EP2358467B1 - Mélangeur - Google Patents

Mélangeur Download PDF

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Publication number
EP2358467B1
EP2358467B1 EP09764834.9A EP09764834A EP2358467B1 EP 2358467 B1 EP2358467 B1 EP 2358467B1 EP 09764834 A EP09764834 A EP 09764834A EP 2358467 B1 EP2358467 B1 EP 2358467B1
Authority
EP
European Patent Office
Prior art keywords
tool
motor
shaft
mixer
housing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09764834.9A
Other languages
German (de)
English (en)
Other versions
EP2358467A1 (fr
Inventor
Andreas Seiler
Wolfgang WÖRNER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Maschinenfabrik Gustav Eirich GmbH and Co KG
Original Assignee
Maschinenfabrik Gustav Eirich GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Maschinenfabrik Gustav Eirich GmbH and Co KG filed Critical Maschinenfabrik Gustav Eirich GmbH and Co KG
Priority to PL09764834T priority Critical patent/PL2358467T3/pl
Publication of EP2358467A1 publication Critical patent/EP2358467A1/fr
Application granted granted Critical
Publication of EP2358467B1 publication Critical patent/EP2358467B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00Mixers with rotating receptacles
    • B01F29/80Mixers with rotating receptacles rotating about a substantially vertical axis
    • B01F29/83Mixers with rotating receptacles rotating about a substantially vertical axis with rotary paddles or arms, e.g. movable out of the receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F29/00Mixers with rotating receptacles
    • B01F29/60Mixers with rotating receptacles rotating about a horizontal or inclined axis, e.g. drum mixers
    • B01F29/64Mixers with rotating receptacles rotating about a horizontal or inclined axis, e.g. drum mixers with stirring devices moving in relation to the receptacle, e.g. rotating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30Driving arrangements; Transmissions; Couplings; Brakes
    • B01F35/32Driving arrangements
    • B01F35/321Disposition of the drive
    • B01F35/3212Disposition of the drive mounted on the receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30Driving arrangements; Transmissions; Couplings; Brakes
    • B01F35/32Driving arrangements
    • B01F35/321Disposition of the drive
    • B01F35/3214Disposition of the drive at the upper side of the axis, e.g. driving the stirrer from the top of a receptacle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C5/00Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
    • B22C5/04Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by grinding, blending, mixing, kneading, or stirring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C5/00Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
    • B22C5/04Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by grinding, blending, mixing, kneading, or stirring
    • B22C5/0409Blending, mixing, kneading or stirring; Methods therefor
    • B22C5/0454Blending, mixing, kneading or stirring; Methods therefor with bottom disc rotating about a vertical axis or with receptacle rotating about a vertical or steeply inclined axis, e.g. with fixed or driven tools, such as rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/30Driving arrangements; Transmissions; Couplings; Brakes
    • B01F2035/35Use of other general mechanical engineering elements in mixing devices
    • B01F2035/351Sealings

Definitions

  • the present invention relates to a mixer with a mixing container and a tool shaft arranged at least partially in the mixing container, wherein the tool shaft has a working end, to which a working tool is fastened or can be attached, and a drive end, which is mounted by means of two tool bearings spaced apart from each other, and wherein a drive motor is provided with a motor shaft for driving the tool shaft.
  • Such a mixer is known, for example from the DE 35 20 409 A1 ,
  • the embodiment shown there comprises a pressure-resistant mixer with a filling opening, a rotating mixing vessel having an emptying device, with mixing tools arranged eccentrically to the mixing vessel axis in the interior of the mixing vessel.
  • FIG. 1 shows a vertical section through a mixer.
  • the mixer 1 has a mixing container 3 accommodated in a mixer housing 2, which can be rotated about a vertical axis of rotation. To ensure this rotation of the mixing container 3 is rotatably mounted on a ball bearing 4.
  • the mixing container may have on its underside an emptying opening (not shown in the figure).
  • the mixer housing 2 has a housing cover 5. Inside the mixing container 3, a working tool 6 designed as a mixing tool is arranged inside the mixing container 3, a working tool 6 designed as a mixing tool is arranged. It can be seen that the working tool 6 about a vertical axis, which is spaced from the axis of rotation of the mixing container 3, is rotatable.
  • a drive end of the working tool 6 is guided through the housing cover 5 and driven by means of the drive motor 7 via, for example, V-belt 9.
  • the work tools 6 are fixed to a tool shaft 8, which has a drive end to which the V-belt 9 engages, and a working end to which the working tools 6 designed as a mixing tool are fastened.
  • the tool shaft 8 is formed in two parts in the embodiment shown, wherein the two parts can be connected to each other via the flange 10 or separated from each other. This flange 10 is among other things there, the working tool 6 against another working tool 6, such. B. one Star vortex against a pin vortex swap.
  • the work tool if it shows signs of wear, be replaced with a new one.
  • both the mixing container 3 and the tool shaft 8 rotate, it can lead to significant lateral forces on the tool shaft 8, which are caused by the material flow through the rotating mixing container 3, especially since the tool shaft is held only on one side in the housing cover 5.
  • the size of the shear force depends inter alia on the type of mix and of course on the rotational speed of both mixing container 3 and the working tool 6.
  • two tool bearings 11, 12 are provided at the drive end, each bearing the shaft with a diameter D.
  • the tool bearings 11, 12 are bolted to the mixer housing 2 or the housing cover 5 via a flange 13.
  • the V-belt 9 then engages the drive end of the tool shaft 8.
  • the drive motor 7 has a motor shaft 20, which is also held by two motor bearings 14, 15. It can be seen that the diameter d 'of the motor shaft 20 is significantly smaller than the diameter D of the tool shaft 8.
  • the belt transmission consisting generally of a set of multiple V-belts or timing belt, a maintenance-intensive machine element. These components must be checked at regular intervals for correct voltage and this must be adjusted if necessary. Likewise, both V-belts and toothed belts are subject to wear and must therefore be replaced at regular intervals.
  • the GB 330834 also shows a mixer with a mixing container and a mixing shaft arranged in the tool shaft to which a working tool is attached. This drive shaft is driven by a drive motor.
  • the DE 197 12 324 C2 and the DE 39 42 679 A1 show mixing devices for mixing liquids.
  • the motors of the mixing device are held by means of rotor bearings.
  • this object is achieved by a mixer according to claim 1.
  • one of the bearings which is provided for the storage of the tool shaft, simultaneously used for the storage of the motor shaft.
  • Motor shaft and tool shaft are therefore directly connected.
  • the motor is arranged between the two tool bearings and the motor shaft is preferably mounted by means of the two tool bearings.
  • the motor shaft is preferably mounted by means of the two tool bearings.
  • the bearings for the tool shaft also serve as a bearing for the motor shaft.
  • no distinction can be made in this embodiment between engine and tool shaft, since a portion of the shaft acts as a motor shaft and another portion of the same shaft as a tool shaft.
  • a direct drive preferably a direct drive and more preferably a three-phase synchronous motor (servo motor, torque motor, reluctance motor) is used.
  • a three-phase synchronous motor servo motor, torque motor, reluctance motor
  • the bearing of the motor shaft facing the tool shaft is suitable for absorbing particularly high radial and axial forces. It is a combined radial thrust bearing (Radiax bearing), e.g. designed as a spherical roller or self-aligning ball bearings and particularly preferably as a double-row spherical roller bearings.
  • Radiax bearing radial thrust bearing
  • a further preferred embodiment provides that the diameter of the motor shaft differs at the two tool bearings, wherein preferably the diameter of the motor shaft d "on the tool shaft facing away from the tool bearing smaller, preferably at least 30%, more preferably at least 50% smaller than the diameter of the motor shaft D at the other tool bearing.
  • the motor is expediently arranged in a motor housing, wherein both tool bearings are arranged on or in the motor housing.
  • the motor housing having a first outer flange, with which the motor housing and thus the motor is fixed to the mixer housing.
  • the motor housing having a second outer flange which is also secured to the mixer housing, wherein the second outer flange preferably has a larger average diameter than the first outer flange.
  • the motor housing could for example have a circular cross-section, in which case expediently also the outer flanges have a circular cross-section. In principle, however, other cross sections, such as square or rectangular cross-sections are conceivable. Characterized in that the second outer flange has a larger average diameter, the motor can be easily attached to the mixer housing.
  • the mixer housing may include a through-stage opening having a first smaller diameter portion and a second larger diameter portion, the second portion having a mean diameter greater than the mean diameter of the first outer flange and smaller than the average diameter of the second Outside flange is.
  • the smallest mean diameter of the passage stage opening in the mixer housing is greater than the largest outer diameter of the working tool. By this measure, the entire work tool including the engine can be removed via the passage step opening.
  • both flanges have holes for attaching the flanges to the mixer housing.
  • the larger flange may have additional openings, which are preferably larger than the holes for attachment, which are provided so that a tool can access through the opening to the holes or fasteners in the smaller flange. This facilitates the attachment of the motor housing to the mixer housing.
  • the tool shaft consists of two parts detachably fastened to one another, wherein one part is connected in one piece with the motor shaft, while the other part carries the working tool.
  • the detachable connection can be made via a flange connection.
  • the tool shaft may also be formed integrally with the motor shaft.
  • FIG. 1 shows an embodiment of the prior art, which has already been described above.
  • FIG. 2 shows a first embodiment of the invention.
  • the drive motor 7 is accommodated in a motor housing 16, the motor housing 16 being fastened to the mixer cover 5 by means of two outer flanges 13, 17.
  • the tool shaft 8 simultaneously acts as a motor shaft 21 at its drive end.
  • the motor shaft 21, which is partially formed in the embodiment shown as a hollow shaft is held by the spherical roller bearing 18 and the radial bearing 19.
  • the second outer flange 13, which faces the product space, ie the mixing container more, has a smaller outer diameter than the first outer flange 17.
  • the entire motor can be inserted from the outside into the housing cover 5, so that first the outer flange with the smaller Outer diameter is inserted into a corresponding stepped bore in the container lid until it rests on the bottom of the extended bore.
  • the distance between the two outer flanges 13, 17 is dimensioned such that in the in FIG. 2 shown situation, both flanges can be screwed to the housing cover 5.
  • the engine can be easily detached and removed from the container lid.
  • FIG. 3 which simultaneously shows a second embodiment of the mixer according to the invention.
  • the engine including working tool 6 has been released from the housing cover 5, so that the engine including working tool 6 can be removed from the corresponding opening in the container lid.
  • the embodiment shown differs from that in FIG. 2 shown embodiment in that the flange 10 is missing, so that here tool shaft and motor shaft are integrally formed.
  • the axis of rotation of the working tool is arranged eccentrically to the axis of rotation of the mixing container.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Accessories For Mixers (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Food-Manufacturing Devices (AREA)
  • Mixers With Rotating Receptacles And Mixers With Vibration Mechanisms (AREA)

Claims (11)

  1. Mélangeur comprenant un récipient de mélange et un arbre d'outil (8) aménagé au moins en partie dans le récipient de mélange, dans lequel l'arbre d'outillage présente une extrémité de travail, à laquelle un outil de travail (6) est fixé ou peut être fixé, et une extrémité d'entraînement, qui est montée au moyen de deux paliers d'outils distants l'un de l'autre, dans lequel il est prévu un moteur d'entraînement (7) avec un arbre moteur (21) pour entraîner l'arbre d'outillage (8), caractérisé en ce que l'arbre moteur (21) est monté par au moins l'un des deux paliers d'outils distants l'un de l'autre et en ce que l'un des paliers, de préférence le palier agencé le plus près de l'extrémité de travail de l'arbre d'outillage (8), est un palier radial-axial(18), de préférence un roulement à tonneaux ou un roulement à billes à rotule et, mieux encore, un roulement à tonneaux à deux rangées (18).
  2. Mélangeur selon la revendication 1, caractérisé en ce que le moteur est aménagé entre les deux paliers d'outils et l'arbre moteur (21) est monté de préférence au moyen des deux paliers d'outils de sorte que l'arbre d'outillage serve également d'arbre moteur.
  3. Mélangeur selon la revendication 1 ou 2, caractérisé en ce que le moteur est un moteur à entraînement direct, de préférence un moteur synchrone à courant triphasé, de préférence un moteur à torsion, un servomoteur ou un moteur à reluctance.
  4. Mélangeur selon l'une quelconque des revendications 1 à 3, caractérisé en ce que le diamètre de l'arbre moteur (21) se distingue sur les deux paliers d'outils, dans lequel, de préférence, le diamètre de l'arbre moteur (21) sur le palier d'outil opposé à l'arbre d'outillage (8) est plus petit, de préférence d'au moins 30 % et en particulier d'au moins 50 % plus petit que le diamètre de l'arbre moteur (21) sur l'autre palier d'outil.
  5. Mélangeur selon l'une quelconque des revendications 1 à 4, caractérisé en ce que le moteur est installé dans un boîtier de moteur (16), dans lequel les deux paliers d'outils sont agencés sur ou dans le boîtier de moteur (16).
  6. Mélangeur selon la revendication 5, caractérisé en ce que le boîtier de moteur (16) présente un premier flasque externe (13) et le mélangeur un boîtier de mélangeur (2), dans lequel est agencé le récipient de mélange (3), dans lequel le flasque externe est fixé sur le boîtier de mélangeur, tout particulièrement sur le couvercle (5) du boîtier.
  7. Mélangeur selon la revendication 6, caractérisé en ce que le boîtier de moteur (16) présente un second flasque externe (17), qui est également fixé sur le boîtier de mélangeur, dans lequel le second flasque externe (17) présente de préférence un diamètre moyen plus grand que le premier flasque externe (13).
  8. Mélangeur selon la revendication 7, caractérisé en ce que le boîtier de mélangeur présente une ouverture de passage en gradins avec une première section de plus faible diamètre moyen et une seconde section de plus grand diamètre moyen, dans lequel la seconde section présente un diamètre moyen qui est plus grand que le diamètre moyen du premier flasque externe (13) et plus petit que le diamètre moyen du second flasque externe (17).
  9. Mélangeur selon la revendication 7, caractérisé en ce que l'ouverture de passage en gradins la plus petite est plus grande que le plus grand diamètre externe de l'outil de travail (6).
  10. Mélangeur selon l'une quelconque des revendications 1 à 9, caractérisé en ce que l'arbre d'outillage (8) présente deux sections fixées l'une à l'autre de manière amovible, dans lequel une des sections est formée d'un seul tenant avec l'arbre moteur (21).
  11. Mélangeur selon l'une quelconque des revendications 1 à 9, caractérisé en ce que l'arbre d'outillage (8) et l'arbre moteur (21) sont formés d'un seul tenant.
EP09764834.9A 2008-12-17 2009-12-04 Mélangeur Active EP2358467B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL09764834T PL2358467T3 (pl) 2008-12-17 2009-12-04 Mieszalnik

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008054842A DE102008054842A1 (de) 2008-12-17 2008-12-17 Mischer
PCT/EP2009/066458 WO2010076120A1 (fr) 2008-12-17 2009-12-04 Mélangeur doté d'un récipient de mélange rotatif

Publications (2)

Publication Number Publication Date
EP2358467A1 EP2358467A1 (fr) 2011-08-24
EP2358467B1 true EP2358467B1 (fr) 2014-07-16

Family

ID=41666436

Family Applications (1)

Application Number Title Priority Date Filing Date
EP09764834.9A Active EP2358467B1 (fr) 2008-12-17 2009-12-04 Mélangeur

Country Status (20)

Country Link
US (1) US9694331B2 (fr)
EP (1) EP2358467B1 (fr)
JP (1) JP5610163B2 (fr)
KR (1) KR101665493B1 (fr)
CN (1) CN102300629B (fr)
AU (1) AU2009334941B2 (fr)
BR (1) BRPI0923457B1 (fr)
CA (1) CA2743256C (fr)
DE (1) DE102008054842A1 (fr)
DK (1) DK2358467T3 (fr)
ES (1) ES2495747T3 (fr)
MX (1) MX2011006161A (fr)
PE (1) PE20120504A1 (fr)
PL (1) PL2358467T3 (fr)
PT (1) PT2358467E (fr)
RU (1) RU2521571C2 (fr)
TW (1) TWI523682B (fr)
UA (1) UA105912C2 (fr)
WO (1) WO2010076120A1 (fr)
ZA (1) ZA201103278B (fr)

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US11684900B2 (en) 2018-03-16 2023-06-27 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Hygienic mixer which is pivotably mounted

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DE102010027885A1 (de) * 2010-04-16 2012-02-09 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Mischvorrichtung mit Verschleißschutzauskleidung
CN102327755A (zh) * 2010-07-12 2012-01-25 南通全技纺织涂层有限公司 用于织物涂层浆料的搅拌机
US8845940B2 (en) 2012-10-25 2014-09-30 Carboncure Technologies Inc. Carbon dioxide treatment of concrete upstream from product mold
CN102908929A (zh) * 2012-11-18 2013-02-06 苏州蓝王机床工具科技有限公司 一种液态类物料搅拌机
AU2014212083A1 (en) 2013-02-04 2015-08-06 Coldcrete, Inc. System and method of applying carbon dioxide during the production of concrete
US9376345B2 (en) 2013-06-25 2016-06-28 Carboncure Technologies Inc. Methods for delivery of carbon dioxide to a flowable concrete mix
US9388072B2 (en) 2013-06-25 2016-07-12 Carboncure Technologies Inc. Methods and compositions for concrete production
US10927042B2 (en) 2013-06-25 2021-02-23 Carboncure Technologies, Inc. Methods and compositions for concrete production
RU2534871C1 (ru) * 2013-06-27 2014-12-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Ярославский государственный технический университет" Бетономешалка с импульсной стержневой мешалкой со свирелеобразными стержнями
WO2015123769A1 (fr) 2014-02-18 2015-08-27 Carboncure Technologies, Inc. Carbonatation de mélanges de ciment
WO2015154174A1 (fr) 2014-04-07 2015-10-15 Carboncure Technologies, Inc. Capture de dioxyde de carbone intégrée
DE102014117509A1 (de) * 2014-11-28 2016-06-02 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Vorrichtung zur Aufbereitung und Kühlung von Gießereiformsand
JP6343683B2 (ja) * 2015-01-19 2018-06-13 株式会社アルバック 撹拌装置
CN105170001B (zh) * 2015-08-25 2017-09-15 晋江兴翼机械有限公司 组合式搅拌装置
DE102016106536A1 (de) * 2016-04-08 2017-10-12 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Mischwelle
SG11201810010PA (en) 2016-04-11 2018-12-28 Carboncure Tech Inc Methods and compositions for treatment of concrete wash water
CN106582394A (zh) * 2016-12-09 2017-04-26 陈红 一种干电池生产工艺用原料密封混合设备
WO2018232507A1 (fr) 2017-06-20 2018-12-27 Carboncure Technologies Inc. Procédés et compositions pour le traitement des eaux de lavage de béton
DE102018106184A1 (de) * 2018-03-16 2019-09-19 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Mischvorrichtung mit Dichtung
DE102018106188A1 (de) * 2018-03-16 2019-09-19 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Vorrichtung zur Umsetzung einer Linearbewegung in einem stationären System in eine Drehbewegung um eine Schwenkachse in einem sich um eine Drehachse drehenden System
DE102018106192A1 (de) * 2018-03-16 2019-09-19 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Mischvorrichtung mit zweiteiligem Verschlussdeckel
DE102018106187A1 (de) * 2018-03-16 2019-09-19 Maschinenfabrik Gustav Eirich Gmbh & Co. Kg Mischvorrichtung mit Verschlusselement
CN108854759A (zh) * 2018-06-19 2018-11-23 广州高蒂丝生物科技有限公司 一种化妆品生产用高效原料混合装置
CN108771988A (zh) * 2018-06-21 2018-11-09 陈文� 一种流体动态混合器
EP3608015B1 (fr) 2018-08-08 2021-10-06 Harro Höfliger Verpackungsmaschinen GmbH Dispositif de fourniture de poudre pour un doseur de poudre
CN114160753A (zh) * 2021-11-26 2022-03-11 马鞍山市绿科环保科技有限公司 一种在铸造砂处理固体废弃物中分选原砂的方法

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JP2012512017A (ja) 2012-05-31
DE102008054842A1 (de) 2010-07-01
KR101665493B1 (ko) 2016-10-24
ES2495747T3 (es) 2014-09-17
RU2521571C2 (ru) 2014-06-27
PL2358467T3 (pl) 2014-11-28
KR20110097959A (ko) 2011-08-31
CA2743256A1 (fr) 2010-07-08
AU2009334941A1 (en) 2011-07-07
PT2358467E (pt) 2014-08-29
CN102300629B (zh) 2016-08-03
ZA201103278B (en) 2012-07-25
CN102300629A (zh) 2011-12-28
US9694331B2 (en) 2017-07-04
PE20120504A1 (es) 2012-05-10
CA2743256C (fr) 2017-03-07
BRPI0923457A2 (pt) 2016-01-12
TWI523682B (zh) 2016-03-01
TW201029732A (en) 2010-08-16
UA105912C2 (uk) 2014-07-10
JP5610163B2 (ja) 2014-10-22
MX2011006161A (es) 2011-07-28
EP2358467A1 (fr) 2011-08-24
US20110249527A1 (en) 2011-10-13
RU2011129206A (ru) 2013-01-27
DK2358467T3 (da) 2014-09-22
AU2009334941B2 (en) 2012-09-20
WO2010076120A1 (fr) 2010-07-08

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