EP1736507B1 - Kautschukzusammensetzung für spikelose Reifenlaufflächen - Google Patents

Kautschukzusammensetzung für spikelose Reifenlaufflächen Download PDF

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Publication number
EP1736507B1
EP1736507B1 EP20060076118 EP06076118A EP1736507B1 EP 1736507 B1 EP1736507 B1 EP 1736507B1 EP 20060076118 EP20060076118 EP 20060076118 EP 06076118 A EP06076118 A EP 06076118A EP 1736507 B1 EP1736507 B1 EP 1736507B1
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EP
European Patent Office
Prior art keywords
rubber
fiber
rubber composition
parts
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP20060076118
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English (en)
French (fr)
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EP1736507A1 (de
Inventor
Jung Tae 401-501 Yeolmaemaeul 4-danji Kim
Yong Jin 105-903 Hana Apt. Kim
Sang Goo Lucky Hana Apt. 101-1203 Kim
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Hankook Tire and Technology Co Ltd
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Hankook Tire Co Ltd
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Publication date
Priority claimed from KR1020050047548A external-priority patent/KR100582003B1/ko
Priority claimed from KR1020050047549A external-priority patent/KR100582005B1/ko
Application filed by Hankook Tire Co Ltd filed Critical Hankook Tire Co Ltd
Publication of EP1736507A1 publication Critical patent/EP1736507A1/de
Application granted granted Critical
Publication of EP1736507B1 publication Critical patent/EP1736507B1/de
Ceased legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/046—Reinforcing macromolecular compounds with loose or coherent fibrous material with synthetic macromolecular fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
    • Y10T428/249937—Fiber is precoated

Definitions

  • the present invention relates, generally, to a rubber composition for a studless tire tread, and more particularly, to a rubber composition for a studless tire tread, in which natural rubber, styrene-butadiene rubber and butadiene rubber, serving as raw rubber, for use in a typical rubber composition for a studless tire tread, are appropriately mixed with a predetermined polyaramide fiber, thereby increasing not only driving force and braking power on snowy and icy roads in the winter season but also handling stability on dry roads and wear resistance.
  • winter tire is largely classified into spike tire and studless tire.
  • the spike tire in which spike pins are mounted to a tread in order to increase frictional force in the snowy and icy region, is advantageous because it exhibits excellent braking performance and driving performance on snowy and icy roads.
  • tire products equipped with rubber spike pins functioning as micro spikes, resulting from a curing process at room temperature through the control of a glass transition temperature, have been commercialized.
  • tire products containing silica acting to increase braking power on wet roads and to decrease fuel consumption, have been proposed.
  • studless tires general studless tires, studless tires using an organic foaming agent, and studless tires using foreign material are exemplary.
  • the studless tires using an organic foaming agent are manufactured by mixing tire tread rubber with an organic foaming agent and then vulcanizing the mixture.
  • This tire has been introduced according to the concept in which the contact area between the road and the tread is increased by a microcell effect due to pores formed upon vulcanization, thus increasing the frictional force and ice gripping power, leading to a shortened braking distance of vehicles on snowy and icy roads and prevention of slip thereof.
  • the foreign material dispersed in the tread rubber composition does not form a chemical bond with base rubber but forms a physical bond therewith, it is readily separated, resulting in irregular wear.
  • the foreign material such as short fiber or natural fiber
  • noise is decreased and environmental problems such as damage to the road are mitigated.
  • the short fiber or natural fiber is spherical and thus easily separated by external impact during motion of the tire, leading to irregular abnormal wear and partial side wear. Such problems shorten the lifetime of the tire and deteriorate the performance of the tire, thus making the users discontent.
  • an object of the present invention is to provide a rubber composition for a studless tire tread, which is capable of preventing abnormal wear and partial side wear of tires and improving ice braking properties by adding the predetermined polyaramide fiber having high Young's modulus and tensile strength.
  • the present invention provides a rubber composition for a studless tire tread, comprising natural rubber (NR), styrene-butadiene rubber (SBR) and butadiene rubber (BR), as raw rubber, which are used in a typical rubber composition for a studless tire tread, and including 1-10 parts by weight of co-poly-(paraphenylene/3,4-oxydiphenylene terephthalamide) fiber based on 100 parts by weight of the solid content of the raw rubber.
  • natural rubber NR
  • SBR styrene-butadiene rubber
  • BR butadiene rubber
  • a rubber composition for a tire tread includes natural rubber, styrene-butadiene rubber, and butadiene rubber, as raw rubber.
  • Natural rubber is naturally occurring rubber.
  • Styrene-butadiene rubber resulting from an emulsion polymerization process, has, specifically 20 ⁇ 25% of styrene, a Mooney viscosity at 100°C of 55-65, and a stress relaxation time gradient of -0.30 ⁇ -0.38.
  • butadiene rubber contained in the raw rubber is diene-based rubber, obtained through a solution polymerization process, and is composed of 96% or more of 1,4-cis-butadiene.
  • the raw rubber may further include a typical rubber mixing agent.
  • the rubber mixing agent include process oil, a reinforcing agent, and other additives.
  • the process oil is preferably composed of 5 ⁇ 25% of an aromatic component, 25 ⁇ 45% of a naphthene component, and 35 ⁇ 65% of a paraffin component. If the composition of the process oil falls outside of the above range, that is, if the amount of the aromatic component is increased, ice braking performance is deteriorated.
  • the process oil is used in an amount of 20-35 parts by weight, based on 100 parts by weight of the solid content of the raw rubber.
  • the carbon black and silica, serving as the reinforcing agent are not particularly limited, and are used in an amount of 40-90 parts by weight based on 100 parts by weight of the solid content of the raw rubber. If the above amount is less than 40 parts by weight based on 100 parts by weight of the raw rubber, rotation resistance is increased but ice braking performance is deteriorated. On the other hand, if the above amount exceeds 100 parts by weight, processibility becomes poor due to poor dispersion of carbon black and silica, and the temperature is increased, thus reducing wear resistance.
  • the rubber composition for a tire tread of the present invention may further include other additives, such as zinc oxide, stearic acid, sulfur, an accelerating agent, an anti-aging agent, etc., which are typically added to the rubber for a tire tread.
  • the polyaramide fiber which is characteristically added to the rubber composition for the tread of the present invention, is para-aramide fiber, and specifically co-poly-(paraphenylene/3,4-oxydiphenylene terephthalamide), having mechanical properties such as Young's modulus of 20-21 GPa and tensile strength of 3000-3250 MPa. Further, the surface of the fiber is treated with RFL (Resorcinol Formaldehyde Liquid) to enable the formation of a chemical bond with rubber, and thus low wear resistance, due to the use of conventional short fiber, may be alleviated. In addition, the addition of the para-polyaramide fiber having high Young's modulus and tensile strength results in high hardness, therefore increasing handling stability on dry roads.
  • RFL Resorcinol Formaldehyde Liquid
  • para-polyaramide fiber When such para-polyaramide fiber is used in the rubber composition for a tire tread, it may function as a stud of a stud tire and therefore can further improve driving force and braking power on snowy and icy roads than when not used.
  • conventional short fiber or natural fiber is spherically arranged upon mixing with rubber
  • the polyaramide fiber used in the present invention is oriented in its original linear shape thanks to its high Young's modulus and tensile strength, and thus is not easily separated by external impact. Also, such fiber, having high Young's modulus and tensile strength, functions to reinforce the mixed rubber.
  • the para-polyaramide fiber is contained in the rubber composition of the present invention in an amount of 1-10 parts by weight based on 100 parts by weight of the solid content of the raw rubber. If the amount of fiber exceeds 10 parts by weight, processibility becomes poor. Further, excess use thereof results in poor dispersibility in rubber, undesirably decreasing wear resistance.
  • the rubber composition of the present invention may further include a foaming agent, which is used in an amount of 3-4 parts by weight based on 100 parts by weight of the raw rubber.
  • the rubber composition of the present invention containing the foaming agent is foamed rubber having 30-120 independent pores having a diameter of 20-140 ⁇ m per unit area of 1 mm 2 .
  • Natural rubber, styrene-butadiene rubber, butadiene rubber, carbon black, and typical additives were mixed at mixing ratios shown in Table 1 below to prepare a rubber composition, which was then vulcanized, thus obtaining a rubber sample.
  • the low-temperature hardness was determined using an ASTM shore A hardness meter (hardness at -20°C) after allowing the sample to stand in a temperature-controlled chamber for 1 hour.
  • the ice friction coefficient was determined by measuring the friction coefficient of the sample at 30 km/hr on an icy road frozen for 24 hours using a dynamic friction tester (available from Sunny Koken).
  • the wear test was conducted using a Lambourn wear tester. The wear performance was considered excellent when the index was high.
  • the braking performance index was determined by subjecting a tire, manufactured at a size of 195/65R 15T using the rubber composition, to a braking test on various roads and then converting the results into the index. The higher the index, the shorter the braking distance.
  • Aladmide Fiber Co-poly-(paraphenylene/3,4-oxydiphenylene terephthalamide) fiber, trade name of Technora, available from Teijin, Young's modulus of 20GPa, tensile strength of 3100Mpa, surface treatment with RFL (Resorcinol Formaldehyde Liquid).
  • SBR Styrene Butadiene Rubber, having 20 ⁇ 25% of styrene, Mooney viscosity at 100°C of 55-65, stress relaxation time gradient of -0.30 ⁇ -0.38.
  • BR Butadiene Rubber having 96% or more of 1,4-cis butadiene, resulting from solution polymerization.
  • Process Oil 5 wt% of aromatic component, 45 wt% of naphthene component, and 50 wt% of paraffin component.
  • the short fiber or natural fiber used is present in a spherical shape, whereas the para-polyaramide fiber of the present invention is present in its original linear shape in the rubber.
  • the sample of Comparative Example 3 using the aradmide short fiber has lower tensile strength than that of the sample of Example 1, and the aramide short fiber used does not undergo surface treatment with RFL and thus has low bondability with the rubber, leading to decreased wear resistance.
  • the short fiber or natural fiber does not preserve its original shape due to the high shear force required for mixing with rubber and is thus present in a spherical shape.
  • the para-polyaramide fiber used in the present invention is present in its original linear shape thanks to its high Young's modulus and tensile strength, it is not easily separated by external impact. Further, the para-polyaramide fiber, having high Young's modulus and tensile strength, can form a chemical bond with rubber through surface treatment with RFL, and therefore functions as a reinforcing agent in the mixed rubber.
  • the para-polyaramide fiber exhibiting such effects is excessively used, low-temperature hardness is greatly increased as in Comparative Example 4 and enveloping performance with the road is decreased, resulting in low braking performance on snowy and icy roads.
  • the para-polyaramide fiber should be contained in the rubber composition of the present invention in an amount of 10 parts by weight or less.
  • Example 3 and 4 and Comparative Example 7 the para-polyaramide fiber according to the present invention was used.
  • the sample of Comparative Example 1 corresponded to typical foamed rubber, and the sample of Comparative Example 2 was conventionally composed of short fiber or natural fiber to increase ice braking performance.
  • Comparative Example 4 as the aramide fiber, short fiber under the trade name of Kevlar was used, instead of the fiber used in the rubber composition of the present invention.
  • the number of pores of the foamed rubber was observed with the naked eye and the number of independent pores having a diameter of 20-140 ⁇ m per 1 mm 2 of the rubber sample was counted.
  • the low-temperature hardness was determined using an ASTM shore A hardness meter (hardness at -20°C) after allowing the sample to stand in a temperature-controlled chamber for 1 hour.
  • the ice friction coefficient was determined by measuring the friction coefficient of the sample at 30 km/hr on an icy road frozen for 24 hours using a dynamic friction tester (available from Sunny Koken). The wear test was conducted using a Lambourn wear tester. The wear performance was considered excellent when the index was high.
  • the braking performance index was determined by subjecting a tire manufactured at a size of 195/65R 15Q using the rubber composition to a braking test on various roads and then converting the results into the index. The higher the index, the shorter the braking distance.
  • the wear resistance was determined in a manner such that a tire manufactured at a size of 195/65R 15Q was run a predetermined distance, after which weight loss of the tire was measured and then represented by a relative index.
  • the handling stability was determined by measuring lap time upon running the tire manufactured in the above size at a predetermined distance, which was then represented by a relative index.
  • BR Solution Polymerized Butadiene Rubber having 96% or more of 1,4-cis butadiene, resulting from solution polymerization.
  • Process Oil 5 wt% of aromatic component, 45 wt% of naphthene component, and 50 wt% of paraffin component.
  • Anti-aging Agent 6PPD 1*.Aramide Short Fiber: Poly-(paraphenylene terephthalamide (Chemical Formula), Kevlar (Trade Name), available from Dupont, Young's Modulus of 25 GPa, Tensile Strength of 2100 MPa.
  • Aladmide Fiber Co-poly-(paraphenylene/3,4-oxydiphenylene terephthalamide) fiber, trade name of Technora, available from Teijin, Young's modulus of 20GPa, tensile strength of 3100Mpa, surface treatment with RFL (Resorcinol Formaldehyde Liquid). Hardness at -20(C (Shore A) 50 51 57 52 51 52 Ice Friction Coefficient (u) 0.35 0.41 0.42 0.39 0.40 0.45 Lambourn Wear Index 100 93 92 85 101 99 No.
  • the used short fiber or natural fiber is present in a spherical shape, while the para-polyaramide fiber of the present invention is present in its original linear shape in the rubber.
  • the samples of Examples 3 and 4 in which predetermined para-polyaramide fiber is added to the foamed rubber, have increased snow/ice braking performance and handling stability on dry roads as in the use of conventional short fiber or natural fiber, and improve wear resistance, which is decreased by the addition of conventional short fiber or natural fiber.
  • the short fiber or natural fiber does not preserve its original shape due to the high shear force required for mixing with rubber and thus is present in a spherical shape, however the para-polyaramide fiber used in the present invention is present in its original linear shape thanks to its high Young's modulus and tensile strength, and thus is not easily separated by external impact. Further, the para-polyaramide fiber functions to reinforce the mixed rubber by virtue of its high Young's modulus and tensile strength.
  • the present invention provides a rubber composition for a studless tire tread.
  • the added para-polyaramide fiber may function as a stud of a stud tire, and thus driving force and braking power on snowy and icy roads may be increased.
  • the polyaramide fiber is present in its original linear shape thanks to its high Young's modulus and tensile strength, and thus is not easily separated by external impact. Further, the polyaramide fiber, having high Young's modulus and tensile strength, can reinforce the mixed rubber, therefore maintaining wear resistance, leading to the prevention of abnormal wear and partial side wear of the tire.
  • the foamed rubber composition of the present invention can increase handling stability on dry roads and wear resistance while exhibiting the excellent ice braking performance of conventional foamed rubber.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Tires In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (9)

  1. Eine Gummizusammensetzung für ein Reifenprofil eines Winterreifen, die Kautschuk, Styrol-Butadien-Gummi und Butadien-Gummi als Rohgummi umfasst, und die 1~10 Gewichtsanteile an Co-poly-(paraphenylene/3,4'oxydiphenylene terephthalamide) Faser basierend auf 100 Gewichtsanteile eines festen Inhalts des Rohgummis einschließen.
  2. Die Gummizusammensetzung nach Anspruch 1, bei der die Co-poly-(paraphenylene/3,4'oxydiphenylene terephthalamide) Faser über ein Young'sches Modul von 20-21 GPa und eine Reißfestigkeit von 3000-3250 MPa verfügen.
  3. Die Gummizusammensetzung nach Anspruch 1, bei der die Co-poly-(paraphenylene/3,4'oxydipherlylene terephthalamide) Faser zubereitet wird, indem kurze Fasern einer Oberflächenbehandlung mit Resorcin-Formaldehyd Flüssigkeit unterzogen werden.
  4. Die Gummizusammensetzung nach Anspruch 1, bei der es sich bei dem Gummi um Schaumgummi handelt, das 30~120 unabhängige Poren mit einem Durchmesser von 20~140 µm pro einer Flächeneinheit von 1 mm2 besitzt.
  5. Die Gummizusammensetzung nach Anspruch 4, die weiterhin 3~4 Gewichtsanteile eines Treibmittels basierend auf 100 Gewichtsanteile eines festen Inhalts des Rohgummis enthält.
  6. Die Gummizusammensetzung nach Anspruch 1 oder 4, die weiterhin ein Gummimischmittel enthält.
  7. Die Gummizusammensetzung nach Anspruch 6, bei der das Gummimischmittel aus der Gruppe ausgewählt wird, die aus Kohlenschwarz, Silica, Prozessöl, Zinkoxid, Stearinsäure, Schwefel, einem Beschleunigungsmittel, und einem Anti-Aging-Mittel besteht.
  8. Die Gummizusammensetzung nach Anspruch 7, bei der die Kohlenschwarz und Silice in einem Volumen von 40~90 Gewichtsanteilen basierend auf 100 Gewichtsanteile des festen Inhalts des Rohgummis enthalten sind.
  9. Die Gummizusammensetzung nach Anspruch 7, bei der das Prozessöl in einem Volumen von 20~35 Gewichtsanteilen basierend auf 100 Gewichtsanteile des festen Inhalts des Rohgummis enthalten ist.
EP20060076118 2005-06-03 2006-05-26 Kautschukzusammensetzung für spikelose Reifenlaufflächen Ceased EP1736507B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020050047548A KR100582003B1 (ko) 2005-06-03 2005-06-03 스터드리스 타이어의 트레드용 고무 조성물
KR1020050047549A KR100582005B1 (ko) 2005-06-03 2005-06-03 스터드리스 타이어의 트레드용 고무 조성물

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EP1736507A1 EP1736507A1 (de) 2006-12-27
EP1736507B1 true EP1736507B1 (de) 2007-09-19

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EP (1) EP1736507B1 (de)
JP (1) JP4683490B2 (de)
DE (1) DE602006000118D1 (de)

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US20110086224A1 (en) * 2009-10-13 2011-04-14 E.I. Du Pont De Nemours And Company Sheet and Method of Making Sheet for Support Structures and Tires
CN105542267A (zh) * 2011-02-23 2016-05-04 株式会社普利司通 橡胶组合物的制造方法
RU2014113228A (ru) * 2011-10-18 2015-11-27 Сумитомо Раббер Индастриз, Лтд. Резиновая смесь для нешипованных зимних шин и нешипованная зимняя шина
JP7053089B2 (ja) * 2017-12-15 2022-04-12 株式会社ブリヂストン ゴム組成物、加硫ゴム及びタイヤ
WO2019116701A1 (ja) * 2017-12-15 2019-06-20 株式会社ブリヂストン ゴム組成物、加硫ゴム及びタイヤ
KR20200021130A (ko) * 2018-08-20 2020-02-28 한국타이어앤테크놀로지 주식회사 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어

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EP1736507A1 (de) 2006-12-27
US20060280925A1 (en) 2006-12-14
JP4683490B2 (ja) 2011-05-18
JP2006336013A (ja) 2006-12-14

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