EP2061585A1 - Réformeur - Google Patents

Réformeur

Info

Publication number
EP2061585A1
EP2061585A1 EP07801203A EP07801203A EP2061585A1 EP 2061585 A1 EP2061585 A1 EP 2061585A1 EP 07801203 A EP07801203 A EP 07801203A EP 07801203 A EP07801203 A EP 07801203A EP 2061585 A1 EP2061585 A1 EP 2061585A1
Authority
EP
European Patent Office
Prior art keywords
zone
mixture
fuel
flue gas
reformer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07801203A
Other languages
German (de)
English (en)
Inventor
Stefan Kah
Johannes EICHSTÄDT
Andreas Lindermeir
Marco Mühlner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enerday GmbH
Original Assignee
Enerday GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enerday GmbH filed Critical Enerday GmbH
Publication of EP2061585A1 publication Critical patent/EP2061585A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278Feeding reactive fluids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00309Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276Mixing of different feed components
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Definitions

  • the invention relates to a reformer having a first media feed area to which fuel and oxidant can be supplied, an oxidation zone adjoining the first media feed area in which the media fed to the first media feed area react at least partially to flue gas, a second media feed area to which at least fuel can be fed , a mixture forming zone, which connects to the oxidation zone and the second RulezuSIC Scheme and in which a fuel-flue gas mixture can be generated, and a subsequent to the mixture formation zone reforming zone, in which the fuel-flue gas mixture is catalytically reformable.
  • Such reformers are used to produce from hydrocarbons, such as natural gas, gasoline or diesel, a hydrogen-rich reformate, which can be supplied to the production of e- lectric energy of the anode side of a fuel cell.
  • hydrocarbons such as natural gas, gasoline or diesel
  • a hydrogen-rich reformate which can be supplied to the production of e- lectric energy of the anode side of a fuel cell.
  • the above-mentioned multistage fuel feed which is described for example in DE 103 59 205 A1, serves in particular for the homogenization of the temperature profile.
  • part of the total supplied fuel is completely oxidized with air and passed in the course of the reaction and thereafter at the reforming zone arranged concentrically to the oxidation zone. In this case, the catalyst can be heated.
  • the flue gas Before the occurrence of the resulting in the oxidation of the flue gas into the catalyst, the flue gas is mixed with more fuel, so that the reforming zone to be supplied fuel-flue gas mixture is available.
  • the total quantities of the supplied air and the supplied fuel determine the important parameter for the reforming of the air ratio.
  • the total air ratio should be in the range of 0.4. In order to further influence the air ratio, provision can also be made for a further oxidant supply to be provided in the second media feed region.
  • the invention has the object of developing a reformer in such a way that an undesirable auto-ignition is prevented in a mixture formation zone in a simple manner.
  • the invention builds on the generic reformer in that the volume of the mixture forming zone is between 20 and 90 cm 3 . By the appropriate choice of the volume of the mixture formation zone can be achieved that a
  • the volume of the mixture forming zone is between 40 and 60 cm 3 .
  • the reformer is suitable for guiding a flue gas volume flow of between 40 and 200 l / min.
  • Such flue gas volume flows in conjunction with the mentioned volumes of the mixture-forming zone, then lead to the residence time of the flue gas volumetric flow in the mixture-forming zone being from 10 to 100 ms.
  • Such residence times are on the order of average ignition delay times of typical mixtures generated in the mixture formation zone. If the residence times are sufficiently short in comparison to the ignition delay times, auto-ignition can be reliably suppressed.
  • the invention is based on the finding that, by suitable choice of the volume of the mixture formation zone, this alone can prevent self-ignition of the mixture in the mixture formation zone.
  • the specification of the volumes serves in particular for the realization of typical applications and system outputs in the range between 2 and 5 kW, which can be made available by using the abovementioned flue gas volume flows.
  • FIG. 1 shows a schematic representation of a reformer according to the invention.
  • the reformer 10 has a first Rulezucited Siemens 12 the fuel 14 and oxidizing agent 16, that is, in particular air are supplied.
  • An oxidation zone 18 adjoins the media feed region 12 and this oxidation zone 18 is at least partially reacted with supplied media, so that flue gas 20 is formed.
  • the resulting flue gas 20 subsequently passes into a mixture-forming zone 26.
  • the mixture-forming zone 26 is supplied with further fuel 24 via a second medium-feed region 22.
  • This results in a fuel-flue gas mixture 28 which is subsequently fed to a reforming zone 30.
  • the fuel-flue gas mixture is catalytically converted to finally be removed as reformate 32.
  • the reformate 32 can then be made available to other applications, in particular a fuel cell.
  • the mixture-forming zone has a volume which prevents the auto-ignition of the fuel smoke gas mixture 28. Volumes for which this can be achieved on the assumption of a system output of between 2 and 5 kW are in the range between 40 and 60 cm 3 .
  • the mixture formation zone is not necessarily a precisely defined area. Rather, the mixture forming zone generally flows smoothly into the oxidation zone 18, the reforming zone 30 and the second media supply zone 22.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un réformeur (10) présentant une première zone d'amenée de milieux (12), dans laquelle un combustible (14) et un agent d'oxydation (16) peuvent être amenés, une zone d'oxydation (18) raccordée à la première zone d'amenée de milieux (12), dans laquelle les milieux amenés dans la première zone d'amenée de milieux réagissent au moins partiellement au gaz de combustion (20), une seconde zone d'amenée de milieux (22), dans laquelle au moins un combustible (24) peut être amené, une zone de formation du mélange (26) raccordée à la zone d'oxydation (18) et à la seconde zone d'amenée de milieux, dans laquelle un mélange combustible-gaz de combustion (28) peut être produit, et une zone de réformage (30) raccordée à la zone de formation du mélange (26), dans laquelle le mélange combustible-gaz de combustion (28) peut être réformé de façon catalytique. Selon l'invention, le volume de la zone de formation du mélange est compris entre 20 et 90 cm<SUP>3</SUP>.
EP07801203A 2006-09-14 2007-08-01 Réformeur Withdrawn EP2061585A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006043128A DE102006043128A1 (de) 2006-09-14 2006-09-14 Reformer
PCT/DE2007/001365 WO2008031381A1 (fr) 2006-09-14 2007-08-01 Reformeur

Publications (1)

Publication Number Publication Date
EP2061585A1 true EP2061585A1 (fr) 2009-05-27

Family

ID=38698735

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07801203A Withdrawn EP2061585A1 (fr) 2006-09-14 2007-08-01 Réformeur

Country Status (9)

Country Link
US (1) US20090325008A1 (fr)
EP (1) EP2061585A1 (fr)
JP (1) JP2010503597A (fr)
CN (1) CN101583416A (fr)
AU (1) AU2007295801A1 (fr)
CA (1) CA2662377A1 (fr)
DE (1) DE102006043128A1 (fr)
EA (1) EA200970276A1 (fr)
WO (1) WO2008031381A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007018311B4 (de) * 2007-04-18 2008-12-04 Enerday Gmbh Zweistufiger Reformer und Verfahren zum Betreiben eines Reformers
EP2123351A1 (fr) * 2008-05-13 2009-11-25 Electro Power Systems S.p.A. Appareil de traitement de carburant à base de reformage de vapeur intégré avec brûleur et générateur de vapeur
DE102008039014A1 (de) * 2008-08-21 2010-02-25 Uhde Gmbh Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas
WO2012005644A1 (fr) * 2010-07-09 2012-01-12 Reformtech Sweden Ab Procédé pour fournir un mélange homogène de combustibles liquides et d'oxydants pour utilisation dans un réacteur catalytique
DE102011100417A1 (de) * 2011-05-04 2012-11-08 Vaillant Gmbh Reformer
DE102013008367A1 (de) 2013-05-16 2014-11-20 Man Truck & Bus Ag Antriebsvorrichtung sowie Verfahren zum Betreiben derselben unter Verwendung eines partiell oxidierten Dieselkraftstoffs

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6348278B1 (en) * 1998-06-09 2002-02-19 Mobil Oil Corporation Method and system for supplying hydrogen for use in fuel cells
DE19860308A1 (de) * 1998-12-21 2000-08-03 Heinrich Koehne Verfahren zur Verwertung eines Brennstoffs unter Nutzung exothermer Vorreaktionen in Form einer Kalten Flamme
DE19981437D2 (de) * 1998-07-29 2002-08-14 Heinrich Koehne Verfahren zur Verwertung eines Brennstoffes unter Nutzung exothermer Vorreaktionen in Form einer kalten Flamme
DE10120375A1 (de) * 2001-04-25 2002-10-31 Webasto Thermosysteme Gmbh Reformer für eine Brennstoffzelle
US7037349B2 (en) * 2002-06-24 2006-05-02 Delphi Technologies, Inc. Method and apparatus for fuel/air preparation in a fuel cell
US6872481B2 (en) * 2002-06-28 2005-03-29 General Motors Corporation Process for utilization of a cold-flame vaporizer in auto-thermal reforming of liquid fuel
DE10240234A1 (de) * 2002-08-28 2004-03-11 Heyder, Michael Verbrennungskraftmaschine mit interner Verbrennung
DE10244676B4 (de) * 2002-09-24 2006-03-30 Enginion Ag Vorrichtung für Altfett- und Altöl-Verwertung
DE10359205B4 (de) * 2003-12-17 2007-09-06 Webasto Ag Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat
US20060021280A1 (en) * 2004-07-30 2006-02-02 Hamilton Daniel B Reformer, and methods of making and using the same
DE102004041815A1 (de) * 2004-08-30 2006-03-09 Gvp Gesellschaft Zur Vermarktung Der Porenbrennertechnik Mbh Verfahren und Vorrichtung zur Verdampfung von Flüssigbrennstoffen
DE102004059647B4 (de) * 2004-12-10 2008-01-31 Webasto Ag Verfahren zum Regenerieren eines Reformers
DE102005001900B4 (de) * 2005-01-14 2010-06-17 Enerday Gmbh Vorrichtung und Verfahren zum Bereitstellen eines homogenen Gemisches aus Brennstoff und Oxidationsmittel
US20070113476A1 (en) * 2005-11-21 2007-05-24 Thomas Stephen M Fuel reformer and method of using the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2008031381A1 *

Also Published As

Publication number Publication date
US20090325008A1 (en) 2009-12-31
WO2008031381A1 (fr) 2008-03-20
CN101583416A (zh) 2009-11-18
AU2007295801A1 (en) 2008-03-20
JP2010503597A (ja) 2010-02-04
DE102006043128A1 (de) 2008-03-27
CA2662377A1 (fr) 2008-03-20
EA200970276A1 (ru) 2009-08-28

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