EP1881090B1 - Composition électrolytique et procédé pour la déposition d'une couche d'alliage zinc-nickel sur un substrat en fonte ou en acier - Google Patents
Composition électrolytique et procédé pour la déposition d'une couche d'alliage zinc-nickel sur un substrat en fonte ou en acier Download PDFInfo
- Publication number
- EP1881090B1 EP1881090B1 EP06014519.0A EP06014519A EP1881090B1 EP 1881090 B1 EP1881090 B1 EP 1881090B1 EP 06014519 A EP06014519 A EP 06014519A EP 1881090 B1 EP1881090 B1 EP 1881090B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrolyte composition
- zinc
- substrate
- nickel
- deposition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003792 electrolyte Substances 0.000 title claims description 45
- 239000000203 mixture Substances 0.000 title claims description 30
- 239000000758 substrate Substances 0.000 title claims description 24
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 title claims description 22
- 229910000990 Ni alloy Inorganic materials 0.000 title claims description 19
- 229910001018 Cast iron Inorganic materials 0.000 title claims description 11
- 230000008021 deposition Effects 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 9
- 239000010959 steel Substances 0.000 title claims description 9
- 229910001208 Crucible steel Inorganic materials 0.000 title claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
- 238000000151 deposition Methods 0.000 claims description 20
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 17
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 7
- 229960002449 glycine Drugs 0.000 claims description 7
- 235000013905 glycine and its sodium salt Nutrition 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 7
- 235000011164 potassium chloride Nutrition 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001632 sodium acetate Substances 0.000 claims description 5
- 235000017281 sodium acetate Nutrition 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- 235000011056 potassium acetate Nutrition 0.000 claims description 3
- -1 potassium halide Chemical class 0.000 claims description 3
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005695 Ammonium acetate Substances 0.000 claims description 2
- 235000019257 ammonium acetate Nutrition 0.000 claims description 2
- 229940043376 ammonium acetate Drugs 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 238000005282 brightening Methods 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229910001453 nickel ion Inorganic materials 0.000 claims 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 14
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 9
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 description 8
- BWHOZHOGCMHOBV-UHFFFAOYSA-N Benzalacetone Natural products CC(=O)C=CC1=CC=CC=C1 BWHOZHOGCMHOBV-UHFFFAOYSA-N 0.000 description 7
- 235000019270 ammonium chloride Nutrition 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 6
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 6
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- 235000005074 zinc chloride Nutrition 0.000 description 3
- FPYUJUBAXZAQNL-UHFFFAOYSA-N 2-chlorobenzaldehyde Chemical compound ClC1=CC=CC=C1C=O FPYUJUBAXZAQNL-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- KZVLNAGYSAKYMG-UHFFFAOYSA-N pyridine-2-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=N1 KZVLNAGYSAKYMG-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229940081974 saccharin Drugs 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
Claims (7)
- Composition d'électrolyte pour la séparation d'une couche d'alliage zinc-nickel sur un substrat comportant une proportion de 10 à 18 % en masse de nickel, dans laquelle la composition d'électrolyte contient des ions zinc et nickel, caractérisée en ce que la composition d'électrolyte présente de l'acide amino-acétique et un acétate du groupe constitué par l'acétate de sodium, l'acétate de potassium, l'acétate d'ammonium ou des mélanges de ceux-ci dans un rapport molaire acétate : acide amino-acétique de 0,35 à 0,91.
- Composition d'électrolyte selon la revendication 1, comprenant en outre au moins un halogénure alcalin, de préférence, un halogénure de potassium, de manière particulièrement préférée, du chlorure de potassium.
- Composition d'électrolyte selon l'une des revendications précédentes, présentant en outre de l'acide borique.
- Composition d'électrolyte selon l'une des revendications précédentes, comprenant en outre un système d'agent de brillance.
- Procédé pour la séparation d'une couche d'alliage zinc-nickel sur un substrat comportant une proportion de 10 à 18 % en masse de nickel, notamment sur un substrat en fonte ou en acier, caractérisé en ce que le substrat est soumis à un contact avec un flux de la composition d'électrolyte selon l'une des revendications 1 à 4 pour la séparation.
- Procédé selon la revendication 5, caractérisé en ce que le substrat est mis en contact avec la composition d'électrolyte à une température entre 20 °C et 60 °C, de préférence, entre 30 °C et 40 °C.
- Procédé selon l'une des revendications 5 ou 6, caractérisé en ce qu'une densité de courant entre 0,5 et 5 A/dm2, de préférence, entre 1,0 et 3,5 A/dm2, est appliquée pour la séparation de la couche.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PT60145190T PT1881090E (pt) | 2006-07-13 | 2006-07-13 | Composição electrolítica e processo para a deposição de uma camada de liga de zinco-níquel num substrato de ferro fundido ou de aço |
| PL06014519T PL1881090T3 (pl) | 2006-07-13 | 2006-07-13 | Kompozycja elektrolityczna i sposób osadzania warstwy stopu cynkowo-niklowego na substrat żeliwny lub stalowy |
| ES06014519.0T ES2553730T3 (es) | 2006-07-13 | 2006-07-13 | Composición de electrolito y procedimiento para la deposición de una capa de aleación de zinc-níquel sobre un sustrato de hierro fundido o de acero fundido |
| HUE06014519A HUE026918T2 (en) | 2006-07-13 | 2006-07-13 | Electrolytic composition and method for separating zinc / nickel alloy layer on cast iron or steel substrate |
| EP06014519.0A EP1881090B1 (fr) | 2006-07-13 | 2006-07-13 | Composition électrolytique et procédé pour la déposition d'une couche d'alliage zinc-nickel sur un substrat en fonte ou en acier |
| US11/778,011 US8435398B2 (en) | 2006-07-13 | 2007-07-13 | Electrolyte composition and method for the deposition of a zinc-nickel alloy layer on a cast iron or steel substrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06014519.0A EP1881090B1 (fr) | 2006-07-13 | 2006-07-13 | Composition électrolytique et procédé pour la déposition d'une couche d'alliage zinc-nickel sur un substrat en fonte ou en acier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1881090A1 EP1881090A1 (fr) | 2008-01-23 |
| EP1881090B1 true EP1881090B1 (fr) | 2015-09-16 |
Family
ID=37499374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06014519.0A Active EP1881090B1 (fr) | 2006-07-13 | 2006-07-13 | Composition électrolytique et procédé pour la déposition d'une couche d'alliage zinc-nickel sur un substrat en fonte ou en acier |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8435398B2 (fr) |
| EP (1) | EP1881090B1 (fr) |
| ES (1) | ES2553730T3 (fr) |
| HU (1) | HUE026918T2 (fr) |
| PL (1) | PL1881090T3 (fr) |
| PT (1) | PT1881090E (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008007133A1 (de) * | 2008-01-31 | 2009-08-06 | Metallveredelung Huber Gmbh | Beschichtung enthaltend einen galvanisch aufgebrachten Korrosionsschutz, insbesondere auf Beschlagteilen, sowie ein Verfahren zur Herstellung einer Beschichtung |
| FR2956123B1 (fr) * | 2010-02-08 | 2017-10-27 | Dalic | Procede de protection d'un substrat metallique contre la corrosion et l'abrasion, et substrat metallique obtenu par ce procede. |
| ES2543789T5 (es) * | 2013-03-26 | 2018-07-05 | Atotech Deutschland Gmbh | Proceso para la protección frente a la corrosión de materiales que contienen hierro |
| CN104651888B (zh) * | 2015-03-04 | 2017-03-22 | 武汉风帆电化科技股份有限公司 | 一种弱酸性至中性具有高耐蚀性锌镍合金电镀添加剂及电镀液 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3930965A (en) * | 1974-03-18 | 1976-01-06 | Mcgean Chemical Company, Inc. | Zinc-copper alloy electroplating baths |
| SU524866A1 (ru) * | 1975-04-10 | 1976-08-15 | Предприятие П/Я А-7697 | Электролит дл осаждени цинк-никелевых сплавов |
| US4146441A (en) * | 1977-10-06 | 1979-03-27 | R. O. Hull & Company, Inc. | Additive compositions, baths, and methods for electrodepositing bright zinc deposits |
| US4388160A (en) | 1980-02-20 | 1983-06-14 | Rynne George B | Zinc-nickel alloy electroplating process |
| US4765871A (en) | 1981-12-28 | 1988-08-23 | The Boeing Company | Zinc-nickel electroplated article and method for producing the same |
| US4543166A (en) | 1984-10-01 | 1985-09-24 | Omi International Corporation | Zinc-alloy electrolyte and process |
| US4825009A (en) * | 1985-12-23 | 1989-04-25 | Shell Oil Company | Preparation of nonionic surfactants |
| JPH01219188A (ja) * | 1988-02-26 | 1989-09-01 | Okuno Seiyaku Kogyo Kk | 亜鉛−ニッケル合金めっき浴 |
| US4832802A (en) | 1988-06-10 | 1989-05-23 | Mcgean-Rohco, Inc. | Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor |
| JP2901523B2 (ja) * | 1995-08-09 | 1999-06-07 | 日本カニゼン株式会社 | 無電解黒色めっき浴組成と皮膜の形成方法 |
| US6238542B1 (en) | 1998-09-15 | 2001-05-29 | Thomas Helden | Water soluble brighteners for zinc and zinc alloy electrolytes |
| DE10146559A1 (de) * | 2001-09-21 | 2003-04-10 | Enthone Omi Deutschland Gmbh | Verfahren zur Abscheidung einer Zink-Nickel-Legierung aus einem Elektrolyten |
| US20060283715A1 (en) * | 2005-06-20 | 2006-12-21 | Pavco, Inc. | Zinc-nickel alloy electroplating system |
-
2006
- 2006-07-13 PL PL06014519T patent/PL1881090T3/pl unknown
- 2006-07-13 PT PT60145190T patent/PT1881090E/pt unknown
- 2006-07-13 HU HUE06014519A patent/HUE026918T2/en unknown
- 2006-07-13 ES ES06014519.0T patent/ES2553730T3/es active Active
- 2006-07-13 EP EP06014519.0A patent/EP1881090B1/fr active Active
-
2007
- 2007-07-13 US US11/778,011 patent/US8435398B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| PL1881090T3 (pl) | 2016-03-31 |
| US8435398B2 (en) | 2013-05-07 |
| EP1881090A1 (fr) | 2008-01-23 |
| HUE026918T2 (en) | 2016-07-28 |
| US20080110762A1 (en) | 2008-05-15 |
| PT1881090E (pt) | 2015-12-01 |
| ES2553730T3 (es) | 2015-12-11 |
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