EP2202289A1 - Produit de lavage - Google Patents
Produit de lavage Download PDFInfo
- Publication number
- EP2202289A1 EP2202289A1 EP09013264A EP09013264A EP2202289A1 EP 2202289 A1 EP2202289 A1 EP 2202289A1 EP 09013264 A EP09013264 A EP 09013264A EP 09013264 A EP09013264 A EP 09013264A EP 2202289 A1 EP2202289 A1 EP 2202289A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent additive
- detergent
- silver
- washing
- additive according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C11D3/048—Nitrates or nitrites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/105—Nitrates; Nitrites
Definitions
- the invention relates to a washing aid which reduces the germ count in the laundry when used, or prevents the proliferation of germs when wearing the washed laundry.
- the antibacterial effect of silver ions has been known for years. The use of silver plate, spoon, cup, ... goes back to the time of the Romans. Also, silver coins were placed years ago in the milk container to prevent acidification of the milk, or to delay.
- silver ions become as in the writings DE 10346387A1 and US 2003 / 0050212A1 , such as DE 10312617A1 represented in particular in the field of hygiene articles (bath and toilet articles, detergents, or detergents and cleaners) used.
- the silver passes into the fibers of the laundry and thus impregnates the clothing and thus presents the antibacterial effect.
- a detailed description provides e.g. the marketing presentation of the company smartfiber AG.
- the consumer either an expensive handling with the corresponding detergents, or detergent additives, or the uncertainty, enough silver ions for the antibacterial equipment of clothing in the washing water to have available.
- all silver colloid-containing solutions generally lose much of their original activity over time.
- the silver ion concentration which is responsible for the antibacterial effect, does not remain constant and decreases with time. It must therefore be started with a much higher silver ion concentration for safety reasons.
- the object of the invention was to provide a washing aid which does not have the disadvantages of the known solutions described above, is easy and convenient to dose and allows a constant in the amount of release of silver ions, without causing a misdosing (over or under dosage) comes.
- the present invention is therefore a washing aid, or detergent additive containing silver ions, characterized in that the silver ions in the form of an at least partially soluble silver compound and the washing aid or the detergent additive, in Pressed, sprayed or injection-molded form is securely encapsulated in a medication blister pack.
- the advantage of the present invention is on the one hand the packaging, that is the medication blister pack.
- the packaging that is the medication blister pack.
- the washing aid or detergent additive does not come into contact with the human skin when it is pressed out of the packaging. As a result, discoloration of the skin caused by contact with silver ions is avoided.
- the longer storage life is given by the encapsulation of the active substance in the blister pack. Furthermore, it is ensured by the inventive design and form of the washing aid, or of the detergent additive with respect to the type of packaging that the use of the active substance can be targeted and controlled.
- Another advantage of the present invention is that an at least partially soluble silver compound is used with a carrier, preferably an excipient which does not react with the silver compound.
- At least partially soluble silver compounds are not complexed silver salts, such as silver nitrate, silver sulfate, silver fluoride, silver acetate and sometimes silver chloride, but which is not particularly suitable by its photosensitivity in question.
- the silver compounds preferably have a solubility of at least 0.1 to 5000 g / l, preferably 5 to 2500 g / l in water.
- Suitable carrier substances are, for example, detergents (surfactants) and their auxiliaries and additives such as, for example, fragrances, dyes, reducing or oxidizing agents and enzymes, and less preferably water-soluble salts which have no negative effect on the washing action.
- detergents surfactants
- auxiliaries and additives such as, for example, fragrances, dyes, reducing or oxidizing agents and enzymes, and less preferably water-soluble salts which have no negative effect on the washing action.
- the washing aid according to the invention or the detergent additive is preferably pressed into tablets, sprayed or injection-molded.
- pressing aids for example, potassium chloride, sodium bicarbonate, or various sugar compounds (e.g., dextrose, maltodextrin, sucrose, etc.) are used. These pressing aids do not adversely affect the action of the partially soluble silver compound and also the washing process.
- the dosage of non-complexed silver ions is at least 2 * 10-9 g per l of water 1 ⁇ 10 -7, more preferably at least 1 ⁇ 10 -4 g per liter of water, thus giving an ideal concentration of 0.1-100 mg of silver salt per 5 liters of wash liquor
- the ratio of the at least partially soluble silver compound to the carrier used can be any have the desired value and serves only to improve the ability to meter the active substance also be 0 (dosage of the pure active substance) up to, for example, 1,000,000 (0.1 mg of silver salt on a total dosage of 100 g) after the total dosage amount used.
- the further essential advantage of the invention underlying this invention is that the at least partially soluble silver compounds in water can decompose into uncomplexed silver ions (Ag +) and thus achieve their complete effectiveness in the wash water, since complexed silver ions have a significantly weaker disinfecting effect.
- This is a significant advantage of the present invention as compared to the technologies already described on the market. Excess silver chloride is deposited on the laundry in its fibers and re-moisturises (e.g., by perspiration) again as an antibacterial silver ion.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09013264A EP2202289A1 (fr) | 2008-12-23 | 2009-10-21 | Produit de lavage |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08022331 | 2008-12-23 | ||
EP09013264A EP2202289A1 (fr) | 2008-12-23 | 2009-10-21 | Produit de lavage |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2202289A1 true EP2202289A1 (fr) | 2010-06-30 |
Family
ID=40666695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09013264A Withdrawn EP2202289A1 (fr) | 2008-12-23 | 2009-10-21 | Produit de lavage |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP2202289A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015113785A1 (fr) * | 2014-01-29 | 2015-08-06 | Unilever N.V. | Compositions de nettoyage contenant de l'argent stable |
US9771549B2 (en) | 2014-01-29 | 2017-09-26 | Conopco, Inc. | Cleansing composition containing oligodynamic metal and efficacy enhancing agent |
US10093885B2 (en) | 2014-01-29 | 2018-10-09 | Conopco, Inc. | Aqueous composition containing oligodynamic metal |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0391087A1 (fr) * | 1989-04-07 | 1990-10-10 | Freytag von Loringhoven, Andreas | Procédé et moyens pour l'addition de parfum à l'eau de lavage ou de rinçage |
JPH06183903A (ja) * | 1992-12-24 | 1994-07-05 | Haiponetsukusu Japan:Kk | 発泡性切花延命錠剤 |
CA2235889A1 (fr) * | 1998-04-27 | 1999-10-27 | Liage International Inc. | Pastille de detergent effervescente |
JP2003013095A (ja) * | 2001-07-02 | 2003-01-15 | Hiroaki Endo | 水流失性除菌洗浄剤 |
US20030050212A1 (en) | 2001-09-13 | 2003-03-13 | Chingsung Su | Constituent of washing aid having anti-bacterial or the like component |
DE10312617A1 (de) | 2003-03-21 | 2004-10-07 | Henkel Kgaa | Keimreduzierendes Wasch- oder Reinigungsmittel und Verfahren zu seiner Herstellung |
DE10346387A1 (de) | 2003-10-07 | 2005-06-09 | Henkel Kgaa | Antimikrobielle Ausrüstung von Bad- und WC-Artikeln |
US20060115440A1 (en) * | 2004-09-07 | 2006-06-01 | Arata Andrew B | Silver dihydrogen citrate compositions |
FR2883478A1 (fr) * | 2005-03-24 | 2006-09-29 | Eurotab Sa | Composition solide compactee desinfectante |
WO2007008776A1 (fr) * | 2005-07-11 | 2007-01-18 | Genencor International, Inc. | Tablettes assouplissantes a base d'enzymes |
-
2009
- 2009-10-21 EP EP09013264A patent/EP2202289A1/fr not_active Withdrawn
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0391087A1 (fr) * | 1989-04-07 | 1990-10-10 | Freytag von Loringhoven, Andreas | Procédé et moyens pour l'addition de parfum à l'eau de lavage ou de rinçage |
JPH06183903A (ja) * | 1992-12-24 | 1994-07-05 | Haiponetsukusu Japan:Kk | 発泡性切花延命錠剤 |
CA2235889A1 (fr) * | 1998-04-27 | 1999-10-27 | Liage International Inc. | Pastille de detergent effervescente |
JP2003013095A (ja) * | 2001-07-02 | 2003-01-15 | Hiroaki Endo | 水流失性除菌洗浄剤 |
US20030050212A1 (en) | 2001-09-13 | 2003-03-13 | Chingsung Su | Constituent of washing aid having anti-bacterial or the like component |
DE10312617A1 (de) | 2003-03-21 | 2004-10-07 | Henkel Kgaa | Keimreduzierendes Wasch- oder Reinigungsmittel und Verfahren zu seiner Herstellung |
DE10346387A1 (de) | 2003-10-07 | 2005-06-09 | Henkel Kgaa | Antimikrobielle Ausrüstung von Bad- und WC-Artikeln |
US20060115440A1 (en) * | 2004-09-07 | 2006-06-01 | Arata Andrew B | Silver dihydrogen citrate compositions |
FR2883478A1 (fr) * | 2005-03-24 | 2006-09-29 | Eurotab Sa | Composition solide compactee desinfectante |
WO2007008776A1 (fr) * | 2005-07-11 | 2007-01-18 | Genencor International, Inc. | Tablettes assouplissantes a base d'enzymes |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Week 199431, Derwent World Patents Index; AN 1994-252656, XP002529899 * |
DATABASE WPI Week 200331, Derwent World Patents Index; AN 2003-319117, XP002529898 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015113785A1 (fr) * | 2014-01-29 | 2015-08-06 | Unilever N.V. | Compositions de nettoyage contenant de l'argent stable |
CN106062161A (zh) * | 2014-01-29 | 2016-10-26 | 荷兰联合利华有限公司 | 含有稳定的银的清洁组合物 |
US9752106B2 (en) | 2014-01-29 | 2017-09-05 | Conopco, Inc. | Cleansing compositions containing stable silver |
US9771549B2 (en) | 2014-01-29 | 2017-09-26 | Conopco, Inc. | Cleansing composition containing oligodynamic metal and efficacy enhancing agent |
EA030203B1 (ru) * | 2014-01-29 | 2018-07-31 | Юнилевер Н.В. | Очищающие композиции, содержащие стабильное серебро |
US10093885B2 (en) | 2014-01-29 | 2018-10-09 | Conopco, Inc. | Aqueous composition containing oligodynamic metal |
CN106062161B (zh) * | 2014-01-29 | 2019-08-30 | 荷兰联合利华有限公司 | 含有稳定的银的清洁组合物 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: HUNDESHAGEN, ARTHUR Inventor name: REDER, ROMAN |
|
17P | Request for examination filed |
Effective date: 20100924 |
|
17Q | First examination report despatched |
Effective date: 20101027 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20121212 |