EP1666624B1 - Hot dip zinc plated steel sheet and method for production thereof - Google Patents

Hot dip zinc plated steel sheet and method for production thereof Download PDF

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Publication number
EP1666624B1
EP1666624B1 EP04772660.9A EP04772660A EP1666624B1 EP 1666624 B1 EP1666624 B1 EP 1666624B1 EP 04772660 A EP04772660 A EP 04772660A EP 1666624 B1 EP1666624 B1 EP 1666624B1
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EP
European Patent Office
Prior art keywords
steel sheet
hot dip
film
galvanized steel
dip galvanized
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EP04772660.9A
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German (de)
English (en)
French (fr)
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EP1666624A4 (en
EP1666624A1 (en
Inventor
Shoichiro I.P. Dept. JFE Steel Corporation TAIRA
Yoshiharu I.P. Dept. JFE Steel Corp. SUGIMOTO
Yoichi I.P. Dept. JFE Steel Corporation MIYAKAWA
Akira I.P. Dept. JFE Steel Corporation GAMOU
Masayasu I.P. Dept. JFE Steel Corporation NAGOSHI
Takashi I.P. Dept. JFE Steel Corporation KAWANO
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JFE Steel Corp
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JFE Steel Corp
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Publication of EP1666624A4 publication Critical patent/EP1666624A4/en
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Publication of EP1666624B1 publication Critical patent/EP1666624B1/en
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
    • C23C2/06—Zinc or cadmium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C18/00—Alloys based on zinc
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26—After-treatment
    • C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36—Elongated material
    • C23C2/40—Plates; Strips
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/53—Treatment of zinc or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78—Pretreatment of the material to be coated
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82—After-treatment
    • C23C22/83—Chemical after-treatment

Definitions

  • a common practice to improve the press-formability of zinc-based plated steel sheet is a method of coating a high viscosity lubricant oil.
  • the method has problems such as the generation of defects during the painting stage caused by insufficient degreasing, and the instable press-formability during the press-forming stage caused by absence of the lubricant oil.
  • minimization of the quantity of lubricant oil is an effective means. To do this, however, the improvement in the press-formability of zinc-based plated steel sheet is required.
  • the average Fe concentration in the alloy layer increases, the ⁇ phase which is hard and brittle is likely formed at the interface between the plating and the steel sheet, thereby likely inducing a phenomenon of peeling of plating (what is called the "powdering") in the vicinity of the interface during the press-forming stage.
  • JP-A-4-88196 discloses a technology to improve the press-formability and the phosphatability by forming an oxide film composed mainly of a P oxide on the surface of a zinc-based plated steel sheet by dipping the steel sheet in an aqueous solution of pH 2 to 6, containing 5 to 6 g/liter of sodium phosphate, by applying electrodeposition treatment in the aqueous solution, or by spraying the aqueous solution onto the steel sheet.
  • the film of an oxide containing Zn and Fe likely becomes fine lamellar-like oxides compared with the film of oxide only of Zn, which likely forms coarse plate-like oxides.
  • the present invention is also applicable to a galvannealed steel sheet on which the hot dip galvanizing layer is processed by alloying treatment.
  • the Fe ion reduction reaction begins to precipitate trace amount of Fe on the surface of plating layer , which suppresses the excess growth of the film of O-containing compound composed mainly of Zn, thereby forming a film of very fine compound.
  • the film composed of a compound containing Zn, Fe, and O contains elements such as F, Mg, Al, Si, P, S, Cl, K, Ca, and Ba, existing in the acidic solution, or contains adsorbed water, the effect of the present invention is not deteriorated.
  • the film is not necessarily formed continuously, and the film covering not the whole area of plateau is also effective. Nevertheless, to decrease the friction resistance, the film preferably covers 60% or more of the plateau.
  • Galvannealed layer was formed on each of cold-rolled steel sheets having 0.8 mm of thickness using an ordinary method, which plated steel sheets were then processed by temper-rolling. After that, a film was formed on the surface of zinc plating layer under the respective treatment conditions given in Table 1 to prepare the sample Nos. 1 to 22.
  • a comparative sample 11 for determining the coefficient of friction is fixed on a sample table 12 which is fixed on the upper face of a horizontally movable slide table 13.
  • a vertically movable slide table support 15 equipped with a roller 14 contacting with the slide table 13.
  • a first load cell 17 is attached to the slide table support 15.
  • the first load cell determines the pressing load N applied from a bead 16 to the sample 11 by pushing-up the slide table support 15.
  • a second load cell 18 is attached to an end of the slide table 13.
  • the second load cell 18 determines the sliding resistance F by moving the slide table 13 in the horizontal direction in a state of pressing the bead 16 against the comparative sample 11.
  • the tests were conducted by coating a lubricant oil on the surface of the comparative sample 11.
  • the applied lubricant oil was PRETON R352L, a washing oil for press-work manufactured by Sugimura Chemical Industrial Co., Ltd.
  • Figure 2 and Fig. 3 show the shapes of applied beads.
  • the bead 16 shown in Fig. 2 has the dimensions of 10 mm in width, 12 mm in the length in the sliding direction, 3 mm in the length in the sliding direction to which the sample is pressed, and 4.5 mm in the radius at each end in the sliding direction.
  • Figure 6 is a schematic drawing of the draw-bead tester used in the examples.
  • the steel sheet was dipped into an acidic solution at 50°C and pH 2.0 to form a liquid film on the surface of the steel sheet using squeeze rolls 3.
  • the formed liquid film was washed in a washing tank 5 by spraying hot water at 50 °C against the steel sheet, and then the steel sheet was passed through a neutralization tank 6 without applying neutralization.
  • the steel sheet was washed by spraying water at 50°C thereto in a washing tank 7, followed by drying in a drier 8, thus forming the film on the surface of plating layer.
  • the quantity of liquid film was adjusted by varying the pressure of squeeze rolls 3.
  • the acidic solution in the acidic solution tank 2 was an acidic solution which contained a pH buffer prepared by mixing 30 g/liter of disodium hydrogenphosphate and 20 g/liter of citric acid, adding a specific amount of iron (II) sulfate to add Fe ion thereto, and further adding sulfuric acid to adjust pH.
  • a pH buffer prepared by mixing 30 g/liter of disodium hydrogenphosphate and 20 g/liter of citric acid, adding a specific amount of iron (II) sulfate to add Fe ion thereto, and further adding sulfuric acid to adjust pH.
  • an acidic solution containing only iron (II) sulfate, not containing pH buffer was used, (Sample Nos. 3 to 5).
  • an acidic solution containing Fe(III) sulfate was also applied to some of the samples, (sample Nos. 18 to 23).

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Coating With Molten Metal (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Chemical Treatment Of Metals (AREA)
EP04772660.9A 2003-08-29 2004-08-26 Hot dip zinc plated steel sheet and method for production thereof Active EP1666624B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2003307073 2003-08-29
JP2003307072 2003-08-29
JP2003324771 2003-09-17
JP2003324770 2003-09-17
JP2004008967 2004-01-16
PCT/JP2004/012704 WO2005021823A1 (ja) 2003-08-29 2004-08-26 溶融亜鉛めっき鋼板およびその製造方法

Publications (3)

Publication Number Publication Date
EP1666624A1 EP1666624A1 (en) 2006-06-07
EP1666624A4 EP1666624A4 (en) 2009-07-22
EP1666624B1 true EP1666624B1 (en) 2017-06-07

Family

ID=34280119

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04772660.9A Active EP1666624B1 (en) 2003-08-29 2004-08-26 Hot dip zinc plated steel sheet and method for production thereof

Country Status (6)

Country Link
EP (1) EP1666624B1 (ja)
KR (1) KR20060033811A (ja)
CN (1) CN1846011B (ja)
CA (1) CA2535894C (ja)
TW (1) TWI288188B (ja)
WO (1) WO2005021823A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2864552B1 (fr) * 2003-12-24 2006-07-21 Usinor Traitement de surface par hydroxysulfate
WO2010070942A1 (ja) * 2008-12-16 2010-06-24 Ｊｆｅスチール株式会社 亜鉛系めっき鋼板およびその製造方法
JP5648309B2 (ja) * 2010-03-31 2015-01-07 Ｊｆｅスチール株式会社 溶融亜鉛系めっき鋼板の製造方法
CN102888578B (zh) * 2011-07-19 2014-12-24 宝山钢铁股份有限公司 一种具有优良表面摩擦特性的热镀锌钢板的生产方法
CN110268083B (zh) * 2017-02-10 2021-05-28 杰富意钢铁株式会社 高强度镀锌钢板及其制造方法
CN113817973B (zh) * 2021-09-23 2022-12-27 马鞍山钢铁股份有限公司 改善合金化镀锌热成形钢表面氧化和涂装性能的表面处理液、热成形钢板及制备方法和应用
CN113832425B (zh) * 2021-09-23 2022-12-27 马鞍山钢铁股份有限公司 一种具有优良耐黑变性能和胶粘性能的锌镁铝镀层钢板及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000160358A (ja) * 1998-11-25 2000-06-13 Sumitomo Metal Ind Ltd 溶融亜鉛系めっき鋼板
JP2003306781A (ja) * 2002-04-18 2003-10-31 Jfe Steel Kk 合金化溶融亜鉛めっき鋼板の製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3318385B2 (ja) * 1993-03-04 2002-08-26 川崎製鉄株式会社 プレス加工性と耐めっき剥離性に優れた合金化溶融亜鉛めっき鋼板
US6129995A (en) * 1997-03-19 2000-10-10 Nkk Corporation Zinciferous coated steel sheet and method for producing the same
EP1288325B1 (en) * 2000-04-24 2014-10-15 JFE Steel Corporation Method for production of galvannealed sheet steel
JP3608519B2 (ja) * 2001-03-05 2005-01-12 Ｊｆｅスチール株式会社 合金化溶融亜鉛めっき鋼板の製造方法および合金化溶融亜鉛めっき鋼板
JP3570409B2 (ja) * 2001-11-01 2004-09-29 Ｊｆｅスチール株式会社 合金化溶融亜鉛めっき鋼板
JP3797478B2 (ja) * 2001-11-01 2006-07-19 Ｊｆｅスチール株式会社 合金化溶融亜鉛めっき鋼板
MX342803B (es) * 2003-04-18 2016-10-13 Jfe Steel Corp Placa de acero galvanizada revestida con zinc por baño caliente, excelente en formabilidad de prensado y metodo par su elaboracion.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000160358A (ja) * 1998-11-25 2000-06-13 Sumitomo Metal Ind Ltd 溶融亜鉛系めっき鋼板
JP2003306781A (ja) * 2002-04-18 2003-10-31 Jfe Steel Kk 合金化溶融亜鉛めっき鋼板の製造方法

Also Published As

Publication number Publication date
TW200516172A (en) 2005-05-16
CN1846011B (zh) 2011-06-08
WO2005021823A1 (ja) 2005-03-10
EP1666624A4 (en) 2009-07-22
CA2535894A1 (en) 2005-03-10
EP1666624A1 (en) 2006-06-07
TWI288188B (en) 2007-10-11
CN1846011A (zh) 2006-10-11
KR20060033811A (ko) 2006-04-19
CA2535894C (en) 2009-10-06

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