EP1694598A2 - Reformeur et procede pour transformer du combustible et un agent oxydant en reformat - Google Patents

Reformeur et procede pour transformer du combustible et un agent oxydant en reformat

Info

Publication number
EP1694598A2
EP1694598A2 EP04816267A EP04816267A EP1694598A2 EP 1694598 A2 EP1694598 A2 EP 1694598A2 EP 04816267 A EP04816267 A EP 04816267A EP 04816267 A EP04816267 A EP 04816267A EP 1694598 A2 EP1694598 A2 EP 1694598A2
Authority
EP
European Patent Office
Prior art keywords
zone
fuel
reforming
oxidation
supplied
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04816267A
Other languages
German (de)
English (en)
Inventor
Stefan Käding
Norbert GÜNTHER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enerday GmbH
Original Assignee
Webasto SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Webasto SE filed Critical Webasto SE
Publication of EP1694598A2 publication Critical patent/EP1694598A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00117—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00157—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Definitions

  • the invention relates to a reformer for converting fuel and oxidizing agent to reformate, with an oxidation zone and a reforming zone, wherein a mixture of fuel and oxidizing agent can be supplied to the oxidation zone, which mixture can be supplied at least partially to the reforming zone after at least partial oxidation of the fuel.
  • the invention further relates to a method for converting fuel and oxidizing agent to reformate in a reformer having an oxidation zone and a reforming zone, the oxidation zone being supplied with a mixture of fuel and oxidizing agent which is at least partially fed to the reforming zone after at least partial oxidation of the fuel.
  • Generic reformers and generic processes have numerous areas of application. In particular, they serve to supply a fuel cell with a hydrogen-rich gas mixture, from which electrical energy can then be generated on the basis of electrochemical processes.
  • Fuel cells of this type are used, for example, in the motor vehicle sector as auxiliary energy sources, so-called APUs ("auxiliary power unit").
  • the reforming process for converting fuel and oxidizing agent to reformate can be carried out according to different principles.
  • catalytic reforming is known in which some of the fuel is in a exothermic reaction is oxidized.
  • the disadvantage of this catalytic reforming is the high heat generation which can irreversibly damage system components, in particular the catalytic converter.
  • hydrocarbons are converted to hydrogen in an endothermic reaction using water vapor.
  • the invention has for its object to provide a reformer and a method for converting fuel and oxidizing agent to reformate, in which the problems mentioned are at least partially overcome and in particular no problems arise from high temperatures or large temperature gradients.
  • the invention builds on the generic reformer in that fuel can also be supplied to the reforming zone and that heat can be supplied to the reforming zone.
  • the additional fuel supplied, together with the exhaust gas from the oxidation zone, thus forms the starting gas mixture for the reforming process.
  • heat from the exothermic oxidation can be supplied to the reforming zone in the oxidation zone.
  • the thermal energy generated in the oxidation zone is thus converted as part of the reforming reaction, so that the net heat production of the overall process does not lead to problems in the temperature balance of the reformer.
  • the reforming zone has an oxidizing agent supply, via which additional oxidizing agents can be supplied. In this way, a further parameter is available for influencing the reforming, so that it can be optimized.
  • the invention is developed in a particularly useful manner in that the additional fuel can be fed to an injection and mixture formation zone and that the additional fuel can flow from the injection and mixture formation zone into the reforming zone.
  • This injection and mixture formation zone is thus upstream of the reforming zone, so that the reforming zone is provided with a well-mixed starting gas for the reforming reaction.
  • Fuel is at least partially evaporated by the thermal energy of the gas mixture emerging from the oxidation zone.
  • the reac- Heat from the oxidation can also be used advantageously for the vaporization process of the fuel.
  • the gas mixture generated in the oxidation zone may be able to be fed to the reforming zone partially bypassing the injection and mixture formation zone. This provides a further possibility for influencing the reforming process, so that a further improvement of the reformate exiting the reformer can be achieved with regard to its application.
  • the invention is based on the generic method in that additional fuel is fed to the reforming zone and that heat is fed to the reforming zone.
  • additional fuel is fed to the reforming zone and that heat is fed to the reforming zone.
  • advantages and special features of the reformer according to the invention are also implemented as part of a process. This also applies to the particularly preferred embodiments of the method according to the invention specified below.
  • the reforming zone can have an oxidant feed, via which additional oxidant is fed.
  • the additional fuel is fed to an injection and mixture formation zone and that the additional fuel flows from the injection and mixture formation zone into the reforming zone.
  • the additional fuel is at least partially evaporated by the thermal energy of the gas mixture emerging from the oxidation zone. Furthermore, it can be provided that the gas mixture generated in the oxidation zone is fed to the reforming zone, partly bypassing the injection and mixture formation zone.
  • the invention is based on the knowledge that by separating the oxidation zone and reforming zone and mixing the exhaust gas from the oxidation zone with additionally supplied fuel, a gas mixture can be generated which offers good conditions with regard to the subsequent reforming or by further supplying exhaust gas and Oxidizing agents can be optimized with regard to the reforming process.
  • Figure 1 is a schematic representation of a reformer according to the invention.
  • FIG. 2 shows a flow chart to explain a method according to the invention.
  • FIG. 1 shows a schematic representation of a reformer according to the invention.
  • the reformer 10 can be fed fuel 12 and oxidizing agent 16 via respective feeds. Diesel can be used as fuel 12, for example, and oxidizing agent 16 is usually air.
  • the heat of reaction which arises immediately during the initial combustion can be partially dissipated in an optionally provided cooling zone 36.
  • the mixture then continues into the oxidation zone 24, which can be realized as a tube arranged within the reforming zone 26.
  • the oxidation zone is implemented by a plurality of pipes or by a special pipe guide within the reforming zone 26.
  • fuel and oxidant are converted in an exothermic reaction with ⁇ «1.
  • the resulting gas mixture 32 then enters an injection and mixture formation zone 30, in which it is mixed with injected fuel 14.
  • the thermal energy of the gas mixture 32 can support the evaporation of the fuel 14.
  • oxidizing agent is fed into the injection and mixture formation zone 30.
  • the mixture thus formed then passes into the reforming zone 26, where it is reacted in an endothermic reaction with, for example, ⁇ ⁇ 0.4.
  • the heat 28 required for the endothermic reaction is removed from the oxidation zone 24.
  • additional oxidizing agent 18 can be fed into the reforming zone 26.
  • the reformate 22 then flows out of the reforming zone 26 and is available for further applications.
  • FIG. 2 shows a flow diagram to explain a method according to the invention.
  • an oxidation zone is supplied with fuel and oxidizing agent. Thereafter, at least partial oxidation of the fuel takes place in step S02.
  • the gas mixture emerging from the oxidation zone is fed to the injection and mixture formation zone.
  • additional fuel is supplied to the injection and mixture formation zone in step S04.
  • the mixture generated in the injection and mixture formation zone is then fed to the reforming zone in step S05, where it is reformed in step S06 in an endothermic reaction using the heat of reaction of the exothermic oxidation.
  • the reformate is removed in step S07.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un reformeur servant à transformer du combustible (12) et un agent oxydant (16, 18, 20) en reformat (22), ledit reformeur présentant une zone d'oxydation (24) et une zone de reformage (26). Un mélange de combustible (12) et d'agent oxydant (16, 18, 20) peut être acheminé à la zone d'oxydation (24), ce mélange pouvant être acheminé au moins partiellement à la zone de reformage (26), après une oxydation au moins partielle du combustible (12). Selon l'invention, du combustible supplémentaire (14) ainsi que de la chaleur (28) peuvent être acheminés à la zone de reformage (26). L'invention concerne en outre un procédé pour transformer du combustible (12) et un agent oxydant (16, 18, 20) en reformat (22).
EP04816267A 2003-12-17 2004-12-16 Reformeur et procede pour transformer du combustible et un agent oxydant en reformat Withdrawn EP1694598A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10359205A DE10359205B4 (de) 2003-12-17 2003-12-17 Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat
PCT/DE2004/002758 WO2005058751A2 (fr) 2003-12-17 2004-12-16 Reformeur et procede pour transformer du combustible et un agent oxydant en reformat

Publications (1)

Publication Number Publication Date
EP1694598A2 true EP1694598A2 (fr) 2006-08-30

Family

ID=34672843

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04816267A Withdrawn EP1694598A2 (fr) 2003-12-17 2004-12-16 Reformeur et procede pour transformer du combustible et un agent oxydant en reformat

Country Status (9)

Country Link
US (1) US20070084118A1 (fr)
EP (1) EP1694598A2 (fr)
JP (1) JP5172149B2 (fr)
KR (1) KR100863759B1 (fr)
CN (1) CN100544814C (fr)
AU (1) AU2004298418B2 (fr)
CA (1) CA2550047A1 (fr)
DE (1) DE10359205B4 (fr)
WO (1) WO2005058751A2 (fr)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8795398B2 (en) 2003-07-31 2014-08-05 Precision Combustion, Inc. Apparatus for vaporizing and reforming liquid fuels
DE102004059647B4 (de) * 2004-12-10 2008-01-31 Webasto Ag Verfahren zum Regenerieren eines Reformers
US8444951B2 (en) * 2005-11-04 2013-05-21 Precision Combustion, Inc. Catalytic process and system for converting liquid fuels into syngas
DE102005058530A1 (de) * 2005-12-08 2007-07-26 J. Eberspächer GmbH & Co. KG Reformeranordnung, Funktionssystem aus Reformeranordnung und Wasserstoff verbrauchendem System und Verfahren zum Betreiben einer Reformeranordnung
DE102006033441B4 (de) * 2006-06-29 2009-05-07 Enerday Gmbh Reformer für ein Brennstoffzellensystem
DE102006032469B4 (de) * 2006-07-13 2008-06-19 Enerday Gmbh Reformer für ein Brennstoffzellensystem und Verfahren zum Betreiben eines Reformers sowie deren Verwendung
DE102006032471A1 (de) 2006-07-13 2008-01-17 Webasto Ag Brennstoffzellensystem mit Reformer und Nachbrenner
DE102006032470B4 (de) * 2006-07-13 2008-07-10 Enerday Gmbh Brennstoffzellensystem mit Reformer und Nachbrenner sowie dessen Verwendung in einem Kraftfahrzeug
DE102006032956B4 (de) * 2006-07-17 2010-07-01 Enerday Gmbh Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu gasförmigem Reformat
DE102006039118B4 (de) * 2006-08-21 2010-09-23 Enerday Gmbh Reformer
DE102006039933A1 (de) * 2006-08-25 2008-02-28 Enerday Gmbh Reformer zum Umsetzen von gasförmigem Brennstoff und Oxidationsmittel zu Reformat
DE102006040563A1 (de) * 2006-08-30 2008-03-20 Enerday Gmbh Verfahren und System zum Einstellen des Temperaturprofils eines Katalysators in einem Reformer
DE102006043128A1 (de) * 2006-09-14 2008-03-27 Enerday Gmbh Reformer
DE102006043350B3 (de) * 2006-09-15 2008-04-17 Enerday Gmbh Verfahren und System zur Regelung/Steuerung einer Gesamtluftverhältniszahl eines Reformers
DE102006043349A1 (de) * 2006-09-15 2008-03-27 Enerday Gmbh Brennstoffzellensystem und Verfahren zum Starten eines Brennstoffzellensystems
DE102006046006B4 (de) * 2006-09-28 2008-11-27 Enerday Gmbh Reformer zur Nutzung von Stickoxiden zur kontinuierlichen Regeneration
DE102007017501A1 (de) 2007-04-13 2008-10-16 Enerday Gmbh Verfahren zum Überprüfen eines Reformers und elektrische Steuereinheit
DE102007018311B4 (de) * 2007-04-18 2008-12-04 Enerday Gmbh Zweistufiger Reformer und Verfahren zum Betreiben eines Reformers
DE102007026923A1 (de) 2007-06-12 2008-12-18 Enerday Gmbh Zweistufiger Gasreformer
DE102007040192A1 (de) * 2007-08-25 2009-02-26 J. Eberspächer GmbH & Co. KG Reformer und Brennstoffzellensystem
US8337757B2 (en) 2008-02-07 2012-12-25 Precision Combustion, Inc. Reactor control method
DE102008017237B4 (de) * 2008-04-04 2022-02-10 Eberspächer Climate Control Systems GmbH & Co. KG Reformer und Brennstoffzellensystem
US20090252661A1 (en) * 2008-04-07 2009-10-08 Subir Roychoudhury Fuel reformer
DE102008039014A1 (de) * 2008-08-21 2010-02-25 Uhde Gmbh Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas
US8439990B2 (en) * 2009-07-21 2013-05-14 Precision Combustion, Inc. Reactor flow control apparatus
DE102011100417A1 (de) * 2011-05-04 2012-11-08 Vaillant Gmbh Reformer
TWI501462B (zh) * 2012-07-19 2015-09-21 Atomic Energy Council 可以防止產生積碳的重組器
CN105705227B (zh) 2013-11-06 2018-09-25 瓦特燃料电池公司 液体燃料催化部分氧化重整器和燃料电池系统、以及产生电力的方法
US9627699B2 (en) 2013-11-06 2017-04-18 Watt Fuel Cell Corp. Gaseous fuel CPOX reformers and methods of CPOX reforming
US10676354B2 (en) 2013-11-06 2020-06-09 Watt Fuel Cell Corp. Reformer with perovskite as structural component thereof
AU2014346844B2 (en) 2013-11-06 2017-06-15 Watt Fuel Cell Corp. Chemical reactor with manifold for management of a flow of gaseous reaction medium thereto
US9624104B2 (en) 2013-11-06 2017-04-18 Watt Fuel Cell Corp. Liquid fuel CPOX reformers and methods of CPOX reforming
MX2016004622A (es) 2013-11-06 2016-08-01 WATT Fuel Cell Corp Reformador de cpox de combustible gaseoso integrado y sistemas de celda de combustible, y metodos para producir electricidad.
US10001278B1 (en) 2014-12-30 2018-06-19 Precision Combustion, Inc. Apparatus and method for operating a gas-fired burner on liquid fuels
US11022318B1 (en) 2014-12-30 2021-06-01 Precision Combustion, Inc. Apparatus and method for operating a gas-fired burner on liquid fuels
US10738996B1 (en) 2014-12-30 2020-08-11 Precision Combustion, Inc. Apparatus and method for operating a gas-fired burner on liquid fuels
TWI746620B (zh) 2016-09-23 2021-11-21 日商索尼半導體解決方案公司 相機模組、製造方法及電子機器
US20190263659A1 (en) 2018-02-26 2019-08-29 Minish Mahendra Shah Integration of a hot oxygen burner with an auto thermal reformer
CN115275287B (zh) * 2022-09-28 2023-02-14 广东佛燃科技有限公司 一种用于sofc系统的反应器及其运行方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2372116A1 (fr) * 1977-03-22 1978-06-23 Banquy David Procede de production de gaz de synthese
DE3532413A1 (de) * 1985-09-11 1987-03-12 Uhde Gmbh Vorrichtung zur erzeugung von synthesegas
GB8609099D0 (en) * 1986-04-15 1986-05-21 British Petroleum Co Plc Production of synthesis gas
DE3806408A1 (de) * 1988-02-29 1989-09-07 Uhde Gmbh Verfahren und vorrichtung zur erzeugung eines h(pfeil abwaerts)2(pfeil abwaerts) und co-enthaltenden synthesegases
JPH01261201A (ja) * 1988-04-12 1989-10-18 Mitsubishi Gas Chem Co Inc 炭化水素改質反応器
ATE275529T1 (de) * 1996-06-28 2004-09-15 Matsushita Electric Works Ltd Reformierungsvorrichtung zum erzeugen eines spaltgases mit verringertem co-gehalt.
DE19943248B4 (de) * 1999-09-10 2005-10-27 Ballard Power Systems Ag Verfahren zum Betreiben eines Brennstoffzellensystems und Anordnung zur Durchführung des Verfahrens
DE19953233A1 (de) * 1999-11-04 2001-05-10 Grigorios Kolios Autotherme Reaktorschaltungen zur direkten Kopplung endothermer und exothermer Reaktionen
AU6000901A (en) * 2000-06-08 2001-12-17 Paul Scherrer Institut Catalytic plate reactor with internal heat recovery
US20020114747A1 (en) * 2000-12-28 2002-08-22 Kevin Marchand Fuel processing system and apparatus therefor
JP2002338207A (ja) * 2001-05-22 2002-11-27 Nissan Motor Co Ltd 燃料改質装置
JP2003022835A (ja) * 2001-07-09 2003-01-24 Aisin Seiki Co Ltd 燃料電池用改質装置
US6855272B2 (en) * 2001-07-18 2005-02-15 Kellogg Brown & Root, Inc. Low pressure drop reforming exchanger
JP2003192306A (ja) * 2001-12-20 2003-07-09 Daikin Ind Ltd 改質装置
US6911193B2 (en) * 2002-04-19 2005-06-28 Conocophillips Company Integration of mixed catalysts to maximize syngas production
US6936238B2 (en) * 2002-09-06 2005-08-30 General Motors Corporation Compact partial oxidation/steam reactor with integrated air preheater, fuel and water vaporizer
US7138001B2 (en) * 2003-03-16 2006-11-21 Kellogg Brown & Root Llc Partial oxidation reformer-reforming exchanger arrangement for hydrogen production

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2005058751A2 *

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WO2005058751A2 (fr) 2005-06-30
CN100544814C (zh) 2009-09-30
JP5172149B2 (ja) 2013-03-27
DE10359205A1 (de) 2005-07-14
AU2004298418A1 (en) 2005-06-30
KR100863759B1 (ko) 2008-10-16
US20070084118A1 (en) 2007-04-19
WO2005058751A3 (fr) 2007-04-26
AU2004298418B2 (en) 2008-11-13
KR20070005561A (ko) 2007-01-10
CA2550047A1 (fr) 2005-06-30
JP2007516328A (ja) 2007-06-21
CN101076394A (zh) 2007-11-21
DE10359205B4 (de) 2007-09-06

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