EP1903134A1 - Etoffe de nappe de fibres élastique et son procédé de fabrication - Google Patents

Etoffe de nappe de fibres élastique et son procédé de fabrication Download PDF

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Publication number
EP1903134A1
EP1903134A1 EP07016270A EP07016270A EP1903134A1 EP 1903134 A1 EP1903134 A1 EP 1903134A1 EP 07016270 A EP07016270 A EP 07016270A EP 07016270 A EP07016270 A EP 07016270A EP 1903134 A1 EP1903134 A1 EP 1903134A1
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EP
European Patent Office
Prior art keywords
web
water
dan
tensile load
heated
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Granted
Application number
EP07016270A
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German (de)
English (en)
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EP1903134B1 (fr
Inventor
Uwe Marg
Rober Dr. Groten
Ulrich Dr. Jahn
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Carl Freudenberg KG
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Carl Freudenberg KG
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Priority to PL07016270T priority Critical patent/PL1903134T3/pl
Publication of EP1903134A1 publication Critical patent/EP1903134A1/fr
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/50Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by treatment to produce shrinking, swelling, crimping or curling of fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/016Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the fineness
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/10Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
    • D04H3/11Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet

Definitions

  • the invention relates to an elastic nonwoven fabric and a method for producing an elastic nonwoven fabric.
  • Nonwovens are used in many areas. They are used in medical devices, personal care products, sports and leisure apparel, footwear, bedding and bedding.
  • the invention is therefore based on the object of specifying a nonwoven fabric and a method with which sufficiently elastic textile fabric can be produced inexpensively.
  • a nonwoven fabric comprises a sheet-like layer of thermoplastic filaments, wherein the layer is elastic and can be enlarged in at least one direction by at least 30% of its initial extent.
  • a layer of a nonwoven fabric whose width is increased by at least 30% of its initial value, provides sufficient elasticity for a variety of applications. Furthermore, it has been recognized that the manufacture of a nonwoven fabric of thermoplastic filaments allows to dispense with the addition of relatively expensive filaments such as spandex filaments.
  • the nonwoven fabric according to the invention can be built up uniformly, namely exclusively from thermoplastic filaments, which are orientable in such a way on account of a special treatment that the layer can be enlarged in at least one direction by at least 30% of its initial extent.
  • Such a uniformly constructed nonwoven fabric can be disposed of in an easy way, since it consists of uniform materials. Due to the uniformity of the filaments used storage costs are minimized, so that the production of the nonwoven fabric is inexpensive to carry out. Consequently, the object mentioned above is achieved.
  • the layer could have a basis weight of 40 to 150 g / m 2 .
  • a nonwoven fabric with this basis weight is particularly suitable for use as a textile fabric, since it surprisingly has sufficient stability despite its low basis weight.
  • the sheet could have microfilaments with a fineness of 0.1 to 0.15 dtex. Microfilaments of this fineness allow the production of a nonwoven fabric with very fine pores, which makes it very absorbent and therefore can be used as a functional underwear.
  • the microfilaments are formed by splitting filaments, which have a fineness of 2 to 2.4 dtex before splitting.
  • bicomponent filaments having a pie structure comprising 30% polyamide and 70% polyester may be used here. Bicomponent filaments of this type are particularly easy to split by high-pressure water jets, resulting in finer filaments.
  • the planar position could be wrinkle-free or wave-free.
  • This embodiment makes a post-processing of the elastic nonwoven fabric, which is initially present as a semi-finished, particularly simple. Methods are already known from the prior art, which give elasticity to a nonwoven fabric. However, these processes are so-called dry processes. The dry processes have the disadvantage that the semi-finished products produced by these processes have wrinkles or wrinkles. The formation of these wrinkles and wrinkles is called "tie-dyeing effect".
  • a nonwoven fabric comprising a sheet of thermoplastic filaments can be configured so elastically that the layer can be reversibly enlarged in at least one direction by at least 30% of its initial extent. Furthermore, it has been recognized that this method produces a semi-finished product with a flat layer, which is wrinkle-free or wave-free. In concrete terms, it has been recognized that this method can overcome the creasing and wrinkling known from the prior art in dry processes. In addition, this method is inexpensive because it is feasible in existing plants such as a high temperature jig for dyeing textiles.
  • the web By reducing the speeds to zero and / or reversing the direction of travel of the web, its width could be reduced.
  • the web By carrying out this process step, the web is surprisingly imparted with an elasticity orthogonal to the direction of the tensile load.
  • the water could be heated to 50 ° C. This concrete process step causes the wetting and impregnation of the web with liquid is improved.
  • This concrete process step supports the process of width reduction of the web, namely allows a better sliding of the filaments together, since the friction between them is reduced.
  • the method could be performed such that the temperature is heated to a certain value and the web is moved at a first speed at a first tensile load first in one direction and then in an opposite direction.
  • the process in a first direction and then in an opposite direction is to be understood as the unwinding of the web from a first roll while being wound onto a second roll and unwinding of the web from the second under winding onto the first roll.
  • the width of the web is slightly reduced.
  • the heating of the water to a second temperature could follow this process step, the web optionally being moved in one direction and then in an opposite direction at the same speed and the same tensile load or with an altered tensile load and / or with a changed speed.
  • the web optionally being moved in one direction and then in an opposite direction at the same speed and the same tensile load or with an altered tensile load and / or with a changed speed.
  • the water could finally be heated to a final temperature and the web can be traversed at a speed which is significantly lower than the speed of the first method steps.
  • the tensile load maintains the same value as was observed in the preceding method steps. Due to the significant reduction in the speed of the web and the significant increase in the water temperature is achieved in a surprising manner, a very significant reduction in the width.
  • the web After reaching the maximum temperature of 130 ° C, the web can be traversed at 80 m / min at a tensile load of 60 or 100 daN and thereby dyed become.
  • the elastification is carried out at the same time with a dyeing step.
  • the water could be heated to 130 ° C and the web be traversed at 20 m / min at a tensile load of 60 or 100 daN.
  • This concrete process step finally achieves the surprising effect of a very strong width reduction.
  • the web could be dried on a tenter at 140 ° C while maintaining a longitudinal tension and wound up.
  • This concrete process step allows the production of a semi-finished product with particularly high elasticity and smooth surface.
  • Fig. 1 shows a schematic view of the basic structure of the Hochtemperaturjiggers, which was used to carry out the examples described below.
  • a container 1 contains a volume of water 2 through which a web 3 can be moved.
  • the web 3 is wound on a first roller 4 and is passed through further rollers 5, 6 and 7 through the volume of water 2.
  • the web 3 is wound on a second roller 8.
  • the traversing speed of the web 3 is reduced to zero and the direction is reversed.
  • the web 3 is then unwound again from the second roller 8, moved through the water volume 2 and wound up again on the first roller 4.
  • the unwinding and winding of web of nonwoven raw material may be carried out at various speeds, temperatures and tensile loads, as described in the introduction to the specification.
  • a wetting agent namely Lavotan DSU of CHT at a concentration of 2 g / l
  • a softening agent namely Tanede PRT from Bayer
  • the water was heated to 70 ° C and the web was unwound at a speed of 100 m / min at a tensile load of 100 daN from a first roll, wound on a second, unwound from the second and rewound on the first ,
  • the water was cooled to 110 ° C and unwound at a tensile load of 100 daN at a speed of 50m / min from a first roll and wound on a second.
  • the water was cooled to 90 ° C and unwound the web at a tensile load of 100 daN and a speed of 50 m / min from the second roll and wound on the first.
  • the water was cooled to 70 ° C and unwound the web at a tensile load of 100 daN and a speed of 50 m / min from the first roll and wound on the second.
  • the web After heating the water to 110 ° C, the web was also subjected to a complete unwinding and rewinding, the web was traversed at a tensile load of 100 daN at 50 m / min.
  • Example 1 The process steps of Example 1 were modified to ensure even greater width reduction and better web guidance.
  • the web was dried on a tenter at 140 ° C while maintaining a corresponding longitudinal tension and wound up.
  • Example 1 The web used in Example 1 had a starting width of 195.5 cm. After wet treatment by the method described in Example 1 Process steps, the web had a width of 135 cm, After subsequent drying in the tenter, the web had a width of 140 cm, which corresponds to a width reduction of 28.39%.
  • Example 2 The web treated in Example 2 had an initial width of 195.5 cm. After wet treatment by the process steps described in Example 2, this web had a width of 150 cm. After subsequent drying in the tenter, the web had a width of 150 cm, which corresponds to a width reduction of 23.27%.
  • nonwoven fabrics comprising a layer having a basis weight of 60 g / m 2
  • nonwoven fabric comprising a layer having a basis weight of 100 g / m 2
  • calendering pretreated nonwoven fabric comprising a layer of 100 g / m 2
  • the nonwoven fabric having a basis weight of 60 g / m 2 was subjected to a tensile load of 60 daN, and the nonwoven fabrics were subjected to a tensile load of 100 daN at 100 g / m 2 .
  • the water was heated to 50 ° C and added plasticizer and wetting agent according to Example 1.
  • Each of the samples was unwound once from a first roll and wound up on a second roll.
  • the water was heated to 90 ° C and the webs were subjected to a complete unwinding and rewinding, the webs were moved at a speed of 40 m / min.
  • the water was kept at 130 ° C and the webs subjected to a complete unwinding and winding at a speed of 80 m / min. In this process step, the webs were dyed at the same time.
  • Example 1 Then the webs were traversed at 20 m / min in a 130 ° C water bath. Finally, the container was cooled in several steps according to Example 1.
  • the nonwoven fabric comprising a layer of 60 g / m 2 basis weight had a starting width of 205 cm. After treatment in Hochtemperaturigig he had a width of 136 cm. After subsequent drying and thermofixing in a tenter, it showed a width of 140 cm and thus a width reduction of 31.7%.
  • the nonwoven fabric comprising a sheet having a basis weight of 100 g / m 2 had a starting width of 212 cm. After treatment in high-temperature jigger this had a width of 168 cm. To subsequent drying and thermofixing in a tenter it had a width of 170 cm. This corresponds to a width reduction of 19.8%.
  • the calendered nonwoven comprising a layer having a basis weight of 100 g / m 2 had a starting width of 211 cm. After the treatment according to the process steps of Example 3, it had a width of 178 cm. After drying and thermofixing in the tenter this had a width of 188 cm, which corresponds to a width reduction of 7.5%.
  • EVO 100 corresponds to a nonwoven fabric with a layer which has a basis weight of 100 g / m 2 .
  • EVO 100 SO corresponds to the nonwoven fabric EVO 100, which has been pretreated with a strand wash.
  • a strand wash a web in the strand is passed through a nozzle at a temperature between 60 ° C and 90 ° C with possibly a wetting agent is added. As a result, the web is mechanically loosened in the filament composite.
  • EVO 100 SO HTJ represents a strand washed sample that has been traversed in a high temperature jig with different tensile loads, speeds and temperatures.
  • EVO 130, EVO 130 SO and EVO 130 SO HTJ denote analog nonwovens, but these have a layer with a basis weight of 130 g / m 2 .
  • Table 1 shows the percent elongation values which were measured by means of an elasticity test in accordance with DIN 14704-1. The right-hand portion of Table 1 shows the percent return percentages after 5 cycles of elongation. Return is the ability of a non-woven fabric to return to its original width after it has been stretched.
  • the untreated nonwovens EVO 100 and EVO 130 have a return behavior of significantly more than 80%, with the nonwovens treated in the high-temperature jigger (HTJ) having a maximum value of 35%.
  • HTJ high-temperature jigger
  • the return behavior can be improved by further treatment methods. These include heat setting, polyurethane coagulation, softener sizing and sizing. Depending on the methods used, the extensibility may be slightly reduced. This is due to the fact that the friction of the filaments is increased against each other.
  • a nonwoven fabric is subjected to a thermal treatment at 175 ° C to 210 ° C while the nonwoven fabric is placed on a tenter for 10 to 120 seconds.
  • a drying after passing through the Hochtemperaturjiggers and heat setting at the same time in one step is possible.
  • heat setting was performed at 195 ° C for 30 seconds following the high temperature jig treatment.
  • Polyurethane coagulation is understood as meaning the introduction of polyurethane into the planar position of the nonwoven fabric. It is conceivable to provide a layer with a solids content of 5 to 35%.
  • the examples in Table 2 were provided at about 20% solids. This process step can be carried out before or after the treatment in Hochtemperaturjigger, wherein the examples described in Table 2 were provided after treatment in Hochtemperaturjigger with solid.
  • the nonwovens may additionally be subjected to a softener finish (WM).
  • WM softener finish
  • 10 to 80 g / l plasticizer can be used in a bath through which the nonwoven fabric is passed.
  • Table 2 used 60 g / l of Finistrol KSE (trade name). This is a self-crosslinking, modified polysiloxane.
  • This plasticizer was added to a bath downstream of the high temperature jigger.
  • a plasticizer may be added to the bath of the high-temperature jigger or a bath connected downstream of it.
  • Sengen is understood to mean the flaming off of the fiber ends protruding from a textile fabric through an open gas flame.
  • the material becomes due to this process slightly fused to the surface, so that the crossing points of the filaments connect with each other. This results in a higher stability and a better return behavior back to the starting position.
  • This process step is preferably carried out after the treatment in Hochtemperaturigigger.
  • EVO nonwovens of the type "Evolon”. All nonwovens mentioned in the examples have microfilaments which have a fineness of 0.1 to 0.15 dtex and are formed by splitting bicomponent filaments.
  • the bicomponent filaments had a pie structure and contained 30% polyamide and 70% polyester.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)
  • Treatment Of Fiber Materials (AREA)
EP07016270A 2006-09-25 2007-08-20 Etoffe de nappe de fibres élastique et son procédé de fabrication Active EP1903134B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07016270T PL1903134T3 (pl) 2006-09-25 2007-08-20 Włóknina elastyczna i sposób jej wytwarzania

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102006045616A DE102006045616B3 (de) 2006-09-25 2006-09-25 Elastischer Vliesstoff und Verfahren zu dessen Herstellung

Publications (2)

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EP1903134A1 true EP1903134A1 (fr) 2008-03-26
EP1903134B1 EP1903134B1 (fr) 2012-12-05

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EP07016270A Active EP1903134B1 (fr) 2006-09-25 2007-08-20 Etoffe de nappe de fibres élastique et son procédé de fabrication

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EP (1) EP1903134B1 (fr)
CN (1) CN101153430B (fr)
DE (1) DE102006045616B3 (fr)
DK (1) DK1903134T3 (fr)
ES (1) ES2400227T3 (fr)
PL (1) PL1903134T3 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7892993B2 (en) 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8178199B2 (en) 2003-06-19 2012-05-15 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US8216953B2 (en) 2003-06-19 2012-07-10 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8512519B2 (en) 2009-04-24 2013-08-20 Eastman Chemical Company Sulfopolyesters for paper strength and process
US8840758B2 (en) 2012-01-31 2014-09-23 Eastman Chemical Company Processes to produce short cut microfibers
US9273417B2 (en) 2010-10-21 2016-03-01 Eastman Chemical Company Wet-Laid process to produce a bound nonwoven article
US9303357B2 (en) 2013-04-19 2016-04-05 Eastman Chemical Company Paper and nonwoven articles comprising synthetic microfiber binders
US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
US9605126B2 (en) 2013-12-17 2017-03-28 Eastman Chemical Company Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion
US9636637B2 (en) 2012-06-13 2017-05-02 Glen Raven, Inc. Permeate carrier fabric for membrane filters

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WO1996041041A1 (fr) * 1995-06-07 1996-12-19 Kimberly-Clark Worldwide, Inc. Fibres de plus fins deniers fabriques a partir de ces fibres
US5997989A (en) * 1992-02-03 1999-12-07 Bba Nonwovens Simpsonville, Inc. Elastic nonwoven webs and method of making same
EP1118305A2 (fr) * 2000-01-22 2001-07-25 Firma Carl Freudenberg Serviette de nettoyage
WO2001066844A2 (fr) * 2000-03-07 2001-09-13 Carl Freudenberg Kg Materiau textile protegeant de la lumiere
DE10105784A1 (de) * 2001-02-07 2002-08-08 Fleissner Gerold Wasservernadeltes Kompositvlies aus Stapel- und Endlosfasern und Verfahren zur Herstellung
EP1396567A1 (fr) * 2002-08-09 2004-03-10 Reifenhäuser GmbH & Co. Maschinenfabrik Procédé de fabrication d'une nappe non-tissé de filaments multicomposés
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DE69309314T2 (de) * 1993-08-02 1997-10-23 Fiberweb North America Inc Elastischer verbundvliesstoff
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US20010008675A1 (en) * 1998-11-06 2001-07-19 Meece Barry Dewayne Unidirectionally cold stretched nonwoven webs of multipolymer fibers for stretch fabrics and disposable absorbent articles containing them
US6762139B2 (en) * 2001-08-14 2004-07-13 3M Innovative Properties Company Flexible adsorbent filter
DE60227390D1 (de) * 2001-09-28 2008-08-14 Invista Tech Sarl Dehnbarer vliesstoff und methode zu dessen herstellung
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Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3244778A1 (de) * 1981-12-10 1983-06-30 Barmag Barmer Maschinenfabrik Ag, 5630 Remscheid Spontan auskraeuselnde, multikomponente chemiefasern
US5997989A (en) * 1992-02-03 1999-12-07 Bba Nonwovens Simpsonville, Inc. Elastic nonwoven webs and method of making same
WO1996041041A1 (fr) * 1995-06-07 1996-12-19 Kimberly-Clark Worldwide, Inc. Fibres de plus fins deniers fabriques a partir de ces fibres
US6767498B1 (en) * 1998-10-06 2004-07-27 Hills, Inc. Process of making microfilaments
EP1118305A2 (fr) * 2000-01-22 2001-07-25 Firma Carl Freudenberg Serviette de nettoyage
WO2001066844A2 (fr) * 2000-03-07 2001-09-13 Carl Freudenberg Kg Materiau textile protegeant de la lumiere
DE10105784A1 (de) * 2001-02-07 2002-08-08 Fleissner Gerold Wasservernadeltes Kompositvlies aus Stapel- und Endlosfasern und Verfahren zur Herstellung
EP1396567A1 (fr) * 2002-08-09 2004-03-10 Reifenhäuser GmbH & Co. Maschinenfabrik Procédé de fabrication d'une nappe non-tissé de filaments multicomposés

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8435908B2 (en) 2003-06-19 2013-05-07 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8163385B2 (en) 2003-06-19 2012-04-24 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8158244B2 (en) 2003-06-19 2012-04-17 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8444896B2 (en) 2003-06-19 2013-05-21 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8178199B2 (en) 2003-06-19 2012-05-15 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US8444895B2 (en) 2003-06-19 2013-05-21 Eastman Chemical Company Processes for making water-dispersible and multicomponent fibers from sulfopolyesters
US8227362B2 (en) 2003-06-19 2012-07-24 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
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Publication number Publication date
CN101153430A (zh) 2008-04-02
PL1903134T3 (pl) 2013-04-30
EP1903134B1 (fr) 2012-12-05
CN101153430B (zh) 2012-05-23
ES2400227T3 (es) 2013-04-08
DE102006045616B3 (de) 2008-02-21
DK1903134T3 (da) 2013-03-11

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