EP2061585A1 - Réformeur - Google Patents
RéformeurInfo
- Publication number
- EP2061585A1 EP2061585A1 EP07801203A EP07801203A EP2061585A1 EP 2061585 A1 EP2061585 A1 EP 2061585A1 EP 07801203 A EP07801203 A EP 07801203A EP 07801203 A EP07801203 A EP 07801203A EP 2061585 A1 EP2061585 A1 EP 2061585A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- zone
- mixture
- fuel
- flue gas
- reformer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
- B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0278—Feeding reactive fluids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00309—Controlling the temperature by indirect heat exchange with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1276—Mixing of different feed components
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
Definitions
- the invention relates to a reformer having a first media feed area to which fuel and oxidant can be supplied, an oxidation zone adjoining the first media feed area in which the media fed to the first media feed area react at least partially to flue gas, a second media feed area to which at least fuel can be fed , a mixture forming zone, which connects to the oxidation zone and the second RulezuSIC Scheme and in which a fuel-flue gas mixture can be generated, and a subsequent to the mixture formation zone reforming zone, in which the fuel-flue gas mixture is catalytically reformable.
- Such reformers are used to produce from hydrocarbons, such as natural gas, gasoline or diesel, a hydrogen-rich reformate, which can be supplied to the production of e- lectric energy of the anode side of a fuel cell.
- hydrocarbons such as natural gas, gasoline or diesel
- a hydrogen-rich reformate which can be supplied to the production of e- lectric energy of the anode side of a fuel cell.
- the above-mentioned multistage fuel feed which is described for example in DE 103 59 205 A1, serves in particular for the homogenization of the temperature profile.
- part of the total supplied fuel is completely oxidized with air and passed in the course of the reaction and thereafter at the reforming zone arranged concentrically to the oxidation zone. In this case, the catalyst can be heated.
- the flue gas Before the occurrence of the resulting in the oxidation of the flue gas into the catalyst, the flue gas is mixed with more fuel, so that the reforming zone to be supplied fuel-flue gas mixture is available.
- the total quantities of the supplied air and the supplied fuel determine the important parameter for the reforming of the air ratio.
- the total air ratio should be in the range of 0.4. In order to further influence the air ratio, provision can also be made for a further oxidant supply to be provided in the second media feed region.
- the invention has the object of developing a reformer in such a way that an undesirable auto-ignition is prevented in a mixture formation zone in a simple manner.
- the invention builds on the generic reformer in that the volume of the mixture forming zone is between 20 and 90 cm 3 . By the appropriate choice of the volume of the mixture formation zone can be achieved that a
- the volume of the mixture forming zone is between 40 and 60 cm 3 .
- the reformer is suitable for guiding a flue gas volume flow of between 40 and 200 l / min.
- Such flue gas volume flows in conjunction with the mentioned volumes of the mixture-forming zone, then lead to the residence time of the flue gas volumetric flow in the mixture-forming zone being from 10 to 100 ms.
- Such residence times are on the order of average ignition delay times of typical mixtures generated in the mixture formation zone. If the residence times are sufficiently short in comparison to the ignition delay times, auto-ignition can be reliably suppressed.
- the invention is based on the finding that, by suitable choice of the volume of the mixture formation zone, this alone can prevent self-ignition of the mixture in the mixture formation zone.
- the specification of the volumes serves in particular for the realization of typical applications and system outputs in the range between 2 and 5 kW, which can be made available by using the abovementioned flue gas volume flows.
- FIG. 1 shows a schematic representation of a reformer according to the invention.
- the reformer 10 has a first Rulezucited Siemens 12 the fuel 14 and oxidizing agent 16, that is, in particular air are supplied.
- An oxidation zone 18 adjoins the media feed region 12 and this oxidation zone 18 is at least partially reacted with supplied media, so that flue gas 20 is formed.
- the resulting flue gas 20 subsequently passes into a mixture-forming zone 26.
- the mixture-forming zone 26 is supplied with further fuel 24 via a second medium-feed region 22.
- This results in a fuel-flue gas mixture 28 which is subsequently fed to a reforming zone 30.
- the fuel-flue gas mixture is catalytically converted to finally be removed as reformate 32.
- the reformate 32 can then be made available to other applications, in particular a fuel cell.
- the mixture-forming zone has a volume which prevents the auto-ignition of the fuel smoke gas mixture 28. Volumes for which this can be achieved on the assumption of a system output of between 2 and 5 kW are in the range between 40 and 60 cm 3 .
- the mixture formation zone is not necessarily a precisely defined area. Rather, the mixture forming zone generally flows smoothly into the oxidation zone 18, the reforming zone 30 and the second media supply zone 22.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006043128A DE102006043128A1 (de) | 2006-09-14 | 2006-09-14 | Reformer |
PCT/DE2007/001365 WO2008031381A1 (fr) | 2006-09-14 | 2007-08-01 | Reformeur |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2061585A1 true EP2061585A1 (fr) | 2009-05-27 |
Family
ID=38698735
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07801203A Withdrawn EP2061585A1 (fr) | 2006-09-14 | 2007-08-01 | Réformeur |
Country Status (9)
Country | Link |
---|---|
US (1) | US20090325008A1 (fr) |
EP (1) | EP2061585A1 (fr) |
JP (1) | JP2010503597A (fr) |
CN (1) | CN101583416A (fr) |
AU (1) | AU2007295801A1 (fr) |
CA (1) | CA2662377A1 (fr) |
DE (1) | DE102006043128A1 (fr) |
EA (1) | EA200970276A1 (fr) |
WO (1) | WO2008031381A1 (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007018311B4 (de) * | 2007-04-18 | 2008-12-04 | Enerday Gmbh | Zweistufiger Reformer und Verfahren zum Betreiben eines Reformers |
EP2123351A1 (fr) * | 2008-05-13 | 2009-11-25 | Electro Power Systems S.p.A. | Appareil de traitement de carburant à base de reformage de vapeur intégré avec brûleur et générateur de vapeur |
DE102008039014A1 (de) * | 2008-08-21 | 2010-02-25 | Uhde Gmbh | Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas |
WO2012005644A1 (fr) * | 2010-07-09 | 2012-01-12 | Reformtech Sweden Ab | Procédé pour fournir un mélange homogène de combustibles liquides et d'oxydants pour utilisation dans un réacteur catalytique |
DE102011100417A1 (de) * | 2011-05-04 | 2012-11-08 | Vaillant Gmbh | Reformer |
DE102013008367A1 (de) | 2013-05-16 | 2014-11-20 | Man Truck & Bus Ag | Antriebsvorrichtung sowie Verfahren zum Betreiben derselben unter Verwendung eines partiell oxidierten Dieselkraftstoffs |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6348278B1 (en) * | 1998-06-09 | 2002-02-19 | Mobil Oil Corporation | Method and system for supplying hydrogen for use in fuel cells |
DE19860308A1 (de) * | 1998-12-21 | 2000-08-03 | Heinrich Koehne | Verfahren zur Verwertung eines Brennstoffs unter Nutzung exothermer Vorreaktionen in Form einer Kalten Flamme |
DE19981437D2 (de) * | 1998-07-29 | 2002-08-14 | Heinrich Koehne | Verfahren zur Verwertung eines Brennstoffes unter Nutzung exothermer Vorreaktionen in Form einer kalten Flamme |
DE10120375A1 (de) * | 2001-04-25 | 2002-10-31 | Webasto Thermosysteme Gmbh | Reformer für eine Brennstoffzelle |
US7037349B2 (en) * | 2002-06-24 | 2006-05-02 | Delphi Technologies, Inc. | Method and apparatus for fuel/air preparation in a fuel cell |
US6872481B2 (en) * | 2002-06-28 | 2005-03-29 | General Motors Corporation | Process for utilization of a cold-flame vaporizer in auto-thermal reforming of liquid fuel |
DE10240234A1 (de) * | 2002-08-28 | 2004-03-11 | Heyder, Michael | Verbrennungskraftmaschine mit interner Verbrennung |
DE10244676B4 (de) * | 2002-09-24 | 2006-03-30 | Enginion Ag | Vorrichtung für Altfett- und Altöl-Verwertung |
DE10359205B4 (de) * | 2003-12-17 | 2007-09-06 | Webasto Ag | Reformer und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat |
US20060021280A1 (en) * | 2004-07-30 | 2006-02-02 | Hamilton Daniel B | Reformer, and methods of making and using the same |
DE102004041815A1 (de) * | 2004-08-30 | 2006-03-09 | Gvp Gesellschaft Zur Vermarktung Der Porenbrennertechnik Mbh | Verfahren und Vorrichtung zur Verdampfung von Flüssigbrennstoffen |
DE102004059647B4 (de) * | 2004-12-10 | 2008-01-31 | Webasto Ag | Verfahren zum Regenerieren eines Reformers |
DE102005001900B4 (de) * | 2005-01-14 | 2010-06-17 | Enerday Gmbh | Vorrichtung und Verfahren zum Bereitstellen eines homogenen Gemisches aus Brennstoff und Oxidationsmittel |
US20070113476A1 (en) * | 2005-11-21 | 2007-05-24 | Thomas Stephen M | Fuel reformer and method of using the same |
-
2006
- 2006-09-14 DE DE102006043128A patent/DE102006043128A1/de not_active Withdrawn
-
2007
- 2007-08-01 WO PCT/DE2007/001365 patent/WO2008031381A1/fr active Application Filing
- 2007-08-01 CN CNA2007800340266A patent/CN101583416A/zh active Pending
- 2007-08-01 EA EA200970276A patent/EA200970276A1/ru unknown
- 2007-08-01 JP JP2009527683A patent/JP2010503597A/ja not_active Withdrawn
- 2007-08-01 EP EP07801203A patent/EP2061585A1/fr not_active Withdrawn
- 2007-08-01 US US12/440,221 patent/US20090325008A1/en not_active Abandoned
- 2007-08-01 CA CA002662377A patent/CA2662377A1/fr not_active Abandoned
- 2007-08-01 AU AU2007295801A patent/AU2007295801A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2008031381A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20090325008A1 (en) | 2009-12-31 |
WO2008031381A1 (fr) | 2008-03-20 |
CN101583416A (zh) | 2009-11-18 |
AU2007295801A1 (en) | 2008-03-20 |
JP2010503597A (ja) | 2010-02-04 |
DE102006043128A1 (de) | 2008-03-27 |
CA2662377A1 (fr) | 2008-03-20 |
EA200970276A1 (ru) | 2009-08-28 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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17P | Request for examination filed |
Effective date: 20090306 |
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AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA HR MK RS |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: MUEHLNER, MARCO Inventor name: LINDERMEIR, ANDREAS Inventor name: EICHSTAEDT, JOHANNES Inventor name: KAH, STEFAN |
|
17Q | First examination report despatched |
Effective date: 20090804 |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20110301 |