EP2017328A2 - Huile de coupe sans silicone et son utilisation - Google Patents
Huile de coupe sans silicone et son utilisation Download PDFInfo
- Publication number
- EP2017328A2 EP2017328A2 EP08156413A EP08156413A EP2017328A2 EP 2017328 A2 EP2017328 A2 EP 2017328A2 EP 08156413 A EP08156413 A EP 08156413A EP 08156413 A EP08156413 A EP 08156413A EP 2017328 A2 EP2017328 A2 EP 2017328A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- cutting oil
- polyalkylene glycol
- oil according
- cutting
- sawing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
- C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
- C10M107/34—Polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/107—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
- C10M2209/1075—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/071—Branched chain compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/091—Water solubility
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
Definitions
- the invention relates to silicone-free cutting oils and their use in band saw systems, for example when sawing polyurethane block foams and the production of furniture with such polyurethane foam parts, which show good results in fire tests.
- Sawing systems require cutting oils to reduce the friction between the saw blade or saw band and the body to be cut.
- band sawing systems are used in the processing of polyurethane block foams.
- the friction between saw and polyurethane foam is particularly high, so that basically a cutting oil is needed.
- silicone oils such as polydimethylsiloxanes having a viscosity of 5 to 1000 mPa s measured at 25 ° C.
- high demands are placed on the cut polyurethane foam parts with respect to flame retardancy, especially if the foam parts are further processed into pieces of furniture such as mattresses or seating. It shows that foam parts, which were produced with silicone-containing cutting oils, achieve poor results in fire tests.
- polyalkylene glycols can be used as cutting oils or in cutting oils and these cutting oils containing polyalkylene glycols, optionally solvents and optionally other auxiliaries and additives, solve this problem.
- silicone-free means that no compounds are present which have Si-C or Si-O-C bonds.
- the cutting oils of the invention preferably contain ethylene oxide / propylene oxide copolymers, which are preferably obtainable by copolymerizing ethylene oxide (EO) and propylene oxide (PO) with a polyhydric alcohol.
- the cutting oils according to the invention preferably comprise polyalkylene glycols which are reacted with glycerol, trimethylolpropane, pentaerythritol, Diglycerol, triglycerol, ditrimethylolpropane, dipentaerythritol or sorbitol, most preferably pentaerythritol were prepared as a polyvalent starting alcohol.
- the polyalkylene glycols contained in the cutting oils according to the invention preferably have an EO / PO weight ratio of from 80:20 to 40:60, preferably from 80:20 to 70:30 and preferably from 75:25.
- the polyalkylene glycols preferably have an average molar mass of from 2,000 to 30,000 g / mol, particularly preferably from 3,500 to 20,000 g / mol and very particularly preferably from 5,000 to 7,500 g / mol.
- the polyalkylene glycols contained in the cutting oils according to the invention are miscible with water in any ratio.
- polyalkylene glycols which are contained in the cutting oils according to the invention can, for. B. commercially available polyalkylene glycols, such as polyglycol P41 / 300, polyglycol P41 / 3000 or polyglycol P41 / 12000 Clariant be.
- polyalkylene glycols (often referred to as polyoxyalkylenes), which may be contained as polyalkylene glycol in the cutting oil according to the invention, as in the prior art, for.
- polyoxyalkylenes polyalkylene glycols
- the preparation of the polyalkylene glycols is preferably carried out in an alkaline catalyzed manner, and more preferably with pentaerythritol as the starting alcohol.
- the cutting oil can also contain one or more solvents in addition to polyalkylene glycol.
- the cutting oil preferably has from 1 to 99% by weight, preferably from 50 to 90% by weight, of solvent (s) B).
- a preferred solvent is water.
- the cutting oil according to the invention may comprise one or more auxiliary and / or additives C).
- Preferred auxiliaries and / or additives C) may, for. B. conventional preservatives such as bactericides or fungicides z.
- triethanolamine and corrosion inhibitors such as Hostacor ® IT, manufacturer Clariant be.
- Another object of the invention is the use of the cutting oils according to the invention in sawing equipment, preferably in band sawing systems and more preferably in band sawing equipment for / sawing polyurethane foams or polyurethane block foams.
- the present invention tailored polyurethane foam parts obtained by sawing, in particular band sawing polyurethane foams using cutting oil according to the invention and the use of polyurethane foam cut parts according to the invention for the production of articles with good fire properties, for the production of furniture and in particular for the production of furniture with good fire properties.
- Good fire properties are understood to mean that the polyurethane foam parts pass the fire test in accordance with ASTM D 1692 (burned-out section maximum 125 mm).
- Cutting oil according to the invention silicone-free, consisting of 99.5% by weight of polyglycol P 41/300, 0.5% by weight of triethanolamine.
- Cutting oil according to the invention silicone-free, consisting of 49.5% by weight of polyglycol P 41/3000, 50% by weight of water, 0.5% by weight of triethanolamine.
- Cutting oil according to the invention silicone-free, consisting of 10% by weight of polyglycol P 41/12000, 89.5% by weight of water, 0.5% by weight of triethanolamine.
- the saw band of a band saw was coated with the particular cutting oil by rubbing it with a soaked rag and then determining the number of cutting operations that were possible before viscoelastic block foam ruptured due to excessive friction during cutting.
- Foam parts of the predetermined size (150 mm ⁇ 50 mm ⁇ 13 mm) were sprayed with the example cutting oils (in each case about 10 g) and dried at room temperature for 48 hours.
- the results of the Fire tests ASTM D 1692 in which the test specimen is placed horizontally on a sieve and is subjected to a flame from below for 60 seconds, is given in the burned-out distance (maximum 125 mm) (Table 1).
- Table 1 Results of sawing tests and burn tests release agent Number of possible cutting operations Results ASTM D 1692 Distance (mm) 1 8th 102 2 8th 110 3 7 120 A 8th > 125, failed test
- the silicone-free cutting oils used according to the invention are equivalent to classic silicone oil in terms of lubricity, but show significantly better results in the burn-off test according to ASTM D 1692.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007033430A DE102007033430A1 (de) | 2007-07-18 | 2007-07-18 | Siliconfreies Schneidöl und seine Verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2017328A2 true EP2017328A2 (fr) | 2009-01-21 |
EP2017328A3 EP2017328A3 (fr) | 2009-04-22 |
Family
ID=39651236
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP08156413A Withdrawn EP2017328A3 (fr) | 2007-07-18 | 2008-05-19 | Huile de coupe sans silicone et son utilisation |
Country Status (5)
Country | Link |
---|---|
US (1) | US20090020904A1 (fr) |
EP (1) | EP2017328A3 (fr) |
CN (1) | CN101348744A (fr) |
DE (1) | DE102007033430A1 (fr) |
RU (1) | RU2008129903A (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2470757C2 (ru) * | 2011-02-28 | 2012-12-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Юго-Западный государственный университет" (ЮЗГУ) | Устройство охлаждения режущего инструмента |
JP6039935B2 (ja) * | 2012-06-29 | 2016-12-07 | 出光興産株式会社 | 水性加工液 |
DE102013204991A1 (de) | 2013-03-21 | 2014-09-25 | Evonik Industries Ag | Herstellung von Polyurethanschäumen, die Polyole auf Polyolefinbasis enthalten |
HUE045347T2 (hu) | 2014-08-19 | 2019-12-30 | Evonik Degussa Gmbh | Hibrid diszperzió és alkalmazása |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1284018B (de) * | 1963-05-17 | 1968-11-28 | Mobil Oil Corp | Waessrige Metallbearbeitungsfluessigkeit |
DE3914887A1 (de) * | 1989-05-05 | 1990-11-08 | Optimol Oelwerke Gmbh | Gleitmittel zur herabsetzung der reibung zwischen gummi und metall |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB846839A (en) * | 1959-01-30 | 1960-08-31 | Shell Res Ltd | Method and lubricating composition for metal rolling, cutting and drilling |
BE469342A (fr) * | 1961-01-23 | |||
GB932893A (en) * | 1961-05-31 | 1963-07-31 | Socony Mobil Oil Co Inc | Cutting fluid |
SE308062B (fr) * | 1968-04-02 | 1969-01-27 | Oerebro Ab | |
CA999400A (en) * | 1972-04-28 | 1976-11-02 | General Tire And Rubber Company (The) | Flame retardant flexible polyurethane foams |
US4058493A (en) * | 1974-12-27 | 1977-11-15 | Union Carbide Corporation | Polyester urethane foam produced with cyano-ether polysiloxane-polyoxyalkylene copolymers |
SE460671B (sv) * | 1988-03-30 | 1989-11-06 | Berol Kemi Ab | Vattenbaserad metallbearbetningsvaetska innehaallande en alkanolaminfoerening som antimikrobiellt medel och ett saett att bearbeta metaller under anvaendning av samma alkanolaminfoerening |
DE19640489A1 (de) * | 1996-10-01 | 1998-04-09 | Henkel Teroson Gmbh | Schmiermittel auf Basis von Polyolen und dessen Verwendung beim Schneiden von Elastomeren |
DE19931218B4 (de) * | 1999-07-06 | 2005-06-02 | Clariant Gmbh | Verwendung von Polymeren als Anti-Nebel-Additiv in wasserbasierenden Kühlschmierstoffen |
EP1148076A1 (fr) * | 2000-04-17 | 2001-10-24 | Clariant GmbH | Glycols de polyoxyalkylène solubles dans l'eau ayant un indice de viscosité élevé et une toxicité faible sous forme d'un aérosol |
DE10049175A1 (de) * | 2000-09-22 | 2002-04-25 | Tea Gmbh | Biologisch abbaubare Funktionsflüssigkeit für mechanische Antriebe |
MX221601B (en) * | 2004-05-14 | 2004-07-22 | Basf Ag | Functional fluids containing alkylene oxide copolymers having low pulmonary toxicity |
US7612024B2 (en) * | 2004-12-22 | 2009-11-03 | Ecolab Inc. | Polyalkylene glycol based solutions with enhanced high temperature stability |
-
2007
- 2007-07-18 DE DE102007033430A patent/DE102007033430A1/de not_active Withdrawn
-
2008
- 2008-05-19 EP EP08156413A patent/EP2017328A3/fr not_active Withdrawn
- 2008-07-03 CN CNA200810136009XA patent/CN101348744A/zh active Pending
- 2008-07-17 US US12/174,799 patent/US20090020904A1/en not_active Abandoned
- 2008-07-17 RU RU2008129903/04A patent/RU2008129903A/ru not_active Application Discontinuation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1284018B (de) * | 1963-05-17 | 1968-11-28 | Mobil Oil Corp | Waessrige Metallbearbeitungsfluessigkeit |
DE3914887A1 (de) * | 1989-05-05 | 1990-11-08 | Optimol Oelwerke Gmbh | Gleitmittel zur herabsetzung der reibung zwischen gummi und metall |
Non-Patent Citations (1)
Title |
---|
"Ullmann's encyclopedia of industrial chemistry", vol. A21, 1992, VCH VERLAGSGESELLSCHAFT MBH, pages: 579 - 589 |
Also Published As
Publication number | Publication date |
---|---|
US20090020904A1 (en) | 2009-01-22 |
DE102007033430A1 (de) | 2009-01-22 |
CN101348744A (zh) | 2009-01-21 |
EP2017328A3 (fr) | 2009-04-22 |
RU2008129903A (ru) | 2010-01-27 |
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