Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
  • H01H9/00—Details of switching devices, not covered by groups H01H1/00 - H01H7/00
  • H01H9/30—Means for extinguishing or preventing arc between current-carrying parts
  • H01H9/44—Means for extinguishing or preventing arc between current-carrying parts using blow-out magnet
  • H01H9/446—Means for extinguishing or preventing arc between current-carrying parts using blow-out magnet using magnetisable elements associated with the contacts
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
  • H01H1/00—Contacts
  • H01H1/0094—Switches making use of nanoelectromechanical systems [NEMS]
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
  • H01H1/00—Contacts
  • H01H1/02—Contacts characterised by the material thereof
  • H01H1/021—Composite material
  • H01H1/023—Composite material having a noble metal as the basic material
  • H01H1/0237—Composite material having a noble metal as the basic material and containing oxides
  • H01H1/02372—Composite material having a noble metal as the basic material and containing oxides containing as major components one or more oxides of the following elements only: Cd, Sn, Zn, In, Bi, Sb or Te
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T29/00—Metal working
  • Y10T29/49—Method of mechanical manufacture
  • Y10T29/49002—Electrical device making
  • Y10T29/49117—Conductor or circuit manufacturing
  • Y10T29/49124—On flat or curved insulated base, e.g., printed circuit, etc.

Definitions

• the present invention relates to the field of electrical contacts. It relates, more particularly, to the use of an electrical contact material with arc extinguishing effect.
• Such a type of material finds its application mainly for the realization of so-called "low voltage" contacts, that is to say whose operating range is approximately between 10 and 1000V and between 1 and
• the energy released by the electric arc is sufficient to melt the material constituting the pads, resulting not only in the degradation of the metal parts but also sometimes their solder, resulting in the blockage of the metal. 'apparatus.
• pseudo-alloys comprising a matrix of silver or copper and, inserted in this matrix, a fraction consisting of about 10 to 50% by volume of refractory particles.
• refractory particles For example, Ni, C, W, WC, CdO, SnO 2
• Ni, C, W, WC, CdO, SnO 2 of a size generally between 1 and 5 microns.
• This method does not allow to limit the mergers and, because of their repetition, problems of erosion and welding of the studs can occur in the short or medium term.
• Another solution, described in US Pat. No. 3,626,124 is to use a material comprising single-domain magnetic particles.
• Such particles are spontaneously magnetized in a random orientation in the absence of an applied external field. These particles are therefore initially magnetized and do not need an external source of magnetization.
• the field generated by each magnetized particle acts on the arc of cutoff, facilitating its blowing.
• the particles described remain monodomains even after a heating beyond their Curie temperature so that the blowing efficiency is not affected by heating due to the arc of cut, during previous openings of contact.
• each particle acts individually on the breaking arc so that the magnetic blow effect is very small. This solution is therefore not satisfactory.
• EP 1 482 525 discloses a magnetic device placed at a distance from the contact and which generates an elongating magnetic field. an electric arc that would occur between the studs, in order to extinguish it.
• the extra cost, size and overweight caused by this solution make it problematic, especially for automotive applications.
• An object of the present invention is therefore to overcome these disadvantages, by proposing to use an electrical contact material to make contact pads whose operation is not altered in the short term or in the long term, by the energy of an electric arc. Disclosure of the invention More specifically, the invention relates to the use of a material comprising a conductive metal matrix and magnetic entities representing between 8 and 80% by weight of the material and comprising hard magnetic phases, said magnetic entities being non-magnetized and being capable of being made magnetized with a mean orientation, defined by the direction of a magnetic field applied to said material, for blowing an electric arc between two pads of electrical contacts, at least one of which comprises said material, and thus reduce the duration of the arc.
• the invention also relates to the use of a material comprising a matrix of conductive metal and magnetic entities representing between 8 and 80% by weight of the material and comprising hard magnetic phases, said magnetic entities initially not magnetized having been rendered magnetized with an average orientation, defined by the direction of a magnetic field applied to said material, for blowing an electric arc between two pads of electrical contacts, at least one of which comprises said material, and thus reducing the duration of the bow.
• the material may further comprise a refractory fraction stable at a temperature above 900 ° C.
• At least one of the phases of the magnetic entities is a hard magnetic compound based on rare earths.
• said material is capable of generating a magnetic induction field, measured at its surface, greater than 20 mT, preferably greater than 60 mT, and more preferably greater than 100 mT.
• said pads define between them an axis, at least one of said pads being made in said material and having a magnetization generating a magnetic field perpendicular to said axis.
• at least one of said pads which comprises said material with the magnetic entities has an overlayer comprising a material selected from silver and copper.
• the present invention relates to a constituent material of an electrical contact pad comprising a conductive metal matrix and magnetic entities representing between 8 and 80% by weight of the material and comprising hard magnetic phases, said magnetic entities being non-magnetized and capable of being made magnetized with a mean orientation, defined by the direction of a magnetic field applied to said material, at least one of the magnetic phases being a rare earth-based compound; except the samarium.
• the present invention also relates to a constituent material of an electrical contact pad comprising a conductive metal matrix and magnetic entities representing between 8 and 80% by weight of the material and comprising hard magnetic phases, said magnetic entities initially not magnetized having been made magnetized with a mean orientation, defined by the direction of a magnetic field applied to said material, at least one of the magnetic phases being a compound based on rare earths, with the exception of samarium.
• the present invention relates to a method of manufacturing an electrical contact pad comprising the following steps:
• the invention relates to a pair of pads of electrical contacts, said pads defining between them an axis, in which that at least one of said pads is made of a material as defined above and has a magnetization generating a magnetic field perpendicular to said axis.
• a pair of electrical contact pads comprising, at the cathode, a contact pad made of a material defined above.
• the contact material used in the present invention essentially consists of:
• a conductive metal matrix generally made of silver or copper
• magnetic entities representing between 8 and 80% by weight of the material and comprising hard magnetic phases, said magnetic entities being initially non-magnetized and capable of being magnetized, with a mean orientation, defined by the direction of an applied magnetic field on said material.
• the material used according to the invention initially contains multidomain magnetic entities forming a set initially largely unmagnetized, and then to be magnetized by the application of a field.
• the material used according to the invention does not initially contain spontaneously magnetized monodomain entities.
• the magnetic entities represent between 10 and 50% by weight of the material, preferably between 12 and 30% by weight, and more preferably between 18 and 22% by weight of said material.
• the magnetic entities comprise magnetic phases that can be obtained from one or more ferromagnetic or ferrimagnetic hard compounds.
• they are chosen from compounds based on rare earths, among which mention may be made of the so-called RE-Fe-B type compounds (RE being the abbreviation of Rare Earth, Rare Earth).
• RE is neodymium or praseodymium.
• Other compounds of the RE-M type can be used, RE being preferably La, Gd, Y or Lu, of the 1/5, 1/7 or 2/17 type, and M being predominantly Co or Fe and possibly containing Cu, Zr, Al and other minority elements.
• the compounds of the RE-Fe-N type can also be used.
• This induction obtained by magnetization of the pads under an external magnetic field, can be characterized by the magnetic field generated on the surface of the pads, and persistent after removal of the applied magnetic field.
• the field generated on the surface must be greater than 20 mT, preferably 60 mT, and more preferably greater than 100 mT, measured using a Hall effect probe distributed by Lakeshore.
• the matrix comprises a refractory fraction, stable at a temperature above 900 ° C.
• the refractory fraction may comprise one or more of the elements selected from the following group: CdO, SnO 2, ZnO, Bi 2 O 3, C, WC, MgO, In 2 O 3, as well as Ni, Fe, Mo, Zr, W or their oxides.
• the refractory fraction is added in amount so that the percentage of the magnetic entities is at least 8% and the amount of conductive metal is at least 20%.
• the magnetic entities are dispersed in the matrix, either regularly, or in a concentration gradient, or again in localized blocks.
• the material may also contain dopants or minor additives, facilitating the implementation of the material, which may be, for example, Ni, Co, Fe, Bi, Re, Zr and their oxides.
• the material described above is used to make pads of electrical contacts.
• the first steps of the process of developing the material and forming the contact pads are common and are known to those skilled in the art who can choose between several techniques.
• the method comprises an additional step of magnetizing the material on the already developed pads.
• the material development step can be performed by metallurgy powders, one of the magnetic entities being nanostructured RE-Fe-B, where RE is a rare earth element.
• a preferred direction of the magnetic entities may be obtained by applying a suitable method during the development of the pads (pressure, magnetic field, heat treatment). This operation is not essential but it makes it possible to increase the magnetization of the studs induced by the field, applied after elaboration of the pads.
• a ribbon The nanostructured RE-Fe-B obtained by a rapid solidification technique, particularly by the technique known as melt spinning gives excellent results. It is not necessary to further describe this technique known to those skilled in the art.
• the RE-Fe-B cools by taking a microstructure, which allows it to present remarkable hard magnetic characteristics for the intended use.
• the RE-Fe-B may be associated with other magnetic materials to optimize the magnetic properties of the assembly, the RE-Fe-B advantageously representing at least 50% by weight of the magnetic entities.
• Contact pads are then shaped by cutting strips, stamping son, unitary compression. They are then arranged on a suitable support, by any traditional method of assembling electrical contacts, in particular: resistance welding, resistance brazing, induction brazing, flame or oven brazing, crimping, incrustation ... view of their use as electrical contacts.
• the material used according to the invention can be formed into a washer or a layer, forming a magnetic system, made integral with a traditional electrical contact pad by inlaying, welding, brazing or riveting, or even layer deposition (s).
• the magnetic material, the contact material or both may be in the form of one or more layers.
• the magnetic system can also serve as a mechanical support and supply current to the electrical contact.
• the magnetic entities are not magnetized.
• the pads must then undergo the magnetization step by applying a magnetizing magnetic field to provide the magnetic non-magnetized entities global magnetization in a mean orientation defined by the applied field.
• the studs can then fully play their role of blower or arc extinguisher. This operation can take place in the factory, after development of the stud. It can also take place at the user, before or after the final assembly of the contact.
• the material used in the form of pads comprises magnetic entities initially not magnetized which are either capable of being made magnetized by the application of a magnetic field to the user, or already made magnetized by the application of a magnetic field in factory.
• the field may in particular be applied in parallel or preferably perpendicular to the longitudinal axis of a stud, so that the latter has field lines as illustrated, respectively, in Figures 1a and 1b. .
• the conditions of the magnetization step are adapted to the magnetic material so that, after having undergone the magnetization step, the studs are source of a magnetic induction field, which, measured on their surface, is greater than 20 mT, preferably 60 mT, and more preferably greater than 10O mT.
• the pads thus obtained are then implemented in electrical contacts formed of two pads defining between them a first axis.
• the contact may comprise a single pad obtained according to the above method, arranged in the case of a DC circuit, the anode or the cathode. It is also possible that the two studs forming the contact are made of a magnetic material used according to the invention. Various magnetic field orientations are possible and conceivable, for example, when a single magnetic pad is used, the field it generates can be oriented parallel or perpendicular to the first axis.
• the stud may comprise an overlay deposited on the magnetic material.
• an overcoat comprises a conductive material selected from silver and copper and optionally a refractory compound selected from the group consisting of compounds CdO, SnO 2, ZnO, Bi 2 O 3, C, WC,
• the overlay advantageously allows to isolate the magnetic entities of the pad of the contact surface and thus reduce the risk of soldering on closing. Indeed, the blowing effect can be attenuated by the ionization of the constituent elements of the magnetic compound, the latter can increase the contact resistance and promote welding. In any case, the extreme surface of the contact is strongly heated under the effect of the arc so that the magnetic properties of the surface entities are generally destroyed in operation.
• the overlayer must be thin enough so that the field created by the underlying magnetic entities in the arc area remains sufficiently intense, and possibly thick enough not to be completely melted under the effect of the arc. However, it turns out that the reduction in the duration of the arc obtained according to the invention leads to very low erosion.
• the overlay may have a thickness of between 0.05 mm and 3 mm, preferably between 0.1 mm and 2 mm, and more preferably between 0.2 mm and 1 mm.
• the powder thus obtained is mixed with powdered silver, the particles have a mean diameter of between 15 and 50 microns.
• the mixture is produced in a mass proportion of 80% of silver and 20% of EM magnetic entity powder.
• a magnetic material is obtained constituting an electrical contact pad.
• An electrical contact pad is then shaped by unit compression and compacted under a pressure of 700MPa.
• the pad is sintered under vacuum at 400 ° C for about 30 minutes.
• the pad is then assembled on a support according to one of the techniques mentioned above, to be used in an electrical contact.
• the pad is magnetized by exposing it to a magnetic field of 8 T.
• the pad is oriented perpendicularly to the magnetic field, as illustrated in FIG. 1a so that it has a perpendicular magnetization to its longitudinal axis.
• the pad is a source of a remanent induction field of about 60 mT at the surface.
• the pad obtained above is then used in a contact of a resistive type electrical circuit, operating under a continuous voltage of 42 V, with an intensity of 37.5 A.
• a resistive type electrical circuit operating under a continuous voltage of 42 V, with an intensity of 37.5 A.
• only one magnetic pad is disposed at the cathode, the other being silver.
• Example 2 [0064] Example 1 is reproduced by replacing 6% by weight of silver of the matrix with 6% by weight of a refractory compound (SnO 2).
• Example 1 The same tests as for Example 1 are carried out. The results obtained are reported in Table 1 below.
• Example 3 An overlayer of 0.6 mm thick is applied to the magnetic material of the pad obtained in Example 1. Said overlayer comprises 100% silver.
• Example 4 The same tests as for Example 1 are carried out. The results obtained are reported in Table 1 below. Examples 4-6
• Example 1 is reproduced by not subjecting the pad to a magnetization (Example 4) or by using other materials to make the pads of the contact (Examples 5 and 6).
• Example 4 shows the importance of the magnetization step of the stud since a contact comprising a non-magnetized stud has an arc duration at the opening of 9 ms while the contact comprising the magnetic pin has a arc duration at opening of 3 ms.

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• Contacts (AREA)
• Arc-Extinguishing Devices That Are Switches (AREA)
• Hard Magnetic Materials (AREA)
• Manufacture Of Switches (AREA)

Priority Applications (3)

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• 2008
  • 2008-05-22 EP EP08156731A patent/EP2124236A1/de not_active Withdrawn
• 2009
  • 2009-05-14 AT AT09749760T patent/ATE545144T1/de active
  • 2009-05-14 CN CN2009801183666A patent/CN102037530A/zh active Pending
  • 2009-05-14 BR BRPI0913030A patent/BRPI0913030A2/pt not_active Application Discontinuation
  • 2009-05-14 PL PL09749760T patent/PL2297757T3/pl unknown
  • 2009-05-14 CA CA2723770A patent/CA2723770A1/fr not_active Abandoned
  • 2009-05-14 MX MX2010012523A patent/MX2010012523A/es active IP Right Grant
  • 2009-05-14 EP EP09749760A patent/EP2297757B1/de active Active
  • 2009-05-14 JP JP2011509934A patent/JP2011521418A/ja active Pending
  • 2009-05-14 ES ES09749760T patent/ES2380310T3/es active Active
  • 2009-05-14 SI SI200930226T patent/SI2297757T1/sl unknown
  • 2009-05-14 US US12/992,308 patent/US20110068088A1/en not_active Abandoned
  • 2009-05-14 PT PT09749760T patent/PT2297757E/pt unknown
  • 2009-05-14 WO PCT/EP2009/055879 patent/WO2009141270A1/fr active Application Filing
• 2010
  • 2010-11-14 IL IL209303A patent/IL209303A0/en unknown
• 2011
  • 2011-06-10 HK HK11105874.7A patent/HK1152146A1/xx unknown

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