EP2300562B1 - Verfahren zur herstellung von pulverisierter kohle - Google Patents
Verfahren zur herstellung von pulverisierter kohle Download PDFInfo
- Publication number
- EP2300562B1 EP2300562B1 EP09757534.4A EP09757534A EP2300562B1 EP 2300562 B1 EP2300562 B1 EP 2300562B1 EP 09757534 A EP09757534 A EP 09757534A EP 2300562 B1 EP2300562 B1 EP 2300562B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- drying gas
- pulverizer
- volume
- temperature
- injected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/08—Non-mechanical pretreatment of the charge, e.g. desulfurization
- C10B57/10—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/04—Safety devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
- B02C23/24—Passing gas through crushing or disintegrating zone
- B02C23/34—Passing gas through crushing or disintegrating zone gas being recirculated to crushing or disintegrating zone
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/001—Injecting additional fuel or reducing agents
- C21B5/003—Injection of pulverulent coal
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B17/00—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement
- F26B17/10—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by fluid currents, e.g. issuing from a nozzle, e.g. pneumatic, flash, vortex or entrainment dryers
- F26B17/101—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by fluid currents, e.g. issuing from a nozzle, e.g. pneumatic, flash, vortex or entrainment dryers the drying enclosure having the shape of one or a plurality of shafts or ducts, e.g. with substantially straight and vertical axis
- F26B17/103—Machines or apparatus for drying materials in loose, plastic, or fluidised form, e.g. granules, staple fibres, with progressive movement with movement performed by fluid currents, e.g. issuing from a nozzle, e.g. pneumatic, flash, vortex or entrainment dryers the drying enclosure having the shape of one or a plurality of shafts or ducts, e.g. with substantially straight and vertical axis with specific material feeding arrangements, e.g. combined with disintegrating means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
- F26B21/06—Controlling, e.g. regulating, parameters of gas supply
Definitions
- the present invention generally relates to a method for the production of pulverized coal, in particular for use in the metallurgical industry.
- pulverized coal In the metallurgical industry, pulverized coal is generally injected as combustible into blast furnaces. It is important, in order to ensure good functioning of the blast furnace, that the pulverized coal is of good quality, i.e. that the pulverized coal has the right consistence, size and humidity level.
- the pulverized coal is generally produced in a grinding and drying installation, wherein raw coal is ground in a pulverizer and dried to the right humidity level before the resulting pulverized coal is fed to a hopper for storage or direct use in a blast furnace. It is known to subject the freshly ground coal to a stream of hot gas so as to dry the pulverized coal.
- the pulverized coal can e.g.
- the hot gas from the pulverizer to a filter, where the pulverized coal is then separated from the gas and fed to the hopper. Part of the gas is recirculated and heated before it is reintroduced into the pulverizer.
- the oxygen level in the drying gas is monitored and, if the measured oxygen level is found to be too high, the amount of fresh air introduced into the drying gas in the recirculation line is reduced. This allows lowering the oxygen level in the drying gas.
- the reduction of the amount of fresh air introduced into the drying gas may not be enough to sufficiently reduce the oxygen level. Indeed, once the amount of fresh air introduced into the drying gas is reduced to zero, i.e. no more fresh air is introduced, the oxygen level may in such circumstances still be too high. In order to avoid any damage to the installation it may then be necessary to shut down the grinding and drying installation. Such a shut down not only leads to a loss of production, but also to extra costs relating to the replacement or conditioning of the drying gas.
- US-A-4,244,529 discloses a method for crushing and drying of coal, wherein the oxygen level is controlled by the addition of water vapor into the primary air stream prior to entering the pulverizer during startup and shutdown.
- EP-A-0 467 375 discloses a method for producing pulverized and dried coal, wherein a drying gas is heated in a hot gas generator (4) and fed to a pulverizer (3), to which coal is fed (1), collecting a mixture of gas and coal, separating them using a filter (42) and recycling part of the gas to the hot gas generator.
- GB-A-1 467 744 discloses a method for crushing and drying of coal, wherein the temperature is controlled by the addition of water via line (30) before the drying gas enters the crusher-dispenser (14).
- the object of the present invention is to provide an improved method for producing pulverized coal, which does not present the drawbacks of the prior art methods. This object is achieved by a method as claimed in claim 1.
- the present invention proposes a method for producing pulverized coal, the method comprising the steps of:
- the method further comprises injecting, in the recirculation line, a volume of fresh air into the drying gas wherein, if the determined oxygen level is higher than the predetermined oxygen level threshold, the volume of fresh air injected into the drying gas is reduced.
- the method comprises first reducing the volume of fresh air injected into the drying gas, and then, if the volume of fresh air injected reaches zero and the oxygen level is still higher than the predetermined oxygen threshold, injecting water into the heated drying gas before it is fed into the pulverizer, the volume of water injected being calculated so as to reduce the oxygen level below the predetermined oxygen level threshold.
- the predetermined oxygen threshold is chosen to be between 0 and 14 volume %, preferably between 5 and 12 volume %.
- the method comprises the further steps of determining an exit temperature of the mixture of drying gas and pulverized coal exiting the pulverizer; and controlling the exit temperature by controlling a volume of water injected into the heated drying gas before feeding it into the pulverizer.
- the temperature of the drying gas entering the pulverizer can be adjusted rapidly so as to take into account temperature differences occurring due to raw coal with different levels of humidity being introduced into the pulverizer. It is thereby possible to maintain the temperature of the drying gas exiting the pulverizer, hereafter referred to as exit temperature, as constant as possible.
- the present aspect is of particular advantage during a startup phase of the installation, wherein the method comprises a startup cycle wherein heated drying gas is fed through the pulverizer without introducing raw coal, the exit temperature being kept below a first temperature threshold, and a grinding cycle wherein heated drying gas is fed through the pulverizer and raw coal is introduced into the pulverizer, the exit temperature being kept at a preferred working temperature.
- the method comprises:
- drying gas is generally fed through the installation before raw coal is introduced into the pulverizer. This allows the individual components to be heated to the desired working temperature.
- the drying gas which may be heated to a temperature above the maximum tolerated exit temperature, can be cooled down again so that the temperature downstream of the pulverizer does not exceed the first temperature threshold.
- the volume of water injected into the heated drying gas can be determined based on the exit temperature. Alternatively, the volume of water injected into the heated drying gas can be determined based on a pressure drop measured across the pulverizer. It is not excluded to use other measurements, alone or in combination, to determine the volume of water to be injected into the heated drying gas.
- the method comprises the further steps of reducing the heating of the drying gas; and reducing the volume of water injected into the heated drying gas to maintain the desired exit temperature.
- This allows reducing consumption of energy once the installation is running.
- the importance of the overheating and subsequent cooling of the drying gas is particularly important during the startup phase of the installation, wherein it allows providing a buffer to compensate for the drop in temperature occurring when the introduction of raw coal is started. Once the installation is running, only smaller temperature drops might occur and the buffer can be reduced.
- part of the drying gas can be removed as exhaust gas.
- hot gas can also be injected into the drying gas in the recirculation line.
- the method may also comprise continuous monitoring of the exit temperature and comparing the measured exit temperature to a maximum temperature, wherein, if the measured exit temperature exceeds the maximum temperature, the volume of water injected into the heated drying gas is increased. This allows using the water injection means used for general process control, to be used for emergency cooling also.
- Fig.1 shows a schematic representation of a grinding and drying installation used for carrying out the method according to the present invention.
- Figure 1 shows a grinding and drying installation for producing pulverized coal using the method according to the present invention.
- Such a grinding and drying installation 10 comprises a pulverizer 20 into which raw coal is fed via a conveyor 22.
- the raw coal is crushed between internal mobile pieces (not shown) or any other conventional grinding means into a fine powder.
- a hot drying gas is fed through the pulverizer 20 to dry the pulverized coal.
- the drying gas enters the pulverizer 20 through a gas inlet 24.
- the grinding and drying installation 10 comprises a hot gas generator 26 in which a drying gas can be heated to a predefined temperature.
- a hot gas generator 26 is powered by a burner 27, such as e.g. a multiple lance burner.
- the heated drying gas is carried from the hot gas generator 26 to the pulverizer 20 via a conduit 28.
- pulverized coal is entrained.
- a mixture of pulverized coal and drying gas is carried from the pulverizer 20, via a conduit 32, to a filter 34, where the pulverized coal is again removed from the drying gas and fed to a pulverized coal collector 36, ready further use.
- the drying gas exiting the filter 34 is fed to a recirculation line 38 for feeding it back to the hot gas generator 26.
- the recirculation line 38 comprises fan means 40 for circulating the drying gas through the installation.
- the fan means 40 may be located upstream or downstream of a line 42, e.g. a stack, which is used to extract part of the drying gas from the recirculation line 38.
- the recirculation line 38 further comprises gas injection means 44 for injecting fresh air and/or hot gas into the recirculation line 38.
- the injected fresh air and/or hot gas is mixed with the recycled drying gas.
- the injected fresh air allows reducing the due point of the drying gas and the injected hot gas is used to improve the thermal balance of the grinding and drying circuit.
- the installation 10 comprises water injection means 46 arranged downstream of the hot gas generator 26 and upstream of the pulverizer 20.
- the importance of the water injection means 46 will become clear in the description herebelow.
- the water injection means 46 helps to regulate the dew point of the drying gas by regulating the oxygen level therein.
- part of the drying gas is extracted via the line 42 and fresh air may be injected via the gas injection means 44.
- the oxygen level is monitored for safety reasons by means of an oxygen sensor 45 and, if the oxygen level is found to be too high, the gas injection means 44 is instructed to reduce the amount of fresh air introduced into the dying gas.
- a problem however occurs when the gas injection means 44 reaches its shut-off point, i.e. when the gas injection means 44 is completely turned off and no fresh air is injected into the dying gas. If the oxygen level is then still found to be too high, the volume of fresh air injected into the dying gas cannot be further reduced and a shutdown of the installation becomes necessary.
- the oxygen level in the drying gas can be reduced by injecting water into the drying gas by means of the water injection means 46.
- the water injection means 46 can be instructed to increase the volume of water injected into the drying gas, thereby reducing the oxygen level downstream of the filter 34.
- the oxygen level is first reduced by the conventional method of reducing the volume of fresh air injected into the dying gas by the gas injection means 44 and if this is not sufficient, the oxygen level is then further reduced by increasing the volume of water injected into the drying gas by the water injection means 46.
- Another function of the water injection means 46 may be to help regulate the temperature of the drying gas at the exit of the pulverizer 20.
- the drying gas is heated to a predefined temperature in the hot gas generator 26 and fed through the pulverizer 20.
- the temperature of the drying gas is reduced in the pulverizer 20 as the heat from the drying gas is used to dry the pulverized coal.
- the level of humidity of the raw coal determines the temperature loss of the drying gas.
- the temperature of the mixture of pulverized coal and drying gas exiting the pulverizer 20, hereafter referred to as the exit temperature is monitored, e.g. by means of a temperature sensor 48.
- the temperature of the drying gas entering the pulverizer needs to be controlled, which is generally achieved by controlling the output power of the burner 27 of the hot gas generator 26.
- This process has a relatively slow response time, meaning that once the installation has determined that the exit temperature is too high or too low and the burner 27 has been made to react in consequence, some time passes before the exit temperature reaches the correct exit temperature again.
- the response time is particularly important during a startup phase of the installation. Indeed, initially, heated drying gas is fed through the installation before the raw coal is introduced. This allows the installation to heat up and reach the ideal working conditions. When, after a certain time, raw coal is then introduced into the pulverizer 20, the exit temperature suddenly drops well below the desired exit temperature. Conventionally, the burner 27 then reacts by further heating the drying gas so as to reach the desired exit temperature. The desired exit temperature is then however only obtained after a long delay and any pulverized coal obtained in the meantime may have to be discarded because it has not been sufficiently dried. Indeed, during a transition period wherein the exit temperature is too low, unusable coal slurry is generally obtained instead of dried pulverized coal.
- this method shows its most dramatic advantages during the startup phase, i.e. during a transition period shortly after raw coal is initially introduced into the pulverizer.
- the present method is however also advantageous during normal operation of the installation.
- the exit temperature can be quickly brought back to the desired exit temperature should a sudden drop in temperature occur.
- the water injection means 46 is also used for an emergency cooling.
- the method may comprise continuous monitoring of the exit temperature and comparing the measured exit temperature to a maximum temperature. When the measured exit temperature exceeds the maximum temperature, the water injection means 46 is instructed to increasing the volume of water injected into the heated drying gas, thereby reducing the temperature of the drying gas entering the pulverizer 20 and consequently also the temperature of the drying gas exiting the pulverizer 20.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Food Science & Technology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Disintegrating Or Milling (AREA)
- Drying Of Solid Materials (AREA)
- Coke Industry (AREA)
Claims (15)
- Verfahren zur Herstellung von pulverisierter Kohle, wobei das Verfahren folgende Schritte umfasst:- Erwärmen eines Trocknungsgases in einem Heißgaserzeuger auf eine vordefinierte Temperatur;- Leiten des erwärmten Trocknungsgases in eine Pulverisiermühle;- Einführen von Rohkohle in die Pulverisiermühle, wobei die Pulverisiermühle die Rohkohle in pulverisierte Kohle umwandelt;- Sammeln einer Mischung von Trocknungsgas und pulverisierter Kohle aus der Pulverisiermühle und Leiten der Mischung zu einem Filter, wobei der Filter die getrocknete pulverisierte Kohle von dem Trocknungsgas trennt;- Sammeln der getrockneten pulverisierten Kohle zur weiteren Verwendung und Leiten des Trocknungsgases von dem Filter zu einer Rückführleitung, um zumindest einen Teil des Trocknungsgases zum Heißgaserzeuger zurückzuleiten;- Ermitteln eines Sauerstoffgehalts im Trocknungsgas und Vergleichen des ermittelten Sauerstoffgehalts mit einem vorgegebenen Sauerstoffgehalt-Schwellenwert,dadurch gekennzeichnet, dass
der Sauerstoffgehalt im Trocknungsgas während eines Mahlzyklus ermittelt wird, wobei erwärmtes Trocknungsgas durch die Pulverisiermühle geleitet wird und Rohkohle in die Pulverisiermühle eingeführt wird, und,
wenn während des Mahlzyklus der ermittelte Sauerstoffgehalt höher als der vorgegebene Sauerstoffgehalt-Schwellenwert ist, ein Wasservolumen in das erwärmte Trocknungsgas eingespritzt wird, bevor es in die Pulverisiermühle geleitet wird, wobei das eingespritzte Wasservolumen berechnet wird, um den Sauerstoffgehalt unter den vorgegebenen Sauerstoffgehalt-Schwellenwert zu senken. - Verfahren nach Anspruch 1,
wobei in der Rückführleitung ein Frischluftvolumen ins Trocknungsgas eingeblasen wird und
wobei, wenn der ermittelte Sauerstoffgehalt höher als der vorgegebene Sauerstoffgehalt-Schwellenwert ist, das ins Trocknungsgas eingeblasene Frischluftvolumen reduziert wird. - Verfahren nach Anspruch 2, wobei,
wenn das eingeblasene Frischluftvolumen null erreicht und der Sauerstoffgehalt immer noch höher als der vorgegebene Sauerstoffschwellenwert ist, ein Wasservolumen in das erwärmte Trocknungsgas eingespritzt wird, bevor es in die Pulverisiermühle geleitet wird, wobei das eingespritzte Wasservolumen berechnet wird, um den Sauerstoffgehalt unter den vorgegebenen Sauerstoffgehalt-Schwellenwert zu senken. - Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei der vorgegebene Sauerstoffschwellenwert derart ausgewählt ist, dass er zwischen 0 und 14 Volumen-% liegt.
- Verfahren nach Anspruch 4, wobei der vorgegebene Sauerstoffschwellenwert derart ausgewählt ist, dass er zwischen 5 und 12 Volumen-% liegt.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, umfassend:Ermitteln einer Austrittstemperatur der aus der Pulverisiermühle austretenden Mischung von Trocknungsgas und pulverisierter Kohle; undSteuern der Austrittstemperatur durch Steuern eines Wasservolumens, das in das erwärmte Trocknungsgas eingespritzt wird, bevor es in die Pulverisiermühle geleitet wird, wobei das eingespritzte Wasservolumen berechnet wird, um die Austrittstemperatur auf eine bevorzugte Arbeitstemperatur zu bringen.
- Verfahren nach Anspruch 6, wobei das Verfahren Folgendes umfasst:- einen Anfahrzyklus, wobei erwärmtes Trocknungsgas durch die Pulverisiermühle ohne Einführen von Rohkohle geleitet wird, wobei die Austrittstemperatur unter einem ersten Temperaturschwellenwert gehalten wird, und- einen Mahlzyklus, wobei erwärmtes Trocknungsgas durch die Pulverisiermühle geleitet wird und Rohkohle in die Pulverisiermühle eingeführt wird, wobei die Austrittstemperatur bei einer bevorzugten Arbeitstemperatur gehalten wird,wobei- während des Anfahrzyklus das Trocknungsgas auf eine Temperatur über dem ersten Temperaturschwellenwert erwärmt wird und ein Wasservolumen in das erwärmte Trocknungsgas eingespritzt wird, wobei das Wasservolumen berechnet wird, um die Temperatur des erwärmten Trocknungsgases zu senken, um eine Austrittstemperatur unter dem ersten Temperaturschwellenwert zu erhalten; und- am Anfang des Mahlzyklus das in das erwärmte Trocknungsgas eingespritzte Wasservolumen reduziert wird, um eine Abnahme der Austrittstemperatur auszugleichen.
- Verfahren nach Anspruch 6 oder 7, wobei das in das erwärmte Trocknungsgas eingespritzte Wasservolumen um einen Betrag reduziert wird, der durch die Austrittstemperatur bestimmt wird.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei das in das erwärmte Trocknungsgas eingespritzte Wasservolumen um einen Betrag reduziert wird, der durch einen durch die Pulverisiermühle hindurch gemessenen Druckabfall bestimmt wird.
- Verfahren nach irgendeinem der Ansprüche 7 bis 9, wobei während des Mahlzyklus und nach dem Ausgleich der Abnahme der Austrittstemperatur das Verfahren folgende Schritte umfasst:- Reduzieren der Erwärmung des Trocknungsgases; und- Reduzieren des in das erwärmte Trocknungsgas eingespritzten Wasservolumens, um die bevorzugte Austrittstemperatur beizubehalten.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei in der Rückführleitung zumindest ein Teil des Trocknungsgases als Abgas entzogen wird.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei in der Rückführleitung Frischluft und/oder Heißgas ins Trocknungsgas eingeblasen wird.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, umfassend:fortlaufendes Überwachen der Austrittstemperatur und Vergleichen der gemessenen Austrittstemperatur mit einer Maximaltemperatur; und,wenn die gemessene Austrittstemperatur die Maximaltemperatur überschreitet, Vergrößern des in das erwärmte Trocknungsgas eingespritzten Wasservolumens.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei das Trocknungsgas in einem durch einen Lanzenbrenner betriebenen Heißgaserzeuger erwärmt wird.
- Verfahren nach irgendeinem der vorangehenden Ansprüche, wobei Wasser mittels einer zwischen dem Heißgaserzeuger und der Pulverisiermühle angeordneten Wassereinspritzvorrichtung in das erwärmte Trocknungsgas eingespritzt wird.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU91451A LU91451B1 (en) | 2008-06-02 | 2008-06-02 | Method for producing pulverized coal |
PCT/EP2009/056763 WO2009147153A1 (en) | 2008-06-02 | 2009-06-02 | Method for producing pulverized coal |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2300562A1 EP2300562A1 (de) | 2011-03-30 |
EP2300562B1 true EP2300562B1 (de) | 2015-02-25 |
Family
ID=40228023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09757534.4A Active EP2300562B1 (de) | 2008-06-02 | 2009-06-02 | Verfahren zur herstellung von pulverisierter kohle |
Country Status (13)
Country | Link |
---|---|
US (1) | US20110192079A1 (de) |
EP (1) | EP2300562B1 (de) |
JP (1) | JP5758800B2 (de) |
KR (1) | KR101590920B1 (de) |
CN (1) | CN102046758A (de) |
AU (1) | AU2009253965B2 (de) |
BR (1) | BRPI0913362B1 (de) |
CA (1) | CA2725276C (de) |
LU (1) | LU91451B1 (de) |
RU (1) | RU2502780C2 (de) |
TW (1) | TWI475105B (de) |
UA (1) | UA104863C2 (de) |
WO (1) | WO2009147153A1 (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX339441B (es) | 2009-12-04 | 2016-05-26 | Barrick Gold Corp | Separacion de minerales de cobre a partir de la pirita usando el tratamiento con aire-metabisulfito. |
US8349036B2 (en) | 2010-01-06 | 2013-01-08 | General Electric Company | Systems and method for heating and drying solid feedstock in a gasification system |
JP5949414B2 (ja) * | 2012-10-05 | 2016-07-06 | 新日鐵住金株式会社 | 粉砕プラント排ガス制御装置、粉砕プラント排ガス制御方法、及びコンピュータプログラム |
US9494319B2 (en) * | 2013-03-15 | 2016-11-15 | General Electric Technology Gmbh | Pulverizer monitoring |
KR101522781B1 (ko) * | 2013-10-17 | 2015-05-26 | 주식회사 포스코 | 미분탄을 이용한 코크스용 점결탄의 제조방법 및 이를 이용한 코크스 제조방법 |
CN104841544B (zh) * | 2015-06-02 | 2017-08-11 | 天华化工机械及自动化研究设计院有限公司 | 一种氮气密闭循环pva制粉方法 |
KR101759329B1 (ko) * | 2015-12-23 | 2017-07-18 | 주식회사 포스코 | 코크스 오븐 가스의 증량시스템 및 그 증량방법 |
CN107051689A (zh) * | 2017-01-16 | 2017-08-18 | 中国电力工程顾问集团西南电力设计院有限公司 | 一种石灰石干磨制备布置结构 |
CN107488770A (zh) * | 2017-10-17 | 2017-12-19 | 中冶赛迪工程技术股份有限公司 | 一种高炉喷煤制粉系统加湿工艺及装置 |
RU2771032C1 (ru) * | 2021-08-13 | 2022-04-25 | Федеральное автономное учреждение "25 Государственный научно-исследовательский институт химмотологии Министерства обороны Российской Федерации" | Технологическая линия получения мелкодисперсного угольного топлива |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1467744A (en) * | 1922-10-24 | 1923-09-11 | Winkler William | Caster |
AR207472A1 (es) * | 1974-08-16 | 1976-10-08 | Coaltek Ass | Un aparato para calentar material granuloso a temperaturas elevadas |
DE2656046A1 (de) * | 1976-12-10 | 1978-06-29 | Babcock Bsh Ag | Verfahren und einrichtung zur steuerung der trocknungstemperatur, insbesondere bei duesenrohrtrocknern |
JPS54108062A (en) * | 1978-02-13 | 1979-08-24 | Hosokawa Micron Kk | Explosionnproof pulverizing method and its device |
SU787448A1 (ru) * | 1978-04-14 | 1980-12-15 | Восточный научно-исследовательский углехимический институт | Способ термической подготовки угл дл коксовани |
DE2852164C2 (de) * | 1978-12-02 | 1985-06-20 | Klöckner-Humboldt-Deutz AG, 5000 Köln | Verfahren und Vorrichtung zum Betrieb eines Heißgaserzeugers innerhalb einer Mahltrocknungsanlage |
US4244529A (en) * | 1979-05-07 | 1981-01-13 | The Cleveland Cliffs Iron Company | Inerting of pulverizing mills for combustible materials |
DE2949720C2 (de) * | 1979-12-11 | 1982-08-26 | Alfelder Eisenwerke Carl Heise, KG vorm. Otto Wesselmann & Cie., 3220 Alfeld | Verfahren und Vorrichtung zum Trocknen und Erhitzen von feuchter Kohle |
DE3128865C2 (de) * | 1981-07-22 | 1989-02-02 | Rheinische Braunkohlenwerke AG, 5000 Köln | Verfahren und Vorrichtung zum Mahltrocknen von vorgebrochener Rohbraunkohle zu Braunkohlenstaub |
KR900002655B1 (ko) * | 1983-08-01 | 1990-04-21 | 더 뱁콕 앤드 윌콕스 컴퍼니 | 석탄미분쇄기의 안전제어시스템 |
SU1736995A1 (ru) * | 1989-05-23 | 1992-05-30 | Восточный научно-исследовательский углехимический институт | Способ подготовки угл дл коксовани |
JPH0742491B2 (ja) * | 1990-07-20 | 1995-05-10 | 川崎製鉄株式会社 | 高炉吹込み微粉炭乾燥装置 |
DE4223151C2 (de) * | 1992-07-14 | 1994-11-10 | Loesche Gmbh | Verfahren zur Mahlung von Rohbraunkohle |
DE10221739A1 (de) * | 2002-05-16 | 2003-12-04 | Kloeckner Humboldt Wedag | Kreislaufmahlanlage mit Mühle und Sichter |
-
2008
- 2008-06-02 LU LU91451A patent/LU91451B1/en active
-
2009
- 2009-06-02 RU RU2010154520/05A patent/RU2502780C2/ru active
- 2009-06-02 CA CA2725276A patent/CA2725276C/en not_active Expired - Fee Related
- 2009-06-02 BR BRPI0913362-3A patent/BRPI0913362B1/pt active IP Right Grant
- 2009-06-02 UA UAA201015594A patent/UA104863C2/uk unknown
- 2009-06-02 US US12/994,927 patent/US20110192079A1/en not_active Abandoned
- 2009-06-02 AU AU2009253965A patent/AU2009253965B2/en active Active
- 2009-06-02 WO PCT/EP2009/056763 patent/WO2009147153A1/en active Application Filing
- 2009-06-02 EP EP09757534.4A patent/EP2300562B1/de active Active
- 2009-06-02 CN CN2009801198479A patent/CN102046758A/zh active Pending
- 2009-06-02 KR KR1020107029782A patent/KR101590920B1/ko active IP Right Grant
- 2009-06-02 TW TW098118117A patent/TWI475105B/zh active
- 2009-06-02 JP JP2011511036A patent/JP5758800B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
KR20110016463A (ko) | 2011-02-17 |
BRPI0913362B1 (pt) | 2018-01-23 |
RU2010154520A (ru) | 2012-07-20 |
TW201009064A (en) | 2010-03-01 |
JP5758800B2 (ja) | 2015-08-05 |
US20110192079A1 (en) | 2011-08-11 |
TWI475105B (zh) | 2015-03-01 |
BRPI0913362A2 (pt) | 2015-11-24 |
UA104863C2 (uk) | 2014-03-25 |
RU2502780C2 (ru) | 2013-12-27 |
KR101590920B1 (ko) | 2016-02-02 |
CN102046758A (zh) | 2011-05-04 |
AU2009253965A1 (en) | 2009-12-10 |
JP2011522916A (ja) | 2011-08-04 |
CA2725276C (en) | 2016-02-09 |
CA2725276A1 (en) | 2009-12-10 |
WO2009147153A1 (en) | 2009-12-10 |
LU91451B1 (en) | 2009-12-03 |
EP2300562A1 (de) | 2011-03-30 |
AU2009253965B2 (en) | 2014-12-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2300562B1 (de) | Verfahren zur herstellung von pulverisierter kohle | |
EP2389456B1 (de) | Verfahren zur herstellung von pulverisierter kohle | |
EP2300561B1 (de) | Verfahren zur herstellung von pulverisierter kohle | |
CN116481329A (zh) | 一种可调节循环烟气用途及用量的系统及方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20101223 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: JUNK, GUY Inventor name: STAMATAKIS, GEORGES Inventor name: SCHMIT, LOUIS |
|
DAX | Request for extension of the european patent (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: F26B 21/06 20060101ALI20140828BHEP Ipc: C10B 57/10 20060101AFI20140828BHEP Ipc: F26B 17/10 20060101ALI20140828BHEP Ipc: C21B 5/00 20060101ALI20140828BHEP Ipc: B02C 23/34 20060101ALI20140828BHEP Ipc: B02C 23/04 20060101ALI20140828BHEP |
|
INTG | Intention to grant announced |
Effective date: 20141001 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602009029568 Country of ref document: DE Effective date: 20150409 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 712014 Country of ref document: AT Kind code of ref document: T Effective date: 20150415 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: T3 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150525 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150526 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150625 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602009029568 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
26N | No opposition filed |
Effective date: 20151126 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150602 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20160229 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150602 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150630 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150630 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: UEP Ref document number: 712014 Country of ref document: AT Kind code of ref document: T Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20090602 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150225 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230524 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20230516 Year of fee payment: 15 Ref country code: DE Payment date: 20221011 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20230516 Year of fee payment: 15 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20230515 Year of fee payment: 15 |