to any one of the conditions (2) (a) to (2) (d) .
  • the conditions (2) (a) and (2) (b) indicate an arrangement pattern of the island component discharge holes 1 and the sea component discharge holes 4 by which the island component has a triangle cross section
  • the condition (2)(c) indicates an arrangement pattern thereof by which the island component has a hexagonal cross section
  • the condition (2)(d) indicates an arrangement pattern thereof by which the island component has a tetragonal cross section.
  • both the island component polymer and the sea component polymer are discharged all together toward the discharge introduction hole 11 located the downstream side of the lowermost layer distribution plate 5, flow in the direction of the polymer spinning path while expanding their width in the direction perpendicular to the direction of the polymer spinning path, and join with one another to form a composite polymer.
  • an important role of the sea component discharge holes 4a on the virtual circular line C1 is to form a heteromorphic cross section of the island component. This partially suppresses the expansion of width of the island-component polymer discharged from the island component discharge hole 1 as a reference, that is, the expansion of width of the island-component polymer is suppressed from three point by arranging three sea component discharge holes 4a equally at a center angle of 120 degrees in order to form a triangle cross section of the island-component polymer.
  • the sea component discharge holes 4b on the virtual circular line C2 are arranged equally at a center angle of 120 degrees with a phase angle between the discharge hole on the C1 and the discharge hole on the C2 being 60 degrees, the island-component polymer flown out from between the sea component discharge holes 4a is suppressed by the sea component polymer discharged from the sea component discharge hole 4b.
  • the sea component discharge holes 4a and the sea component discharge holes 4b have a phase difference and are respectively arranged on the virtual circular line C1 and the virtual circular line C2 having different radii
  • the sea component discharge holes 4a arranged on an inner circumference side has a role of forming a side of the triangle cross section
  • the sea component discharge holes 4b arranged on an outer circumference side has a role of forming an edge (corner) portion of the triangle cross section.
  • these discharge holes have a role of suppressing joining of the island-component polymer stream discharged from the island component discharge hole 1 as a reference to the island-component polymer stream discharged from the island component discharge hole 1a on the virtual circular line C4.
  • the radius R4 of the virtual circular line C4 may be reduced to bring the island component discharge hole 1 as a reference closer to the island component discharge hole 1a, and in this case, the present inventors have found that the island-component polymer streams discharged from respective island component discharge holes expand their widths and there is a limiting distance at which the island-component polymer streams join with one another.
  • the hole arrangement whereby the island-component polymer streams can be prevented from joining with one another while forming a space to adequately expand the island-component polymer discharged from the island component discharge hole 1 in a space sandwiched between the virtual circular line C1 and the virtual circular line C2 is a key. That is, in order to achieve this, the radius R4, which is a center distance between the island component discharge hole 1 as a reference and the island component discharge hole 1a adjacent to the island component discharge hole 1 as a reference, may be determined to satisfy the expression (1).
  • this arrangement is characterized in that the great number of islands can be arranged to increase the island packing density; however, a ratio of the island-component polymer may not be increased to 50% or more in some cases, this arrangement is suitable for achieving composite fibers with fiber diameter of nano-order size such as nano-fibers.
  • other arrangement patterns in which the island component has a triangle cross section include the arrangement according to the condition (2)(b).
  • three sea component discharge holes 4 are arranged equally at a center angle of 120 degrees on a virtual circular line C1 around the island component discharge hole 1 as a reference, and three island component discharge holes 1 are arranged equally at a center angle of 120 degrees on an outer virtual circular line C4 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C4 being 0 degree, and three sea component discharge holes 4 are arranged equally at a center angle of 120 degrees on an outer virtual circular line C2 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C2 being 60 degrees.
  • a ratio of the island-component polymer can be large, and fibers can be obtained, in which the island component polymer streams do not join with one another and the island component has a uniform triangle cross section even at an island ratio as high as 70% or more.
  • an arrangement pattern in which the island component has a hexagonal cross section includes the arrangement according to the condition (2)(c).
  • the arrangement according to the condition (2)(c) six sea component discharge holes 4 are arranged equally at a center angle of 60 degrees on a virtual circular line C1 around the island component discharge hole 1 as a reference, and six island component discharge holes 1 are arranged equally at a center angle of 60 degrees on an outer virtual circular line C4 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C4 being 30 degree, and six sea component discharge holes 4 are arranged equally at a center angle of 60 degrees on an outer virtual circular line C2 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C2 being 30 degrees.
  • the hole packing density can be large and a ratio of the island-component polymer can be large, and fibers can be obtained, in which the island component polymer streams do not join with one another and the island component has a uniform hexagonal cross section even at an island ratio as high as 70% or more.
  • an arrangement pattern in which the island component has a tetragonal cross section includes the arrangement according to the condition (2)(d).
  • four sea component discharge holes 4 are arranged equally at a center angle of 90 degrees on a virtual circular line C1 around the island component discharge hole 1 as a reference, and four island component discharge holes 1 are arranged equally at a center angle of 90 degrees on an outer virtual circular line C4 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C4 being 0 degree, and eight sea component discharge holes 4 are arranged on an outer virtual circular line C2 of the virtual circular line C1 with a phase angle between the discharge hole on the C1 and the discharge hole on the C2 being 26.6 degrees.
  • the hole packing density can be large and a ratio of the island-component polymer can be large, and fibers in which the island component has a uniform tetragonal cross section can be obtained even at an island ratio as high as 70% or more.
  • a plurality of the distribution plates 6 are provided, and the plural laminated distribution plates 6 are configured in such a way that the number of the distribution holes 7 formed in the distribution plate 6 increases toward the downstream side in the direction of the polymer spinning path, and the distribution groove 8 is formed so as to communicate the distribution hole 7 positioned to the upstream side in the direction of the polymer spinning path with the distribution hole 7 positioned to the downstream side in the direction of the polymer spinning path by alternately laminating a distribution plate 6 in which a distribution hole 7 guiding a polymer in the direction of the polymer spinning path is formed and a distribution plate 6 in which the distribution groove 8 guiding a polymer in the direction perpendicular to the direction of the polymer spinning path is formed.
  • the distribution hole 7 is formed on one surface of one distribution plate 6 and the distribution groove 8 is formed on the other surface of one distribution plate 6, and the distribution hole 7 is communicated with the distribution groove 8.
  • the distribution hole 7 may be formed through the distribution plate 6, or the distribution groove 8 may be formed through the distribution plate 6.
  • a flow through path of a polymer of a sequential branch system in which the distribution groove 8 in communication with a position at the downstream side in the direction of the polymer spinning path is formed per one distribution hole 7 and a plurality (two in Fig. 17 ) of the distribution holes 7 in communication with an end of the distribution groove 8 are formed.
  • the lengths of paths from the distribution hole 7 or the distribution groove 8 of the distribution plate 6 positioned at the highest end in the direction of the polymer spinning path to the island component discharge holes 1 of the lowermost layer distribution plate 5 are equal.
  • the flow through path of a polymer has a structure in which hole diameters of the distribution holes 7, and widths, depths and lengths of the distribution grooves 8 are equalized in each distribution plate 6 of the laminated plural distribution plates 6.
  • a hole diameter of the distribution hole 7 or a width or depth of the distribution groove 8 is increased sequentially to suppress an increase in the flow-path pressure loss.
  • the flow through path of a polymer of a sequential branch system of two-way branch is suitable, in which one distribution groove 8 is communicated with two distribution holes 7 at the downstream side in the direction of the polymer spinning path; however, the sequential branch system is not limited to this.
  • the distribution groove 8 is communicated with two or more distribution holes 7 (the case of a flow path of a sequential branch system of two-way or more branch)
  • this structure has an advantage of eliminating abnormal retention of a polymer, and uniformly distributing and precisely controlling a polymer.
  • examples of other structure in which flow-path pressure losses of the flow through paths of the respective polymers are equalized, include structures with respect to a plurality of polymer flow through paths composed of the distribution hole 7 and the distribution groove 8 within the distribution plate 6, a diameter of the distribution hole 6 in a path in which a length of the polymer flow through path from an upper end of the distribution plate 6 to the lowermost layer distribution plate 5 of the distribution plate 6 is comparatively long is larger than a diameter of the distribution hole 6 in a path in which a length of the polymer flow through path is comparatively short, and thereby, it becomes possible to equalize flow-path pressure losses.
  • examples of other structure in which flow-path pressure losses of the flow through paths of the.respective polymers are equalized, include structures in which a diameter of the island component discharge hole 1 of the lowermost layer distribution plate 5 is adjusted so that flow-path pressure losses are equalized in the respective flow paths of the distribution plate 6 on the upstream side thereof. Specifically, it becomes possible to equalize flow-path pressure losses by increasing a diameter of the island component discharge hole 1 in communication with a flow path having a large flow-path pressure loss, and decreasing a diameter of the island component discharge hole 1 in communication with a flow path having a smaller flow-path pressure loss on the upstream side.
  • one distribution groove 8 is communicated with a plurality of the distribution holes 7 on the downstream side in the direction of the polymer spinning path, and communicated with a plurality of the distribution holes 7 on the upstream side in the direction of the polymer spinning path, it becomes possible to equalize flow-path pressure losses by employing, as the structure of equalizing flow-path pressure losses of the flow through paths of the respective polymers, a structure in which a diameter of the distribution hole 7 positioned at an end part of the distribution groove 8 is increased as compared with a central part in order to equalize flow rates of polymers passing through the distribution hole 7 in communication with the central part and the distribution hole 7 in communication with the end part of the distribution groove 8.
  • the distribution hole 7 disposed in the distribution plate 6 distributes a polymer mainly in the direction of the polymer spinning path
  • the distribution groove 8 distributes a polymer mainly in the direction perpendicular to the direction of the polymer spinning path
  • the polymer can be freely and easily distributed in the direction of a fiber cross section, and by using this, the sea component discharge holes 4 can be arranged in an extremely narrow region between neighboring island component discharge holes 1.
  • the distribution holes 7 and the distribution grooves 8 are preferably disposed in the distribution plate 6 immediately above the lowermost layer distribution plate 5.
  • the distribution hole 7 is communicated with the island component discharge hole 1
  • the distribution groove 8 is communicated with the sea component discharge hole 4.
  • the distribution groove 8 can be arranged at a position closer to the distribution hole 7, and the sea component discharge hole 4 communicated with the distribution groove 8 can be arranged in a state of being closer to the island component discharge hole 1, and the hole packing density can be increased.
  • the distribution plate 6 immediately above the lowermost layer distribution plate 5 when the downstream side of the distribution groove 8 in the direction of the polymer spinning path is communicated with the distribution hole 7 as shown in Fig.
  • the distribution plate 6 and the lowermost layer distribution plate 5 of the present invention have a laminate structure of thin plates.
  • a shape of the composite spinneret 18 in the present invention is not limited to a circular shape, and may be a tetragonal shape or a polygonal shape. Further, an array of the spinneret discharge hole 42 in the composite spinneret 18 may be appropriately determined according to the number of the islands-in-the-sea composite fibers, the number of line of yarn, and the cooling apparatus 17. With respect to the cooling apparatus 17, for an annular cooling apparatus, the spinneret discharge holes 42 may be arrayed in an annular form over one column or plural columns, and for a cooling apparatus of one way, the spinneret discharge holes 42 may be arrayed in zigzag alignment.
  • a cross section of the spinneret discharge hole 42 in the direction perpendicular to the direction of the polymer spinning path is not limited to a circular shape, and may be a cross section other than the circular shape or a hollow cross section. However, a cross section other than the circular shape is employed, a length of the spinneret discharge hole 42 is preferably lengthened in order to ensure the polymer metering capability.
  • a cross section in the direction perpendicular to the direction of the polymer spinning path is not limited to a circular shape, and may be a cross section other than the circular shape or a hollow cross section.
  • all shapes of the island component discharge holes 1 disposed in the lowermost layer distribution plate 5 are preferably the same.
  • the island component discharge hole 1 is previously shaped to a similar shape, and therefore, fibers with a heteromorphic cross section are easily obtained.
  • the island component discharge hole 1 has a cross section other than a circular shape
  • a cross section in the direction perpendicular to the direction of the polymer spinning path is not limited to a circular shape, and may be a cross section shape other than the circular shape.
  • all shapes of the sea component discharge holes 4 disposed in the lowermost layer distribution plate 5 are preferably the same.
  • the discharge introduction hole 11 in the present invention can mitigate a difference in flow velocities immediately after the island component polymer stream joins with the sea component polymer stream by providing a certain entrance section from a bottom surface of the lowermost layer distribution plate 5 in the direction of the polymer spinning path to stabilize a composite polymer stream.
  • a diameter of the discharge introduction hole 11 is preferably configured to be larger than an outer diameter of a virtual circle 52 of a group of discharge holes of the island component discharge holes 1 and the sea component discharge holes 4 disposed in the lowermost layer distribution plate 5, and is preferably configured in such a way that a ratio of a cross section area of the virtual circle 52 to a cross section area of the discharge introduction hole 11 is as small as possible.
  • the contracting hole 12 in the present invention it is possible to inhibit unstable phenomena such as draw resonance of the composite polymer stream and supply the composite polymer stream stably by setting a taper angle ⁇ of a flow path from the discharge introduction hole 11 to the spinneret discharge hole 42 to a range of 50 to 90°.
  • a taper angle ⁇ is less than 50°, the unstable phenomena of the composite polymer stream can be inhibited; however, the composite spinneret 18 itself grows in size, and when the taper angle ⁇ is more than 90°, the unstable phenomena of the composite polymer stream may become more remarkable.
  • the island component discharge hole 1, the sea component discharge hole 4 and the distribution hole 7 in the present invention preferably have a hole cross section area which is constant in the direction of the polymer spinning path; however, the hole cross section area may gradually decrease or may increase, or may gradually decrease and increase.
  • the reason for this is that in the distribution plate 6 and the lowermost layer distribution plate 5 in the present invention, since hole processing is mainly performed by using etching processing, the hole cross section area may not become constant in the direction of the polymer spinning path in some cases in processing minute holes, and in this case, processing conditions and the like may be appropriately made to be proper.
  • the number of the lowermost layer distribution plates 5 in the present invention may be one; however, a plurality of the lowermost layer distribution plates 5 may be laminated. In case that one lowermost layer distribution plate 5 cannot achieve the polymer metering capability of the island component discharge holes 1 and the sea component discharge holes 4, and a fiber form varies with time, the metering capability of a polymer can be ensured by laminating a plurality of the lowermost layer distribution plates 5.
  • the distribution hole 7 may be disposed to the upstream side of the distribution plate 6, and the distribution groove 8 (downstream side) may be disposed in communication with the distribution hole 7, or the distribution groove 8 may be arranged to the upstream side of the distribution plate 6, and the distribution hole 7 (downstream side) may be disposed in communication with the distribution groove 8.
  • the polymer can be distributed by communicating the distribution hole 7 with the distribution groove 8 and repeating the communication once or more.
  • a sequential branch system is most preferred; however, as shown in Fig. 38 , a slit system may be employed, in which one distribution groove 8 is configured for a plurality of the distribution holes 7, or a plurality of the distribution grooves 8 are configured for a plurality of the distribution holes 7, or a combined method which is a combination of the sequential branch system and the slit system may be employed.
  • polymers of other components employ the same distribution method as described above; however, for the sake of simplicity, only the case of a polymer of one component will be described.
  • the sequential branch system has, as described above, an advantage of eliminating abnormal retention of a polymer, and uniformly distributing and precisely controlling a polymer by disposing the distribution hole 7 at an end part of the distribution groove 8.
  • the distribution hole 7 is clogged with a polymer in production, the polymer is not distributed to the downstream side, and consequently fibers with a desired composite cross section may not be obtained in some cases.
  • the slit system is highly responsible for the problems of clogging in the hole or groove since a plurality of the distribution holes 7 are formed for one distribution groove 8, and the slit system has an advantage of keeping manufacturing costs of the composite spinneret 18 low since one distribution plate 6 can distribute many polymers in the direction perpendicular to the direction of the polymer spinning path to reduce the number of the distribution plate 6.
  • abnormal retention of a polymer easily occurs, and this method may be inferior in precise control of polymer distribution to the sequential branch system in some cases.
  • a combined method in which the slit system is configured at the upstream side (metering plate 9 side), and the sequential branch system is configured at the downstream side (lowermost layer distribution plate 5 side), and defective polymer distribution due to clogging of the hole or groove is eliminated at the upstream side and metering capability of a polymer is enhanced at the downstream side to distribute the polymer uniformly.
  • a method of enhancing metering capability of a polymer in which in the case where a polymer of one component passes through the distribution hole 7 (flow-in side), the distribution groove 8 and the distribution hole 7 (flow-out side), a diameter of a hole close to the distribution hole 7 on the flow-in side is smaller and a diameter of a hole remote to the distribution hole 7 on the flow-in side is larger. That is, a hole diameter is preferably adjusted so as to equalize a flow-path pressure loss of the distribution hole 7 (flow-out side) close to the distribution hole 7 on the flow-in side and a flow-path pressure loss of the distribution hole 7 (flow-out side) remote to the distribution hole 7 on the flow-in side.
  • adjustment of the flow-path pressure loss may be performed by adjusting a groove width of the flow path groove 8. Further, as described above, in order to equalize flow-path pressure losses at all the distribution plates 6, dimensions of the distribution hole 7 and the distribution groove 8 may be adjusted; however, diameters of only distribution holes 7 of the distribution plate 6 in contact with the lowermost layer distribution plate 5 may be adjusted so as to equalize all flow-path pressure losses on the upstream side thereof.
  • a diameter of the distribution hole 7, a groove width and a groove depth of the distribution groove 8 are increased, and it is particularly preferred that at the upstream side (metering plate 9 side) in the direction of the polymer spinning path, a thickness of the distribution plate 6 constituting the distribution groove 8 is increased, and a groove depth and a groove width of the distribution groove 8 is increased, and a diameter of the distribution hole 7 is increased.
  • the distribution groove 8 and the distribution hole 7 in the distribution plate 6 may be appropriately arranged according to desired fiber cross section form, and the method is not particularly limited to the above method.
  • a spinning velocity varies depending on the properties of the polymer and an object of the composite fibers, and can be set to about 500 to 6000 m/min. Particularly, when high mechanical properties are required in industrial material applications, preferably, a high molecular weight polymer is used and spun at a spinning velocity of 500 to 2000 m/min, and thereafter it is stretched at a high ratio.
  • a temperature at which a polymer can be softened such as a glass transition temperature of the polymer is used as a standard, and a pre-heating temperature is appropriately set.
  • a temperature is preferably set at which fluctuations of a yarn route due to self-extension of a fiber does not occur in a pre-heating process.
  • the pre-heating temperature is generally set to about 80 to 95°C.
  • a discharge velocity ratio between polymers of the respective components discharged from the island component discharge holes 1 and the sea component discharge holes 4 of the present invention is preferably controlled by a discharge amount, a hole diameter and the number of holes (the discharge velocity refers to a value obtained by dividing a discharge flow rate by a cross section area of the island component discharge hole 1 or the sea component discharge hole 4).
  • a ratio thereof (Va/Vb or Vb/Va) is preferably in a range of 0.05 to 20, and more preferably in a range of 0.1 to 10, and when the ratio is in this range, since a polymer discharged from the lowermost layer distribution plate 5, as a laminar flow, is guided to the contracting hole 12 through the discharge introduction hole 11, a cross section form is significantly stabilized and can be maintained accurately.
  • a melt viscosity ratio of the polymer used in the present invention is less than 2.0, a composite polymer stream can be stably formed.
  • the melt viscosity ratio is 2.0 or more, a composite polymer stream becomes unstable when the island-component polymer joins with the sea component polymer, and uneven thickness of the resulting fiber cross section may occur in a running direction in some cases.
  • etching processing is a processing method in which a thin plate is etched (dissolved/chemically cut) with use of a chemical reaction/corrosive action by chemicals such as an etching solution, and in this method, an objective processing shape is subjected to anti-corrosion treatment by masking (required partial surface is partially coated/protected), and an unnecessary portion is removed with a corrosive agent such as an etching solution, and thereby, an objective processing shape can be obtained with significantly high precision.
  • the cross section form can be altered by replacing only the distribution plate 6 and the lowermost layer distribution plate 5, and therefore this is a preferable feature recently in the progress of high performance and various kinds of fiber products.
  • a method of preparing the distribution plate and the lowermost layer distribution plate it is possible to employ a method of using a turning machine, machining, press, laser machining and the like which are drilling or metal precision processing used in conventional spinneret preparation.
  • the processing has a limitation on a lower limit of a thickness of a plate to be processed from the viewpoint of suppressing distortion of the processed materials, it is necessary to consider a thickness of the distribution plate 6 for applying the processing to the composite spinneret of the present invention formed by laminating a plurality of distribution plates.
  • the fibers obtained by the composite spinneret of the present invention means fibers formed by combining two types or more of polymers into one, and refer to fibers in which two types or more of polymers exist in the form of islands-in-the-sea or the like at the transverse section of the fiber.
  • two types or more of polymers referred to in the present invention includes that two types or more of polymers having different molecular structures such as polyester, polyamide, polyphenylenesulfide, polyolefin, polyethylene, and polypropylene are used; however, this also includes that within a range not impairing the stability of yarn-making, addition amounts of delustering agents such as titanium dioxide; various functional particles such as silicon oxide, kaolin, anticoloring agent, stabilizer, antioxidant agent, deodorant, flame retarder, anti-yarn friction agent, color pigment and surface modifier; and additives or particles of organic compounds are different, and that molecular weights thereof are different, and that copolymerization thereof is performed, and the like.
  • delustering agents such as titanium dioxide
  • various functional particles such as silicon oxide, kaolin, anticoloring agent, stabilizer, antioxidant agent, deodorant, flame retarder, anti-yarn friction agent, color pigment and surface modifier
  • additives or particles of organic compounds are different, and that molecular weights thereof are
  • a cross section of a single yarn of fibers obtained by the composite spinneret 18 of the present invention may have a shape such as a triangle shape or a flat shape other than a circular shape in addition to a circular shape, or may be hollow.
  • the present invention is an extremely versatile invention, and it is not particularly limited by a single yarn fineness of the composite fibers, nor particularly limited by the number of single yarns of the composite fibers, nor particularly limited by the number of lines of yarns of the composite fibers, and may be one line of yarn or multi lines of two or more lines of yarns.
  • the islands-in-the-sea composite fiber obtained by the composite spinneret of the present invention refers to, as shown in Figs. 8 (a), 8(b) and 8(c) , Figs. 32 (a), 32 (b), 32(c) and 32(d) , a fiber in which different two types or more of polymers form an islands-in-the-sea structure (the islands-in-the-sea structure referred to herein is a structure in which an island portion composed of an island component polymer 13 is separated into plural portions by a sea portion composed of a sea component polymer 20) in the cross section perpendicular to the direction of a fiber axis.
  • a shape of the cross section of the island portion is not limited, and as shown in Fig. 1 or Fig. 2 , the shape of the cross section of the island portion may be configured by one island component discharge hole 1, or as shown in Fig. 16 , the shape of the cross section of the island portion may be configured by an island component discharge portion 21 formed by aggregation of a plurality of the island component discharge holes 1.
  • an islands-in-the-sea composite fiber having a triangle cross section can be obtained.
  • FIG. 8 (b) can be obtained by employing an arrangement of the island component discharge hole 1 and the sea component discharge hole 4 as shown in Fig. 3 , and an islands-in-the-sea composite fiber having a tetragonal cross section shown in Fig. 8(c) can be obtained by employing an arrangement as shown in Fig. 4 .
  • a heteromorphic cross section although polymers such as polyesters and polyamides obtained by melt spinning generally often have a completely circular cross section.
  • the islands-in-the-sea composite fiber refers to a fiber in which different two types or more of polymers form an islands-in-the-sea structure (the islands-in-the-sea structure referred to herein is a structure in which an island portion composed of the island component polymer 13 is separated into plural portions by a sea portion composed of the sea component polymer 20) in the cross section perpendicular to the direction of a fiber axis.
  • a shape of the cross section of the island portion is not limited, and the shape of the cross section of the island portion is controlled by a shape of the cross section of the island component discharge hole 1, and the shape of the cross section of the island portion is controlled by a combination of shapes of the cross sections of the island component discharge hole 1 and the discharge hole 25.
  • the island part can be star-shaped by forming the island component discharge hole 1 into a circular shape and the discharge hole 25 into a star shape, or forming the island component discharge hole 1 into a star shape and the discharge hole 25 into a circular shape.
  • the island portion of the islands-in-the-sea composite fiber is composed of two types of an island-component polymer 13 (c) and an island-component polymer 13 (d), core-sheath type composite fibers can be obtained.
  • the core-sheath composite fiber is a composite fiber in which different two types or more of polymers are configured in such a way that a core component is covered with a sheath component in the cross section perpendicular to the direction of a fiber axis.
  • multi-core-sheath fibers can be prepared by a method of laminating a distribution plate for discharging a polymer of third component to surround a composite core-sheath component polymer stream obtained at the discharge hole 25 of a lower layer plate 37.
  • the fibers become fibers having excellent quality and feeling, and the fibers can be effectively used for industrial material applications since the fibers become fibers having characteristics which a polymer of a single component cannot achieve from the viewpoint of mechanical properties, chemical resistance and heat resistance. Particularly, bending fatigue and abrasion properties are improved as compared with conventional products, and the fibers can be suitably used for not only rubber reinforcing applications such as tire cord or a tire-cap layer material, but also fish net, agricultural materials and screen gauze.
  • side-by-side composite fibers when the island portion of the islands-in-the-sea composite fibers is composed of two types of island component polymers, side-by-side composite fibers can be also obtained.
  • the side-by-side composite fiber refers to a fiber in which different two types or more of polymers constitute the form of being bonded to one another in the cross section perpendicular to the direction of a fiber axis, and the forms of the cross section are regularly arrayed at one or two types of gaps.
  • a method of manufacturing the side-by-side composite fiber a method may be employed, in which in the upper layer plate 29 of the composite spinneret 18, the island component discharge hole 1 for discharging an island component polymer (A) 13 and the island component discharge hole 4 for discharging an island component polymer (B) 14 different from the island component polymer (A) 13 are respectively gathered as a discharge hole group, and the discharge hole groups are brought close to one another, and arrayed symmetrically or unsymmetrically to configure the island component discharge part 21.
  • side-by-side composite fibers can be obtained by eluting a sea component polymer.
  • two types or more of polymers may be bonded to one another as a multilayer, and it is also suitable to provide three types or more of properties by bonding three types or more of polymers.
  • fibers in which a shrinkage property and a dyeing property vary in the direction of a fiber cross section can be obtained.
  • a polymer which exhibits the shrinkage property by taking up moisture is arranged to one side, a network of a cloth or the like is changed by taking up moisture, and therefore this becomes a cloth having a function of self-control of aeration property and a function of moisture transmission and water-proof for clothing.
  • the hole packing density is preferably 0.5 hole/mm 2 or more.
  • the hole packing density is 0.5 hole/mm 2 or more, the difference with conventional composite spinneret technology is more apparent.
  • a hole packing density of 0.5 to 20 hole/mm 2 can be performed. From the viewpoint of the hole packing density, it is preferably in a range of 1 to 20 hole/mm 2 as the range where the superiority of the composite spinneret of the present invention can be achieved.
  • the islands-in-the-sea composite fibers in the present invention by eluting a sea component polymer 20, can prepare highly uniform filament type nanofibers having a circumscribing fiber diameter of 10 to 1000 nm and a fiber diameter CV% of 0 to 30% which represents fiber diameter variation, as highly reduced extremely ultrafine heteromorphic fibers unavailable from spinning of a single component.
  • This filament type nanofibers can be suitably used for finish processing an aluminum alloy substrate or a glass substrate used for magnetic recording disks with ultra high precision by forming the fibers into a sheet.
  • sheet-like products can be prepared, in which a part of islands are made to join together intentionally to control a fiber diameter distribution freely.
  • composite forms which can be manufactured by the composite spinneret 18 of the present invention have been described by way of examples of conventionally known cross section forms; however, since in the composite spinneret 18 of the present invention, the cross section form can be arbitrarily controlled, a free form can be prepared without limiting to the above-mentioned forms.
  • Strength of the composite fiber of the present invention is preferably 2 cN/dtex or more, and preferably 5 cN/dtex or more in consideration of mechanical properties required in industrial material applications.
  • a practical upper limit of the strength is 20 cN/dtex.
  • An elongation is preferably set to 2 to 60% for stretched yarns, and 2 to 25% for an industrial material field in which particularly high strength is required, and 25 to 60% for clothing.
  • the composite fiber of the present invention can be formed into multipurpose fiber products such as fiber take-up package, tow, cut fiber, cotton, fiber ball, cord, pile, textile, nonwoven fabric, paper and liquid dispersion.
  • Fig. 33 is a schematic sectional view of a composite spinneret used in a first embodiment
  • Fig. 34 is a schematic sectional view of a composite spinneret, and surroundings of a spin pack and a cooling apparatus, which are used in a first embodiment
  • Fig. 24 is a partially enlarged sectional view of Fig. 33
  • Fig. 29 is a view taken in the direction of arrows Y-Y in Fig. 24
  • FIG. 27 is a partially enlarged sectional view of a composite spinneret used in a first embodiment.
  • Fig. 25 is a partially enlarged sectional view of a composite spinneret used in a second embodiment
  • Fig. 26 is a partially enlarged sectional view of a composite spinneret used in a third embodiment
  • Fig. 28 is a view taken in the direction of arrows X-X in Fig. 26
  • Fig. 30 is a view taken in the direction of arrows Z-Z in Fig. 27 .
  • a reference numeral 36 indicates a middle layer plate
  • a reference numeral 37 indicates a lower layer plate
  • a reference numeral 38 indicates an upper layer projection
  • a reference numeral 39 indicates a virtual circumscribed-circle
  • a reference numeral 46 indicates a bottom surface of the upper layer projection
  • a reference numeral 47 indicates a top surface of the lower layer plate
  • a reference numeral 48 indicates a joining chamber
  • a reference numeral 49 indicates a virtual inscribed-circle
  • a reference numeral 50 indicates an outer circumference end hole, respectively.
  • a composite spinneret 18 used in the first embodiment of the present invention is fitted in a spin pack 15 and fixed in a spin block 16, and a cooling apparatus 17 is configured immediately below the composite spinneret 18.
  • Two types or more of polymers introduced into the composite spinneret 18 respectively pass through a metering plate 9, a distribution plate 6, an upper layer plate 29, a middle layer plate 36 and a lower layer plate 37, and are discharged from a spinneret discharge plate 42 of a discharge plate 10 and then cooled by an air stream blown out from the cooling apparatus 17 and provided with a spinning oil, and then the polymers are taken up as a multifilament yarn.
  • annular cooling apparatus 17 which blows an air stream annually-inwardly is employed; however, a cooling apparatus which blows an air stream from one direction may be used.
  • a member disposed to the upstream side of the metering plate 9 a flow path or the like used in the existing spin pack 15 may be used, and the member does not need to be exclusive.
  • the composite spinneret 18 used in the first embodiment is configured by laminating the metering plate 9, a plurality of the distribution plates 6, the upper layer plate 29, the middle layer plate 36, the lower layer plate 37 and the discharge plate 10 in turn, and particularly the distribution plates 6, the upper layer plate 29, the middle layer plate 36, the lower layer plate 37 are preferably composed of a thin plate.
  • the metering plate 9 and the distribution plate 6, and the upper layer plate 29, the middle layer plate 36, the lower layer plate 37 and the discharge plate 10 are positioned so as to be aligned with a center position (core) of the spin pack 15 by a locating pin, laminated, and then may be fixed by a screw or bolt, or may be metal-joined (diffusion-bonded) by thermocompression bonding.
  • the distribution plates 6, the distribution plate 6 and the upper layer plate 29, the upper layer plate 29 and the middle layer plate 36, and the middle layer plate 36 and the lower layer plate 37 are preferably metal-joined (diffusion-bonded) to each other by thermocompression bonding since a thin plate is used for these plates.
  • polymers of the respective components supplied from the metering plate 9 pass through a distribution groove 8 and a distribution hole 7 of the distribution plate 6 formed by laminating plural plates, and then are discharged from an island component discharge hole 1 for discharging an island component polymer and a sea component discharge hole 4 for discharging a sea component polymer of the upper layer plate 29 to a joining chamber 48 of the middle layer plate 36, and thereby, the polymers of the respective components join with each other in such a way that the sea component polymer surrounds the outer circumference of the island component polymer to form a core-sheath type islands-in-the-sea composite polymer stream.
  • the core-sheath type islands-in-the-sea composite polymer stream passes through a discharge introduction hole 11 and a contracting hole 12 of the discharge plate 10 through a discharge hole 25 of the lower layer plate 37, and is discharged from a spinneret discharge hole 42.
  • the number of the sea component discharge holes 4 needs to be equal to or more than the number of the island component discharge holes 1 disposed in the upper layer plate 29, and for example, as shown in Fig. 41 , an array of surrounding one island component discharge hole 1 as a reference with six sea component discharge holes 4 from six directions is conceivable, and in this case, the number of the sea component discharge holes 4 needs to be three times as many as the number of the island component discharge holes 1.
  • a mechanism for uniformly supplying/distributing and metering the island component polymer at the island component discharge hole 1 or the upstream side thereof is required. Accordingly, for example as shown in Fig. 18 , it is conceivable to increase a flow-path pressure loss by having a projection 43 around the island component discharge hole 1 as a metering mechanism to narrow a gap; however, in this case, the island component discharge holes 1 cannot be arranged in a state of being close to one another, and therefore the number of the island component discharge holes 1 which can be arranged in the upper layer plate 29 is limited and the hole packing density cannot be increased.
  • radial grooves 27 are placed around the island component discharge hole 1
  • grooves 28 on a concentric circle are placed around the discharge hole 25 as a distribution mechanism of the sea component polymer, or the like; however, in this case, the island component discharge holes 1 or the discharge holes 25 opposed thereto cannot be arranged in a state of being close to one another, and therefore the number of the island component discharge holes 1 which can be arranged in the upper layer plate 29 is limited and the hole packing density cannot be increased.
  • the distribution hole 7 and/or the distribution groove 8 for respectively distributing an island component polymer and a sea component polymer are formed in the distribution plate 6 formed by laminating plural plates, one or more sea component discharge holes 4 communicated with the distribution hole 7 or the distribution groove 8 and the island component discharge holes 1 arranged more than the sea component discharge holes 4 are formed in the upper layer plate 29, the joining chamber 48 communicated with the island component discharge holes 1 and the sea component discharge holes 4 is formed in the a middle layer plate 36, and the discharge hole 25 communicated with the joining chamber 48 is formed at a position opposed to the island component discharge hole 1 in the lower layer plate 37.
  • the island component polymer is discharged to the joining chamber 48 where the sea component polymer fills around all the island component discharge holes 1, and therefore the sea component polymer surrounds the outer circumference of the island component polymer immediately after discharge to form a core-sheath type islands-in-the-sea composite polymer stream and the core-sheath type islands-in-the-sea composite polymer stream is guided to the discharge hole 25, the island component polymer streams hardly join with one another.
  • the island component discharge holes 1 can be arranged in a state of being close to one another to increase the hole packing density. Moreover, by equalizing flow-path pressure losses of a plurality of flow through paths of a polymer from the distribution plate 6 at a top end in the direction of the polymer spinning path to the island component discharge holes 1 of the upper layer plate 29, island-component polymer streams can be uniformly discharged from all the island component discharge holes 1 disposed in the upper layer plate 29, and can be prevented from joining with one another. As a result of the above, uniform core-sheath type islands-in-the-sea composite polymer streams can be formed, and a highly precise fiber cross section form can be formed.
  • etching processing generally used for processing electric/electronic parts is suitable.
  • neighboring island component discharge holes 1 can be brought close to one another, and also in the lower layer plate 37, neighboring discharge holes 25 can be brought close to one another, and therefore the hole packing density can be more increased.
  • the sea component discharge holes 4 are disposed around the island component discharge hole 1 constituting a hole group.
  • the island component discharge holes 1 can be disposed in a state of being close to one another and the hole packing density can be increased.
  • the island component discharge holes 1 constituting a hole group are favorably disposed with periodicity, but may be disposed without periodicity.
  • the sea component discharge holes 4 disposed around the island component discharge hole 1 are favorably disposed so as to surround all the circumference of the hole group; however, the arrangement pattern is not limited to this. For example, when the hole group is rectangular, the sea component discharge holes 4 may be disposed at only two side surfaces opposed to each other.
  • the sea component discharge holes 4 may be disposed in a region where the island component discharge holes 1 disposed in the upper layer plate 29 forms a hole group (in Fig. 30 , a region of a hole group of 5 rows and 4 columns).
  • the hole packing density is slightly lower as compared with that of a hole arrangement of the island component discharge holes 1 shown in Fig. 29
  • the sea component polymer so as to surround the outer circumference of the island component polymer at all the island component discharge holes 1 in the hole group region.
  • the sea component discharge holes 4 are disposed in the hole group region of the island component discharge holes 1 by laminating the distribution plates 6 in which the distribution holes 7 and the distribution grooves 8 are formed, and forming flow paths in communication with the sea component discharge holes 4 in the region of the island component discharge holes 1. Since in the composite spinneret, the flow path is formed by using a plurality of the distribution plates 6, the degree of freedom of a flow path is high, and the required number of the island component discharge holes 1 and the required number of the sea component discharge holes 4 can be disposed at required locations. Therefore, as described above, hole arrangements of the island component discharge holes 1 and the sea component discharge holes 4 may be appropriately determined according to polymer properties, spinning conditions and the like.
  • the upper layer plate 29 and the middle layer plate 36 are composed of the same thin plate. Then, the number of thin plates to be laminated can be reduced by previously forming the joining chamber 48, the island component discharge holes 1, and the sea component discharge holes 4 in one thin plate by etching processing, and consequently production cost of the composite spinneret can be reduced.
  • processing precision of holes or grooves formed in the thin plate may be deteriorated in the etching processing in some cases, it is preferred that processing precision is checked in advance and a plate thickness, a hole diameter, a groove width and the like are determined.
  • the middle layer plate 36 and the lower layer plate 37 may be composed of the same thin plate, and in this case, the composite spinneret has the same feature as in the above description.
  • an upper layer projection 38 protruded to the downstream side in the direction of the polymer spinning path from a bottom surface of the upper layer plate 29 is formed at a circumference centered on the island component discharge hole 1, the discharge hole 25 having a virtual circumscribed-circle 39 larger than the outer circumference of the upper layer projection 38 and a virtual inscribed-circle 49 smaller than the outer circumference of the upper layer projection 38 is formed, and a bottom surface 46 of the upper layer projection 38 is disposed at the same level as a top surface 47 of the lower layer plate 37 or to the downstream side of the top surface 47 in the direction of the polymer spinning path, and an outer end hole 50 is formed for supplying a sea component polymer around an end of the upper layer projection 38.
  • the bottom surface 46 of the upper layer projection 38 and the top surface 47 of the lower layer plate 37 are in the same plane, these surfaces are preferably diffusion-bonded by metal press-bonding.
  • the island component polymer is discharged toward the downstream side in the direction of the polymer spinning path, and the sea component polymer is discharged toward the downstream side in the direction of the polymer spinning path from the outer end hole 50 around the end of the upper layer projection 38, and thereafter the polymers of the respective components join with each other in such a way that the sea component polymer surrounds the outer circumference of the island component polymer to form a core-sheath type composite polymer stream, and the core-sheath type composite polymer stream is guided to the downstream side in the direction of the polymer spinning path.
  • a highly precise cross section form of the island-component polymer can be formed; however, by employing the third embodiment, all the island-component polymer stream, the sea component polymer stream and the core-sheath type composite polymer stream can be formed in the same direction, unnecessary collision between the polymer streams can be avoided, and turbulence of the polymer stream can be suppressed, and therefore a more highly precise cross section form of the island-component polymer can be formed, and the cross section form can be maintained with high dimensional stability.
  • the strength of the distribution plate can be improved by forming a multilayer of thin plates and press-bonding the resulting multilayer; however, in the third embodiment, the strength of the thin plate is further improved, and bending and defective distribution of a polymer due to bending can be inhibited by joining the bottom surface 46 of the upper layer projection 38 with the top surface 47 of the lower layer plate 37 at the same plane. Further, when a cross section of the island component discharge hole 1 in the direction perpendicular to the direction of the polymer spinning path is a circular shape and a cross section of the discharge hole 25 in the direction perpendicular to the direction of the polymer spinning path is a heteromorphic shape, a shape of the resulting island component cross section can be a heteromorphic shape.
  • the island component discharge holes 1 are formed so as to have a circular shape and the discharge holes 25 are formed so as to have a cross-like shape, a shape of the resulting island component cross section becomes a cross shape.
  • cross section shapes of the island component discharge hole 1 and the discharge hole 25 may be appropriately determined according to a desired island component cross section shape.
  • the island component discharge hole 1 may be formed in a cross shape and the discharge hole 25 may be formed in a circular shape, and in this case, the composite spinneret has the same feature as in the above description.
  • core-sheath type composite fibers can be obtained by employing a method in which, as shown in Fig. 33 , the composite spinneret 18 composed of the metering plate 9, the distribution plate 6, the upper layer plate 29, the middle layer plate 36, the lower layer plate 37 and the discharge hole 10 is used and melt spinning is performed.
  • Fig. 19 is a partially enlarged plan view of a composite spinneret used in another embodiment of the present invention.
  • the composite spinneret 18 used in another embodiment of the present invention is configured by laminating the metering plate 9, at least one distribution plate 6, the lowermost layer distribution plate 5 and the discharge plate 10 in turn, and particularly the distribution plate 6 and the lowermost layer distribution plate 5 are preferably composed of a thin plate. Then, as shown in Fig.
  • polymers of the respective components supplied from the metering plate 9 pass through the distribution groove 8 and the distribution hole 7 of the distribution plate 6 formed by laminating at least one plate, and then are discharged from the island component discharge hole 1 for discharging an island component polymer and the sea component discharge hole 4 for discharging a sea component polymer of the lowermost layer distribution plate 5, and thereby, the polymers of the respective components join with each other to form a composite polymer stream. Thereafter, the composite polymer stream passes through the discharge introduction hole 11 and the contracting hole 12 of the discharge plate 10, and is discharged from the spinneret discharge hole 42.
  • the island component polymer streams can be prevented from joining with one another while increasing the hole packing density of the composite spinneret 18.
  • the island component discharge holes 1 need to be close to one another as much as possible, and in this case, island-component polymer streams join with one another between neighboring island component discharge holes. For example as shown in Fig.
  • the respective discharge holes are arranged in such a way that at least a part of sea component discharge holes is present in a region surrounded with neighboring two island component discharge holes with the shortest distance between centers thereof and two lines commonly circumscribing the two island component discharge holes. Specifically, as shown in Fig.
  • the respective discharge holes are arranged in such a way that at least a part of the sea component discharge holes 4 is present in a region surrounded with the island component discharge hole 1 as an reference, the island component discharge hole 2a, and two lines 54 commonly circumscribing the two island component discharge holes 1 and 2a.
  • both the island component polymer and the sea component polymer are discharged all together toward the discharge introduction hole 11 located downstream side of the lowermost layer distribution plate 5, flow in the direction of the polymer spinning path while expanding their width in the direction perpendicular to the direction of the polymer spinning path, and join with one another to form a composite polymer.
  • it is effective to interpose a sea component polymer which physically isolates island-component polymer streams from each other.
  • the island component polymer streams from joining with one another when the discharge holes are configured in such a way that at least a part of the sea component discharge holes 4 supplying a sea component polymer is present in a flow path space (in this case, a region surrounded with the island component discharge hole 1 as a reference, the island component discharge hole 2a and two lines 54 commonly circumscribing the two island component discharge holes 1 and 2a) connecting the island component discharge hole 1 as a reference and the island component discharge hole 2a.
  • a flow path space in this case, a region surrounded with the island component discharge hole 1 as a reference, the island component discharge hole 2a and two lines 54 commonly circumscribing the two island component discharge holes 1 and 2a
  • the island component discharge holes 1 are often composed of one type or two types of intervals.
  • the island component discharge holes 1 are composed of two types of intervals.
  • One interval is a distance between the center of the island component discharge hole 1 as a reference and the center of the island component discharge hole 2a, and this is a shorter interval.
  • the shorter interval is the above-mentioned "shortest distance between centers”.
  • the other interval is a distance between the center of the island component discharge hole 1 as a reference and the center of an island component discharge hole 2b, and this is a longer interval.
  • the distance between the center of the island component discharge hole 1 as a reference and the center of the island component discharge hole 2a is equal to the distance between the center of the island component discharge hole 1 as a reference and the center of the island component discharge hole 2b.
  • directions of repetition of two types of intervals are orthogonal to each other; however, the directions may not be orthogonal to each other.
  • the respective discharge holes are preferably arranged in such a way that (i) at least a part of the sea component discharge holes 4 is present in a region surrounded with the island component discharge hole 1 as a reference and the island component discharge hole 2a which are adjacent to each other at a shorter interval, and two lines 54 commonly circumscribing the two island component discharge holes 1 and 2a, and (ii) at least a part of the sea component discharge holes 4 is present in a region surrounded with the island component discharge hole 1 as a reference and the island component discharge hole 2b which are adjacent to each other at a longer interval, and two lines 54 commonly circumscribing the two island component discharge holes 1 and 2b.
  • each of at least two of the sea component discharge holes is present in a region surrounded with neighboring two island component discharge holes and two lines commonly circumscribing the two island component discharge holes, and the two sea component discharge holes are arranged across a line segment connecting centers of the neighboring two island component discharge holes.
  • each of at least two of the sea component discharge holes 4 is present in a flow path space connecting neighboring two island component discharge holes 1 (the island component discharge hole 1 as a reference and the island component discharge hole 2a, or the island component discharge hole 1 as a reference and the island component discharge hole 2b), and the two sea component discharge holes 4 are arranged across a line segment connecting centers of the neighboring two island component discharge holes 1 (the island component discharge hole 1 as a reference and the island component discharge hole 2a, and the island component discharge hole 1 as a reference and the island component discharge hole 2b).
  • the two sea component discharge holes 4 can be placed at a position closest to each other in a state in which the neighboring two island component discharge holes 1 are placed close to a limit level of processing, the island component polymer streams can be prevented from joining with one another while increasing the hole packing density to a limit.
  • An arrangement of the two sea component discharge holes 4 is not particularly limited; however, the sea component discharge holes 4 are preferably arranged symmetrically with respect to a line segment A.
  • Expansion of the island-component polymer discharged from the island component discharge hole 1 in width is blocked by the sea component polymers discharged from the two sea component discharge holes 4 and the island-component polymer forms a certain shape; however, when the two sea component discharge holes 4 are arranged symmetrically with respect to a line segment A, it is preferred because a shape of the expanded island-component polymer is a clear symmetric shape with respect to a line segment A.
  • a plurality of the island component discharge holes 1 for discharging an island component polymer to join together may be gathered to form a hole group (aggregate).
  • a plurality of the sea component discharge holes 4 for discharging a sea component polymer to join together may be gathered to form a hole group (aggregate) .
  • a region surrounded with a line connecting, in a state of being tangent, the outermost island component discharge hole 1 of the island component discharge holes 1 constituting one hole group in turn is taken as an island component discharge part.
  • a region surrounded with a line connecting, in a state of being tangent, the outermost sea component discharge hole 4 of the sea component discharge holes 4 constituting one hole group in turn is taken as a sea component discharge part.
  • the hole group of the island component discharge holes 1 is taken as an island component discharge part 21
  • the hole group of the island component discharge holes 2a is taken as an island component discharge part 22a
  • the hole group of the island component discharge holes 2b is taken as an island component discharge part 22b
  • the hole group of the sea component discharge holes 4 is taken as a sea component discharge part 24, and the island component discharge hole 1, the island component discharge hole 2a, the island component discharge hole 2b and the sea component discharge hole 4, which have been described, may be read as the island component discharge part 21, the island component discharge part 22a, the island component discharge part 22b and the sea component discharge part 24, respectively.
  • 19 , 35 , 36 and 37 is a lowermost layer distribution plate in which the island component discharge part is composed of one island component discharge hole, and the sea component discharge part is composed of one sea component discharge hole.
  • the island component discharge part is composed of one island component discharge hole
  • the sea component discharge part is composed of one sea component discharge hole.
  • an island-component polymer discharged from the island component discharge hole 1 (2a, 2b) within the island component discharge part 21 (22a, 22b), and a sea component polymer discharged from the sea component discharge hole 4 within the sea component discharge part 24 join with one another immediately after discharge; however, since these streams are discharged with the intention to join together, joining does not make a problem.
  • a minimum gap DA between the neighboring two island component discharge holes 1 and a minimum gap DB between the two sea component discharge holes 4 to satisfy a relation of DB/DA ⁇ 0.7, it is possible to prevent stably the island component polymer streams from joining with one another within a range of spinning conditions under which composite fibers can be industrially manufactured regardless of physical properties such as melt viscosity of an island-component polymer or a sea component polymer, and spinning conditions such as discharge amounts and discharge amount ratio of the respective polymers.
  • DB/DA > 0.7 the island component polymer streams may join with one another in some cases.
  • a lower limit of DB/DA is not particularly limited, and when the lower limit becomes smaller, the island-component polymer streams can be prevented from joining together; however, the minimum gap DA is increased and the hole packing density is decreased, and therefore the lower limit may be set within a practical range.
  • the island component discharge holes 1 and the sea component discharge holes 4 may be arranged on the entire surface thereof, or as shown in Fig. 39 , the island component discharge holes 1 and the sea component discharge holes 4 may be arranged in a state of being close-packed locally (a part surrounded with the virtual circle 52 in Fig. 39 ).
  • the arrangement of the island component discharge holes 1 and the sea component discharge holes 4 in each virtual circle 52 may be the same in all the virtual circles 52, or may vary among the virtual circles 52.
  • Fig. 37 shows that the island component discharge holes 1 and the sea component discharge holes 4 in each virtual circle 52 are arranged as described above, the arrangement of the island component discharge holes 1 and the sea component discharge holes 4 in each virtual circle 52 may be the same in all the virtual circles 52, or may vary among the virtual circles 52.
  • Fig. 37 if the island component discharge holes 1 and the sea component discharge holes 4 in each virtual circle 52 are arranged as described above, the arrangement of the island component discharge holes 1 and the sea component discharge holes 4 in each virtual circle 52 may be the same in all
  • arrangements of the island component discharge holes 1 and the sea component discharge holes 4 may be partially different (right-half portion and left-half portion in the virtual circle 52 in Fig. 39 ). Also in this case, the island component discharge hole 1 and the sea component discharge hole 4 in each area may be arranged as described above.
  • the composite spinneret 18 of another embodiment of the present invention can easily distribute the sea component polymer in the direction of a fiber cross section by using the lowermost layer distribution plate 5 and the distribution groove 8 of the distribution plate 6 immediately above the lowermost layer distribution plate 5, the sea component discharge part 24 or the sea component discharge hole 4 can be easily arranged in an extremely narrow region between neighboring two island component projections 21 or the island component discharge holes 1. Consequently, the hole packing density can be increased by bringing the neighboring two island component projections 21 or the island component discharge holes 1 closer to each other. Further, since an arrangement pattern of the island component discharge holes 1 can be easily changed by overlaying an additional distribution plate 6 immediately below the lowermost layer distribution plate 5, the composite spinneret 18 also has an advantage of reducing a time, cost or the like associated with design change.
  • FIG. 35, Fig. 36 and Fig. 37 is a partially enlarged plan view of a composite spinneret used in a fifth embodiment, a sixth embodiment, and a seventh embodiment, respectively, and Fig. 35, Fig. 36 and Fig. 37 are respectively a schematic partial sectional view of a lowermost layer distribution plate.
  • the sea component discharge holes 4 are disposed to block fully a flow path space connecting neighboring two island component discharge holes 1 (the island component discharge hole 1 as a reference and the island component discharge hole 2a, and the island component discharge hole 1 as a reference and the island component discharge hole 2b).
  • the sea component polymer since the sea component polymer is present in path spaces in which the island component polymer streams are expected to join with one another, the island component polymer streams can be further prevented from joining with one another.
  • a distance between the neighboring island component discharge holes 1 cannot be smaller than a size of the sea component discharge hole 4.
  • a cross section shape of the sea component discharge hole 4 is a shape different from a circular shape.
  • the sea component discharge hole 4 can be arranged even in a location where the sea component discharge hole 4 having a circular shape cross section cannot be arranged without reducing its hole diameter, and therefore the sea component polymer can be locally discharged, the island component polymer streams can be further prevented from joining with one another, and the neighboring island component holes 1 can be brought close to each other to the utmost limit, and the hole packing density can be increased.
  • the sea component discharge hole 4 has such a cross section form other than a circular shape
  • the cross section shape of the sea component discharge hole 4 is controlled, the island component polymer discharged from the island component discharge hole 1 to be expanded in width can be controlled to have an arbitrary cross section shape.
  • the sea component discharge hole 4 is a circular slit surrounding the island component discharge hole 1.
  • the sea component discharge hole 4 has such a cross section shape, it is preferred that by arranging the distribution holes 7 having a circular cross section shape to the upstream side of the sea component discharge holes 4 in communication with the sea component discharge holes 4, the metering capability of the sea component polymer is ensured at the distribution hole 7 immediately above the sea component discharge hole 4, and then the sea component polymer is discharged at the sea component discharge hole 4.
  • the islands-in-the-sea composite fibers were immersed in a solution in which a sea component of an easy-to-elute component can be eluted to remove the sea component to obtain multifilaments of the island component of a hard-to elute component.
  • the easy-to-elute component is copolymerized PET formed by copolymerization of 5-sodium sulfoisophthalic acid and the like, polylactic acid (PLA) or the like
  • an alkali aqueous solution such as sodium hydroxide aqueous solution was used. Since the alkali aqueous solution can accelerate the progress of hydrolysis when it is heated to 50°C or more, if a fluid dyeing machine or the like is used for treatment, a large amount can be treated at a time.
  • the obtained multifilaments composed of ultrafine fibers were embedded with an epoxy resin, and the embedded sample was frozen by Cryosectioning System FC 4E manufactured by Reichert, and the frozen sample was cut by Reichert-Nissei Ultracut N (ultramicrotome) equipped with a diamond knife, and the cut surfaces were photographed at a magnification of 5000 times by using VE-7800 scanning electron microscope (SEM) manufactured by KEYENCE CORPORATION. From the obtained photographs, 150 ultrafine fibers selected at random were sampled, and all circumscribed-circle diameters (fiber diameters) were measured from the photographs using image processing software (WINROOF), and an average fiber diameter and a fiber diameter standard deviation were obtained.
  • SEM scanning electron microscope
  • the circumscribed-circle refers to a broken line 14 in Fig. 8 (a) .
  • the fiber diameter CV% coefficient of variation
  • intersection angle The number of intersections of neighboring two lines was counted, and its intersection angle was measured, and the total sum of the intersection angles was divided by the number of intersections, and the resulting value, of which the first place of decimals was rounded, was taken as an intersection angle per one multifilament. The same calculation was carried out for 150 multifilaments, and the simple average thereof was taken as an intersection angle.
  • the islands-in-the-sea composite fibers were circularly knitted, and more than 99% of the easy-to-solve component in the knitted fabric was removed by immersing the composite fiber in a 3 wt% sodium hydroxide aqueous solution (80°C, bath ratio 1:100), and then multifilaments composed of ultrafine fibers were drawn out by releasing knitted fibers, and 1 m of the multifilament was weighed and was multiplied by 10000 to determine fineness. This determination was repeated 10 times, and the second place of decimals of the simple average value was rounded to determine the fineness.
  • a polymer in a chip shape was dried to a water content of 200 ppm or less by a vacuum drying machine, and the melt viscosity was measured using Capillograph 1B manufactured by Toyo Seiki Seisaku-sho, Ltd., while stepwisely changing the strain rate.
  • the measuring temperature was the same as the spinning temperature, and each Example or Comparative Example describes a melt viscosity at 1216/s. Incidentally, the measurement was started at 5 minutes after charging a sample into a heating furnace, and it was performed in a nitrogen atmosphere.
  • the obtained multifilaments composed of ultrafine fibers were embedded with an epoxy resin, and the embedded sample was frozen by Cryosectioning System FC 4E manufactured by Reichert, and the frozen sample was cut by Reichert-Nissei Ultracut N (ultramicrotome) equipped with a diamond knife, and the cut surfaces were photographed at a magnification of 5000 times by using VE-7800 scanning electron microscope (SEM) manufactured by KEYENCE CORPORATION.
  • SEM scanning electron microscope
  • the number of all islands of the obtained fibers was measured using image processing software (WINROOF), and it was assumed that when the number of all islands divided by the number of all discharge holes (sum of the discharge holes disposed in the lowermost layer plate and neighboring discharge holes) was 1, the island component polymer streams do not join with one another (no joining), and when the number of all islands divided by the number of all discharge holes was less than 1, the island component polymer streams joins with one another (joining occurs) .
  • image processing software WINROOF
  • PET Polyethylene terephthalate
  • IV intrinsic viscosity
  • island component discharge holes per one discharge introduction hole were holed at equal intervals in a' lowermost distribution plate for island component polymers.
  • a ratio between the sea component and the island component was set to 50/50, and the discharged composite polymer streams were cooled/solidified, and then provided with a spinning oil, and wound at a spinning speed of 1500 m/min, to obtain non-stretched fibers of 150 dtex-15 filaments (discharged amount of a single hole 2.25 g/min).
  • the wound non-stretched fibers were drawn between rollers heated to 90°C and 130°C by 3.0 times to form islands-in-the-sea composite fibers of 50 dtex-15 filaments, and 99% or more of the sea component was dissolved by the above-mentioned method to obtain 15000 multifilaments.
  • a distribution plate having holed distribution holes and a distribution plate having cut distribution grooves are alternately laminated, and at the downstream side of the distribution plate, a lowermost layer distribution plate shown in Fig. 1 is laminated thereon.
  • the distribution plate has a thickness of 0.1 mm, and holes and grooves are holed and cut under the conditions of a hole diameter of 0.2 mm, a groove width of 0.3 mm, a groove depth of 0.1 mm and a minimum hole pitch of 0.4 mm.
  • the lowermost layer distribution plate has a thickness of 0.1 mm, and island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.8 mm and a virtual circular line C4 with a radius R4 of 0. 693 mm so as to be arranged according to the condition (2) (a) .
  • the island component had a triangle cross section (three straight line portions, an intersection angle was 60 degree), the island component polymer streams were not joined with one another, fiber diameter variation was 4.6%, the degree of heteromorphy was 1. 9, and variation of the degree of heteromorphy was 4.5%, and a fiber diameter of the multifilament was 537 nm.
  • Example 2 Using the same composite spinneret as in Example 1 except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate to the arrangement of the condition (2) (b) as shown in Fig. 2 , spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1 except for increasing an island-component polymer ratio (a ratio between the sea component and the island component was 20/80) to obtain 13500 multifilaments.
  • an island-component polymer ratio a ratio between the sea component and the island component was 20/80
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0. 8 mm and a virtual circular line C4 with a radius R4 of 0.8 mm.
  • the island component had a triangle cross section (three straight line portions, an intersection angle was 60 degree), the island component polymer streams were not joined with one another, fiber diameter variation was 5.9%, the degree of heteromorphy was 1.84, and variation of the degree of heteromorphy was 6.3%, and a fiber diameter of the multifilament was 955 nm.
  • Example 2 Using the same composite spinneret as in Example 1 except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate to the arrangement of the condition (2) (c) as shown in Fig. 3 , spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1 except for changing a ratio between the sea component and the island component to 20/80 to obtain 15000 multifilaments.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.8 mm and a virtual circular line C4 with a radius R4 of 0.693 mm.
  • the island component had a hexagonal cross section (six straight line portions, an intersection angle was 120 degree), the island component polymer streams were not joined with one another, fiber diameter variation was 5.9%, the degree of heteromorphy was 1.23, and variation of the degree of heteromorphy was 3.9%, and a fiber diameter of the multifilament was 488 nm.
  • Example 2 Using the same composite spinneret as in Example 1 except for changing the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate to the arrangement of the condition (2) (d) as shown in Fig. 4 , spinning was carried out in the same manner (same polymer, same fineness and same spinning conditions) as in Example 1 except for changing a ratio between the sea component and the island component to 30/70 to obtain 13000 multifilaments.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.894 mm and a virtual circular line C4 with a radius R4 of 0.8 mm.
  • the island component had a tetragonal cross section (four straight line portions, an intersection angle was 90 degree), the island component polymer streams were not joined with one another, fiber diameter variation was 5.3%, the degree of heteromorphy was 1.71, and variation of the degree of heteromorphy was 5.6%, and a fiber diameter of the multifilament was 868 nm.
  • Example 1 Using the same composite spinneret as in Example 1 except for changing to the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate as shown in Fig. 9 , spinning was carried out in the same manner (same polymer, same ratio between the sea component and the island component, same fineness and same spinning conditions) as in Example 1 to obtain multifilaments.
  • three sea component discharge holes are arranged equally at a center angle of 120 degrees on a virtual circular line C1
  • three sea component discharge holes are arranged equally at a center angle of 120 degrees on a virtual circular line C2
  • three island component discharge holes are arranged equally at a center angle of 120 degrees on a virtual circular line C4
  • these discharge holes are arranged at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C2, of 60 degrees and at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C4, of 30 degrees.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.8 mm and a virtual circular line C4 with a radius R4 of 0.4 mm, and R4 is out of the range specified by the expression (1).
  • R4 is out of the range specified by the expression (1).
  • the island component polymer streams were joined with one another, and multifilaments having a triangle cross section could not be obtained.
  • Example 2 Using the same composite spinneret as in Example 2 except for changing to the arrangement pattern of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate as shown in Fig. 10 , spinning was carried out in the same manner (same polymer, same ratio between the sea component and the island component, same fineness and same spinning conditions) as in Example 2 to obtain multifilaments.
  • each sea component discharge hole is arranged equally at a center angle of 90 degrees on a virtual circular line C1
  • eight sea component discharge holes are arranged on a virtual circular line C2
  • four island component discharge holes are arranged equally at a center angle of 90 degrees on a virtual circular line C4, and these discharge holes are arranged at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C2, of 26.6 degrees and at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C4, of 45 degrees.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.
  • Example 2 Using the same composite spinneret as in Example 2 except for changing to the arrangement of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate as shown in Fig. 11 , spinning was carried out in the same manner (same polymer, same ratio between the sea component and the island component, same fineness and same spinning conditions) as in Example 2 to obtain multifilaments.
  • hole arrangement of Fig. 11 is contrived by the present inventors so that the island component has a parallelogram-shaped cross section as a modified pattern of the tetragonal cross section.
  • Island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.566 mm and a virtual circular line C4 with a radius R4 of 0.8 mm, and R4 is out of the range specified by the expression (1).
  • the island component polymer streams were joined with one another, and multifilaments having a parallelogram-shaped cross section could not be obtained.
  • Example 3 Using the same composite spinneret as in Example 3 except for changing to the arrangement pattern of the island component discharge holes and the sea component discharge holes of the lowermost layer distribution plate as shown in Fig. 12 , spinning was carried out in the same manner (same polymer, same ratio between the sea component and the island component, same fineness and same spinning conditions) as in Example 3 to obtain multifilaments.
  • six sea component discharge holes are arranged equally at a center angle of 60 degrees on a virtual circular line C1
  • six sea component discharge holes are arranged equally at a center angle of 60 degrees on a virtual circular line C2
  • six island component discharge holes are arranged equally at a center angle of 60 degrees on a virtual circular line C4
  • these discharge holes are arranged at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C2, of 30 degrees and at a phase angle between two discharge holes, one arranged on C1 and the other arranged on C4, of 0 degrees.
  • island component discharge holes and sea component discharge holes respectively having a hole diameter of 0.2 mm are holed on a virtual circular line C1 with a radius R1 of 0.4 mm, a virtual circular line C2 with a radius R2 of 0.693 mm and a virtual circular line C4 with a radius R4 of 0.8 mm, and R4 is out of the range specified by the expression (1) .
  • the island component had a hexagonal cross section (six straight line portions, an intersection angle was 120 degree), the island component polymer streams were not joined with one another, fiber diameter variation was 5.9%, the degree of heteromorphy was 1.22, and variation of the degree of heteromorphy was 4.2%; however, a fiber diameter was 1.4 ⁇ m, and therefore multifilaments having a diameter of nano-order size could not be obtained.
  • PET Polyethylene terephthalate
  • copolymerized PET having a limiting viscosity [ ⁇ ] of 0.58 as a sea component polymer were separately melted at 285°C, then metered and made to flow into a spin pack including the composite spinneret shown in Fig. 33 , and core-sheath type islands-in-the-sea composite polymer streams were discharged from discharge holes of the spinneret.
  • island component discharge holes per one discharge introduction hole were holed at equal intervals in a lowermost distribution plate for island component polymers.
  • a ratio between the sea component and the island component was set to 30/70, and the discharged composite polymer streams were cooled/solidified, and then provided with a spinning oil, and wound at a spinning speed of 1500 m/min, to obtain non-stretched fibers of 150 dtex-15 filaments (discharged amount of a single hole 2.25 g/min).
  • the wound non-stretched fibers were drawn between rollers heated to 90°C and 130°C by 3.0 times to form islands-in-the-sea composite fibers of 50 dtex-15 filaments, and 99% or more of the sea component was dissolved by the above-mentioned method to obtain 27000 multifilaments.
  • a flow path of a sequential branch system to be a two-way branch is formed by alternately laminating a distribution plate having holed distribution holes and a distribution plate having cut distribution grooves, and at the downstream side of the distribution plate, an upper layer plate, a middle layer plate and a lower layer plates are laminated in order.
  • These distribution plates have a thickness of 0.1 mm, and holes and grooves are holed and cut under the conditions of a hole diameter of 0.2 mm, a groove width of 0.3 mm, a groove depth of 0.1 mm and a minimum hole pitch of 0.4 mm.
  • flow-path pressure losses of the flow through paths of a polymer from the distribution hole at the top end to the island component discharge hole are equalized by equalizing groove lengths of the distribution grooves cut in one distribution plate.
  • the island component polymer streams were not joined with one another at the start of spinning and after a lapse of 72 hours, and fiber diameter variation was 5.8% at the start of spinning and 5.9% after a lapse of 72 hours.
  • the island component discharge holes are holed so as to have a circular shape and the discharge holes are holed so as to have a cross-like shape as shown in Fig. 4 , and a bottom surface of the upper layer projection is press-bonded and fixed to a part of a top surface of the lower layer plate through diffusion joint, and a sea component polymer is supplied from outer end holes in a nonpress-bonded part.
  • the island component polymer streams were not joined with one another at the start of spinning and after a lapse of 72 hours, and the resulting island component cross section had a cross-like shape. Further, fiber diameter variation was 7.2% at the start of spinning and 7.3% after a lapse of 72 hours.
  • PET Polyethylene terephthalate
  • copolymerized PET having a limiting viscosity [ ⁇ ] of 0.58 as a sea component polymer were separately melted at 285°C, and discharged at a discharge ratio of the sea component to the island component of 30/70 by using the composite spinneret 18, and composite polymer streams were cooled in the cooling apparatus 17, and then subjected to oil feeding, entanglement treatment and thermal stretching, and wound at a speed of 1500 m/min by a winding roller, to obtain non-stretched fibers of 150 dtex-10 filaments (discharged amount of a single hole 2.25 g/min). The wound non-stretched fibers were stretched between rollers heated to 90°C and 130°C by 2. 5 times to obtain stretched fibers of 60 dtex-10 filaments
  • the lowermost layer distribution plate of the composite spinneret was configured as shown in Fig. 19 .
  • the number of holes was 1200
  • the hole packing density was 2. 0 hole/mm 2
  • a hole diameter ⁇ was 0.2 mm
  • a longer interval was 0.6 mm
  • a shorter interval was 0.45 mm.
  • At least a part of each of two sea component discharge holes 4 was present in a region surrounded with neighboring two island component discharge holes 1 (the island component discharge hole 1 as a reference and the island component discharge hole 2a, the island component discharge hole 1 as a reference and the island component discharge hole 2b in Fig.
  • a diameter ⁇ of the sea component discharge hole 4 was 0.2 mm.
  • a ratio DB/DA of a minimum gap DB between the two sea component discharge holes 4 to a minimum gap DA between the two island component discharge holes 1 was set to 0.35.
  • DB/DA was set to 0.35 in both of the case where a minimum gap between the island component discharge hole 1 as a reference and the island component discharge hole 2a was denoted by DA and the case where a minimum gap between the island component discharge hole 1 as a reference and the island component discharge hole 2b was denoted by DA.
  • the island component polymer streams were not joined with one another at the start of spinning and after a lapse of 72 hours.
  • the lowermost layer distribution plate of the composite spinneret was configured as shown in Fig. 35 .
  • the number of holes was 1020
  • the hole packing density was 1.7 hole/mm 2
  • a hole diameter ⁇ was 0.2 mm
  • a longer interval was 0.6 mm
  • a shorter interval was 0.5 mm.
  • One sea component discharge hole 4 was disposed so as to block fully a region surrounded with neighboring two island component discharge holes 1 (the island component discharge hole 1 as a reference and the island component discharge hole 2a, the island component discharge hole 1 as a reference and the island component discharge hole 2b in Fig. 35 ) and two lines 54 commonly circumscribing the two island component discharge holes 1.
  • a diameter ⁇ of the sea component discharge hole was 0.2 mm.
  • the island component polymer streams were not joined with one another at the start of spinning and after a lapse of 72 hours.
  • the lowermost layer distribution plate of the composite spinneret was configured as shown in Fig. 19 .
  • the number of holes was 900
  • the hole packing density was 1.5 hole/mm 2
  • a hole diameter ⁇ was 0.2 mm
  • a longer interval was 0. 6 mm
  • a shorter interval was 0.55 mm.
  • a diameter ⁇ of the sea component discharge hole was 0.2 mm.
  • a part of the sea component discharge holes 4 was not present within a region surrounded with neighboring two island component discharge holes 1 and two lines 54 commonly circumscribing the two island component discharge holes.
  • the present invention can be applied not only to composite spinnerets used in a common solution spinning method, but also to composite spinnerets used in a melt blowing method and a spunbonding method and further to spinnerets used in a wet spinning method and a dry-wet spinning method; however, its application range is not limited to these.

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Claims (10)

  1. Verbund-Spinndüse zum Ausstoßen von Verbundpolymerströmen, die aus einem Inselkomponenten-Polymer und einem Meerkomponenten-Polymer zusammengesetzt sind, die aus einer oder mehreren Verteilungsöffnungen, worin Verteilungsöffnungen und Verteilungsnuten zum Verteilen der Polymerkomponenten ausgebildet sind; und einer Verteilerplatte einer untersten Schicht zusammengesetzt ist, die an der stromabwärtsseitigen Seite der Verteilungsplatte in der Richtung der Polymer-Spinnbahn positioniert ist und mit einer darin ausgebildeten Vielzahl von Inselkomponenten-Ausstoßöffnungen und einer Vielzahl von Meerkomponenten-Ausstoßöffnungen ausgebildet ist, wobei die Meerkomponenten-Ausstoßöffnungen auf einer virtuellen Kreislinie C1 mit einem auf der Inselkomponenten-Ausstoßöffnung zentrierten Radius R1 angeordnet sind, die Meerkomponenten-Ausstoßöffnungen auf einer virtuellen Kreislinie C2 mit einem auf der Inselkomponenten-Ausstoßöffnung zentrierten Radius R2 angeordnet sind, und die Inselkomponenten-Ausstoßöffnungen auf einer virtuellen Kreislinie C4 mit einem auf der Inselkomponenten-Ausstoßöffnung zentrierten Radius R4 angeordnet sind, und R1, R2 und R4 den nachfolgenden Ausdruck (1) erfüllen:
    (1) R 2 ≥ R 4 ≥ 3 × R 1
    Figure imgb0009
    und jede Ausstoßöffnung gemäß einer der nachfolgenden Gegebenheiten (2)(a) bis (2)(d) angeordnet ist:
    (2) Gegebenheit (a)
    C1: drei Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 120 Grad gleichmäßig angeordnet
    C2: drei Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 120 Grad gleichmäßig angeordnet
    C4: sechs Inselkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 60 Grad gleichmäßig angeordnet
    θ3: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C2 angeordnet, beträgt 60 Grad
    θ5: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C4 angeordnet, beträgt 30 Grad
    (2) Gegebenheit (b)
    C1: drei Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 120 Grad gleichmäßig angeordnet
    C2: drei Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 120 Grad gleichmäßig angeordnet
    C4: drei Inselkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 120 Grad gleichmäßig angeordnet
    θ3: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C2 angeordnet, beträgt 60 Grad
    θ5: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C4 angeordnet, beträgt 0 Grad
    (2) Gegebenheit (c)
    C1: sechs Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 60 Grad gleichmäßig angeordnet
    C2: sechs Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 60 Grad gleichmäßig angeordnet
    C4: sechs Inselkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 60 Grad gleichmäßig angeordnet
    θ3: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C2 angeordnet, beträgt 0 Grad
    θ5: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C4 angeordnet, beträgt 30 Grad
    (2) Gegebenheit (d)
    C1: vier Meerkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 90 Grad gleichmäßig angeordnet
    C2: acht Meerkomponenten-Ausstoßöffnungen sind angeordnet
    C4: vier Inselkomponenten-Ausstoßöffnungen sind in einem Mittenwinkel von 90 Grad gleichmäßig angeordnet
    θ3: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C2 angeordnet, beträgt 26,6 Grad
    θ5: ein Phasenwinkel zwischen zwei Ausstoßöffnungen, eine gemäß C1 angeordnet und die andere gemäß C4 angeordnet, beträgt 0 Grad.
  2. Verbund-Spinndüse nach Anspruch 1, die eine Vielzahl von Verteilungsplatten aufweist, wobei die Anzahl der Verteilungsöffnungen in den Verteilungsplatten zur stromabwärtsseitigen Seite in der Richtung der Polymer-Spinnbahn zunimmt, und die Verteilungsnut zum Verbinden der Verteilungsöffnung, die auf der stromaufwärtsseitigen Seite in der Richtung der Polymer-Spinnbahn positioniert ist, mit der Verteilungsöffnung ausgebildet ist, die auf der stromabwärtsseitigen Seite in der Richtung der Polymer-Spinnbahn positioniert ist, und eine Vielzahl von Verteilungslöchern konfiguriert sind, die mit einem Endbereich der Verteilungsnut verbunden sind.
  3. Verbund-Spinndüse nach Anspruch 1 oder 2, wobei in Bezug auf eine Vielzahl von Polymerströmen durch Bahnen, die aus der Verteilungsöffnung und der Verteilungsnut in der Verteilungsplatte zusammengesetzt sind, ein Durchmesser der Verteilungsöffnung in einer Bahn, in der eine Länge der Polymerströmung durch die Bahn von einem oberen Ende der Verteilungsplatte zur Verteilungsplatte der untersten Schicht vergleichsweise lang ist, größer als ein Durchmesser der Verteilungsöffnung in einer Bahn ist, in der eine Länge der Polymerströmung durch eine Bahn vergleichsweise kurz ist.
  4. Verbund-Spinndüse nach einem der Ansprüche 1 bis 3, wobei zumindest ein Teil der Meerkomponenten-Ausstoßöffnung in einem Bereich vorhanden ist, der mit zwei Linien umschlossen ist, welche die benachbarten beiden Inselkomponenten-Ausstoßöffnungen gemeinsam umgeben.
  5. Verbund-Spinndüse nach Anspruch 4, wobei zumindest ein Teil einer jeden der zumindest zwei Meerkomponenten-Ausstoßöffnungen in einem Bereich vorhanden ist, der mit zwei Linien umschlossen ist, welche die benachbarten beiden Inselkomponenten-Ausstoßöffnungen gemeinsam umgeben, und die beiden Meerkomponenten-Ausstoßöffnungen über ein Liniensegment angeordnet sind, das Mittelpunkte der beiden Inselkomponenten-Ausstoßöffnungen verbindet.
  6. Verbund-Spinndüse nach einem der Ansprüche 1 bis 5, wobei eine Dicke einer Verteilungsplatte mit einer Verteilungsnut, die darin auf der stromaufwärtsseitigen Seite in der Richtung der Polymer-Spinnbahn konfiguriert ist, größer als jene auf der stromabwärtsseitigen Seite ist.
  7. Verbund-Spinndüse nach einem der Ansprüche 1 bis 6, wobei ein Durchmesser DMIN einer minimalen Öffnung, die in der Verteilungsplatte oder der Verteilungsplatte einer untersten Schicht ausgebildet ist, und eine Dicke BT einer Platte, in der die minimale Öffnung ausgebildet ist, den nachfolgenden Ausdruck erfüllt: BT / DMIN ≤ 2
    Figure imgb0010
    wobei DMIN einen Durchmesser (mm) einer minimalen Öffnung repräsentiert, die in der Verteilungsplatte oder der Verteilungsplatte einer untersten Schicht ausgebildet ist, und BT eine Dicke (mm) der Verteilungsplatte oder der Verteilungsplatten einer untersten Schicht repräsentiert, in der die minimale Öffnung ausgebildet ist.
  8. Verbund-Spinndüse nach einem der Ansprüche 1 bis 7, wobei eine Dicke der Verteilungsplatte oder der Verteilungsplatte einer untersten Schicht 0,1 bis 0,5 mm beträgt.
  9. Verbund-Spinndüse nach einem der Ansprüche 1 bis 8, wobei eine Öffnungs-Packungsdichte der Inselkomponenten-Ausstoßöffnung 0,5 Öffnungen/mm2 oder darüber beträgt.
  10. Verfahren zum Herstellen einer Verbundfaser, wobei ein Schmelzspinnen mit einem Anteil des Inselkomponenten-Polymers von 50 % oder darüber durch eine Verbund-Spinnmaschine unter Verwendung der Verbund-Spinndüse nach einem der Ansprüche 1 bis 9 ausgeführt wird.
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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5821714B2 (ja) * 2012-03-09 2015-11-24 東レ株式会社 複合口金および複合繊維の製造方法
WO2014077359A1 (ja) * 2012-11-19 2014-05-22 東レ株式会社 複合口金および複合繊維、複合繊維の製造方法
BE1024623B1 (nl) * 2016-09-30 2018-05-24 Nv Michel Van De Wiele Spinplaat
MX2019015033A (es) 2017-06-28 2020-02-24 Toray Industries Paquete para hilar y metodo para producir fibra.
CN109112651A (zh) * 2018-10-19 2019-01-01 江苏尚科聚合新材料有限公司 一种海岛复合纺丝组件及一种复合纤维
CN109306532A (zh) * 2018-12-07 2019-02-05 常州纺兴精密机械有限公司 一种复合导电纤维及其纺制组件
CN111763998A (zh) * 2020-07-16 2020-10-13 常州纺兴精密机械有限公司 三组份并列复合纤维及其纺丝组件
CN112725912B (zh) * 2020-12-04 2022-05-10 江苏立新化纤科技有限公司 一种在直径104mm内制备144孔的涤锦复合喷丝组件
WO2023171363A1 (ja) * 2022-03-11 2023-09-14 東レ株式会社 複合繊維の製造方法および複合口金
CN114917686B (zh) * 2022-05-17 2024-04-02 苏州工业园区拓朴环保净化有限公司 长纤维复合滤芯的制备方法、滤芯及其模具

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0413688B1 (de) 1987-10-02 1994-06-22 Basf Corporation Vorrichtung und Verfahren zur Herstellung von profilierten Mehrkomponentenfasern
IT1252556B (it) * 1991-12-19 1995-06-19 Savio Spa Disco distributore di materiale termoplastico fuso per una testa di filatura
US5366804A (en) * 1993-03-31 1994-11-22 Basf Corporation Composite fiber and microfibers made therefrom
JPH07118913A (ja) 1993-10-25 1995-05-09 Mitsubishi Rayon Co Ltd 海島繊維の紡糸口金装置
JP3970440B2 (ja) 1998-10-02 2007-09-05 株式会社クラレ 海島構造繊維およびその製造方法
JP2000265316A (ja) * 1999-03-17 2000-09-26 Toray Ind Inc 紡糸パック
US6478563B1 (en) * 2000-10-31 2002-11-12 Nordson Corporation Apparatus for extruding multi-component liquid filaments
DE50301678D1 (de) * 2003-06-13 2005-12-22 Reifenhaeuser Gmbh & Co Kg Vorrichtung zur Herstellung von Filamenten
JP4602071B2 (ja) 2004-12-24 2010-12-22 日本バイリーン株式会社 海島型繊維用紡糸口金装置及びこれを用いた海島型繊維の製造方法
JP2007039858A (ja) * 2005-08-03 2007-02-15 Hiroshi Tabata 規則性極微構造繊維の形成方法
JP4676857B2 (ja) 2005-10-04 2011-04-27 帝人ファイバー株式会社 高タフネス極細繊維用海島型複合繊維
JP2008038275A (ja) 2006-08-03 2008-02-21 Teijin Fibers Ltd 分割型複合繊維の複合紡糸口金
JP5145004B2 (ja) 2007-10-05 2013-02-13 帝人ファイバー株式会社 海島型複合繊維用紡糸口金
DE112008003614A5 (de) * 2008-03-14 2011-01-27 Oerlikon Textile Gmbh & Co. Kg Vorrichtung zum Schmelzspinnen von Mehrkomponentenfasern
CN201268733Y (zh) * 2008-09-27 2009-07-08 宁波荣溢化纤科技有限公司 一种冻胶纺丝用喷丝组件
KR100953437B1 (ko) * 2009-02-13 2010-04-20 웅진케미칼 주식회사 해도사 제조용 방사구금

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EP2660369A1 (de) 2013-11-06
EP2660369A4 (de) 2015-01-07

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