EP1603999B1 - Agent servant a traiter un textile - Google Patents

Agent servant a traiter un textile Download PDF

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Publication number
EP1603999B1
EP1603999B1 EP04717600.3A EP04717600A EP1603999B1 EP 1603999 B1 EP1603999 B1 EP 1603999B1 EP 04717600 A EP04717600 A EP 04717600A EP 1603999 B1 EP1603999 B1 EP 1603999B1
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EP
European Patent Office
Prior art keywords
skin
oil
acid
textile
agent according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP04717600.3A
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German (de)
English (en)
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EP1603999A1 (fr
EP1603999B2 (fr
Inventor
Wilfried Rähse
Ulrike Ruffer
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Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL04717600T priority Critical patent/PL1603999T5/pl
Publication of EP1603999A1 publication Critical patent/EP1603999A1/fr
Publication of EP1603999B1 publication Critical patent/EP1603999B1/fr
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

Definitions

  • the invention relates to a textile treatment agent, a laundry treatment or aftertreatment agent, a detergent and the use of the textile treatment or aftertreatment agent in the context of a washing or textile drying process or textile treatment process. Furthermore, the invention relates to a conditioning substrate containing a textile treatment agent, and a conditioning method using the Konditioniersubstrates in a textile drying process. Furthermore, the invention relates to a detergent.
  • the classic treatment of textile garments with textile treatment agents fulfills a variety of needs with regard to the textiles to be treated, eg. As the hygiene, the fragrance or the soft touch.
  • US 5,610,189 describes a composition for treating household laundry containing tea tree oil.
  • DE 197 37 072 A1 describes the use of a mixture containing a citrus oil concentrate and castor oil for laundry cleaning.
  • DE 198 21 106 A1 discloses a miticidal detergent with a high content of essential oils.
  • the essential oils may be tree oils such as tea tree oil or cedar oil, or vegetable oils such as cumin oil and dill oil.
  • US Pat. No. 6,494,920 B1 describes fabric softeners containing aloe vera and ester quats.
  • JP 06136386 discloses cleanser with skin protection agent based on Aspalathus Linearis.
  • WO 00/40687 A1 describes a fabric care composition comprising a plasticizer and a protein, wherein the protein can deposit on the fiber. It can later be released to the skin from the fiber.
  • US 3,640,883 discloses powdered mild detergents containing 1-5% by weight of a skin-protecting substance.
  • compositions for textile treatment and / or conditioning which enable textiles treated therewith to be less problematic for dermatological problems than textiles treated with conventional means so that z.
  • the risk of skin irritation due to the contact skin / treated textile is not additionally increased, but rather is reduced or so that already irritated or irritated or sensitized skin is not further damaged by the contact with the treated textile.
  • the subject invention offers numerous advantages. It is advantageous that laundry treatment within a holistic and multi-functional approach take on special functions by z. B. additionally directly or indirectly beneficial to the health of the skin. Such textile treatment agents are to be seen as supplements to the classic textile treatment agents such as detergents or softeners.
  • the Applicant assumes that upon contact of the skin with a textile treated according to the invention, one or more skin-supporting or even healing agents are at least partially delivered to the skin natural skin flora of humans is not impaired by the substances released, but is advantageously supported in their self-regulatory powers.
  • the term skin healing or the attribute skin-healing can be defined most simply by the state of the healthy human skin.
  • Healthy human skin is characterized by the fact that it provides sufficient protection against microorganisms, germs and pathogens by means of their intact acid mantle that their buffering capacity and alkali neutralizing capacity sufficient to ward off the harmful effects of surrounding fluids, that there is a high degree of freedom from redness and that freedom from skin damage such as cuts, abrasions and burns, Irritation, inflammation and allergies, and that it is neither cracked nor dried out.
  • healthy skin is characterized by the fact that it takes on a depot function for fat, water and blood and an important role in the metabolism.
  • Skin healing in the context of the present invention is now all that helps the skin to return to its original state. It is also all skin-healing, which stimulates, trains, supports and promotes the self-regulation of the skin, so that it is able to fulfill their functions, in that it returns to the natural state of equilibrium. Furthermore, the term skin healing in the context of this invention is understood to mean all the influences which lead to at least alleviate, if not heal, obvious skin diseases such as eczema, rashes, redness, itching, swelling, blistering, oozing, crusting in various forms ,
  • the term skin protection means everything that is necessary to maintain the normal performance of the skin in terms of its functions under specific stress situations and goes beyond its own protective mechanisms. This concept also differs significantly from the skin care, because the skin care achieved only a cosmetic benefit in terms of sensory needs z. Softness or gloss under normal conditions.
  • the skin protection supports the skin with additional agents that help the skin, for example, even in adverse conditions, to fulfill their multifaceted functions. Such adverse conditions can z. As friction, cold, heat, UV radiation, aggressive ambient fluids, contact with skin-irritating materials.
  • textile, textile fiber or linen all conceivable textile fibers and textile fabrics produced from it but also unformed structures are understood, for example, natural fibers of plant and animal and mineral origin, as well as man-made fibers Also referred to as synthetic fibers or as synthetic fibers, of natural and synthetic polymers and inorganic substances.
  • textile in the context of this invention, paper, cardboard, cardboard to understand, especially when the paper, cardboard, cardboard clothing purposes.
  • such substances or active substances are particularly advantageous if they are antiseptic active.
  • the attribute of anti-spasmodic efficacy means an effect that is beneficial to the self-regulating forces of human skin. This effectiveness is not in their expression with that of classical germicidal or germicidal agents such. As phenols, halogens, alcohols with which z. B. skin u. mucous Treat wounds or even medical instruments to achieve asepsis (germ-free).
  • the classical antiseptic includes antimicrobial measures at the point of origin or at the portal of entry of a possible infection or at the site of infection on the body surface.
  • the particular advantage of the antiseptic active substances which can be used according to the invention results from a synergistic interaction of these substances with the general functional mechanisms of human skin, since these substances have a mildly antiseptic action, eg. B. germs, including harmful germs reduce, but not perfect, so to sterility, destroy. So there are enough germs on the skin that are sufficient to train and strengthen the self-regulating powers of human skin.
  • the interaction of the self-regulating forces of the skin with the antiseptic capacity of the active ingredients in the middle of the skin supports the general functioning of the skin. This is of great advantage, especially with regard to already irritated and / or otherwise damaged skin.
  • the textile treatment agent or the laundry treated with it supports the natural skin flora of humans.
  • compositions of such an embodiment are particularly useful for their purpose when the antiseptic agent is an oil, preferably an essential oil.
  • This antiseptic oil is preferably an essential oil selected from the group consisting of Angelica fine - Angelica archangelica, Anis - Pimpinella anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus, Cajeput - Melaleuca leucadendron, Cistrose - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltann needle - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce Spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle (Strawflower) Helichrysum ang., Ginger extra - Zingiber off., St.
  • an essential oil selected from the group consisting of Angelica fine - Angelica
  • Another advantage of the aforementioned essential oils lies in their particular multifunctionality, which, in addition to the described mild antiseptic activity, results from a multitude of other desirable organoleptic properties attributable to these oils.
  • These oils are in most cases given an expectorant effect because they exert on the mucous membranes of the respiratory organs a mild, positive stimulus. Furthermore, a desirable feeling of warmth can be established. Deodorizing, analgesic, circulation-promoting, calming effects could be observed in connection with the use according to the invention of these designated oils by the applicant and be recognized as particularly advantageous.
  • the organoleptic Properties of these oils are usually not influenced by the main components, but by the Mau- od. Trace components, which often go into the hundreds and sometimes synergistically work together.
  • Another advantage associated with the oils mentioned is their harmonious fragrance and scent, which in many cases leads to positive feelings in humans.
  • the textile treatment agent or the laundry treated with it not only supports the natural skin flora of humans, but also helps the human organism to obtain additional advantages of the type just described.
  • tea tree oil is of great advantage for the subject invention.
  • tea tree oil In addition to its considerable germicidal, antiseptic, fungicidal, antiviral, wound-healing, anti-inflammatory, scarring-promoting effect, it has excellent skin tolerance and offers a wide range of other applications, for example with regard to the supportive treatment of colds or diseases of the rheumatic type, gout, muscle pain.
  • oils are natural emollients, d. H. Means that soften and soften body tissues and reduce the roughness of the skin. So these oils have a skin conditioning effect. On the other hand, it is precisely these oils which have further specific effects which result in a synergistic interaction with the skin and its self-regulating forces and also enable protection under adverse conditions.
  • a particularly preferred oil in the context of this invention is z. B. the hemp oil.
  • Hemp oil which contains a high proportion of essential fatty acids and also contains up to 6% by weight of valuable ⁇ -linolenic acid (GLA), also has an anti-inflammatory, slightly analgesic, healing, nourishing, skin structure improving, preventing the appearance of old age. It improves tissue regeneration processes and has a high regenerative effect on injured tissue. In addition, it may increase the care properties or other properties of other oils in particular of all oils explicitly mentioned here.
  • hemp oil Since essential fatty acids are significantly involved in maintaining the barrier function of the skin, because they help to regulate and normalize the transepidermal water loss through the skin, the hemp oil for the purposes of this invention, as a result of its high GLA content, a special role, since In case of disturbed transepidermal water loss, topical treatment with GLA leads to the greatest reduction in transepidermal water loss. Furthermore, hemp oil has further positive effects on the human organism in terms of arteriosclerosis, rheumatoid arthritis, diabetic neuropathy to heart problems.
  • Another preferred oil for the purposes of this invention is the borage oil.
  • the textile treatment agents according to the invention comprise skin-healing active substances which have a minimum content of 0.1% by weight of GLA, preferably of 0.3% by weight, particularly preferably of 0.5% by weight.
  • GLA skin-healing active substances
  • these include, for example, black cumin oil, evening primrose oil, Echiumöl, Trichodesmaöl and the blackcurrant seed oil.
  • almond oil is characterized by the fact that it can enhance the effect of other oils, which is why it is advantageously used in combination with other oils.
  • the textile treatment agents contain at least 1 wt .-%, preferably at least 5 wt .-%, particularly preferably at least 10 wt .-%, most preferably at least 15 wt .-% of one or more skin-protecting and / or skin-healing Active substances or oils or essential oils, wherein it is even more advantageous if even at least 20% by weight, in particular even more than 25% by weight, more preferably even more than 30% by weight, of one or more skin-protecting and / or or skin-healing active substances or oils or essential oils are contained in the textile treatment agent.
  • the textile treatment agent is dye-free.
  • Dye-free is particularly advantageous because dyes generally have a significant potential for allergization.
  • dyes are desired, for example, for optical reasons, the usual colorants such.
  • pigments but preferably organic dyes used.
  • Organic dyes are more skin-friendly in the context of the invention.
  • the colorant content is preferably below 0.002% by weight of the composition, in particular it is 0% by weight.
  • the textile treatment agent is in solid, dispersed, powdered, compressed or granular form, but preferably in liquid form, in particular emulsified.
  • the textile treatment agent is present in non-aqueous form.
  • non-aqueous form in the context of this invention are water contents below 15 % By weight, based on the agent, preferably water contents of less than 10% by weight, more preferably less than 8% by weight, water contents of less than 6% by weight being preferred, but in particular water contents of between 2 and 0.001 Wt .-% based on the agent preferred.
  • the advantage of a reduction of the proportion of water on average is that the ingredients of the textile treatment agent can be used in concentrated and therefore more effective form in the application, as well as that the agents are better processable, for example emulsifiable.
  • the textile treatment agents contain no additional perfumes or perfume oils. This is particularly advantageous, since most of these fragrances or perfume oils, which are not skin-healing and / or skin-protecting active substances in the context of the invention, have an allergy potential which counteracts the present invention. In addition, there are large groups of people who show safe proven allergic reactions to a variety of such fragrances and / or perfume oils.
  • compositions according to the invention are preferably free of the aforementioned fragrances, it may be desirable to produce a particularly attractive fragrance which can not be generated solely from the skin-healing active ingredients according to the invention and their inherent odor effects. Therefore, in a preferred embodiment it is possible to add a small amount of such fragrances, which are not skin-healing and / or skin-protecting active substances according to the invention, to the respective agents. It must be ensured that no allergic reactions are caused by these additional fragrances.
  • the usual perfumes or fragrances or perfume oils include, for example, the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, allylcyclohexyl propionate, styrallyl propionate and benzyl salicylate.
  • the ethers include, for example, benzyl ethyl ether to the aldehydes z.
  • the hydrocarbons mainly include the terpenes such as limonene and pinene.
  • Perfume oils may also contain natural fragrance mixtures obtainable from vegetable sources, for example pine oil, muscatel, clove oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, galbanum oil and labdanum oil and orange blossom oil, orange peel oil. However, these latter oils are not skin-healing and / or skin-protecting oils in the context of the invention.
  • the textile treatment agent is an aftertreatment agent, preferably a rinse aid.
  • Aftertreatment agents are understood to mean agents which are used only after the actual textile cleaning for a subsequent textile treatment.
  • Under rinsing agents are generally understood to mean those agents which are added to the liquor only after the actual textile cleaning and are preferably applied in an acidic medium. Such rinsing agents thus usually enter the liquor only after the last rinse, so as not to be removed during rinsing with the actual wash liquor without leaving or unfolding an effect.
  • a proper application of a rinse aid can be done manually, ie by a subsequent manual addition of the rinse aid as a separate means.
  • a proper application can also be accomplished via a controlled-release mechanism.
  • a controlled-release mechanism means the time-controlled release of active substances. Such control of the release of the active ingredient can be controlled via various actuators.
  • a sensitive material preferably with mixtures of polyvinyl alcohol and cellulose ethers (methylhydroxycellulose, methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, hydroxyethycellulose).
  • the characteristic dissolution behavior of the cladding material as a function of specific parameters is utilized.
  • the dissolution behavior may be a function of time, temperature, pH, ionic strength, mechanical stress or corresponding parameters.
  • it is z. B. expedient to choose a pH-sensitive, but temperaturbestustes wrapping material. In this way, the rinse aid after a completed wash cycle be released by the fact that the pH is shifted from alkaline to acidic environment, so that the coating material dissolves.
  • laundry or textiles of any kind are treated with a corresponding textile treatment agent such that the respective textile at least briefly or partially comes into contact with the textile treatment agent.
  • Such contact may be in the ordinary laundry treatment, for. B. in the course of machine washing, fabric softening, hand washing, machine drying.
  • the textile treatment agent is used as a post-treatment agent, d. H. You can give it as a rinse after washing in the washing machine, you can give it in the form of a conditioning substrate in the dryer, you can also treat the already completely washed and dried textiles individually.
  • various methods are applicable, for.
  • compositions according to the invention are particularly useful for their purpose if the substances mentioned in the embodiments at least partially remain on the textile after the textile treatment and are partially released to the skin on contact of the skin with the textile.
  • the only factor is that the substances mentioned in contact textile / skin at least in traces on the skin.
  • a further preferred embodiment of this invention are thus textile treatment agents, which are characterized in that the skin-healing and / or skin-protecting active in the course of textile treatment with such an agent on the textile passes, at least partially remains on the textile and at least partially from the textile back to the Skin is released when the textile comes into contact with the skin.
  • the agents according to the invention additionally contain urea and / or its derivatives.
  • Urea and / or its derivatives promote the health of the skin, as they can be antimicrobial, water-binding, quenching itching, dandruff, skin-smoothing and can inhibit excessive cell growth.
  • they can serve the skin as a moisturizing factor, i. H. they can help the skin to retain moisture.
  • the agents according to the invention additionally contain lactic acid and / or citric acid and / or salts thereof.
  • These two skin-friendly acids and / or their salts are used, inter alia, to support or renew the natural acid mantle or hydrolipid film of the skin.
  • the hydrolipidic film of the skin is attacked or destroyed by alkaline influences, resulting in a loss of the barrier function of the skin, so that microorganisms or pollutants can more easily penetrate into the skin.
  • the lactic and / or citric acid in the compositions according to the invention can be z.
  • B. Remove residual alkali from clothing and adjust the pH of the textiles to a pH range around 5.
  • the additional lactic acid which is already part of the epidermis, has an additional stabilizing effect on the acidic pH of the skin (pH approx. 5.2) and serves as a moisturizing factor, since it can improve the water binding ability of the skin. Furthermore, the lactic acid smoothes the skin and supports the detachment of dander.
  • the pH of the textile treatment agent is between 4 and 6.5, measured at a temperature of 20 ° C., in particular on a 1% strength aqueous solution of the textile treatment agent. This corresponds to the pH of the skin of a healthy person.
  • the skin surface is only weakly acidic (pH 5.5 - 6.5), just there is a reduced defenses against germs or bacteria, so that it is particularly advantageous in the context of the invention, if the pH of the fabric treatment agent is not greater than pH 5.5 measured at a temperature of 20 ° C.
  • Such a pH range is particularly advantageous in terms of a group of people with particularly sensitive skin, such as babies or toddlers, or a group of people with already existing skin problems, eg. B. Allergy sufferers.
  • baby skin is significantly thinner than the skin of an adult human. Since the sebum production of the baby skin is significantly reduced, it has only an incomplete barrier function and a very thin hydrolipid film.
  • textile treatment agents according to the invention There is a particular need here for the textile treatment agents according to the invention.
  • the advantage of the textile treatment agent having a pH as described above is that textiles treated therewith are able to assist the skin's self-regulating powers in terms of its alkali neutralizing ability, by virtue of the fact that the textile contacting the skin, e.g. As a Abtrockentuch or underwear, has a skin-optimal pH.
  • the textile treatment agent or the laundry treated with it supports the natural skin flora of humans.
  • compositions according to the invention may contain further moisturizing factors, for example those selected from the following group: amino acids, chitosan or chitosan salts / derivatives, ethylene glycol, glucosamine, glycerol, diglycerol, triglycerol, uric acid, honey and hardened Honey, creatinine, cleavage products of collagen, lactitol, polyols and polyol derivatives (for example, butylene glycol, erythritol, propylene glycol, 1,2,6-hexane triol, polyethylene glycols such as PEG-4, PEG-6, PEG-7, PEG-8, PEG-9 , PEG-10, PEG-12, PEG-14, PEG-16, PEG-18, PEG-20), pyrrolidonecarboxylic acid, sugar and sugar derivatives (for example, fructose, glucose, maltose, maltitol,
  • the textile treatment agent according to the invention serves as a fabric softener.
  • the compositions preferably contain small amounts of quaternary ammonium compounds such. As esterquats, but preferably the agents contain no quaternary ammonium compounds such.
  • the fabric treatment agent may contain nonionic fabric softening agents, such as silicone oils.
  • a particular advantage of the textile treatment agents according to the invention is that, in a preferred embodiment, they function as fabric softeners, despite extensive or absolute freedom from quaternary ammonium compounds or esterquats.
  • ingredients of the invention of the textile treatment agent which have already been listed or are still listed, such.
  • B. various oils such as. B. almond oil, such as. B. hemp oil, such as.
  • citric acid and / or lactic acid have partially fiber softening properties or are effective in a meadow that sets a softer feel of textiles.
  • the textile treatment agent according to the invention contains an ironing relief agent and / or crease-reducing agent, for example those which will be mentioned elsewhere in the course of the description.
  • the advantage of this embodiment is that can be reduced by the Bügelerfug ceremoniess- and crease reduction effect, the ironing time, so that the valuable ingredients of the textile treatment agent according to the invention are not exposed to excessive thermal stress by ironing, and thus retain their full effectiveness.
  • the textile treatment agent is reversibly fixed to a polymeric carrier, for. B. on adsorption, optionally with the participation of surfactants, so that a delayed release of the healing active ingredients is possible.
  • a polymeric carrier for. B. on adsorption, optionally with the participation of surfactants, so that a delayed release of the healing active ingredients is possible.
  • Particularly preferred polymeric carriers belong to the class of silicic acid esters. But it can also be any other carrier, with the only provisos that it delayed Allow drug release and as such have no negative or irritating effect on the skin, if used in the context of this invention.
  • the textile treatment agent receives in addition to the curative active ingredients one or more deodorizing agents.
  • oils as such also have a deodorizing effect.
  • the particular advantage of adding one or more deodorizing agents to the fabric treatment composition of the present invention is that these ingredients, together with the said oils, provide a particularly enhanced, because of synergistic, effect on deodorizing activity. The effect is only in one facet of the covering of evil-smelling or unpleasant odors.
  • an additional effect which is based on the synergistic interaction of the healing active ingredients according to the invention with the added deodorizing agent and the self-regulatory forces, so that not alone the symptom, the bad smell, but the smell triggering this moment is eliminated.
  • bacteria that are located on the skin or in hair or pubic hair in varying numbers. These bacteria can proteins and fats, z. B. from body sweat, decompose into malodorous sulfur compounds. These bacteria are effectively counteracted by the synergistic interaction of these factors.
  • the self-regulating powers of the skin are stimulated and trained.
  • the textile treatment agent is in the form of a microemulsion.
  • Emulsions are disperse systems of at least two immiscible liquids, one phase being dispersed in the form of fine droplets in the other continuous phase.
  • macroemulsions and microemulsions this invention encompassing both emulsion types.
  • microemulsions are particularly advantageous.
  • microemulsions in the disperse phase active ingredients can be much finer dispersed than in the disperse phase of macroemulsions. Another advantage is that they are well sprinkled due to their usually low viscosity.
  • the preparation of the emulsions according to the invention is carried out according to the classical procedures, for. By shaking, beating, stirring, turbulent mixing, injecting one liquid into another, by emulsifying centrifuges, colloid mills, homogenizers, by vibration and cavitation in the mixture and many others.
  • the emulsions can also spontaneously form from the components.
  • the emulsions can be stabilized with so-called emulsifiers or stabilizers, so that a possible creaming or sedimentation or the tendency of the dispersed particles to agglomerate is difficult.
  • emulsifiers or stabilizers usually have an amphiphilic character, ie they have at least one polar and one nonpolar group, and there may also be a preponderance of the apolar group, which is referred to as co-emulsifiers.
  • Saturated or unsaturated, branched or unbranched alkyl radicals and aryl or alkylaryl radicals are generally used as nonpolar groups.
  • polar engroups occur carboxylate, sulfonate, sulfate, phosphate, polyphosphate, lactate, citrate, tartrate, amine salts, quaternary ammonium compounds, betaines, alcohol, polyethers, - glycerol, sorbitol, pentaerythritol, sucrose, acetic acid, Lactic acid residues, as polar intermediates function hydroxy, ester, sulfamide, amide, polyamide, polyamine, amine, ether, polyether, glycerol, sorbitol, pentaerythritol and sucrose groups, to only to name a few.
  • anionic, cationic, amphoteric and zwitterionic and nonionic emulsifiers which in principle can be used in the context of this invention, all of these emulsifiers and those that do not fit into the above categories.
  • a physiological and toxicological safety of the emulsifier when used according to the invention which is in accordance with the spirit of the invention, namely to give the skin an advantage.
  • Nonionic emulsifiers are preferably used. All conceivable and customary emulsifying auxiliaries can advantageously be used according to the invention.
  • compositions of the invention may include, optionally, penetration enhancers, especially when emulsified, especially when sprayed.
  • penetration enhancers especially when emulsified, especially when sprayed.
  • substances that inhibit the penetration of Accelerate active substances from the textile into the skin are, for example, phenoxyethanol or phenylethanol.
  • the textile treatment agents according to the invention in the form of such emulsions can be applied to the textile in various ways.
  • the textile treatment agent is applied directly and directly to the textile. This can be z. B. by spraying using a spray applicator o. ⁇ .
  • the textile treatment agent according to the invention is incorporated in a water-soluble packaging, preferably portioned in a disposable portion.
  • a water-soluble packaging preferably portioned in a disposable portion.
  • one-time serving means that amount of textile treatment agent which is required for a treatment process, in particular for a rinsing process, in particular in the machine.
  • disposable portions are each preferably incorporated in water-soluble packages. This has the advantage that the valuable ingredients of the agent are better protected from external influences.
  • the textile treatment agent is in tablet form, which preferably consists of several separate phases.
  • This has the advantage of easy dosing. By separating the tablet into different phases or regions, it is possible to incorporate the valuable healing ingredients spatially separate from other active ingredients in a dosing unit, so that no negative interaction between individual ingredients can occur.
  • the aforementioned moldings contain blasting systems which allow easy release of the active substances. Suitable blasting systems in addition to the classic effervescent systems, such as acid / carbonate, for example, citric acid or citrate with sodium carbonate, and swelling polymers, such as finely divided cellulose and the like.
  • compositions according to the invention contain, in addition to the skin-protecting and / or skin-healing substances according to the invention, one or more additional substances which have an effect on the human organism, eg. B. have the respiratory organs and / or the human psyche.
  • additional substances may also be skin-functional in terms of the attributes according to the invention, but they do not need skin-healing and / or skin-protecting properties.
  • Part of the substances already listed eg. As St. John's wort, lavandin, lemon balm, frankincense, for example, not only has a skin-functional effect, but also has a calming or mood-enhancing on the human psyche.
  • the olfactory bulb in the nose enter the essential oils of such substances into the limbic system of the brain.
  • the essential oils z. T. without the essential oils have previously been detected by the sense of smell, since the effective concentrations are often below the consciously noticeable concentration.
  • the classic fragrances listed above for the purposes of which it is essential that they are covered by the sense of smell. In this context according to the invention, however, it is not about the generation of a fragrance, but about the production of certain effects on the human organism.
  • vanilla, ylang-ylang, jasmine, musk, sandalwood, Tonka bean, cinnamon bark to apply accordingly.
  • absorption takes place via the respiratory tract and / or the nerve pathways.
  • textiles can be provided which facilitate adjuvant treatment of skin diseases, e.g. B. skin fungus (use of tea tree oil) or the physical dysfunctions such. B. Hyperhidrosis (use of sage), counteract.
  • Another object of the invention is accordingly a product comprising a textile treatment agent according to the invention in liquid form, in particular emulsified, and a spray dispenser.
  • the spray dispenser is preferably a manually activatable spray dispenser, in particular selected from the group comprising aerosol spray dispensers, pressure-building spray dispensers, pump spray dispensers and trigger spray dispensers, in particular pump spray dispensers and trigger spray dispensers with a transparent polyethylene or polyethylene terephthalate container.
  • Such and similar spray dispensers or related application devices are commercially available and all commercially available spray dispensers or related application devices come into consideration for the application according to the invention.
  • another object of the invention is a process for textile treatment in which an effective amount of an agent according to the invention, preferably using a product just described, is preferably applied to the textile to be treated by spraying.
  • An effective amount is understood to mean an amount which makes it possible to support and promote the self-regulating forces of human skin in the above-described inventive sense. This amount is an individual, which depends on many factors such. As skin type, skin damage, desired or to be achieved result depends. All that is decisive is that the treated textile, upon contact with the skin, can deliver to it curative active ingredients according to the invention, at least in the trace range.
  • the agent according to the invention in particular using a product according to the invention, is applied to and / or into the textile article or onto the textile surface, in particular from a distance of 10 to 100 cm, preferably 20 to 50 cm, more preferably 25 to 40 cm, most preferably about 30 cm, sprayed.
  • the textile treatment agents according to the invention contain one or more of all those active ingredients which are described in US Pat EP 0 789 070 A1 are disclosed active ingredients from the groups of waxes, the hydrophobic plant extracts, certain hydrocarbons, higher fatty acids and esters, essential oils, lipids, vitamins, sunscreens, phospholipids derivatives of alpha-hydroxy acids and / or mixtures of the aforementioned components in each case to the extent mentioned and even beyond this, at the same time no quaternary ammonium compounds or other relevant fabric softening compounds are included.
  • the textile treatment agents are surfactant-free.
  • the invention further relates to a detergent, in particular a liquid detergent consisting of at least two components.
  • these components are at least one washing or cleaning agent component and at least one textile treatment component in the above sense, which thus contains one or more skin-protecting and / or skin-healing active ingredients, these two components preferably released at different times of a washing or textile treatment process become.
  • the detergent or cleaning agent component is preferably released first, the textile treatment component preferably at a later time.
  • the two components of the detergent can be strictly separated spatially, z. B. in the form of two separate chambers or two bags. But they can also be incorporated into each other, for. B. in the form of capsules, which are in a gel, a Liquid, a powder or the like, or they are mixed or mixed together.
  • washing or cleaning agent component is understood to mean formulations or components of all conceivable substances which are relevant in connection with a washing or cleaning process. These are primarily the actual detergents or cleaners with their individual components further explained in the further course of the description. These include active ingredients such as surfactants (anionic, nonionic, cationic and amphoteric surfactants), builders (inorganic and organic builders), bleaches (such as peroxy bleach and chlorine bleach), bleach activators, bleach stabilizers, bleach catalysts, enzymes, special polymers (e.g. with cobuilder properties), graying inhibitors, without the term being restricted to these substance groups.
  • active ingredients such as surfactants (anionic, nonionic, cationic and amphoteric surfactants), builders (inorganic and organic builders), bleaches (such as peroxy bleach and chlorine bleach), bleach activators, bleach stabilizers, bleach catalysts, enzymes, special polymers (e.g. with cobuilder properties), graying inhibitors, without the term being restricted to these substance groups.
  • washing or cleaning agent component is also understood to mean washing auxiliaries and cleaning auxiliaries.
  • these are optical brighteners, UV protective substances and so-called soil repellents, ie polymers which counteract re-soiling of fibers or hard surfaces.
  • the detergent according to the invention is a liquid detergent, this too consists of at least two components, namely at least one washing or cleaning agent component and at least one textile treatment component.
  • the liquid detergent is preferably present as an emulsion, in particular as a microemulsion, which corresponds to a preferred embodiment.
  • liquid detergents are understood to be liquid to gel-like textile cleaners at 20 ° C., which can be used universally. These may be aqueous or non-aqueous.
  • Non-aqueous liquid detergents in the context of this invention are liquid to gel-type textile cleaners which preferably have a low water content and are preferably packaged in portions in water-soluble coatings.
  • the detergents according to the invention may therefore optionally contain one or more anionic surfactants in their detergent or cleaner component.
  • anionic surfactants for example, those of the sulfonate type and sulfates are used.
  • the surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C 12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration.
  • alkanesulfonates which are obtained from C 12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
  • esters of sulfo fatty acids for example the sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • sulfated fatty acid glycerol esters are to be understood as meaning the mono-, di- and triesters and mixtures thereof, as obtained in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol.
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
  • Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 18 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
  • C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred.
  • 2,3-alkyl sulfates which, for example, according to the U.S. Patents 3,234,258 or 5,075,041 are manufactured and can be obtained as commercial products from Shell Oil Company under the name DAN ®, are suitable anionic surfactants.
  • EO ethylene oxide
  • Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
  • Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C 8-18 fatty alcohol residues or mixtures of these.
  • Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic surfactants.
  • alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
  • anionic surfactants are particularly soaps into consideration.
  • Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
  • the anionic surfactants including the soaps may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases such as mono-, di- or tri-ethanolamine.
  • the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • Ethercarboxylic acids are water hardness insensitive and have excellent surfactant properties on. Production and use are for example in soaps, Oils, fats, waxes 101, 37 (1975 ); 115, 235 (1989 ) and Surfactants Deterg. 25, 308 (1988 ).
  • Suitable anionic surfactants are, for example, the partial esters of di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the ene-adducts of maleic anhydride to at least monounsaturated carboxylic acids having a chain length of 10 to 25 carbon atoms with an acid number of 10 to 140, in of the DE 38 08 114 A1 (Grillo works ) and the EP 0 046 070 A (Grillo Works ), Referred to in this regard and both of whose contents are hereby incorporated in this application are described.
  • preferred anionic surfactants have 4 to 28, preferably 6 to 20, in particular 8 to 18, particularly preferably 10 to 16, most preferably 12 to 14 carbon atoms, two or more anionic, especially two, acid groups, preferably carboxylate, sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group on.
  • Examples of these compounds are the sulfo fatty acid salts, the acyl glutamates, the monoglyceride disulfates and the alkyl ethers of glyceryl disulfate, and in particular the monoester sulfosuccinates described below.
  • Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates.
  • the sulfosuccinates are the salts of the monoesters and diesters of sulfosuccinic acid HOOCCH (SO 3 H) CH 2 COOH
  • the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid
  • the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid.
  • the salts are preferably alkali metal salts, ammonium salts and mono-, di- or trialkanolammonium salts, for example mono-, di- or triethanolammonium salts, in particular lithium, sodium, potassium or ammonium salts, particularly preferably sodium or ammonium salts , most preferably sodium salts.
  • one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acylclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, especially 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified.
  • esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4.
  • the monoesters are preferred in the context of the present invention over the diesters.
  • a particularly preferred sulfosuccinate is Sulfobernsteinklarylpolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.
  • one or both form carboxyl groups of the sulfosuccinic acid preferably with a primary or secondary amine having one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22 , preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms carries, a carboxylic acid amide.
  • Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.
  • sulfosuccinates designated under INCI and sulfosuccinamates, which are described in the International Cosmetic Ingredient Dictionary and Handbook detail are: ammonium dinonyl sulfosuccinates, Ammonium Lauryl Sulfosuccinate, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl sulfosuccinate
  • the detergent according to the invention contains in its washing or cleaning agent component one or more sulfosuccinates, sulfosuccinamates and / or sulfosuccinamides, preferably sulfosuccinates and / or sulfosuccinamates, in particular sulfosuccinates, in an amount of usually 0.05 to 15% by weight, preferably 0.1 to 10 wt .-%, in particular 0.3 to 6 wt .-%, particularly preferably 0.5 to 3 wt .-%, most preferably 0.7 to 2 wt .-%, for example 0.75 or 1.5% by weight.
  • the detergents according to the invention may optionally contain one or more nonionic surfactants in their detergent or cleaner component.
  • nonionic surfactants are preferably alkoxylated, advantageously ethoxylated and / or propoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of alcohol, used.
  • EO ethylene oxide
  • PO propylene oxide
  • C 8 -C 16 -alcohol alkoxylates advantageously ethoxylated and / or propoxylated C 10 -C 15 -alcohol alkoxylates, in particular C 12 -C 14 -alcohol alkoxylates, having a degree of ethoxylation of between 2 and 10, preferably between 3 and 8, and / or a degree of propoxylation between 1 and 6, preferably between 1.5 and 5.
  • the alcohol radical may preferably be linear or more preferably methyl-branched in the 2-position or contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten.
  • alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO or 4 EO, C 9-11 alcohols with 7 EO, C 13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-18 -alcohol with 5 EO.
  • the indicated degrees of ethoxylation and propoxylation represent statistical averages which may be an integer or a fractional number for a particular product.
  • Preferred alcohol ethoxylates and propoxylates have a narrow homolog distribution (narrow range ethoxylates / propoxylates, NRE / NRP).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • alkoxylated amines advantageously ethoxylated and / or propoxylated, in particular primary and secondary amines having preferably 1 to 18 carbon atoms per alkyl chain and an average of 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per Mole of amine.
  • EO ethylene oxide
  • PO propylene oxide
  • nonionic surfactants and alkyl glycosides of the general formula RO (G) x , z. B. be used as compounds, especially with anionic surfactants, in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 carbon atoms, preferably for Glucose, stands.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
  • nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters as they are
  • alkoxylated preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters as they are
  • JP 58/217598 are described or preferably according to the in the international patent application WO 90/13533 be prepared described methods.
  • Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
  • gemini surfactants are so-called gemini surfactants. These are generally understood as meaning those compounds which have two hydrophilic groups and two hydrophobic groups per molecule. These groups are usually separated by a so-called “spacer”. This spacer is usually a carbon chain that should be long enough for the hydrophilic groups to be spaced sufficiently apart for them to act independently of each other. Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to greatly reduce the surface tension of the water. In exceptional cases, however, the term gemini surfactants is understood to mean not only dimeric but also trimeric surfactants.
  • Suitable gemini surfactants are, for example, sulfated hydroxy mixed ethers according to the German patent application DE-A-43 21 022 or dimer alcohol bis- and trimer alcohol trissulfates and ether sulfates according to the international patent application WO-A-96/23768 , End-capped dimeric and trimeric mixed ethers according to the German patent application DE-A-195 13 391 They are characterized by their bi- and multi-functionality.
  • the end-capped surfactants mentioned have good wetting properties and are low foaming, so that they are particularly suitable for use in machine washing or cleaning processes.
  • polyhydroxy fatty acid amides of the following formula in which RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 2 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the following formula R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R 3 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R 4 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C 1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.
  • [Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a reduced sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then be used, for example, according to the teaching of the international application WO-A-95/07331 be converted by conversion with fatty acid methyl esters in the presence of an alkoxide as catalyst into the desired Polyhydroxyfettklaamide.
  • Preferred nonionic surfactants are one or more ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C 10-22 alcohols having a degree of alkoxylation of up to 30, preferably ethoxylated C 10-18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C 12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C 12-14 fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or Isotridecylalkoholethoxylat with 5, 8 or 12 EO, as described for example in the DE 40 14 055 C2 (Grillo works ) to which reference is made in this regard and the contents of which are hereby incorporated by reference.
  • EO ethylene oxide
  • PO propylene oxide
  • the nonionic surfactants can usually be used in amounts of up to 50 wt .-%, preferably from 0.1 to 40 wt .-%, particularly preferably from 0.5 to 30 and in particular from 2 to 25 wt .-%, each based on the entire means available.
  • the detergents according to the invention may optionally contain amphoteric surfactants.
  • the betaines represent an important class.
  • Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds.
  • the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein one mole of salt is formed per mole of betaine.
  • unsaturated carboxylic acids such as acrylic acid is possible.
  • betaines are the carboxyalkylation products of secondary and especially tertiary amines, which follow the formula: in the R 5 for alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R 6 is hydrogen or alkyl radicals having 1 to 4 carbon atoms, R 7 is alkyl radicals having 1 to 4 carbon atoms, n is from 1 to 6 and X 1 is from an alkali and / or alkaline earth metal or ammonium.
  • Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C 12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C 16/18 tallowalkyldimethylamine, and technical mixtures thereof.
  • R 8 CO is an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds
  • m is a number from 1 to 3 and R 6 , R 7 , n and X 1 are as defined above.
  • Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate.
  • Preference is given to the use of a condensation product of C 8/18 coconut fatty acid N, N-dimethylamino-propylamide
  • R 9 is an alkyl radical having 5 to 21 carbon atoms
  • R 10 is a hydroxyl group
  • an OCOR 9 or NHCOR 9 radical and m is 2 or 3.
  • These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethylethanolamine (AEEA) or diethylenetriamine.
  • AEEA aminoethylethanolamine
  • the corresponding carboxyalkylation products are mixtures of different open-chain betaines.
  • Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably Imidazolines based on lauric acid or again C 12/14 coconut fatty acid, which are then betainized with sodium chloroacetate.
  • the detergents according to the invention are in liquid form.
  • the use of both liquid organic solvents and water may be indicated.
  • the agents according to the invention therefore optionally contain solvents.
  • the detergents according to the invention may advantageously also contain cationic surfactants, preferably quaternary ammonium compounds, in particular those which are biodegradable.
  • cationic polymers may also be included.
  • Solvents that can be used in the compositions according to the invention originate, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers, provided they are miscible with water in the concentration range indicated.
  • the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, diglycol, propyl or butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether , Diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylene glycol monomethyl, or ethyl ether, di-
  • glycol ethers are available under the trade name Arcosolv ® (Arco Chemical Co.) or Cellosolve ®, carbitol ® or Propasol ® (Union Carbide Corp.); this includes for example ButylCarbitol® ®, ® hexyl carbitol, methyl ®, and Carbitol ® itself, (2- (2-ethoxy) ethoxy) ethanol.
  • Arcosolv ® Arco Chemical Co.
  • Cellosolve ® Carbitol ® or Propasol ® (Union Carbide Corp.)
  • the choice of glycol ether can be readily made by one skilled in the art on the basis of its volatility, water solubility, weight percent of total dispersion, and the like.
  • Pyrrolidone solvents such as N-alkylpyrrolidones, for example N-methyl-2-pyrrolidone or NC 8 -C 12 -alkylpyrrolidone, or 2-pyrrolidone, may also be used.
  • N-alkylpyrrolidones for example N-methyl-2-pyrrolidone or NC 8 -C 12 -alkylpyrrolidone, or 2-pyrrolidone
  • glycerol derivatives in particular glycerol carbonate.
  • alcohols which can be used as cosolvents in the present invention are low molecular weight liquid polyethylene glycols, for example, polyethylene glycols having a molecular weight of 200, 300, 400 or 600.
  • suitable cosolvents are other alcohols, for example (a) lower Alcohols such as ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and methyl ethyl ketone, (c) C 2 -C 4 polyols such as a diol or a triol, for example ethylene glycol, propylene glycol, glycerol or mixtures thereof.
  • 1,2-octanediol from the class of diols.
  • the detergent contains one or more solvents from the group comprising C 1 to C 4 monoalcohols, C 2 to C 6 glycols, C 3 to C 12 glycol ethers and glycerol, in particular ethanol.
  • the C 3 - to C 12 glycol ethers according to the invention contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms.
  • Preferred C 1 to C 4 monohydric alcohols are ethanol, n -propanol, isopropanol and tert- butanol.
  • Preferred C 2 to C 6 glycols are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,5-pentanediol, neopentyl glycol and 1,6-hexanediol, in particular ethylene glycol and 1,2-propylene glycol.
  • Preferred C 3 - to C 12 glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, tri- and tetrapropylene glycol, propylene glycol monotertiary butyl ether and propylene glycol monoethyl ether and the solvents designated according to INCI butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyloctanol, ethoxydiglycol, Ethoxyhanol, ethyl hexanediol, isobutoxypropanol, isopentyldiol, 3-methoxybutanol, methoxyethanol, methoxyisopropanol and methoxymethylbutanol.
  • the detergent according to the invention may contain one or more solvents in an amount of usually up to 40% by weight, preferably 0.1 to 30% by weight, in particular 2 to 20% by weight, particularly preferably 3 to 15% by weight, most preferably 5 to 12 wt .-%, for example, 5.3 or 10.6 wt .-%, each based on the total agent included.
  • the detergent according to the invention optionally contains water in an amount of more than 50 wt .-%, in particular 60 to 95 wt .-%, particularly preferably 70 to 93 wt .-% and most preferably 80 to 90 wt .-% ,
  • the detergent according to the invention in the detergent or cleaner component one or more conventional auxiliaries and additives, in particular selected from the group of builders, enzymes, bleach, bleach activators, electrolytes, colorants, fragrances, pH adjusters, complexing agents, fluorescers, foam inhibitors, Graying inhibitors, anti-wrinkling agents, antioxidants, antistatic agents, ironing aids, UV absorbers, optical brighteners, anti-redeposition agents, germicides, viscosity regulators, pearlescers, color transfer inhibitors, run-in inhibitors, corrosion inhibitors, preservatives, repellents and impregnating agents, hydrotropes, silicone oils and swelling and anti-slip agents and quaternary ammonium compounds, if appropriate containing ester bonds.
  • auxiliaries and additives in particular selected from the group of builders, enzymes, bleach, bleach activators, electrolytes, colorants, fragrances, pH adjusters, complexing agents, fluorescers, foam inhibitors, Graying inhibitors, anti-wrinkling agents, antioxidants
  • builders are the most important ingredients of detergents and cleaners.
  • builders usually used in detergents, dishwashing detergents and cleaners can be present in the detergent or cleaner component, in particular zeolites, silicates, carbonates, organic cobuilders and, where there are no ecological prejudices against their use, also the phosphates.
  • Suitable crystalline layered sodium silicates have the general formula NaMSi x O 2x + 1 .H 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2, 3 or 4 are.
  • Such crystalline layered silicates are described, for example, in the European patent application EP-A-0 164 514 described.
  • Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3.
  • both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 .yH 2 O are preferred, and ⁇ -sodium disilicate can be obtained, for example, by the method described in International Patent Application WO-A-91/08171 is described.
  • amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
  • the release delay opposite conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
  • the term "amorphous” is also understood to mean "X-ray amorphous”.
  • the silicates do not give sharp X-ray reflections typical of crystalline substances but at best one or more maxima of the scattered X-rays having a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, values of up to max. 50 nm and in particular up to max. 20 nm are preferred.
  • Such so-called X-ray-amorphous silicates which likewise have a dissolution delay compared with the conventional water glasses, are described, for example, in the German patent application DE-A-44 00 024 described.
  • Especially preferred are densified / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
  • a fine crystalline, synthetic and bound water-containing zeolite optionally used is preferably zeolite A and / or P.
  • Zeolite MAP eg, commercial product: Doucil A24 from Crosfield
  • zeolite X eg, commercial product: Doucil A24 from Crosfield
  • zeolite X and mixtures of the zeolites A, X and / or P are also suitable, however, are zeolite X and mixtures of the zeolites A, X and / or P.
  • Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight).
  • Zeolite X manufactured by CONDEA Augusta SpA Suitable zeolites have an average particle size of less than 10 m (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight bound water.
  • phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
  • Useful organic builders are, for example, usable in the form of their sodium salts polycarboxylic acids, wherein.
  • Polycarboxylic acids understood such carboxylic acids which carry more than one acidity function. These are, for example, citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), provided their use is not objectionable for ecological reasons, and mixtures of these.
  • Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used.
  • the acids typically also have the property of an acidifying component and thus also serve to set a lower and milder pH of washing and cleaning agent portions according to the invention.
  • an acidifying component typically also serve to set a lower and milder pH of washing and cleaning agent portions according to the invention.
  • citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixtures of these are to be mentioned in this context.
  • polymeric polycarboxylates are suitable. These are, for example, the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those having a molecular weight of 500 to 70,000 g / mol.
  • the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M W of the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrene acids are generally significantly higher than the molecular weights specified in the context of the present invention.
  • Suitable polymers are in particular polyacrylates, which preferably have a molecular weight of 2,000 to 20,000 g / mol. Because of their superior solubility, the short-chain polyacrylates which have molecular weights of from 2,000 to 10,000 g / mol, particularly preferably from 3,000 to 5,000 g / mol, may in turn be preferred from this group.
  • copolymeric polycarboxylates in particular those of acrylic acid with methacrylic acid or of acrylic acid or methacrylic acid with maleic acid.
  • Particularly suitable copolymers of acrylic acid with maleic acid have proven that 50 to 90 Wt .-% acrylic acid and 50 to 10 wt .-% maleic acid.
  • Their relative molecular weight, based on free acids, is generally 2,000 to 70,000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.
  • the (co) polymeric polycarboxylates can be used either as a powder or as an aqueous solution.
  • the content of (co) polymeric polycarboxylates according to the invention is preferably from 0.5 to 20% by weight, in particular from 3 to 10% by weight.
  • the polymers may also allylsulfonic acids, such as in the EP-B 0 727 448 , Allyloxybenzenesulfonic acid and methallylsulfonic acid as a monomer.
  • biodegradable polymers of more than two different monomer units are also preferred DE-A 43 00 772 as monomers, salts of acrylic acid and maleic acid and vinyl alcohol or vinyl alcohol derivatives or according to the DE-C 42 21 381 as monomers, salts of acrylic acid and 2-alkylallylsulfonic acid and sugar derivatives.
  • copolymers are those described in the German patent applications DE-A 43 03 320 and DE-A 44 17 734 are described and preferably contain as monomers acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate.
  • polymeric aminodicarboxylic acids their salts or their precursors.
  • polyaspartic acids or their salts and derivatives of which in the German patent application DE-A 195 40 086 is disclosed that they also have a bleach-stabilizing effect in addition to co-builder properties.
  • polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids having 5 to 7 carbon atoms and at least 3 hydroxyl groups, for example as described in the European patent application EP-A 0 280 223 , Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.
  • dextrins for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes.
  • it is hydrolysis products having average molecular weights in the range of 400 to 500,000 g / mol.
  • a polysaccharide with a dextrose equivalent (DE) in the range of 0.5 to 40, in particular from 2 to 30, is preferred, DE being a common measure of the reducing action of a polysaccharide compared to dextrose, which is a DE of 100 owns.
  • DE dextrose equivalent
  • the oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.
  • oxidizing agents capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.
  • Such oxidized dextrins and processes for their preparation are in particular from the European patent applications EP-A 0 232 202 . EP-A 0 427 349 . EP-A 0 472 042 and EP-A 0 542 496 as well as from the international patent applications WO 92/18542 . WO 93/08251 . WO 93/16110 . WO 94/28030 . WO 95/07303 . WO 95/12619 and WO 95/20608 known. Also suitable is an oxidized oligosaccharide according to the German patent application DE-A 196 00 018 , A product oxidized to C 6 of the sac
  • Oxydisuccinates and other derivatives of disuccinates are also other suitable co-builders.
  • ethylenediamine-N, N'-disuccinate (EDDS) ethylenediamine-N, N'-disuccinate (EDDS)
  • EDDS ethylenediamine-N, N'-disuccinate
  • its synthesis for example, in the document US-A 3,158,615 is described, preferably used in the form of its sodium or magnesium salts.
  • glycerol disuccinates and glycerol trisuccinates as described, for example, in US Pat U.S.
  • organic co-builders are, for example, acetylated hydroxycarboxylic acids or salts thereof, which may optionally also be present in lactone form, and which contain at least 4 carbon atoms and at least one hydroxyl group and a maximum of two acid groups.
  • Such co-builders are described, for example, in the international patent application WO 95/20029 described.
  • phosphonates are, in particular, hydroxyalkane or aminoalkanephosphonates.
  • Preferred aminoalkanephosphonates are ethylenediamine tetramethylenephosphonate (EDTMP), diethylenetriaminepentamethylenephosphonate (DTPMP) and their higher homologs. They are preferably in the form of the neutral reacting sodium salts, for. B.
  • the builder used here is preferably HEDP from the class of phosphonates.
  • the Aminoalkanphosphonate also have a pronounced heavy metal binding capacity. Accordingly, in particular if the agents according to the invention also contain bleach, it may be preferable to use aminoalkanephosphonates, in particular DTPMP, or to use mixtures of the phosphonates mentioned.
  • the detergent according to the invention may optionally additionally contain one or more complexing agents.
  • INCI chelating agents also called sequestrants, are ingredients that are capable of complexing and inactivating metal ions to prevent their detrimental effects on the stability or appearance of the agents, such as clouding. On the one hand, it is important to complex the incompatible with numerous ingredients calcium and magnesium ions of water hardness. The complexation of the ions of heavy metals such as iron or copper retards the oxidative decomposition of the finished agents.
  • Suitable are, for example, the following complexing agents designated according to INCI, which are described in more detail in the International Cosmetic Ingredient Dictionary and Handbook : Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphate, Pentasodium Aminotrimethylene Phosphonate, Pentasodium Ethylenediamine Tetramethylene Phosphon
  • Preferred complexing agents are tertiary amines, in particular tertiary alkanolamines (amino alcohols).
  • the alkanolamines have both amino and hydroxy and / or ether groups as functional groups.
  • Particularly preferred tertiary alkanolamines are triethanolamine and tetra-2-hydroxypropylethylenediamine (N, N, N ', N'-tetrakis- (2-hydroxypropyl) ethylenediamine).
  • a particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxy-ethane-1,1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts.
  • the agent according to the invention accordingly contains etidronic acid and / or one or more of its salts as complexing agent.
  • the detergent according to the invention contains a complexing agent combination of one or more tertiary amines and one or more further complexing agents, preferably one or more complexing acids or salts thereof, in particular triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more several of their salts.
  • the detergent according to the invention contains complexing agents in an amount of usually 0 to 20 wt .-%, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, particularly preferably 1 to 8 wt .-%, most preferably 1.5 to 6 wt .-%, for example, 1.5, 2.1, 3 or 4.2 wt .-%.
  • the detergent according to the invention optionally contains one or more viscosity regulators, which preferably act as thickeners.
  • the viscosity of the compositions can be measured by conventional standard methods (for example Brookfield Viscometer RVD-VII at 20 rpm and 20 ° C., spindle 3) and is preferably in the range from 10 to 5000 mPas.
  • Preferred liquid to gel compositions have viscosities of 20 to 4000 mPas, with values between 40 and 2000 mPas being particularly preferred.
  • Suitable thickeners are inorganic or polymeric organic compounds. It is also possible to use mixtures of several thickeners.
  • the inorganic thickeners include, for example, polysilicic acids, clay minerals such as montmorillonites, zeolites, silicas, aluminum silicates, phyllosilicates and bentonites.
  • the organic thickeners are derived from the groups of natural polymers, modified natural polymers and fully synthetic polymers.
  • Naturally derived polymers which are used as thickeners are, for example, xanthan gum, agar agar, carrageenan, tragacanth, gum arabic, alginates, pectins, polyoses, guar gum, gellan gum, locust bean gum, starch, dextrins, gelatin and casein ,
  • Modified natural products come mainly from the group of modified starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and -propylcellulose, highly etherified methylhydroxyethylcellulose and Kernmehlether called.
  • a large group of thickeners which find wide use in a variety of applications, are the fully synthetic polymers such as polyacrylic and polymethacrylic compounds, which may be crosslinked or uncrosslinked and optionally cationically modified, vinyl polymers, polycarboxylic acids, polyethers, activated polyamide derivatives, castor oil derivatives, Polyimines, polyamides and polyurethanes.
  • polyacrylic and polymethacrylic compounds which may be crosslinked or uncrosslinked and optionally cationically modified, vinyl polymers, polycarboxylic acids, polyethers, activated polyamide derivatives, castor oil derivatives, Polyimines, polyamides and polyurethanes.
  • polymers examples include acrylic resins, ethyl acrylate-acrylamide copolymers, acrylic ester-methacrylic acid ester copolymers, ethyl acrylate-acrylic acid-methacrylic acid copolymers, N-methylol methacrylamide, maleic anhydride-methyl vinyl ether copolymers, polyether-polyol copolymers and butadiene-styrene copolymers.
  • thickeners are derivatives of organic acids and their alkoxide adducts, for example aryl polyglycol ethers, carboxylated nonylphenol ethoxylate derivatives, sodium alginate, diglycerol monoisostearate, nonionic ethylene oxide adducts, coconut fatty acid diethanolamide, isododecenylsuccinic anhydride and galactomannan
  • Thickeners from the mentioned substance classes are commercially available and are described, for example, under the trade names Acusol®-820 (methacrylic acid (stearyl alcohol-20-EO) ester-acrylic acid copolymer, 30% in water, Rohm & Haas), Dapral®-GT-282 -S (alkyl polyglycol ether, Akzo), Deuterol® polymer 11 (dicarboxylic acid copolymer, Schöner GmbH), Deuteron®-XG (anionic heteropolysaccharide based on bD-glucose, D-mannose, D-glucuronic acid, Schöner GmbH), deuteron ®-XN (nonionic polysaccharide, Schöner GmbH), Dicrylan® thickener O (ethylene oxide adduct, 50% in water / isopropanol, Pfersse Chemie), EMA®-81 and EMA®-91 (ethylene-maleic anhydride copolymer, Monsanto), thickener QR
  • the detergent according to the invention optionally contains one or more enzymes.
  • Particularly suitable enzymes are those from the classes of hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. In addition, cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils. Oxireductases can also be used for bleaching or inhibiting color transfer.
  • hydrolases such as the proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures of the enzymes mentioned. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
  • Bacillus subtilis Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • Bacillus subtilis Bacillus subtilis
  • Bacillus licheniformis Bacillus licheniformis
  • Streptomyceus griseus and Humicola insolens derived enzymatic agents.
  • subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
  • enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases.
  • Suitable amylases include in particular ⁇ -amylases, iso-amylases, pullulanases and pectinases.
  • As cellulases are preferably cellobiohydrolases, endoglucanases and ⁇ -glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases.
  • the enzymes may be adsorbed as a shaped body to carriers or embedded coated to protect against premature decomposition.
  • the proportion of enzymes, enzyme mixtures or enzyme granules may be, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%.
  • the detergents may optionally contain bleaching agents.
  • bleaching agents include sodium percarbonate, sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
  • bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as persulfates or persulfuric acid.
  • peracidic salts or peracids such as persulfates or persulfuric acid.
  • urea peroxohydrate percarbamide which can be described by the formula H 2 N-CO-NH 2 .H 2 O 2 .
  • they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents.
  • Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide.
  • peroxyacids examples of which include the alkyl peroxyacids and the aryl peroxyacids.
  • Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy- ⁇ -naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ⁇ -phthalimidoperoxycaproic acid (phthalimidoperoxyhexanoic acid, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonenylamidopersuccinates, and aliphatic and araliphatic peroxydicarboxylic acids, such as 1,12-diperoxycarboxylic acid, 1,9-diperoxyazelaic acid, diperoxyse
  • the bleaching agents may be coated to protect against premature degradation.
  • Dyes can be used in the detergent according to the invention, wherein the amount of one or more dyes is to be chosen so low that remain after application of the agent no visible residues.
  • the agent according to the invention is free of dyes.
  • the detergents may furthermore optionally contain UV absorbers which are applied to the treated textiles and improve the lightfastness of the fibers and / or the lightfastness of the other formulation constituents.
  • UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg heat to give back.
  • Compounds exhibiting these desired properties include, for example, the compounds which function by nonradiative deactivation and Derivatives of benzophenone with substituents in the 2- and / or 4-position.
  • substituted benzotriazoles such as the water-soluble benzenesulfonic acid 3- (2H-benzotriazol-2-yl) -4-hydroxy-5- (methylpropyl) monosodium salt (Cibafast® H), in the 3-position phenyl-substituted acrylates (cinnamic acid derivatives) , optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's urocanic acid suitable.
  • UV-B absorber are 3-benzylidene camphor or 3-Benzylidennorcampher and its derivatives, for example 3- (4-methylbenzylidene) camphor, as in EP 0693471 B1 described; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid ester; Esters of cinnamic acid, preferably 4-methoxycinnamic acid 2-ethylhexyl ester, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid isoamyl ester, 2-cyano-3
  • 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts
  • Sulfonic acid derivatives of 3-Benzylidencamphers such as 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.
  • UV-A filter in particular derivatives of benzoylmethane are suitable, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert-butyl 4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) -propane-1,3-dione, and enamine compounds as described in U.S.P. DE 19712033 A1 (BASF).
  • UV-A and Of course, UV-B filters can also be used in mixtures.
  • insoluble photoprotective pigments namely finely dispersed, preferably nano-metal oxides or salts
  • suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof.
  • salts silicates (talc), barium sulfate or zinc stearate can be used.
  • the oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics.
  • the particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm.
  • the pigments may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape.
  • the pigments can also be surface-treated, ie hydrophilized or hydrophobized. Typical examples are coated titanium dioxides, such as titanium dioxide T 805 (Degussa) or Eusolex® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Preferably, micronized zinc oxide is used. Further suitable UV sunscreen filters are the overview of P. Finkel in SOFW Journal 122, 543 (1996 ) refer to.
  • the UV absorbers can be used in amounts of from 0.01% by weight to 5% by weight, preferably from 0.03% by weight to 1% by weight.
  • the detergents may optionally contain ironing aids to improve the water absorbency, rewettability of the treated fabrics and to facilitate ironing of the treated fabrics.
  • silicone derivatives can be used in the formulations. These additionally improve the rinsing out of the wash-active formulations by their foam-inhibiting properties.
  • Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
  • Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
  • the viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C, wherein the silicones in amounts between 0.2 and 5 wt .-%, based on the total agent can be used.
  • the detergents may crease-resistant btw.
  • Reductant included. include, for example, synthetic products based on fatty acids, fatty acid esters. Fatty acid amides, -alkylolestem, -alkylolamiden or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.
  • Another object of the invention is a Konditioniersubstrat for use in textile drying process, which is impregnated with a composition of the invention and / or coated and / or impregnated.
  • the embodiment of the impregnating or coating agent or impregnating agent can be found in the above description.
  • the substrate material is preferably made of porous sheet-like cloths. They may consist of a fibrous or cellular flexible material which has sufficient thermal stability for use in the dryer and which can retain sufficient quantities of impregnating or coating agent to effectively condition fabrics without significant bleeding or bleeding during storage By means of done.
  • These wipes include cloths of woven and non-woven synthetic and natural fibers, felt, paper or foam, such as hydrophilic polyurethane foam.
  • Nonwovens are generally defined as adhesively bonded fibrous products having a mat or layered fibrous structure, or those comprising fibrous mats in which the fibers are randomly or randomly distributed.
  • the fibers may be natural such as wool, silk, jute, hemp, cotton, flax, sisal or ramie; or synthetically, such as rayon, cellulose esters, polyvinyl derivatives, polyolefins, polyamides or polyesters. In general, any fiber diameter or titer is suitable for the present invention.
  • nonwoven fabrics employed herein tend not to rupture or disintegrate due to the random or random arrangement of fibers in the nonwoven material which impart excellent strength in all directions when used, for example, in a household tumble dryer.
  • nonwoven fabrics suitable as substrates in the present invention include, for example WO 93/23603 known.
  • Preferred porous and flat conditioning cloths consist of one or different fiber materials, in particular of cotton, more refined Cotton, polyamide, polyester or mixtures of these.
  • the conditioning substrates in fabric form preferably have an area of from 0.2 to 0.005 m 2 , preferably from 0.15 to 0.01 m 2 , in particular from 0.1 to 0.03 m 2 and particularly preferably from 0.09 to 0, 06 m 2 up.
  • the grammage of the material is usually between 20 and 1000 g / m 2 , preferably from 30 to 500 g / m 2 and in particular from 50 to 150 g / m 2 .
  • Conditioning substrates can be obtained by impregnation or impregnation or else by melting the agents or conditioners according to the invention onto a substrate.
  • Another object of this invention is a fabric conditioning process wherein one or more conditioning substrates are used in a textile drying process as just described.
  • composition suitable for textile treatment comprising at least one or more skin-healing and / or skin-protecting active substances within the meaning of the invention, a further subject of this invention, wherein the skin-healing and / or skin-protecting active advantageously antiseptic, preferably an oil is and especially preferably an essential oil, in particular selected from the previously named by name essential oils.
  • the use of a composition described suitable for textile treatment is accompanied by the fact that in this use, at least one healing active in the course of textile treatment passes to the fibers of a suitably treated textile and remains at least partially on the textile, even if in contact with the skin, albeit only in traces, with the proviso that at least part of this healing active substance is released on contact of the skin with a suitably treated textile from it to the skin.
  • a further subject of this invention in a preferred embodiment is the use of at least one skin-protecting and / or skin-healing active substance for producing a medically active textile treatment agent according to the features of the textile treatment agent according to the invention for finishing textiles for supporting irritated and / or sensitized and / or diseased human skin and for the prophylactic treatment of healthy skin.
  • a further subject of this invention in a preferred embodiment is the use of at least one skin-protecting and / or skin-healing active substance for the production of a medically effective conditioning substrate in accordance with the features to be taken from the description for finishing textiles for the supportive and / or prophylactic treatment of healthy and / or irritated and / or sensitized and / or diseased human skin.
  • Another object of this invention in a preferred embodiment is the use of at least one skin-protecting and / or skin-healing active for the production of a medically active detergent according to the description to be taken features for finishing textiles for supportive and / or prophylactic treatment of healthy and / or irritated and / or sensitized and / or diseased human skin.
  • the emulsion was prepared in a laboratory homogenizer (rotor-stator system, type Janke & Kunkel) at 30 ° C, then cooling to 20 ° C.
  • the mined starch is natural starch from rice, corn, wheat, potato, oats and the like. a., Preferably, partially hydrolyzed starch (acid or enzyme hydrolysis).
  • the solids citric acid, sodium citrate, urea and starch are dissolved successively with stirring at about 30 ° C. in the initially introduced water. Subsequently, the addition of the oils and the emulsifier (ethoxylated castor oil) takes place successively.
  • the emulsion is produced by using a homogenizer.
  • this emulsion can be carried out in all the ways described above in the context of a textile treatment.
  • Sebutapes® are applied at three points on the inside of the forearm or body parts where the textile / skin contact was present for one minute each. With a roller (1000g) is standardized six times rolled over the pasted area.
  • Sebutapes® To quantify the proteins on the Sebutapes®, they are each mixed with 1.5 ml of the lysis buffer (0.9% by weight NaCl + 0.1% by weight Triton X in double-distilled water). The treatment took place in 6 corrugated dishes, which were carefully closed with Parafilm. Each three plates are treated together in an ultrasonic bath for 10 minutes. The quantification of the total protein is carried out by a common method z. B. with the MicroBCA protein assay from Pierce according to the manufacturer.
  • the active substance is eluted from the sebum tapes with a suitable buffer.
  • the analysis is carried out by suitable methods (e.g., HPLC / GC / MS or others).
  • the active ingredients are extracted from the skin using a cotton pad with 2 ml of reagent grade ethanol.
  • a plastic ring with an inner diameter of 40 mm is placed on the skin, and extracted the skin area to be tested 3 times with circular motion.
  • the pad is placed in 8 ml units of analytical ethanol.
  • the quantification of the active substances then takes place, for example, via HPLC / GC / MS or other customary analytical methods.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Claims (30)

  1. Agent de traitement des textiles sous la forme d'une émulsion, caractérisé en ce qu'il contient une ou plusieurs substances actives dermoprotectrices ou une ou plusieurs substances actives dermoprotectrices et une ou plusieurs substances actives dermocuratives, à savoir
    a) une huile dermoprotectrice choisie parmi le groupe comprenant : l'huile d'algues Oleum Phaeophyceae, l'huile de noyau d'abricot Prunus armeniaca, l'huile d'arnica Arnica montana, l'huile d'avocat Persea americana, l'huile de bourrache Borago officinalis, l'huile de calendula Calendula officinalis, l'huile de camélia Camellia oleifera, l'huile de chardon Carthamus tinctorius, l'huile d'arachide Arachis hypogaea, l'huile de chanvre, Cannabis sativa, l'huile de noisette Corylus avellana, l'huile de millepertuis Hypericum perforatum, l'huile de jojoba Simondsia chinensis, l'huile de carotte Daucus carota, l'huile de coco Cocos nucifera, l'huile de graines de courge Curcubita pepo, l'huile de kukui Aleurites moluccana, l'huile de macadamia Macadamia ternifolia, l'huile d'amande Prunus dulcis, l'huile de noyau de pêche Prunus persica, l'huile de colza Brassica oleifera, l'huile de cumin noir Nigella sativa, l'huile de sésame Sesamium indicum, l'huile de tournesol Helianthus annus, l'huile de pépins de raisin Vitis vinifera, l'huile de noix Juglans regia, l'huile de germes de blé Triticum sativum, et
    b) en outre, de l'urée et/ou ses dérivés et/ou de l'acide lactique et/ou de l'acide citrique et/ou leurs sels.
  2. Agent selon la revendication 1, caractérisé en ce qu'au moins une des substances actives développe une activité antiseptique ou contient au moins une substance à activité antiseptique.
  3. Agent selon la revendication 2, caractérisé en ce que, en ce qui concerne la substance à activité antiseptique, il s'agit d'une huile, en particulier d'une huile éthérée.
  4. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il contient au moins 1 % en poids d'une ou plusieurs substances actives dermoprotectrices et/ou dermocuratives.
  5. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il contient au moins des substances actives dermoprotectrices et/ou dermocuratives qui présentent une teneur minimale de 0,1 % en poids en acide γ-linolénique (GLA).
  6. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce que sa valeur de pH à une température T = 20 °C n'est pas supérieur à 5,5.
  7. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce que la composition ne contient pas de colorants.
  8. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce que la composition est non aqueuse.
  9. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il ne contient aucun arôme ou autres huiles de parfum supplémentaires.
  10. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il contient un agent facilitant le repassage et/ou un agent antifroissement.
  11. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il est fixé de manière réversible sur un support polymère, si bien qu'une libération retardée des substances actives dermoprotectrices et/ou dermocuratives est possible.
  12. Agent selon la revendication 11, caractérisé en ce que le support polymère est un ester de l'acide silicique.
  13. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il contient une substance active désodorisante.
  14. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il contient une quantité minime d'un composé d'ammonium quaternaire, mais en particulier aucun, en particulier aucun composé d'ammonium quaternaire dans lequel des groupes hydrophobes sont liés via des liaisons ester à une diéthanolamine ou une (tri)éthanolamine quaternaire ou à un composé analogue.
  15. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il est incorporé, en particulier par portions, dans un conditionnement soluble dans l'eau, si bien que les portions individuelles sont incorporées dans des conditionnements solubles dans l'eau.
  16. Agent selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il est présent sous la forme d'une microémulsion.
  17. Utilisation d'un agent selon l'une quelconque des revendications précédentes 1 à 16, comme agent de rinçage.
  18. Utilisation d'un agent selon l'une quelconque des revendications précédentes 1 à 16, comme assouplissant.
  19. Utilisation d'une composition selon l'une quelconque des revendications précédentes 1 à 16, pour le traitement des textiles, caractérisée en ce que l'application de l'agent sur le textile a lieu au moyen d'un applicateur par pulvérisation, avec cette mesure que la composition est présente sous forme liquide.
  20. Utilisation d'au moins une substance active dermoprotectrice et/ou dermocurative pour la préparation d'un agent actif du point de vue médical selon l'une quelconque des revendications 1 à 16 pour l'apprêt de textiles destinés au traitement de soutien d'une peau humaine irritée et/ou rendue sensible et/ou malade, ainsi que pour le traitement prophylactique d'une peau saine.
  21. Procédé pour le traitement des textiles, caractérisé en ce qu'on applique un agent selon l'une quelconque des revendications 1 à 16 en utilisant un applicateur par pulvérisation sur le textile à traiter, avec cette mesure que l'agent de traitement des textiles est présent sous forme liquide.
  22. Substrat de conditionnement pour la mise en oeuvre dans un procédé de séchage des textiles, caractérisé en ce qu'il s'agit d'un substrat imprégné et/ou imbibé et/ou enduit avec un agent selon l'une quelconque des revendications 1 à 16.
  23. Substrat de conditionnement selon la revendication 22, caractérisé en ce que le substrat est constitué d'un non-tissé, en particulier d'un non-tissé à base de viscose.
  24. Substrat de conditionnement selon l'une quelconque des revendications 22 à 23, caractérisé en ce que le substrat présente un grammage de 20 à 1000 g/m2, en particulier de 30 à 500 g/m2.
  25. Substrat de conditionnement selon l'une quelconque des revendications 22 à 24, caractérisé en ce que le substrat présente une dimension de 0,2 à 0,005 m2.
  26. Procédé pour le conditionnement des textiles, caractérisé en ce qu'on met en oeuvre dans un processus de séchage des textiles, un ou plusieurs substrats de conditionnement selon l'une quelconque des revendications 22 à 25.
  27. Utilisation d'au moins une substance active dermoprotectrice et/ou dermocurative pour la fabrication d'un substrat de conditionnement actif du point de vue médical selon l'une quelconque des revendications 22 à 26, pour l'apprêt de textiles destinés au traitement de soutien d'une peau humaine irritée et/ou rendue sensible et/ou malade, ainsi que pour le traitement prophylactique d'une peau saine.
  28. Agent de lavage constitué par au moins deux composants, caractérisée en ce que, en ce qui concerne ces deux composants, il s'agit d'au moins un composant d'agent de lavage ou de nettoyage, et d'au moins un composant de traitement des textiles selon les revendications 1 à 16, ces deux composants étant libérés en particulier à des moments différents au cours d'un processus de lavage, respectivement de traitement des textiles.
  29. Agent de lavage selon la revendication 28, caractérisé en ce qu'il s'agit d'un agent de lavage liquide qui est présent en particulier sous la forme d'une microémulsion.
  30. Produit, constitué par un applicateur par pulvérisation et un agent de traitement des textiles selon l'une quelconque des revendications 1 à 16, avec cette mesure que l'agent de traitement des textiles est présent sous forme liquide, en particulier sous la forme d'une microémulsion.
EP04717600.3A 2003-03-17 2004-03-05 Agent servant a traiter un textile Expired - Lifetime EP1603999B2 (fr)

Priority Applications (1)

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PL04717600T PL1603999T5 (pl) 2003-03-17 2004-03-05 Środek do obróbki tekstyliów

Applications Claiming Priority (3)

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DE10311852A DE10311852A1 (de) 2003-03-17 2003-03-17 Textilbehandlungsmittel
DE10311852 2003-03-17
PCT/EP2004/002232 WO2004083355A1 (fr) 2003-03-17 2004-03-05 Agent servant a traiter un textile

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EP1603999A1 EP1603999A1 (fr) 2005-12-14
EP1603999B1 true EP1603999B1 (fr) 2013-06-19
EP1603999B2 EP1603999B2 (fr) 2016-08-17

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US (1) US20060070189A1 (fr)
EP (1) EP1603999B2 (fr)
JP (1) JP4425268B2 (fr)
DE (1) DE10311852A1 (fr)
ES (1) ES2420931T5 (fr)
PL (1) PL1603999T5 (fr)
WO (1) WO2004083355A1 (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005044514A1 (de) * 2005-09-16 2007-03-22 Henkel Kgaa Wasch- und Reinigungsmittel mit hautpflegenden Inhaltsstoffen
DE102005049429A1 (de) * 2005-10-15 2007-04-19 Cognis Ip Management Gmbh Verfahren zur Ausrüstung von Textilien
ITTO20050788A1 (it) * 2005-11-09 2007-05-10 Sagitta Srl Procedimento per il trattamento di tessuti e capi di abbigliamento
DE102006020976A1 (de) * 2006-05-05 2007-11-08 Ismail Karacaoglan Bekleidung zur Körperenthaarung
US8664173B2 (en) * 2007-01-11 2014-03-04 Basf Se Premoistened cleaning disposable substrate for leather and method of preserving a leather surface by contacting said surface with said substrate
JP4633075B2 (ja) * 2007-02-28 2011-02-16 大王製紙株式会社 衛生用薄葉紙
CH699297A1 (de) * 2008-08-08 2010-02-15 Tex A Tec Ag Carrier-System zur nachträglichen Applikation auf Substrate und Verfahren dazu.
US8252122B2 (en) * 2009-03-17 2012-08-28 Bbt Bergedorfer Biotechnik Gmbh Use of an agent that contains carbamide and/or at least a derivative thereof as a cleaning agent
US20130139327A1 (en) * 2010-08-03 2013-06-06 Henkel Ag & Co. Kgaa Textile treatment composition for removal of deodorant stains
US8703205B2 (en) 2011-08-04 2014-04-22 Hasan Ali ALZAHRANI Natural compositions and methods of promoting wound healing
US20130111675A1 (en) * 2011-11-03 2013-05-09 Ecolab Usa Inc. Sustainable laundry sour compositions with iron control
US9222058B2 (en) * 2013-03-12 2015-12-29 Ecolab Usa Inc. Cleaning composition and method for removal of sunscreen stains
CA2904948A1 (fr) 2013-03-14 2014-10-02 Mary Kay Inc. Compositions cosmetiques
CN103147311B (zh) * 2013-04-07 2015-07-15 江苏悦达纺织集团有限公司 茶树油微胶囊抗菌保健纤维及其制备方法
KR102067702B1 (ko) * 2014-02-25 2020-01-17 주식회사 엘지생활건강 섬유유연제 조성물
KR102123613B1 (ko) * 2014-02-25 2020-06-17 주식회사 엘지생활건강 섬유유연제 조성물
KR101703138B1 (ko) * 2014-02-25 2017-02-06 주식회사 엘지생활건강 섬유유연제 조성물
KR102161046B1 (ko) * 2014-02-25 2020-10-05 주식회사 엘지생활건강 섬유유연제 조성물
KR102067701B1 (ko) * 2014-02-25 2020-01-17 주식회사 엘지생활건강 섬유유연제 조성물
KR102058480B1 (ko) * 2014-02-25 2019-12-23 주식회사 엘지생활건강 섬유유연제 조성물
DE102014010875A1 (de) * 2014-07-25 2016-01-28 Basf Se Transparente Textilpflegemittel
BR112019002568A2 (pt) 2016-09-07 2019-05-21 Ecolab Usa Inc. composição, e, métodos de limpeza, sanitização e/ou de alvejamento e para estabilizar uma enzima em um detergente sólido
GR1009377B (el) * 2016-11-23 2018-10-09 Συμεων Καρατζογλου & Σια Ο.Ε Επεξεργασια υφασματων με φυσικα-μη τοξικα υλικα
US20200297629A1 (en) * 2019-06-29 2020-09-24 3J's Green Equine Care, LLC Emollient emulsion
DE102019219242A1 (de) * 2019-12-10 2021-06-10 Henkel Ag & Co. Kgaa Knitterneigungsvermeidung bei Textilien
CR20230492A (es) 2021-04-01 2023-11-23 Sterilex LLC Desinfectante/sanitizante en polvo sin quats
WO2022232692A1 (fr) * 2021-04-30 2022-11-03 Noble Biomaterials, Inc. Traitement de tissu antimicrobien à base de plante, tissus traités et méthodes associées

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3158615A (en) * 1960-07-20 1964-11-24 Union Carbide Corp Stabilized polymerizable vinyl pyridines
US3234258A (en) * 1963-06-20 1966-02-08 Procter & Gamble Sulfation of alpha olefins
DK130078C (fr) * 1967-12-14
US4524009A (en) * 1984-01-31 1985-06-18 A. E. Staley Manufacturing Company Detergent builder
DE3413571A1 (de) * 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
US4639325A (en) * 1984-10-24 1987-01-27 A. E. Staley Manufacturing Company Detergent builder
FR2588187B1 (fr) † 1985-10-07 1989-04-14 Rochas Parfums Nouvelles compositions cosmetiques ou dermatologiques riches en acides gras essentiels presents a la fois sous forme de triglycerides et sous forme libre ou salifiee
FR2597473B1 (fr) * 1986-01-30 1988-08-12 Roquette Freres Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus.
DE3706036A1 (de) * 1987-02-25 1988-09-08 Basf Ag Polyacetale, verfahren zu deren herstellung aus dialdehyden und polyolcarbonsaeuren und verwendung der polyacetale
US5108643A (en) * 1987-11-12 1992-04-28 Colgate-Palmolive Company Stable microemulsion cleaning composition
YU221490A (sh) * 1989-12-02 1993-10-20 Henkel Kg. Postupak za hidrotermalnu izradu kristalnog natrijum disilikata
US5075041A (en) * 1990-06-28 1991-12-24 Shell Oil Company Process for the preparation of secondary alcohol sulfate-containing surfactant compositions
DE4134914A1 (de) * 1991-10-23 1993-04-29 Henkel Kgaa Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen
DE4221381C1 (de) * 1992-07-02 1994-02-10 Stockhausen Chem Fab Gmbh Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4203923A1 (de) * 1992-02-11 1993-08-12 Henkel Kgaa Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis
NZ249441A (en) * 1992-03-03 1995-12-21 Reginald Keith Whiteley Disinfectant composition containing an aqueous solution of tea tree oil
JPH06136386A (ja) * 1992-10-21 1994-05-17 Kawaken Fine Chem Co Ltd アスパラサス・リネアリス抽出物を含有する皮膚保護剤および洗浄剤組成物
DE4303320C2 (de) * 1993-02-05 1995-12-21 Degussa Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür
DE4317519A1 (de) * 1993-05-26 1994-12-01 Henkel Kgaa Herstellung von Polycarboxylaten auf Polysaccharid-Basis
DE4400024A1 (de) * 1994-01-03 1995-07-06 Henkel Kgaa Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet
DE4402851A1 (de) * 1994-01-31 1995-08-03 Henkel Kgaa Wirbelschicht-Oxidationsverfahren zur Herstellung von Polycarboxylaten auf Polysaccharid-Basis
DE4426215A1 (de) * 1994-07-23 1996-01-25 Merck Patent Gmbh Ketotricyclo [5.2.1.0] decan-Derivate
DE4426216A1 (de) * 1994-07-23 1996-01-25 Merck Patent Gmbh Benzyliden-Norcampher-Derivate
DE19503061A1 (de) * 1995-02-01 1996-08-08 Henkel Kgaa Dimeralkohol-bis- und Trimeralkohol-tris-sulfate und -ethersulfate
US5930956A (en) * 1995-11-02 1999-08-03 Stephen Trosper Dropcloth
DE19600018A1 (de) * 1996-01-03 1997-07-10 Henkel Kgaa Waschmittel mit bestimmten oxidierten Oligosacchariden
DE59709127D1 (de) * 1996-07-08 2003-02-20 Ciba Sc Holding Ag Triazinderivate als UV-Filter in Sonnenschutzmitteln
DE19737072C2 (de) * 1997-08-26 2003-12-24 Monika Romaine-Niesner Reinigungsmittel mit hohem Reinigungserfolg und vernachlässigbarer allergener Wirkung
DE19821106A1 (de) * 1998-05-12 1999-11-18 Grewe Helmut F Milbentötendes - Reinigungsmittel für Textilien auf Basis ätherischer Pflanzen- und Baumöle
AU2452599A (en) * 1999-01-07 2000-07-24 Procter & Gamble Company, The Fabric care composition containing a protein
DE19904513A1 (de) * 1999-02-04 2000-08-10 Cognis Deutschland Gmbh Detergensgemische
US6413529B1 (en) * 1999-04-13 2002-07-02 The Procter & Gamble Company Antimicrobial wipes which provide improved residual benefit versus gram negative bacteria
US6440437B1 (en) * 2000-01-24 2002-08-27 Kimberly-Clark Worldwide, Inc. Wet wipes having skin health benefits
DE10029284A1 (de) † 2000-06-14 2002-01-10 Henkel Kgaa Flüssiges bis gelförmiges Textilbehandlungsmittel
DE10031703A1 (de) * 2000-06-29 2002-01-10 Beiersdorf Ag Verwendung von Calcium freisetzenden oder bindenden Substanzen zur gezielten Schächung oder Stärkung der Barrierefunktion der Haut
US6653378B2 (en) * 2000-12-18 2003-11-25 Dow Corning Corporation Silicone elastomer compositions
US7938812B2 (en) * 2001-10-26 2011-05-10 Sca Hygiene Products Ab Insert for an absorbent article with skincare agent and spacing sheet

Also Published As

Publication number Publication date
ES2420931T3 (es) 2013-08-27
US20060070189A1 (en) 2006-04-06
PL1603999T5 (pl) 2017-09-29
PL1603999T3 (pl) 2013-11-29
EP1603999A1 (fr) 2005-12-14
DE10311852A1 (de) 2004-10-14
ES2420931T5 (es) 2016-12-01
WO2004083355A1 (fr) 2004-09-30
EP1603999B2 (fr) 2016-08-17
JP2006520434A (ja) 2006-09-07
JP4425268B2 (ja) 2010-03-03

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