EP2145967A3 - Titanium aluminide alloys - Google Patents

Titanium aluminide alloys Download PDF

Info

Publication number
EP2145967A3
EP2145967A3 EP09010152A EP09010152A EP2145967A3 EP 2145967 A3 EP2145967 A3 EP 2145967A3 EP 09010152 A EP09010152 A EP 09010152A EP 09010152 A EP09010152 A EP 09010152A EP 2145967 A3 EP2145967 A3 EP 2145967A3
Authority
EP
European Patent Office
Prior art keywords
phase
alloys
lamella
tial
titanium aluminide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP09010152A
Other languages
German (de)
French (fr)
Other versions
EP2145967B1 (en
EP2145967A2 (en
Inventor
Fritz Appel
Jonathan Paul
Michael Oehring
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Helmholtz Zentrum Geesthacht Zentrum fuer Material und Kustenforschung GmbH
Original Assignee
GKSS Forshungszentrum Geesthacht GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GKSS Forshungszentrum Geesthacht GmbH filed Critical GKSS Forshungszentrum Geesthacht GmbH
Priority to EP11187502.7A priority Critical patent/EP2423341B1/en
Publication of EP2145967A2 publication Critical patent/EP2145967A2/en
Publication of EP2145967A3 publication Critical patent/EP2145967A3/en
Application granted granted Critical
Publication of EP2145967B1 publication Critical patent/EP2145967B1/en
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals
    • C22C1/0458Alloys based on titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/047Making non-ferrous alloys by powder metallurgy comprising intermetallic compounds
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/16Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
    • C22F1/18High-melting or refractory metals or alloys based thereon
    • C22F1/183High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon

Abstract

Die Erfindung betrifft Legierungen auf der Basis von, insbesondere unter Verwendung von schmelz- oder pulvermetallurgischen Verfahren hergestellten, Titanaluminiden, vorzugsweise auf Basis von y (TiAl), wobei TiAl-Legierungen mit weiteren Zusätzen Volumenanteile der β-Phase enthalten. Die Legierungen zeichnen sich aus durch Komposit-Lamellen-Strukturen mit B19-Phase und β-Phase in jeder Lamelle, wobei das Verhältnis, insbesondere das Volumenverhältnis, der B19-Phase und β-Phase jeweils in einer Lamelle zwischen 0.05 und 20, insbesondere zwischen 0.1 und 10, beträgt.The invention relates to alloys based on, in particular using melt or powder metallurgy produced titanium aluminides, preferably based on y (TiAl), wherein TiAl alloys containing further additives volume fractions of the β-phase. The alloys are characterized by composite lamellar structures with B19 phase and β-phase in each lamella, wherein the ratio, in particular the volume ratio, the B19 phase and β-phase in each case in a lamella between 0.05 and 20, in particular between 0.1 and 10, is.

Die Legierungen zeichnen sich durch hohe Festigkeit und Kriechbeständigkeit bei gleichzeitig hoher Duktilität und Bruchzähigkeit aus.The alloys are characterized by high strength and creep resistance combined with high ductility and fracture toughness.

EP09010152.8A 2007-12-13 2008-11-25 Titanium aluminide alloys Not-in-force EP2145967B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11187502.7A EP2423341B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007060587A DE102007060587B4 (en) 2007-12-13 2007-12-13 titanium aluminide
EP08020431.6A EP2075349B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys

Related Parent Applications (3)

Application Number Title Priority Date Filing Date
EP08020431.6A Division EP2075349B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys
EP08020431.6A Division-Into EP2075349B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys
EP08020431.6 Division 2008-11-25

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP11187502.7 Division-Into 2011-11-02

Publications (3)

Publication Number Publication Date
EP2145967A2 EP2145967A2 (en) 2010-01-20
EP2145967A3 true EP2145967A3 (en) 2010-04-21
EP2145967B1 EP2145967B1 (en) 2013-07-24

Family

ID=40527708

Family Applications (3)

Application Number Title Priority Date Filing Date
EP11187502.7A Not-in-force EP2423341B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys
EP09010152.8A Not-in-force EP2145967B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys
EP08020431.6A Not-in-force EP2075349B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP11187502.7A Not-in-force EP2423341B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP08020431.6A Not-in-force EP2075349B1 (en) 2007-12-13 2008-11-25 Titanium aluminide alloys

Country Status (10)

Country Link
US (3) US20090151822A1 (en)
EP (3) EP2423341B1 (en)
JP (1) JP5512964B2 (en)
KR (1) KR20090063173A (en)
CN (1) CN101457314B (en)
BR (1) BRPI0806979A2 (en)
CA (1) CA2645843A1 (en)
DE (1) DE102007060587B4 (en)
IL (1) IL195756A0 (en)
RU (1) RU2466201C2 (en)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009215631A (en) * 2008-03-12 2009-09-24 Mitsubishi Heavy Ind Ltd Titanium-aluminum-based alloy and production method therefor, and moving blade using the same
DE102009050603B3 (en) * 2009-10-24 2011-04-14 Gfe Metalle Und Materialien Gmbh Process for producing a β-γ-TiAl base alloy
WO2012041276A2 (en) 2010-09-22 2012-04-05 Mtu Aero Engines Gmbh Heat-resistant tial alloy
DE102011110740B4 (en) * 2011-08-11 2017-01-19 MTU Aero Engines AG Process for producing forged TiAl components
EP2620517A1 (en) 2012-01-25 2013-07-31 MTU Aero Engines GmbH Heat-resistant TiAl alloy
US20130248061A1 (en) * 2012-03-23 2013-09-26 General Electric Company Methods for processing titanium aluminide intermetallic compositions
US10597756B2 (en) 2012-03-24 2020-03-24 General Electric Company Titanium aluminide intermetallic compositions
CN103320648B (en) * 2012-03-24 2017-09-12 通用电气公司 Titanium aluminide intermetallic complex
KR101261885B1 (en) * 2012-07-25 2013-05-06 한국기계연구원 Lamellar structure tial base alloy having beta-gamma phase
RU2502824C1 (en) * 2012-11-13 2013-12-27 Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" Heat treatment method of castings from alloys based on gamma titanium aluminide
DE102012222745A1 (en) 2012-12-11 2014-06-12 MTU Aero Engines AG Turbine blade, useful in fluid-flow machine e.g. stationary gas turbine or aircraft engine, comprises monocrystalline of titanium aluminide material in blade portion, and blade root made of polycrystalline material
WO2014115921A1 (en) * 2013-01-23 2014-07-31 한국기계연구원 Titanium-aluminum alloy having enhanced high temperature strength and oxidation resistance
EP2969319A4 (en) 2013-03-15 2016-11-09 United Technologies Corp Process for manufacturing a gamma titanium aluminide turbine component
CN103484701B (en) * 2013-09-10 2015-06-24 西北工业大学 Method for refining cast titanium alloy crystalline grains
CN103773981B (en) * 2013-12-25 2016-06-29 西安西工大超晶科技发展有限责任公司 A kind of method of smelting of high Nb-TiAl base alloy
CN103820697B (en) * 2014-03-10 2016-08-17 北京工业大学 A kind of multi-element alloyed β phase solidifies high Nb containing TiAl based alloy and preparation method thereof
CN103820675A (en) * 2014-03-12 2014-05-28 北京工业大学 Novel V-contained beta-gamma TiAl intermetallic compound material with high Nb content and preparation method thereof
CN103820674B (en) * 2014-03-12 2016-05-25 北京工业大学 A kind of W, Mn alloying β solidify high Nb-TiAl Alloy And Preparation Method mutually
CN103834844B (en) * 2014-03-12 2016-08-24 北京工业大学 A kind of V, Mn alloying β phase solidifies high Nb containing TiAl based alloy and preparation method thereof
CN103820672B (en) * 2014-03-12 2017-05-03 北京工业大学 Cr and Mn alloying beta phase solidifying high Nb-TiAl alloy and preparation method thereof
CN103820677B (en) * 2014-03-12 2016-03-02 北京工业大学 A kind of containing the novel β of Mn height Nb-γ TiAl intermetallic compound material and preparation method thereof
JP6439287B2 (en) * 2014-06-18 2018-12-19 株式会社デンソー Driving support device, driving support method, image correction device, and image correction method
RU2592657C2 (en) * 2014-12-29 2016-07-27 Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") Heat-resistant titanium-based alloy and article made therefrom
RU2621500C1 (en) * 2015-12-21 2017-06-06 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" INTERMETALLIC TiAl BASED ALLOY
CN105624465A (en) * 2015-12-29 2016-06-01 青岛博泰美联化工技术有限公司 Blade of automobile engine
CN105441715A (en) * 2015-12-29 2016-03-30 青岛博泰美联化工技术有限公司 Automobile charging turbine
EP3249064A1 (en) 2016-05-23 2017-11-29 MTU Aero Engines GmbH Additive manufacture of high temperature components from tial
CN105970026A (en) * 2016-05-31 2016-09-28 黄河科技学院 Light weight alloy material and preparation method thereof
CN106148739B (en) * 2016-06-29 2018-02-06 西安西工大超晶科技发展有限责任公司 A kind of preparation method of the alloy cast ingots of Ti3Al containing niobium
JP6687118B2 (en) 2016-09-02 2020-04-22 株式会社Ihi TiAl alloy and method for producing the same
CN106367633A (en) * 2016-09-12 2017-02-01 江苏大学 La2O3-microalloyed TiAl-based alloy being high in acid corrosion resistance
CN106367624B (en) * 2016-09-12 2017-10-13 江苏大学 High acid etching resistance Y microalloying TiAl-base alloys
RU2633135C1 (en) * 2016-11-11 2017-10-11 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" Intermetallic tial-based alloy
KR101890642B1 (en) 2016-12-14 2018-08-22 안동대학교 산학협력단 Method for preparing Ti-Al-Nb-V alloy improved fracture toughness and creep properties
KR101888049B1 (en) 2016-12-14 2018-08-13 안동대학교 산학협력단 Method for preparing Ti-Al-Nb-Fe alloy improved fracture toughness and creep properties
US20180230822A1 (en) * 2017-02-14 2018-08-16 General Electric Company Titanium aluminide alloys and turbine components
CN107034384A (en) * 2017-04-26 2017-08-11 东北大学 A kind of excellent low cost titanium acieral of thermal deformation working ability
CN107475595A (en) * 2017-07-10 2017-12-15 江苏鑫龙化纤机械有限公司 A kind of polyethylene fibre dry heat draw box electric heating tube alloy material
CN107699738A (en) * 2017-09-29 2018-02-16 成都露思特新材料科技有限公司 A kind of fine-grained TiAl alloy and preparation method thereof, aero-engine, automobile
WO2019103539A1 (en) * 2017-11-24 2019-05-31 한국기계연구원 Titanium-aluminum-based alloy for 3d printing, having excellent high temperature characteristics, and manufacturing method therefor
KR102095463B1 (en) * 2018-05-24 2020-03-31 안동대학교 산학협력단 TiAl-BASED ALLOY HAVING EXCELLENT HIGH-TEMPERATURE FORMABILITY AND METHOD FOR MANUFACTURING TiAl-BASED ALLOY MEMBER USING THE SAME
EP3943627A4 (en) 2019-03-18 2022-11-16 IHI Corporation Titanium aluminide alloy material for hot forging, forging method for titanium aluminide alloy material, and forged body
WO2020235200A1 (en) * 2019-05-23 2020-11-26 株式会社Ihi Tial alloy and production method therefor
CN110438369A (en) * 2019-09-18 2019-11-12 大连大学 A kind of high rigidity, the preparation method of high oxidative Ti-Al-Nb-Re alloy
WO2022219991A1 (en) 2021-04-16 2022-10-20 株式会社神戸製鋼所 Tial alloy for forging, tial alloy material, and method for producing tial alloy material
WO2022260026A1 (en) * 2021-06-09 2022-12-15 株式会社Ihi Tial alloy, tial alloy powder, tial alloy component, and method for producing same
CN115261657B (en) * 2022-08-03 2023-02-28 南京铖联激光科技有限公司 Preparation method and preparation device of high-temperature alloy

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1069775A (en) * 1991-12-31 1993-03-10 北京科技大学 High-temperature resistant materials of Nb-Ti-Al series metal compounds
JPH0578769A (en) * 1991-09-25 1993-03-30 Mitsubishi Heavy Ind Ltd Heat resistant alloy on intermetallic
JPH05320791A (en) * 1992-05-15 1993-12-03 Mitsubishi Heavy Ind Ltd Ti-al intermetallic compound alloy
US5296056A (en) * 1992-10-26 1994-03-22 General Motors Corporation Titanium aluminide alloys
JPH06116691A (en) * 1992-10-05 1994-04-26 Mitsubishi Materials Corp Method for heat-treating ti-al intermetallic compound series ti alloy
JPH06346173A (en) * 1993-06-11 1994-12-20 Mitsubishi Heavy Ind Ltd Ti-al intermetallic compound base alloy
JPH08120372A (en) * 1994-10-25 1996-05-14 Mitsubishi Heavy Ind Ltd Tial intermetallic compound base alloy and its production
JPH08199264A (en) * 1995-01-19 1996-08-06 Mitsubishi Heavy Ind Ltd Titanium-aluminum series intermetallic compound base alloy
US5746846A (en) * 1995-01-27 1998-05-05 The United States Of America As Represented By The Secretary Of The Air Force Method to produce gamma titanium aluminide articles having improved properties
JPH1161298A (en) * 1997-08-18 1999-03-05 Natl Res Inst For Metals Titanium-aluminum intermetallic compound-base alloy and its production
JP2000199025A (en) * 1999-01-05 2000-07-18 Mitsubishi Heavy Ind Ltd TiAl INTERMETALLIC COMPOUND BASE ALLOY, ITS PRODUCTION, TURBINE MEMBER AND ITS PRODUCTION
DE102004056582A1 (en) * 2004-11-23 2006-06-01 Gkss-Forschungszentrum Geesthacht Gmbh Alloy based on titanium aluminides
CN101011705A (en) * 2007-01-31 2007-08-08 哈尔滨工业大学 Method for preparation of Yt-containing TiAl intermetallic compound plate material
EP1889939A2 (en) * 2006-08-19 2008-02-20 Rolls-Royce plc An alloy and method of treating titanium aluminide

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2734794B2 (en) * 1991-03-15 1998-04-02 住友金属工業株式会社 Method for producing Ti-Al-based intermetallic compound-based alloy
DE4224867A1 (en) * 1992-07-28 1994-02-03 Abb Patent Gmbh Highly heat-resistant material
JPH06116692A (en) * 1992-10-05 1994-04-26 Honda Motor Co Ltd Ti-al intermetallic compound excellent in high temperature strength and its production
JPH07197154A (en) * 1994-01-10 1995-08-01 Mitsubishi Heavy Ind Ltd Titanium aluminum base alloy and its production
JP3374553B2 (en) * 1994-11-22 2003-02-04 住友金属工業株式会社 Method for producing Ti-Al-based intermetallic compound-based alloy
DE4443147A1 (en) * 1994-12-05 1996-06-27 Dechema Corrosion-resistant material for high-temperature applications in sulfidizing process gases
DE19735841A1 (en) * 1997-08-19 1999-02-25 Geesthacht Gkss Forschung Titanium aluminide alloy contains niobium
US6174387B1 (en) * 1998-09-14 2001-01-16 Alliedsignal, Inc. Creep resistant gamma titanium aluminide alloy
DE10351946A1 (en) * 2003-03-21 2004-10-07 Dechema Gesellschaft Für Chemische Technik Und Biotechnologie E.V. Process for treating the surface of a component consisting of an AL alloy, in particular a TiAL alloy, and the use of organic halocarbon compounds or halides incorporated in an organic matrix

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0578769A (en) * 1991-09-25 1993-03-30 Mitsubishi Heavy Ind Ltd Heat resistant alloy on intermetallic
CN1069775A (en) * 1991-12-31 1993-03-10 北京科技大学 High-temperature resistant materials of Nb-Ti-Al series metal compounds
JPH05320791A (en) * 1992-05-15 1993-12-03 Mitsubishi Heavy Ind Ltd Ti-al intermetallic compound alloy
JPH06116691A (en) * 1992-10-05 1994-04-26 Mitsubishi Materials Corp Method for heat-treating ti-al intermetallic compound series ti alloy
US5296056A (en) * 1992-10-26 1994-03-22 General Motors Corporation Titanium aluminide alloys
JPH06346173A (en) * 1993-06-11 1994-12-20 Mitsubishi Heavy Ind Ltd Ti-al intermetallic compound base alloy
JPH08120372A (en) * 1994-10-25 1996-05-14 Mitsubishi Heavy Ind Ltd Tial intermetallic compound base alloy and its production
JPH08199264A (en) * 1995-01-19 1996-08-06 Mitsubishi Heavy Ind Ltd Titanium-aluminum series intermetallic compound base alloy
US5746846A (en) * 1995-01-27 1998-05-05 The United States Of America As Represented By The Secretary Of The Air Force Method to produce gamma titanium aluminide articles having improved properties
JPH1161298A (en) * 1997-08-18 1999-03-05 Natl Res Inst For Metals Titanium-aluminum intermetallic compound-base alloy and its production
JP2000199025A (en) * 1999-01-05 2000-07-18 Mitsubishi Heavy Ind Ltd TiAl INTERMETALLIC COMPOUND BASE ALLOY, ITS PRODUCTION, TURBINE MEMBER AND ITS PRODUCTION
DE102004056582A1 (en) * 2004-11-23 2006-06-01 Gkss-Forschungszentrum Geesthacht Gmbh Alloy based on titanium aluminides
EP1889939A2 (en) * 2006-08-19 2008-02-20 Rolls-Royce plc An alloy and method of treating titanium aluminide
CN101011705A (en) * 2007-01-31 2007-08-08 哈尔滨工业大学 Method for preparation of Yt-containing TiAl intermetallic compound plate material

Non-Patent Citations (24)

* Cited by examiner, † Cited by third party
Title
APPEL F ET AL: "A novel in situ composite structure in TiAl alloys", MATERIALS SCIENCE AND ENGINEERING A: STRUCTURAL MATERIALS:PROPERTIES, MICROSTRUCTURE & PROCESSING, LAUSANNE, CH, vol. 493, no. 1-2, 15 October 2008 (2008-10-15), pages 232 - 236, XP024100346, ISSN: 0921-5093, [retrieved on 20071214] *
APPEL F ET AL: "Creep behavior of TiAl alloys with enhanced high-temperature capability", METALLURGICAL AND MATERIALS TRANSACTIONS A, SPRINGER-VERLAG, NEW YORK, vol. 34, no. 10, 1 October 2003 (2003-10-01), pages 2149 - 2164, XP019694532, ISSN: 1543-1940 *
APPEL F. ET AL.: "Recent Progress in the Development of Gamma Titanium Aluminide Alloys", ADVANCED ENGINEERING MATERIALS, vol. 2, no. 11, 2000, pages 699 - 720, XP002523946 *
APPEL, FRITZ ET AL: "Atomistic processes of phase transformation and dynamic recrystallization during hot-working of intermetallic titanium aluminides", MATERIALS SCIENCE FORUM , 558-559(PT. 1, RECRYSTALLIZATION AND GRAIN GROWTH III), 465-470 CODEN: MSFOEP; ISSN: 0255-5476, 2007, pages 465 - 470, XP009115410 *
APPEL, FRITZ ET AL: "Nano -scale design of TiAl alloys based on .beta.-phase decomposition", ADVANCED ENGINEERING MATERIALS , 8(5), 371-376 CODEN: AENMFY; ISSN: 1438-1656, 2006, XP002523822 *
APPEL, FRITZ ET AL: "Nano -scale design of TiAl alloys based on beta-phase decomposition", MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS , 980, 383-388 CODEN: MRSPDH; ISSN: 0272-9172, 2007, XP009115409 *
CHEN G L ET AL: "Deformation mechanism at large strains in a high-Nb-containing TiAl at room temperature", MATERIALS SCIENCE AND ENGINEERING A: STRUCTURAL MATERIALS:PROPERTIES, MICROSTRUCTURE & PROCESSING, LAUSANNE, CH, 1 June 2002 (2002-06-01), pages A329 - A331, XP009129927, ISSN: 0921-5093 *
CHEN YU-YONG ET AL: "Microstructure and interface reaction of investment casting TiAl alloys", TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY, CHANGSHA, CN, vol. 16, no. 3, 1 January 2006 (2006-01-01), pages 1910 - 1914, XP009129914, ISSN: 1003-6326 *
CHENG T T ET AL: "Effects of major alloying additions on the microstructure and mechanical properties of gamma-TiAl", INTERMETALLICS, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 7, no. 1, 1 January 1999 (1999-01-01), pages 89 - 99, XP004143846, ISSN: 0966-9795 *
FIGGE U ET AL: "The effect of chromium, niobium and yttrium additions on the growth phenomena of oxide scales on titanium aluminide (TiAl)-based intermetallic compounds", EUROCORR. EUROPEAN CORROSION MEETING,, vol. 1/12th Meeting, 31 May 1992 (1992-05-31), pages 591 - 599, XP009129912 *
HU ET AL: "On the massive phase transformation regime in TiAl alloys: The alloying effect on massive/lamellar competition", INTERMETALLICS, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 15, no. 3, 9 December 2006 (2006-12-09), pages 327 - 332, XP005882072, ISSN: 0966-9795 *
HUANG Z W ET AL: "The effects of long-term air exposure on the stability of lamellar TiAl alloys", INTERMETALLICS, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 8, no. 4, 1 April 2000 (2000-04-01), pages 417 - 426, XP004191091, ISSN: 0966-9795 *
JOHN C WOO ET AL: "Oxidation behavior and transmission electron microscope characterization of Ti-44Al-x Nb-2(Ta,Zr) alloys", METALLURGICAL AND MATERIALS TRANSACTIONS A, SPRINGER-VERLAG, NEW YORK, vol. 34, no. 10, 1 October 2003 (2003-10-01), pages 2263 - 2271, XP019694545, ISSN: 1543-1940 *
KOBAYASHI SATORU ET AL: "Formation of .beta.-Ti phase in multi-component gamma alloys", MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS, MATERIALS RESEARCH SOCIETY, US, vol. 753, 1 January 2003 (2003-01-01), pages 123 - 128, XP009129929, ISSN: 0272-9172 *
MARTIN P L ET AL: "Thermomechanical processing effects on microstructure in alloys based on .gamma.-TiAl", STRUCTURAL INTERMETALLICS : ISSI ; PROCEEDINGS OF THE FIRST INTERNATIONAL SYMPOSIUM ON STRUCTURAL INTERMETALLICS ; HELD SEPTEMBER 26 - 30, 1993 AT SEVEN SPRINGS MOUNTAIN RESORT, CHAMPION, PENNSYLVANIA, MINERAL, METALS & MATERIALS SOCIETY, US, 1 January 1993 (1993-01-01), pages 177 - 186, XP009129933, ISBN: 978-0-87339-253-2 *
PATHER R ET AL: "Thermo-mechanical processing of high niobium .gamma.-TiAl alloys: Microstructure and mechanical properties", STRUCTURAL INTERMETALLICS 2001, PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON STRUCTURAL INTERMETALLICS, 3RD, JACKSON HOLE, WY, UNITED STATES,, 23 September 2001 (2001-09-23), pages 207 - 215, XP009129934 *
PENG JI-HUA ET AL: "Tensile properties and fracture behavior of Ti2AlNb based alloys at room temperature", TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY, CHANGSHA, CN, vol. 10, no. 3, 1 January 2000 (2000-01-01), pages 378 - 381, XP009129925, ISSN: 1003-6326 *
TETSUI TOSHIMITSU ET AL: "Heat-resistant cast TiAl alloy for passenger vehicle turbochargers", MITSUBISHI JUKO GIHO,, vol. 38, no. 5, 1 January 2001 (2001-01-01), pages 238 - 241, XP009129932 *
TETSUI TOSHIMITSU: "Heat-resistant cast gamma-TiAl alloy with high niobium addition for passenger vehicle turbochargers", NIOBIUM : HIGH TEMPERATURE APPLICATIONS ; PROCEEDINGS OF THE INTERNATIONAL SYMPOSIUM ON NIOBIUM FOR HIGH TEMPERATURE APPLICATIONS, ARAXA, MG, BRASIL, DECEMBER 1 - 3, 2003, TMS, US, 1 January 2004 (2004-01-01), pages 205 - 213, XP009129923, ISBN: 978-0-87339-575-5 *
WOO J C ET AL: "Effect of Ta and Zr additions on the oxidation characteristics of Ti-44Al-xNb alloys", GAMMA TITANIUM ALUMINIDES 2003,, 1 January 2003 (2003-01-01), pages 585 - 589, XP009129918 *
ZHANG L C ET AL: "Structural change of deformation twin boundaries in a heavily deformed gamma-TiAl-based alloy", MATERIALS LETTERS, NORTH HOLLAND PUBLISHING COMPANY. AMSTERDAM, NL, vol. 45, no. 6, 1 October 2000 (2000-10-01), pages 320 - 325, XP004256576, ISSN: 0167-577X *
ZHANG L C ET AL: "Twin thickness dependence of type-I twin intersections in a .gamma.-TiAl-based Ti-45Al-8Nb-2.5Mn alloy deformed at room temperature", JOURNAL OF MATERIALS SCIENCE LETTERS, CHAPMAN AND HALL LTD. LONDON, GB, vol. 19, no. 19, 1 October 2000 (2000-10-01), pages 1727 - 1730, XP009129920, ISSN: 0261-8028 *
ZHANG L C ET AL: "Twin-intersection-related nanotwinning in a heavily deformed .gamma.-TiAl-based alloy", PHILOSOPHICAL MAGAZINE LETTERS, HAMPSHIRE, GB, vol. 79, no. 2, 1 January 1999 (1999-01-01), pages 49 - 54, XP009129928, ISSN: 0950-0839 *
ZHANG NING ET AL: "Influence of W, B and Y elements on antioxidation of high temperature and long term for TiAl based alloys with high Nb content", XIYOU JINSHU CAILIAO YU GONGCHENG - RARE METAL MATERIALS ANDENGINEERING, XIBEI YOUSE JINSHU YANJIUYUAN, BAOJI, CN, vol. 36, no. 5, 1 January 2007 (2007-01-01), pages 884 - 887, XP009129913, ISSN: 1002-185X *

Also Published As

Publication number Publication date
US20100000635A1 (en) 2010-01-07
EP2423341B1 (en) 2013-07-10
RU2008149177A (en) 2010-06-20
DE102007060587A1 (en) 2009-06-18
CA2645843A1 (en) 2009-06-13
US20140010701A1 (en) 2014-01-09
IL195756A0 (en) 2009-11-18
EP2075349A2 (en) 2009-07-01
JP5512964B2 (en) 2014-06-04
EP2145967B1 (en) 2013-07-24
EP2145967A2 (en) 2010-01-20
CN101457314B (en) 2013-07-24
KR20090063173A (en) 2009-06-17
US20090151822A1 (en) 2009-06-18
RU2466201C2 (en) 2012-11-10
EP2075349B1 (en) 2016-03-09
DE102007060587B4 (en) 2013-01-31
EP2075349A3 (en) 2009-09-09
CN101457314A (en) 2009-06-17
EP2423341A1 (en) 2012-02-29
JP2009144247A (en) 2009-07-02
BRPI0806979A2 (en) 2010-04-20

Similar Documents

Publication Publication Date Title
EP2145967A3 (en) Titanium aluminide alloys
DE10734173T1 (en) ALUMINUM COPPER LITHIUM ALLOY WITH IMPROVED MECHANICAL STRENGTH AND INCREASED RESISTANCE
DE102007051499A1 (en) Material for a gas turbine component, method for producing a gas turbine component and gas turbine component
ATE453731T1 (en) AL-ZN-CU-MG ALUMINUM-BASED ALLOYS, METHOD FOR THEIR PRODUCTION AND USE
EP1015650B1 (en) Alloy based on titanium aluminides
DE04753336T1 (en) AL-CU-MG-AG-MN ALLOY FOR CONSTRUCTION APPLICATIONS REQUIRING HIGH STRENGTH AND HIGH DUCTILITY
DE112004000603T5 (en) AI-Zn-Mg-Cu alloy
EP2013482A1 (en) Rotors or stators of a turbomolecular pump
EP2905350A1 (en) High temperature TiAl alloy
WO2013050355A1 (en) Method for producing an engine component and engine component
CA2909202A1 (en) Aluminum-free magnesium wrought alloy
EP1589122B1 (en) Coating containing NiAl beta Phases
DE102010006502B4 (en) vehicle body
EP2481518A3 (en) Brazing alloy and method for repairing a workpiece
WO2015082518A1 (en) Gamma/gamma' hardened cobalt-based superalloy, powder and component
DE202006004118U1 (en) Component based on a hybrid material used in the production of vehicle parts comprises a first component formed as a matrix and a second component formed as a characterizing component
EP3322829B1 (en) Sliding bearing, sliding bearing material, process for the production of a sliding material and use of sliding bearing material as a sliding bearing
WO2019243411A1 (en) Aluminum alloy, method for producing an engine component, engine component, and use of an aluminum alloy to produce an engine component
DE102006029121A1 (en) Heat-resistant bearing material used for bearing ring comprises austenitic iron matrix alloy with sulfur content sufficient for producing solid lubricating action on its bearing surface
EP1970459A1 (en) Light metal composite containing carbon nanotubes and its use
EP2411551A1 (en) Copper-zinc alloy
EP2832872B1 (en) Highly temperature resistant lightweight construction alloy made of NiAl
DE19812444B4 (en) TiAl-based alloy
EP1835044A1 (en) Component based on a hybrid material
EP2409793B1 (en) Method for manufacturing a workpiece with defined surface

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AC Divisional application: reference to earlier application

Ref document number: 2075349

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA MK RS

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA MK RS

17P Request for examination filed

Effective date: 20100618

17Q First examination report despatched

Effective date: 20100713

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FUER MATERIAL

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: C22C 14/00 20060101AFI20130312BHEP

Ipc: C22C 1/04 20060101ALI20130312BHEP

Ipc: C22F 1/18 20060101ALI20130312BHEP

INTG Intention to grant announced

Effective date: 20130416

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 2075349

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 623525

Country of ref document: AT

Kind code of ref document: T

Effective date: 20130815

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502008010386

Country of ref document: DE

Effective date: 20130926

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: ISLER AND PEDRAZZINI AG, CH

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20130724

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131124

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131024

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131125

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130814

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20131025

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

BERE Be: lapsed

Owner name: HELMHOLTZ-ZENTRUM GEESTHACHT ZENTRUM FUR MATERIAL

Effective date: 20131130

26N No opposition filed

Effective date: 20140425

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502008010386

Country of ref document: DE

Effective date: 20140425

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20131125

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20081125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130724

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 8

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20161124

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20161122

Year of fee payment: 9

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 623525

Country of ref document: AT

Kind code of ref document: T

Effective date: 20171125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171130

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171125

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20191125

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20191121

Year of fee payment: 12

Ref country code: IT

Payment date: 20191120

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20191126

Year of fee payment: 12

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502008010386

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20201125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201125

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210601

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201125