EP2019809A1 - Verfahren sowie vorrichtung zum gesteuerten aufschäumen eines in flaschen oder dergleichen behälter eingebrachten füllgutes - Google Patents
Verfahren sowie vorrichtung zum gesteuerten aufschäumen eines in flaschen oder dergleichen behälter eingebrachten füllgutesInfo
- Publication number
- EP2019809A1 EP2019809A1 EP07725136A EP07725136A EP2019809A1 EP 2019809 A1 EP2019809 A1 EP 2019809A1 EP 07725136 A EP07725136 A EP 07725136A EP 07725136 A EP07725136 A EP 07725136A EP 2019809 A1 EP2019809 A1 EP 2019809A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pump
- controlled
- aufschäummedium
- container
- injection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005187 foaming Methods 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 11
- 238000002347 injection Methods 0.000 claims abstract description 65
- 239000007924 injection Substances 0.000 claims abstract description 65
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims 2
- 230000000903 blocking effect Effects 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 claims 1
- 238000012544 monitoring process Methods 0.000 claims 1
- 239000007921 spray Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 21
- 239000000047 product Substances 0.000 description 17
- 230000008569 process Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 4
- 230000001419 dependent effect Effects 0.000 description 3
- 235000013361 beverage Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 235000020023 weizenbier Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
- B67C—CLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
- B67C3/00—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
- B67C3/02—Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
- B67C3/22—Details
- B67C3/222—Head-space air removing devices, e.g. by inducing foam
Definitions
- the invention relates to a method according to the preamble of claim 1 and to a device according to the preamble of claim 14.
- bottles, barrels or the like containers that have been filled in a filling machine with a liquid filling material, preferably with a filling material containing carbonic acid, before closing with a pressurized liquid AufMummedium.
- the aim is foaming the filling material in the respective container in order thereby to displace air or existing atmospheric oxygen above the level of contents in the container and to avoid the deterioration of the contents or its durability and taste due to oxygen.
- water is used as the liquid foaming medium, for example in each case in the heated state.
- At least one injection nozzle which is supplied with the foaming medium under pressure and under which the containers filled with the contents are passed on a transport path between a filling machine and a closing machine following this filling machine in the production line, serves to introduce the foaming medium.
- the introduction or injection of the frothing liquid should also take into account product-specific parameters as well as the production line performance, i. depending on the number of per unit time treated with the AufMummedium done so that on the one hand, a sufficiently strong foaming is achieved, on the other hand, a foaming is avoided. Furthermore, it is necessary to carry out the introduction of the AufMummediums germ-free.
- the introduced into the container for foaming energy input depends on various parameters, such as. from the temperature and quantity of the foaming medium introduced into the respective container as well as from the injection pressure with which this medium is injected into the containers. Also the injection time has to be considered.
- the object of the invention is to provide a method by which an improved foaming of a bottled or similar container filled filling material is achieved.
- the injection pressure is suitable for controlling the energy input or the foaming process as a function of the performance of the production line or as a function of the performance of the filling machine and the subsequent closing machine.
- the invention is still based on the finding that a regulation of the foaming process and in particular the injection pressure in dependence on the performance of the production line or the filler and thus also by the number of per unit time treated with the AufMummedium container is only possible if the injection pressure can be regulated in a wide range, for example in a range between at least 1 bar and 8 bar, preferably in a range between at least about 1 bar and 15 bar, namely at a correspondingly low volume flow of the liquid AufMummediums, for example at a maximum flow 2 l / min, preferably of at most 1, 5 l / min for the injection pressure generating pump.
- the setpoint for the injection pressure is determined by this control device for the respective power of the production line , for example, by removal from an electronically stored in the memory list or table.
- this actual injection pressure is compared as an actual value with the desired value and the speed and / or power of the pump is readjusted such that the actual value corresponds to the desired value.
- the generally designated 1 in the figure device is part of a production line for filling bottles 2 or the like container with a liquid product and for closing the filled bottles 2 and serves to fill the bottles 2 filled product, in particular carbonated product by a controlled Enriching energy input so that is displaced by the foam forming air and in particular atmospheric oxygen above the Gregutspiegels from the bottle 2, without causing overfoaming.
- the energy input is controlled by at least one injection nozzle 3, which is provided above the movement path of the upright bottles 2 between a filling machine, not shown, and a sealing machine, also not shown.
- the AufFummedium is for example water or product.
- the respective energy input is in particular from the kinetic energy, d. H. from the amount and from the injection pressure of the introduced foaming medium and from the heat energy, d. H. from the temperature of the foaming medium together.
- d. H. the kinetic energy
- the injector 3 passing bottles 2 to keep the energy input into each bottle 2 as constant as possible is in the device 1 in the manner described in more detail below at constant or substantially constant temperature of the Aufbulums the kinetic energy of the energy input controlled by changes in the injection pressure as a function of power, wherein during operation of the device 1, the Aufbulummedium constantly from the injection nozzle 3 with the adapted to the performance of the production line and the adjusted injection pressure emerges from the injection nozzle 3.
- the device 1 is u.a. from a pump circuit 4, the essential part of which is a high-pressure pump 5 with a frequency-controlled drive motor.
- the inlet of the pump 5 communicates via a flowmeter 6 and a conduit 7 with a source 8 which provides the liquid foaming medium.
- This source 8 is, for example, the respective supply network for fresh water, in which case in the line 7 even more elements such.
- control and / or check valves, filters, etc. are provided.
- 9 designates a temperature sensor provided in the line 7, with which the temperature of the foaming medium provided by the source 8 is determined.
- a bypass Parallel to the series arrangement of the pump 5 and the flow meter 6 is a bypass, which is essentially formed by a line 10, which connects the output of the pump 5 with the upstream of the pump 5 in the flow direction of Aufschummummed inlet of the flow meter 6.
- a throttle 11 and a pressure at the output of the pump 5 measuring pressure sensor 12 and another temperature sensor 13 is arranged in the line 10 u.a.
- the flow cross-section formed by this throttle 11 is selected so that even at a low volume flow or in the absence of a volume flow at the output of the pump circuit 4 sufficient for the lubrication and cooling of the pump 5 minimum flow is ensured by the pump 5.
- the output of the pump circuit 4 is connected via a line 14 to the input of an example, electrically operated boiler 15, which is an integral part of a heating circuit 16 and to the u in the illustrated embodiment. a. a pressure sensor 17, a level sensor 18 and a temperature sensor 19 are provided.
- the output of the boiler 15 is connected via a line 20 to the injection nozzle 3, which has, for example, a defined, but adjustable to the respective filling material nozzle or flow cross-section.
- bypass line 22 In which an electrically controllable check valve 24 is provided and which leads to a drain 25.
- the boiler 15 is first filled with the CruMummedium (for example, water) and the AufMummedium heated to a temperature slightly above the later operating or operating temperature of this medium, for example, at an operating or operating temperature of 85 ° C to a Temperature of 90 0 C.
- the filling of the boiler 15 via the example, shut off the pump 5 and / or the pump bypass 10.
- the heating of the boiler is activated as soon as the level gauge 18 has detected the complete filling of the boiler.
- closed check valve 21 and open check valve 24 is a stream of liquid heated AufMummediums from the boiler 15 via the line 20 to the bypass line 23 and from there into the sequence 25.
- About the temperature sensors 19 and 22 is a control the temperature of the AufMummediums to operating temperature (for example, 85 0 C), by appropriate control of the heating of the boiler 15th
- the bypass line 23 is closed with the check valve 24 and the check valve 21 is opened so that the AufMummedium heated to operating temperature is injected with the pump pressure generated by the pump 5 in the past under the injector 3 2 bottles.
- the check valve 21 In a production interruption, the check valve 21 is closed and the bypass line 23 is opened via the check valve 24, so that further heated Aufschummummium flows through the line 20 while maintaining the required temperature.
- the check valve 21 could be closed and the bypass line 23 can be opened via the check valve 24, namely when the production is interrupted.
- the bypass lines 23 and 26 are opened via the associated shut-off valves 24 and 27 when the shut-off valve 21 is closed.
- the control of the energy input in the high-pressure injection by controlling the pressure at the outlet of the pump 5 and thus the injection pressure of the AufMummediums at the injection nozzle 3 in response to a typical for each product performance-dependent setpoint occurs.
- This product-typical desired value is stored, for example, as a data set in a memory 30 of the computer-aided control device 29, so that the control device 29 can regulate the pump 5 product and performance-dependent (container / hour), taking into account one of the performance of the production line (filled and closed Bottles 2 per unit of time) and, for example, derived at the filling machine control signal and taking into account the voltage applied to the injection nozzle 3 and for example determined by the pressure sensor 17 pressure, each as actual values.
- the pump 5 and the pump circuit 4 are formed so that a regulation of the pump pressure in the range between at least 2 bar and 16 bar is possible, namely at a relatively small flow in the range of about 0.7 - 1, 5 l / min.
- the diameter of the injection nozzle 3 is changed, i. for a product which is liable to froth, e.g., sobier, an injection nozzle 3 is used with reduced nozzle diameter. Conversely, in a product or product, which is difficult to foaming, an injection nozzle 3 with a larger nozzle diameter is used.
- the table below shows typical process parameters for three different products, taking into account bottles 2 with an internal diameter of 22 mm at their mouths.
- the ratio V ma / V m i n is about 3-4, the pump pressure at high power is well above 8 bar and the maximum injected quantity V max at the foaming medium even with the hardly foamable product 3 and with low output of the production plant is well below 0.05 ml per bottle.
- the small amount of AufMummedium to be introduced into the bottles 2 has u.a. also the advantage that when using water as AufQuummedium no or substantially no dilution of the product occurs and that in particular the consumption of AufQuummedium is significantly reduced.
- the pump bypass By formed by the line 10 pump bypass, it is possible to keep the emerging from the injection nozzle 3 amount of AufMummedium small in the desired manner and still ensure a sufficient minimum flow for the pump 5, especially for lubrication and / or cooling Pump 5. Furthermore, the pump bypass avoids overshoot in regulating the pump pressure as a function of the output of the production plant, ie With only extremely small pressure fluctuations, for example in the range of a maximum of +/- 0.3 bar, readjustment of the pump pressure can be achieved in an extremely short time, for example in 0.5 sec., even in the case of extreme changes in system performance.
- the injection nozzle 3 sensor e.g. with an opto-electrical sensor 31, for example in the form of a camera to detect the foaming generated by the high-pressure injection as actual foaming and to compare with an associated desired foaming, so then relevant parameters of the injection process, in particular injection pressure, etc. can be acted regulating or controlling ,
- the injection pressure is controlled by the pressure of the pump 5.
- Other measures are conceivable, for example a Control by controlled opening and closing of a bypass line, for example the bypass line 26 and / or by controlled opening and closing of the pump-bypass forming line 10.
- various combinations for controlling the injection pressure at the injection nozzle 3 are conceivable.
- each injection nozzle 3 with a check valve 21 and an associated controllable bypass line 23, for example, such that each bottle 2 for foaming a plurality of injection nozzles 3 passes.
Landscapes
- Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
- Basic Packing Technique (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Supply Of Fluid Materials To The Packaging Location (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07725136T PL2019809T3 (pl) | 2006-05-13 | 2007-05-11 | Sposób oraz urządzenie do sterowanego pienienia produktu napełniającego, umieszczonego w butelkach lub tego rodzaju pojemnikach |
SI200731494T SI2019809T1 (sl) | 2006-05-13 | 2007-05-11 | Postopek in naprava za krmiljeno penjenje polnilnega materiala, shranjenega v steklenicah ali podobnih vsebnikih |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006022464A DE102006022464B4 (de) | 2006-05-13 | 2006-05-13 | Verfahren sowie Vorrichtung zum gesteuerten Aufschäumen eines in Flaschen oder dergleichen Behälter eingebrachten Füllgutes |
PCT/EP2007/004216 WO2007131733A1 (de) | 2006-05-13 | 2007-05-11 | Verfahren sowie vorrichtung zum gesteuerten aufschäumen eines in flaschen oder dergleichen behälter eingebrachten füllgutes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2019809A1 true EP2019809A1 (de) | 2009-02-04 |
EP2019809B1 EP2019809B1 (de) | 2014-07-02 |
Family
ID=38292674
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07725136.1A Active EP2019809B1 (de) | 2006-05-13 | 2007-05-11 | Verfahren sowie vorrichtung zum gesteuerten aufschäumen eines in flaschen oder dergleichen behälter eingebrachten füllgutes |
Country Status (11)
Country | Link |
---|---|
US (1) | US8037907B2 (de) |
EP (1) | EP2019809B1 (de) |
JP (1) | JP2009537401A (de) |
CN (1) | CN101443259A (de) |
BR (1) | BRPI0711013B1 (de) |
DE (1) | DE102006022464B4 (de) |
MX (1) | MX2008014498A (de) |
PL (1) | PL2019809T3 (de) |
RU (1) | RU2386579C1 (de) |
SI (1) | SI2019809T1 (de) |
WO (1) | WO2007131733A1 (de) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008006770B4 (de) * | 2008-01-30 | 2013-06-13 | Khs Gmbh | Vorrichtung sowie Verfahren zum Aufschäumen von in Behältern abgefüllten Produkten |
DE102008032822A1 (de) * | 2008-07-11 | 2010-01-14 | Krones Ag | Vorrichtung zum Abfüllen von Getränken |
CN102976254A (zh) * | 2012-12-10 | 2013-03-20 | 江苏新美星包装机械股份有限公司 | 易拉罐击沫装置 |
DE102013113955A1 (de) | 2013-12-12 | 2015-06-18 | Khs Gmbh | Verfahren sowie Vorrichtung zum Aufschäumen eines in Behälter, insbesondere Flaschen eingebrachten flüssigen Füllgutes, insbesondere Bier |
JP6831794B2 (ja) | 2015-04-22 | 2021-02-17 | テトラ ラバル ホールディングス アンド ファイナンス エス エイ | 容器内に製品を充填するための装置及び方法 |
JP6584851B2 (ja) * | 2015-07-31 | 2019-10-02 | アサヒビール株式会社 | 発泡性飲料の充填システム、及び、充填方法 |
JP6895966B2 (ja) * | 2015-12-14 | 2021-06-30 | アイエムフラックス インコーポレイテッド | ネイティブコントローラからリモートコントローラにフィードバック信号を迂回させることにより装置を制御するためのリモートコントローラ及びその制御方法 |
MX2018007123A (es) * | 2015-12-14 | 2019-01-30 | Imflux Inc | Control remoto para el control de aparatos mediante la desviacion de la señal de realimentacion del control nativo al control remoto y metodos para el mismo. |
DE102018214972A1 (de) * | 2018-09-04 | 2020-03-05 | Krones Ag | Verfahren und Vorrichtung zum Verdrängen von Luft aus Flaschen mit karbonisierten Getränken |
DE102019207654A1 (de) * | 2019-05-24 | 2020-11-26 | Krones Ag | Vorrichtung und Verfahren zum Einbringen eines Schutzgases in Behälter |
DE102020120834A1 (de) | 2020-08-06 | 2022-02-10 | Krones Aktiengesellschaft | Aufschäumen eines in Behälter eingebrachten Füllprodukts |
DE102020129217A1 (de) * | 2020-11-05 | 2022-05-05 | Krones Aktiengesellschaft | Vorrichtung und Verfahren zum Befüllen von Behältern mit einem Füllprodukt |
Family Cites Families (18)
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DE1632034A1 (de) | 1967-11-24 | 1972-03-02 | Enzinger Union Werke Ag | Verfahren und Vorrichtung zum Erzeugen von Schaum im Halse von mit kohlensaeurehaltigen Getraenken gefuellten Flaschen |
DE1979515U (de) * | 1967-11-30 | 1968-02-22 | Enzinger Union Werke Ag | Vorrichtung zum erzeugen von schaum im halse von mit kohlensaeurehaltigen getraenken gefuellten flaschen. |
US3710538A (en) * | 1969-01-31 | 1973-01-16 | L Lowy | Method for filling pressurized packages and aerosol dispensers |
US3548891A (en) * | 1969-05-27 | 1970-12-22 | Haskon Inc | Method and apparatus for filling receptacles |
DE2132522A1 (de) * | 1971-06-30 | 1973-01-11 | Seitz Werke Gmbh | Verfahren zum entfernen der luft aus in flaschen abgefuellten getraenken, insbesondere bier |
JPS56106790A (en) * | 1980-01-29 | 1981-08-25 | Mitsubishi Heavy Ind Ltd | Method of discharging air in vessel head space after filling liquid |
CA1195303A (en) * | 1983-03-01 | 1985-10-15 | Rudolf W. Voss | Bottle deaerating device |
DE3311200C1 (de) * | 1983-03-26 | 1984-04-05 | Krones Ag Hermann Kronseder Maschinenfabrik, 8402 Neutraubling | Vorrichtung zum Behandeln von Flaschen od.dgl. |
DE3825093C2 (de) * | 1988-07-23 | 1994-01-13 | Kronseder Maschf Krones | Verfahren und Vorrichtung zum Füllen von Flaschen oder dgl. in Gegendruckfüllmaschinen |
CA2002915C (en) * | 1988-11-14 | 2000-06-06 | Iver J. Phallen | Precision filling machine |
DE4030081A1 (de) | 1990-09-22 | 1992-03-26 | Seitz Enzinger Noll Masch | Aufschaeumvorrichtung zum verdraengen des restluftvolumens aus mit einem aufschaeumbaren fluessigen fuellgut gefuellten behaeltern, insbesondere flaschen |
DE4135438A1 (de) * | 1991-10-26 | 1993-04-29 | Orthmann & Herbst | Vorrichtung zum aufschaeumen von karbonisierten getraenken in flaschen |
JPH085445B2 (ja) * | 1993-01-29 | 1996-01-24 | 澁谷工業株式会社 | 加圧式充填装置 |
DE19613142B4 (de) * | 1995-04-07 | 2004-08-12 | Norbert Fleuren | Vorrichtung zur Gaszufuhr zu Getränkedosen |
JP3536479B2 (ja) * | 1995-09-29 | 2004-06-07 | 澁谷工業株式会社 | 加圧式充填装置 |
DE29712148U1 (de) * | 1997-04-29 | 1997-09-11 | GEA Till GmbH & Co., 65830 Kriftel | Vorrichtung zum Füllen von Gebinden |
JP2005228237A (ja) * | 2004-02-16 | 2005-08-25 | Hitachi Ltd | 液冷システム及びそれを備えた電子機器 |
JP2005267969A (ja) * | 2004-03-17 | 2005-09-29 | Toyota Motor Corp | 燃料電池システム |
-
2006
- 2006-05-13 DE DE102006022464A patent/DE102006022464B4/de not_active Expired - Fee Related
-
2007
- 2007-05-11 SI SI200731494T patent/SI2019809T1/sl unknown
- 2007-05-11 EP EP07725136.1A patent/EP2019809B1/de active Active
- 2007-05-11 CN CNA2007800174092A patent/CN101443259A/zh active Pending
- 2007-05-11 PL PL07725136T patent/PL2019809T3/pl unknown
- 2007-05-11 RU RU2008149136/12A patent/RU2386579C1/ru active
- 2007-05-11 MX MX2008014498A patent/MX2008014498A/es active IP Right Grant
- 2007-05-11 JP JP2009510332A patent/JP2009537401A/ja active Pending
- 2007-05-11 BR BRPI0711013-8A patent/BRPI0711013B1/pt active IP Right Grant
- 2007-05-11 WO PCT/EP2007/004216 patent/WO2007131733A1/de active Application Filing
-
2008
- 2008-11-12 US US12/269,467 patent/US8037907B2/en active Active
Non-Patent Citations (1)
Title |
---|
See references of WO2007131733A1 * |
Also Published As
Publication number | Publication date |
---|---|
US8037907B2 (en) | 2011-10-18 |
WO2007131733A1 (de) | 2007-11-22 |
DE102006022464A1 (de) | 2007-11-15 |
US20090283177A1 (en) | 2009-11-19 |
BRPI0711013A2 (pt) | 2011-08-23 |
BRPI0711013B1 (pt) | 2019-02-19 |
CN101443259A (zh) | 2009-05-27 |
MX2008014498A (es) | 2008-11-27 |
RU2386579C1 (ru) | 2010-04-20 |
SI2019809T1 (sl) | 2014-09-30 |
PL2019809T3 (pl) | 2014-12-31 |
JP2009537401A (ja) | 2009-10-29 |
EP2019809B1 (de) | 2014-07-02 |
DE102006022464B4 (de) | 2008-09-25 |
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