EP2075349A3 - Titanium aluminide alloys - Google Patents
Titanium aluminide alloys Download PDFInfo
- Publication number
- EP2075349A3 EP2075349A3 EP08020431A EP08020431A EP2075349A3 EP 2075349 A3 EP2075349 A3 EP 2075349A3 EP 08020431 A EP08020431 A EP 08020431A EP 08020431 A EP08020431 A EP 08020431A EP 2075349 A3 EP2075349 A3 EP 2075349A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- phase
- alloys
- lamella
- atomic
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/045—Alloys based on refractory metals
- C22C1/0458—Alloys based on titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/047—Making non-ferrous alloys by powder metallurgy comprising intermetallic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
Abstract
Die Erfindung betrifft Legierungen auf der Basis von, insbesondere unter Verwendung von schmelz- oder pulvermetallurgischen Verfahren hergestellten, Titanaluminiden, vorzugsweise auf Basis von γ (TiAl). Eine erfindungsgemäße Legierung verfügt über die Zusammensetzung Ti - (38 bis 42 Atom %) Al - (5 bis 10 Atom %) Nb, wobei die Zusammensetzung Komposit-Lamellen-Strukturen mit B19-Phase und β-Phase in jeder Lamelle aufweist, wobei das Verhältnis, insbesondere das Volumenverhältnis, der B19-Phase und β-Phase jeweils in einer Lamelle zwischen 0.05 und 20, insbesondere zwischen 0.1 und 10, beträgt.The invention relates to alloys based on titanium aluminides, in particular those produced using melt or powder metallurgical processes, preferably based on γ (TiAl). An alloy according to the invention has the composition Ti - (38 to 42 atomic%) Al - (5 to 10 atomic%) Nb, the composition comprising B19 phase and β phase composite lamellar structures in each lamella Ratio, in particular the volume ratio, the B19 phase and β-phase in each case in a lamella between 0.05 and 20, in particular between 0.1 and 10, is.
Die Legierungen zeichnen sich durch hohe Festigkeit und Kriechbeständigkeit bei gleichzeitig hoher Duktilität und Bruchzähigkeit aus.The alloys are characterized by high strength and creep resistance combined with high ductility and fracture toughness.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09010152.8A EP2145967B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP11187502.7A EP2423341B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007060587A DE102007060587B4 (en) | 2007-12-13 | 2007-12-13 | titanium aluminide |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09010152.8A Division-Into EP2145967B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP09010152.8A Division EP2145967B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP11187502.7A Division-Into EP2423341B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2075349A2 EP2075349A2 (en) | 2009-07-01 |
EP2075349A3 true EP2075349A3 (en) | 2009-09-09 |
EP2075349B1 EP2075349B1 (en) | 2016-03-09 |
Family
ID=40527708
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11187502.7A Not-in-force EP2423341B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP09010152.8A Not-in-force EP2145967B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP08020431.6A Not-in-force EP2075349B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11187502.7A Not-in-force EP2423341B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
EP09010152.8A Not-in-force EP2145967B1 (en) | 2007-12-13 | 2008-11-25 | Titanium aluminide alloys |
Country Status (10)
Country | Link |
---|---|
US (3) | US20090151822A1 (en) |
EP (3) | EP2423341B1 (en) |
JP (1) | JP5512964B2 (en) |
KR (1) | KR20090063173A (en) |
CN (1) | CN101457314B (en) |
BR (1) | BRPI0806979A2 (en) |
CA (1) | CA2645843A1 (en) |
DE (1) | DE102007060587B4 (en) |
IL (1) | IL195756A0 (en) |
RU (1) | RU2466201C2 (en) |
Families Citing this family (47)
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JP2009215631A (en) * | 2008-03-12 | 2009-09-24 | Mitsubishi Heavy Ind Ltd | Titanium-aluminum-based alloy and production method therefor, and moving blade using the same |
DE102009050603B3 (en) * | 2009-10-24 | 2011-04-14 | Gfe Metalle Und Materialien Gmbh | Process for producing a β-γ-TiAl base alloy |
WO2012041276A2 (en) | 2010-09-22 | 2012-04-05 | Mtu Aero Engines Gmbh | Heat-resistant tial alloy |
DE102011110740B4 (en) * | 2011-08-11 | 2017-01-19 | MTU Aero Engines AG | Process for producing forged TiAl components |
EP2620517A1 (en) | 2012-01-25 | 2013-07-31 | MTU Aero Engines GmbH | Heat-resistant TiAl alloy |
US20130248061A1 (en) * | 2012-03-23 | 2013-09-26 | General Electric Company | Methods for processing titanium aluminide intermetallic compositions |
CN103320648B (en) * | 2012-03-24 | 2017-09-12 | 通用电气公司 | Titanium aluminide intermetallic complex |
US10597756B2 (en) | 2012-03-24 | 2020-03-24 | General Electric Company | Titanium aluminide intermetallic compositions |
KR101261885B1 (en) * | 2012-07-25 | 2013-05-06 | 한국기계연구원 | Lamellar structure tial base alloy having beta-gamma phase |
RU2502824C1 (en) * | 2012-11-13 | 2013-12-27 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Heat treatment method of castings from alloys based on gamma titanium aluminide |
DE102012222745A1 (en) | 2012-12-11 | 2014-06-12 | MTU Aero Engines AG | Turbine blade, useful in fluid-flow machine e.g. stationary gas turbine or aircraft engine, comprises monocrystalline of titanium aluminide material in blade portion, and blade root made of polycrystalline material |
WO2014115921A1 (en) * | 2013-01-23 | 2014-07-31 | 한국기계연구원 | Titanium-aluminum alloy having enhanced high temperature strength and oxidation resistance |
US10179377B2 (en) | 2013-03-15 | 2019-01-15 | United Technologies Corporation | Process for manufacturing a gamma titanium aluminide turbine component |
CN103484701B (en) * | 2013-09-10 | 2015-06-24 | 西北工业大学 | Method for refining cast titanium alloy crystalline grains |
CN103773981B (en) * | 2013-12-25 | 2016-06-29 | 西安西工大超晶科技发展有限责任公司 | A kind of method of smelting of high Nb-TiAl base alloy |
CN103820697B (en) * | 2014-03-10 | 2016-08-17 | 北京工业大学 | A kind of multi-element alloyed β phase solidifies high Nb containing TiAl based alloy and preparation method thereof |
CN103820672B (en) * | 2014-03-12 | 2017-05-03 | 北京工业大学 | Cr and Mn alloying beta phase solidifying high Nb-TiAl alloy and preparation method thereof |
CN103820674B (en) * | 2014-03-12 | 2016-05-25 | 北京工业大学 | A kind of W, Mn alloying β solidify high Nb-TiAl Alloy And Preparation Method mutually |
CN103834844B (en) * | 2014-03-12 | 2016-08-24 | 北京工业大学 | A kind of V, Mn alloying β phase solidifies high Nb containing TiAl based alloy and preparation method thereof |
CN103820675A (en) * | 2014-03-12 | 2014-05-28 | 北京工业大学 | Novel V-contained beta-gamma TiAl intermetallic compound material with high Nb content and preparation method thereof |
CN103820677B (en) * | 2014-03-12 | 2016-03-02 | 北京工业大学 | A kind of containing the novel β of Mn height Nb-γ TiAl intermetallic compound material and preparation method thereof |
JP6439287B2 (en) * | 2014-06-18 | 2018-12-19 | 株式会社デンソー | Driving support device, driving support method, image correction device, and image correction method |
RU2592657C2 (en) * | 2014-12-29 | 2016-07-27 | Федеральное государственное унитарное предприятие "Всероссийский научно-исследовательский институт авиационных материалов" (ФГУП "ВИАМ") | Heat-resistant titanium-based alloy and article made therefrom |
RU2621500C1 (en) * | 2015-12-21 | 2017-06-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | INTERMETALLIC TiAl BASED ALLOY |
CN105441715A (en) * | 2015-12-29 | 2016-03-30 | 青岛博泰美联化工技术有限公司 | Automobile charging turbine |
CN105624465A (en) * | 2015-12-29 | 2016-06-01 | 青岛博泰美联化工技术有限公司 | Blade of automobile engine |
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CN106148739B (en) * | 2016-06-29 | 2018-02-06 | 西安西工大超晶科技发展有限责任公司 | A kind of preparation method of the alloy cast ingots of Ti3Al containing niobium |
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CN106367633A (en) * | 2016-09-12 | 2017-02-01 | 江苏大学 | La2O3-microalloyed TiAl-based alloy being high in acid corrosion resistance |
CN106367624B (en) * | 2016-09-12 | 2017-10-13 | 江苏大学 | High acid etching resistance Y microalloying TiAl-base alloys |
RU2633135C1 (en) * | 2016-11-11 | 2017-10-11 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Intermetallic tial-based alloy |
KR101888049B1 (en) | 2016-12-14 | 2018-08-13 | 안동대학교 산학협력단 | Method for preparing Ti-Al-Nb-Fe alloy improved fracture toughness and creep properties |
KR101890642B1 (en) | 2016-12-14 | 2018-08-22 | 안동대학교 산학협력단 | Method for preparing Ti-Al-Nb-V alloy improved fracture toughness and creep properties |
US20180230822A1 (en) * | 2017-02-14 | 2018-08-16 | General Electric Company | Titanium aluminide alloys and turbine components |
CN107034384A (en) * | 2017-04-26 | 2017-08-11 | 东北大学 | A kind of excellent low cost titanium acieral of thermal deformation working ability |
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Citations (5)
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JPH0578769A (en) * | 1991-09-25 | 1993-03-30 | Mitsubishi Heavy Ind Ltd | Heat resistant alloy on intermetallic |
JPH05320791A (en) * | 1992-05-15 | 1993-12-03 | Mitsubishi Heavy Ind Ltd | Ti-al intermetallic compound alloy |
JPH06116691A (en) * | 1992-10-05 | 1994-04-26 | Mitsubishi Materials Corp | Method for heat-treating ti-al intermetallic compound series ti alloy |
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JPH1161298A (en) * | 1997-08-18 | 1999-03-05 | Natl Res Inst For Metals | Titanium-aluminum intermetallic compound-base alloy and its production |
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-
2007
- 2007-12-13 DE DE102007060587A patent/DE102007060587B4/en not_active Expired - Fee Related
-
2008
- 2008-11-25 EP EP11187502.7A patent/EP2423341B1/en not_active Not-in-force
- 2008-11-25 EP EP09010152.8A patent/EP2145967B1/en not_active Not-in-force
- 2008-11-25 EP EP08020431.6A patent/EP2075349B1/en not_active Not-in-force
- 2008-12-04 CA CA002645843A patent/CA2645843A1/en not_active Abandoned
- 2008-12-07 IL IL195756A patent/IL195756A0/en unknown
- 2008-12-10 US US12/331,909 patent/US20090151822A1/en not_active Abandoned
- 2008-12-11 BR BRPI0806979-4A patent/BRPI0806979A2/en not_active IP Right Cessation
- 2008-12-12 KR KR1020080126803A patent/KR20090063173A/en not_active Application Discontinuation
- 2008-12-12 CN CN2008101727696A patent/CN101457314B/en not_active Expired - Fee Related
- 2008-12-12 RU RU2008149177/02A patent/RU2466201C2/en not_active IP Right Cessation
- 2008-12-15 JP JP2008318555A patent/JP5512964B2/en active Active
-
2009
- 2009-07-30 US US12/512,451 patent/US20100000635A1/en not_active Abandoned
-
2013
- 2013-06-28 US US13/931,051 patent/US20140010701A1/en not_active Abandoned
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JPH0578769A (en) * | 1991-09-25 | 1993-03-30 | Mitsubishi Heavy Ind Ltd | Heat resistant alloy on intermetallic |
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Title |
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APPEL F ET AL: "A novel in situ composite structure in TiAl alloys", MATERIALS SCIENCE AND ENGINEERING A: STRUCTURAL MATERIALS:PROPERTIES, MICROSTRUCTURE & PROCESSING, LAUSANNE, CH, vol. 493, no. 1-2, 15 October 2008 (2008-10-15), pages 232 - 236, XP024100346, ISSN: 0921-5093, [retrieved on 20071214] * |
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APPEL, FRITZ ET AL: "Atomistic processes of phase transformation and dynamic recrystallization during hot-working of intermetallic titanium aluminides", MATERIALS SCIENCE FORUM , 558-559(PT. 1, RECRYSTALLIZATION AND GRAIN GROWTH III), 465-470 CODEN: MSFOEP; ISSN: 0255-5476, 2007, pages 465 - 470, XP009115410 * |
APPEL, FRITZ ET AL: "Nano -scale design of TiAl alloys based on .beta.-phase decomposition", ADVANCED ENGINEERING MATERIALS , 8(5), 371-376 CODEN: AENMFY; ISSN: 1438-1656, 2006, XP002523822 * |
APPEL, FRITZ ET AL: "Nano -scale design of TiAl alloys based on beta-phase decomposition", MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS , 980, 383-388 CODEN: MRSPDH; ISSN: 0272-9172, 2007, XP009115409 * |
Also Published As
Publication number | Publication date |
---|---|
RU2466201C2 (en) | 2012-11-10 |
IL195756A0 (en) | 2009-11-18 |
CN101457314B (en) | 2013-07-24 |
EP2145967B1 (en) | 2013-07-24 |
BRPI0806979A2 (en) | 2010-04-20 |
EP2075349B1 (en) | 2016-03-09 |
US20090151822A1 (en) | 2009-06-18 |
JP5512964B2 (en) | 2014-06-04 |
DE102007060587A1 (en) | 2009-06-18 |
CA2645843A1 (en) | 2009-06-13 |
CN101457314A (en) | 2009-06-17 |
EP2423341A1 (en) | 2012-02-29 |
US20100000635A1 (en) | 2010-01-07 |
EP2145967A3 (en) | 2010-04-21 |
RU2008149177A (en) | 2010-06-20 |
US20140010701A1 (en) | 2014-01-09 |
JP2009144247A (en) | 2009-07-02 |
EP2423341B1 (en) | 2013-07-10 |
EP2075349A2 (en) | 2009-07-01 |
KR20090063173A (en) | 2009-06-17 |
DE102007060587B4 (en) | 2013-01-31 |
EP2145967A2 (en) | 2010-01-20 |
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