EP2523901B1 - Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci - Google Patents

Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci Download PDF

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Publication number
EP2523901B1
EP2523901B1 EP11707220.7A EP11707220A EP2523901B1 EP 2523901 B1 EP2523901 B1 EP 2523901B1 EP 11707220 A EP11707220 A EP 11707220A EP 2523901 B1 EP2523901 B1 EP 2523901B1
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Prior art keywords
composition
powder
solution
preparing
iron
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Not-in-force
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EP11707220.7A
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German (de)
English (en)
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EP2523901A1 (fr
Inventor
Aleksandr Paukson
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Uusen Tarvi
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Uusen Tarvi
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • C09K21/04—Inorganic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/37—Phosphates of heavy metals
    • C01B25/375—Phosphates of heavy metals of iron
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34—Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C23C22/17—Orthophosphates containing zinc cations containing also organic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/22—Orthophosphates containing alkaline earth metal cations

Definitions

  • the invention relates to an iron phosphate composition, to a method of manufacturing such composition and using the composition for high temperature impregnating solutions, paints, emulsions, pastes, putties for protecting surfaces of wood, metal, stone, concrete, paper, plastic, textiles, etc as well as in chemical industry for manufacturing reactants.
  • the composition can be used in industry, agriculture and forestry as fire resistant, anticorrosive, decorative or antiseptic agent.
  • the obtained aqueos solution solidifies slowly at lower temperatures (e.g., at normal room temperature). However, at higher temperatures the composition solidifies quickly.
  • US patent US6350474 describes phosphate composition comprising (stated in parts by weight): orthophosphoric acid (85% solution) about 100, iron oxide from about 20 to about 41, metal powder from about 0.5 to about 2.5 and water from about 30 to about 70.
  • This phosphate composition is aqueous solution with cold solidification capacity.
  • Metal powder is aluminium, magnesium, zinc, calcium, cobalt, ytrium, nickel or scandium. The temperature rises during exothermal reaction to 40-50°C. Metal powder content above 2.5 part by weight will increase the temperature to 120-130°C, by which dissolved particles stick together and ortophosphate anion will turn into polyphosphate. Heat released in the exothermal reaction is enough for dissolution of iron oxide and metal powder in 2 hours.
  • the output of the reaction represents transparent, brownish, sticky liquid with density of 1.5 kg/m 3 .
  • Such non-toxic non-carcinogenic solution is produced ecologically safely and is used for coating wood, metal, concrete, textiles and paper for increasing fire resistance of these.
  • the amount of the solution for 1 square meter is 0.2 liters.
  • the solution does not damage the surface, does not alter its color and material quality.
  • the solution obtained is used as anticorrosive solution for removing the rust and for protecting against further rusting.
  • the solution is used also for producing paints and ceramic materials. Because of its antimicrobic and antibacterial properties the phosphate composition can be used in medicine, agriculture and forestry.
  • Estonian utility model EE00444U1 describes producing of phosphate composition, having the following ratio of ingredients in parts by weight: orthophosphoric acid 100, iron oxide 20-41, metal powder 0.5-2.5, and water 30-70. To the mixture is added ethyl alcohol or glycerine 0.05-0.2 parts by weight for increasing the stability and wetting ability. Aluminium powder is used.
  • Estonian utility model EE00549U1 describes surface protecting material, having the following ratio of ingredients in parts by weight: orthophosphoric acid 60-80, iron oxide 50-60, metal powder 5-10, and water 40-60.
  • the surface protecting material includes additionally aluminium nitrate 7-10 parts by weight and copper sulphate 7-10 parts by weight.
  • Fe 2 O 3 , TiO 2 and MnO 2 are added as pigments. If the surface of e.g. wood is treated with such surface protecting material, the fire resistance increases and putrefaction decreases. This will guarantee long stability of wood. Long-time persistence of other materials, for example paper, textiles, metal, is guaranteed in the same way.
  • the present invention relates to a new iron phosphate composition and its synthesis using exothermal process. For improving physical properties and for increasing stability calcium and citric acid are added into the composition.
  • the iron phosphate composition of the present invention has better stability and better fire resistance compared to known compositions and has anticorrosive, antibacterial and antiseptic properties. No organic solvents such as ethyl alcohol and glycerol were used.
  • the method for preparing of iron phosphate composition according to the invention comprises: pouring orthophosphoric acid into reactor, switching on the mixer, adding iron(III)oxide, adding metal powder, keeping the temperature in the range suitable for reaction (preferably 120-130°C) by adding water and adding calcium and citric acid. All the mentioned components are taken in parts by weight: orthophosphoric acid (85% solution) 100, iron(III)oxide 10-19, metal powder (Al, Zn, Mg) 1.1-1.8 (preferably 1.1 to 1.6), water 8-30 (preferably 10-30), calcium 1-3 (preferably 1-2) and citric acid 0.5 - 1.8 (preferably 0.5 - 1.5).
  • the product is prepared at higher temperature and substantially less water is added during the exothermal preparation process.
  • a continuously rotating mixer reactor with blades made, e.g. from stainless steel, is used.
  • the reactor has inside ventilation and its volume depends on desired amount and purpose of the composition.
  • the method for preparing of iron phosphate composition according to the invention comprises: pouring orthophosphoric acid into a mixing reactor, switching on the mixer, adding iron(III)oxide, adding metal powder, keeping the temperature in the range suitable for the reaction (preferably 120-130°C) by adding water and adding calcium and citric acid. All the mentioned components are taken in ratio in parts by weight: orthophosphoric acid 100, iron(III)oxide 10-19, metal powder (Al, Zn, Mg) 1.1 to 1.8, preferably 1.1 to 1.6, water 8-30, preferably 10 - 30, calcium 1-3, preferably 1-2, and citric acid 0.5 - 1.8, preferably 0.5 - 1.5.
  • a continuously rotating mixer reactor with blades made, e.g. from stainless steel, is used.
  • the reactor has inside ventilation and its volume depends on desired amount and purpose of the composition.
  • reaction time depends on volume of the reactor. After the reaction is finished, enough water is added to the concentrate to make a product with desired properties; which is left into reactor for sufficient time (e.g., for several hours) to settle, then it is pored out of the reactor.
  • the temperature range between 120 and 130°C is enough to dissolve iron oxide, metal powder and additives in less than two hours.
  • the dissolved particles do not stick and do not form polyphosphates at this temperature when reactor with constantly rotating blades is used and because of the ratio of ingridients.
  • the compound does not evaluate smoke, CO 2 and other dangerous compounds in an amount harmful for humans and environment.
  • compositions with different content in parts by weight have been used in the following tests about flammability and burning of impregnated wood: TUV NORD (Estonia, test protocol no TM-17/08), TUV SUD (Singapore, test report no S08ME C03108/OKN), EXOVA (Canada test ASTM E 84 SBC Report 09-002-716 9/2009) and Forest and Wood Products Research Development Institute, Jelgava, Lithuania (test report no 220/009).
  • Solution of iron phosphate composition obtained is not toxic as inorganic compounds of 5 valence phosphorus are harmless for human.
  • the production of solution of iron phosphate composition is ecologically safe.
  • the main purpose of using the solution of iron phosphate composition is coating wood, metal, plastic, paper, stone, concrete, textiles, etc or impregnating materials that can be impregnated, mixing with other components for achieving fire resistance and for giving antiseptic properties to treated materials.
  • the amount of solution of iron phosphate composition for treating one square meter is around 200 to 400g.
  • the surfaces are treated with vacuum impregnation, paintbrush, sprayer or paint roller 2-3 times, while drying time is 2-48 hours.
  • Fire resistant and fire protective coating agent is transparent, light pink aqueous solution with density of 1.1 - 1.20 kg/m 3 , which forms non-flammable layer on the treated surface of material.
  • non-flammable resins and adhesives 5-35%, elastic or hard, film forming layer (for example white, yellow, mat, with shine) is created with density of 1.15-1.50 kg/m 3 , which is fire barrier and can not be washed out.
  • Anticorrosive solution with density of 1.40-1.50 kg/m 3 is used for removing or for keeping off the rust by adding first layer, after that the rust is removed.
  • the second layer is added for forming protecting layer on surface, which can be coated later with the same solution or suitable paint. 5-35% resins or adhesives can be added by mixing for obtaining the coating as needed.
  • Powder is made by evaporating of concentrate or by crystallization and adding organic solvents. By drying and crushing of the material fine, dispersed, light gray powder is prepared with 80% of particles with size of ⁇ 0.003 mm and 10% of particles with size of >0.05 mm. Depending of the desired characteristic of the plastic 8-25% of powder is added on melt temperature (before molding) by mixing and for giving the shade to plastic.
  • the emulsion is prepared by mixing of the concentrate with water in ratio 1:4 and by adding to this solution 2-5% sodium hydroxide (NaOH) or potassium hydroxide (KOH).
  • the emulsion is prepared for coating metal or stone, for forming upper layer in protecting film against enviromental damage.
  • Putty is used also for fire protection and against corrosion of metal, wood, stones of the building constuctions. It is also used for restoring fire resistant coatings, for binding chamotte stoves and chamotte lining in heating elements. Because of high fire resistance (1800° C) it is suitable for high-temperature heating elements of kettles, glassmelters etc., also for conventional stoves and fireplaces. It prevents overheating and annealing of metal.
  • Enough water is added to the composition so that the composition would stay well on the surfase to be treated.
  • Putty should be put on surface as 1-2 mm layer using putty spade or other suitable applicator. It can be applied directly on rust.
  • the drying time is 24 hours at 18° C.
  • the composition of putty is as following (% by weight): sand 10%, argillaceous 56%, Al 2 O 3 12%, 20% solution of iron phosphate 22%.
  • Solutions, powders, emulsions and putties are kept in closed plastic or glass ware.
  • Table 1 Orthophosphoric acid (85%) Iron(III) oxide Al powder Water Ca Citric acid Time, h Temperature, °C Stability 1 100 10 1.1 8 0.5 0.5 2-4 140 to 150 stable 2 100 10 1.1 10 0,5 0.5 2-4 120 to 130 stable 3 100 11 1.2 15 0.8 0.7 2-4 120 to 130 stable 4 100 13 1.3 20 1 1 2-4 120 to 130 stable 5 100 15 1.4 20 1.3 1 2-4 120 to 130 stable 6 100 17 1.5 25 1.8 1.3 2-4 120 to 130 stable 7 100 19 1.6 30 2 1.5 2-4 120 to 130 stable 8 100 19 1.8 30 3 1.8 2-4 120 to 130 stable
  • Yielded mixture of iron phosphates does not need sedimentation.
  • the composition is ready for use. Water, additives, pigments, etc are added for obtaining a product with desired properties.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Claims (15)

  1. La composition de phosphate de fer comprenant une solution d'acide orthophosphorique, de l'oxyde de fer (III), de la poudre métallique, et de l'eau, caractérisée en ce que la composition comprend du calcium et de l'acide citrique.
  2. La composition selon la revendication 1, dans laquelle la quantité d'ingrédients dans la solution, mésurée en parties en poids, est la suivante : solution à 85% de l'acide orthophosphorique 100 oxyde de fer (III) de 10 à 19 poudre métallique de 1,1 à 1,8 eau de 8 à 30 calcium de 1 à 3 acide citrique de 0,5 à 1,8.
  3. La composition selon la revendication 2, comprenant de la poudre métallique en parties en poids de 1,1 à 1,6.
  4. La composition selon les revendications 1 à 3, dans laquelle ladite poudre métallique est choisie dans le groupe consistant en Al, Zn et Mg.
  5. La composition selon les revendications 1 à 3, dans laquelle ladite poudre métallique est une poudre d'Al.
  6. Le procédé de production d'une composition de phosphate de fer selon les revendications 1 à 5, consistant en un versement d'une solution à 85% de l'acide orthophosphorique dans un réacteur, une addition de l'oxyde de fer (III), ainsi qu'une addition de l'eau, de la poudre de métal, de l'acide citrique, et du calcium dans les 1 à 2 heures afin de contrôler la température nécessaire pour la réaction et pour neutraliser l'acidité.
  7. L'utilisation de la composition selon l'une quelconque des revendications 1 à 5 pour la préparation de réactifs destinés pour le revêtement et l'imprégnation des matériaux choisis parmi le groupe consistant en le bois, le métal, le plastique, le papier, la pierre, le béton, et les textiles, afin de garantir la résistance au feu et les propriétés antiseptiques, selon laquelle ledit matériau est revêtu de ladite composition en ayant recours, au moins une fois, à une imprégnation sous vide, à un pinceau, à un pulvérisateur, ou à un rouleau de peinture.
  8. L'utilisation de la composition selon l'une quelconque des revendications 1 à 5 pour la préparation des solutions de protection contre l'incendie et des solutions anticorrosives, des émulsions, des mastics, et des matières plastiques.
  9. L'utilisation de la composition selon la revendication 8, dans laquelle la solution de protection contre l'incendie comprend de 5 à 35% des résines ou des adhésifs non inflammables.
  10. L'utilisation de la composition selon la revendication 7 pour la protection des métaux avec une solution anticorrosive comprenant de 5 à 35% des résines ou des adhésifs non inflammables, selon laquelle la surface est couverte d'une première couche pour transformer la rouille, suivie d'une seconde couche appliquée afin de former une couche protectrice sur la surface.
  11. L'utilisation de la composition selon la revendication 8 pour la préparation d'une poudre par l'évaporation ou par la cristallisation de la composition et par l'addition des solvants organiques à la poudre, suivi d'un séchage et d'un broyage en poudre, dont jusqu'à 80% de particules sont d'une taille de <0,003 mm et jusqu'à 10 % de particules sont d'une taille de > 0,05 mm, avec l'ajout de 8 à 25% de ladite poudre au matériau en plastique, à son température de fusion, avant le moulage.
  12. L'utilisation de la composition selon la revendication 7 pour créer une couche de protection sur ledit matériau contre l'action nuisible de l'environnement, en diluant la composition avec de l'eau dans un rapport en poids de 1:4, et en ajoutant d'une solution de 2 % à 5 % d'hydroxyde de sodium ou d'hydroxyde de potassium.
  13. L'utilisation de la composition selon la revendication 7 pour la préparation d'un mastic permettant de fournir ou de rétablir des revêtements résistants au feu, pour lier les briques de chamotte, ainsi que pour la bardage en chamotte chez les éléments chauffants comme par exemple les chaudières, fours de verre, poêles et cheminées des habitations, car elle évite la surchauffe ainsi que le recuit du métal.
  14. L'utilisation de la composition selon la revendication 13, dans laquelle la composition du dit mastic est la suivante (% en poids) : sable 10 %, argile 56 %, Al2O3 12 %, solution à 20 % de ladite composition 22 %
    tandis que la distribution des particules dans le mastic est la suivante :
    < 0,4 mm - 1 %
    < 0,09 mm - 2 %
    et le procédé comprend l'ajout de l'eau en une quantité suffisante pour permettre l'application du mastic sur la surface à traiter.
  15. Le procédé selon la revendication 6, comprenant la préparation de la composition en ayant recours à une réaction exothermique à la température allant de 120 à 130 °C, et la préparation d'une poudre par l'évaporation ou cristallisation du concentré, ainsi que par l'ajout des solvants organiques à la poudre, suivi d'un séchage et d'un broyage de la compostition en une poudre dont aux environs 80 % de particules sont d'une taille de < 0,003 mm et 10 % de particules sont de taille de > 0,05 mm, et qui soit chimiquement uniforme et hydroscopique.
EP11707220.7A 2010-01-15 2011-01-14 Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci Not-in-force EP2523901B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EEP201000005 2010-01-15
PCT/IB2011/050178 WO2011086526A1 (fr) 2010-01-15 2011-01-14 Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci

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Publication Number Publication Date
EP2523901A1 EP2523901A1 (fr) 2012-11-21
EP2523901B1 true EP2523901B1 (fr) 2017-09-06

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EP (1) EP2523901B1 (fr)
EA (1) EA201270691A1 (fr)
EE (1) EE01207U1 (fr)
NO (1) NO2523901T3 (fr)
WO (1) WO2011086526A1 (fr)

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WO2011086526A1 (fr) 2010-01-15 2011-07-21 Uusen, Tarvi Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci
CN102431988B (zh) * 2011-10-12 2013-05-29 浙江南都电源动力股份有限公司 一种由碱式醋酸铁制备低成本电池级磷酸铁材料的方法
EE201700016A (et) * 2016-03-21 2017-10-16 Paukson Anita Tuldtõrjuv ja -tõkestav kompositsioon, selle valmistamise meetod ja kasutamine tulekahjude leviku piiramiseks ja orgaanilise materjali tulekindluse suurendamiseks
CN109941980B (zh) * 2019-03-13 2022-06-14 乳源东阳光新能源材料有限公司 一种窄径距的磷酸铁的制备方法
CN112678792B (zh) * 2020-12-28 2022-05-13 大连博融新材料有限公司 一种磷酸铁、其制备方法及用途

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EE00444U1 (et) 2004-03-17 2004-07-15 Nargo Holding OÜ Fosforiühend
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EE05408B1 (et) 2008-08-22 2011-04-15 Gennadi Nikolaev Raudfosfaadip?hine kompositsioon, selle valmistamine ja kasutamine
WO2011086526A1 (fr) 2010-01-15 2011-07-21 Uusen, Tarvi Composition de phosphate de fer et procédé pour la préparation et l'utilisation de celle-ci

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EP2523901A1 (fr) 2012-11-21
WO2011086526A1 (fr) 2011-07-21
NO2523901T3 (fr) 2018-02-03
EA201270691A1 (ru) 2014-01-30

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