EP1593000B1 - Afficheur electrochrome - Google Patents
Afficheur electrochrome Download PDFInfo
- Publication number
- EP1593000B1 EP1593000B1 EP04706771A EP04706771A EP1593000B1 EP 1593000 B1 EP1593000 B1 EP 1593000B1 EP 04706771 A EP04706771 A EP 04706771A EP 04706771 A EP04706771 A EP 04706771A EP 1593000 B1 EP1593000 B1 EP 1593000B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrochromic
- doped
- working electrode
- layer
- tio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000463 material Substances 0.000 claims abstract description 34
- 239000000758 substrate Substances 0.000 claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 239000012777 electrically insulating material Substances 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 37
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 239000004020 conductor Substances 0.000 claims description 12
- 229910044991 metal oxide Inorganic materials 0.000 claims description 12
- 150000004706 metal oxides Chemical class 0.000 claims description 12
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004065 semiconductor Substances 0.000 claims description 9
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 229910003437 indium oxide Inorganic materials 0.000 claims description 7
- 229910001887 tin oxide Inorganic materials 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000003566 sealing material Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229910052682 stishovite Inorganic materials 0.000 claims description 5
- 229910052905 tridymite Inorganic materials 0.000 claims description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052787 antimony Inorganic materials 0.000 claims description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002322 conducting polymer Substances 0.000 claims description 4
- 229920001940 conductive polymer Polymers 0.000 claims description 4
- 239000011244 liquid electrolyte Substances 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- 229920000123 polythiophene Polymers 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 claims description 3
- 229910005264 GaInO3 Inorganic materials 0.000 claims description 2
- 229910017902 MgIn2O4 Inorganic materials 0.000 claims description 2
- 229910007694 ZnSnO3 Inorganic materials 0.000 claims description 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- 239000011810 insulating material Substances 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000012780 transparent material Substances 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 2
- 229910004158 TaO Inorganic materials 0.000 claims 1
- BFRGSJVXBIWTCF-UHFFFAOYSA-N niobium monoxide Inorganic materials [Nb]=O BFRGSJVXBIWTCF-UHFFFAOYSA-N 0.000 claims 1
- 230000008021 deposition Effects 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 description 8
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 4
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 4
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011859 microparticle Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- -1 for example Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Chemical compound O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 229940116411 terpineol Drugs 0.000 description 2
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 1
- HSTRVBYSLWZHSR-UHFFFAOYSA-O 2,5-dimethyl-3-propyl-1H-imidazol-3-ium Chemical compound CCC[NH+]1C=C(C)N=C1C HSTRVBYSLWZHSR-UHFFFAOYSA-O 0.000 description 1
- PZYQWVWYKLGFIL-UHFFFAOYSA-N 2-[4-[1-(2-phosphonoethyl)pyridin-1-ium-4-yl]pyridin-1-ium-1-yl]ethylphosphonic acid;dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](CCP(O)(=O)O)=CC=C1C1=CC=[N+](CCP(O)(O)=O)C=C1 PZYQWVWYKLGFIL-UHFFFAOYSA-N 0.000 description 1
- VWIIJDNADIEEDB-UHFFFAOYSA-N 3-methyl-1,3-oxazolidin-2-one Chemical compound CN1CCOC1=O VWIIJDNADIEEDB-UHFFFAOYSA-N 0.000 description 1
- 244000304337 Cuminum cyminum Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910021541 Vanadium(III) oxide Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- GUVUOGQBMYCBQP-UHFFFAOYSA-N dmpu Chemical compound CN1CCCN(C)C1=O GUVUOGQBMYCBQP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- JROGBPMEKVAPEH-GXGBFOEMSA-N emetine dihydrochloride Chemical compound Cl.Cl.N1CCC2=CC(OC)=C(OC)C=C2[C@H]1C[C@H]1C[C@H]2C3=CC(OC)=C(OC)C=C3CCN2C[C@@H]1CC JROGBPMEKVAPEH-GXGBFOEMSA-N 0.000 description 1
- ZTOMUSMDRMJOTH-UHFFFAOYSA-N glutaronitrile Chemical compound N#CCCCC#N ZTOMUSMDRMJOTH-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1503—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/1533—Constructional details structural features not otherwise provided for
- G02F2001/1536—Constructional details structural features not otherwise provided for additional, e.g. protective, layer inside the cell
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
- G02F2001/1552—Inner electrode, e.g. the electrochromic layer being sandwiched between the inner electrode and the support substrate---- this group, now to be changed, should already been created by implementation of a previous DOC14 ----
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/153—Constructional details
- G02F1/155—Electrodes
- G02F2001/1555—Counter electrode
Landscapes
- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Control Of Indicators Other Than Cathode Ray Tubes (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Gas-Insulated Switchgears (AREA)
Claims (27)
- Dispositif électrochromique comprenant un substrat de support unique (1) sur lequel sont disposées :(a) une électrode de travail (6) comprenant une couche poreuse d'une matière électriquement conductrice ou semi-conductrice, l'électrode de travail comprenant une matière qui est électrochromique en soi et/ou au moins une partie de ladite électrode de travail portant une matière électrochromique ;(b) une contre-électrode (3) comprenant une couche poreuse d'une matière électriquement conductrice ou semi-conductrice ;(c) une couche (4) d'une matière électriquement isolante qui est perméable aux ions et qui sépare les couches d'électrode de travail et de contre-électrode ; dans lequel ladite matière électrochromique a une surface principale dont au moins une partie forme au moins une partie d'une surface externe du dispositif.
- Dispositif selon la revendication 1, dans lequel essentiellement la totalité de ladite surface principale forme une partie de la surface externe du dispositif.
- Dispositif selon la revendication 1 ou 2, dans lequel ladite électrode de travail comporte une surface principale qui est électrochromique en soi.
- Dispositif selon la revendication 1 ou 2, dans lequel ladite électrode de travail comporte une surface principale dont au moins une partie porte une matière électrochromique.
- Dispositif selon la revendication 4, dans lequel ladite matière électrochromique couvre essentiellement ladite surface principale de ladite électrode de travail.
- Dispositif selon l'une quelconque des revendications précédentes, dans lequel l'électrode de travail, la contre-électrode et les couches isolantes sont essentiellement parallèles ; et/ou dans lequel l'électrode de travail, la contre-électrode et les couches isolantes s'étendent essentiellement dans le même sens les unes par rapport aux autres.
- Dispositif selon l'une quelconque des revendications 1 à 5, dans lequel au moins une partie de l'électrode de travail est décalée latéralement par rapport à la contre-électrode.
- Dispositif selon l'une quelconque des revendications précédentes, dans lequel le substrat de support est formé à partir d'une matière transparente ou non transparente.
- Dispositif selon la revendication 8, dans lequel le substrat est formé en verre ou métal ou en une matière céramique ou plastique.
- Dispositif selon la revendication 8 ou 9, dans lequel le substrat de support porte un revêtement électriquement conducteur sur au moins une partie de sa surface interne.
- Dispositif selon la revendication 10, dans lequel le revêtement électriquement conducteur comprend un oxyde métallique dopé, de préférence de l'oxyde d'étain dopé au fluor ou à l'antimoine, ou de l'oxyde d'indium dopé à l'étain, ou un polymère ou métal conducteur.
- Dispositif selon l'une quelconque des revendications 1 à 9, dans lequel la résistance de couche intrinsèque de la matière de l'électrode de travail et/ou de la contre-électrode est inférieure à 10000 ohms par carré.
- Dispositif selon l'une quelconque des revendications précédentes, dans lequel l'électrode de travail et/ou la contre-électrode comprennent une matière électriquement conductrice comprenant des nanoparticules d'un oxyde métallique sélectionné parmi les oxydes métalliques suivants :(a) SnO2 dopé au F, Cl, Sb, P, As ou B ;(b) ZnO dopé à l'Al, In, Ga, B, F, Si, Ge, Ti, Zr ou Hf ;(c) In2O3 dopé au Sn ;(d) CdO;(e) ZnSnO3, Zn2h2O5, In4Sn3O12, GaInO3 ou MgIn2O4 ;(f) Fe2O3 dopé au Sb ;(g) Systèmes TiO2/WO3 ou TiO2/MoO3 ; et(h) Systèmes Fe2O3/Sb ou SnO2/Sb ;de préférence du SnO2 dopé au Sb.
- Dispositif selon l'une quelconque des revendications 1 à 13, dans lequel l'électrode de travail et/ou la contre-électrode comprennent une matière électriquement semi-conductrice comprenant des nanoparticules d'un oxyde métallique sélectionné parmi les oxydes métalliques suivants : TiO2, ZrO2, HfO2, CrO3, MoO3, WO3, VO, NbO, SnO2, TaO, AgO, ZnO, SrO, FeO, Fe2O3 ou NiO, ou un pérovskite de ceux-ci, de préférence le TiO2, WO3, MoO3, ZnO ou SnO2.
- Dispositif selon la revendication 3 ou n'importe quelle revendication dépendant de celle-ci, dans lequel la matière électrochromique de l'électrode de travail est un oxyde métallique sélectionné parmi le WO3 et le TiO2 ou un oxyde métallique dopé sélectionné parmi l'oxyde d'étain dopé à l'antimoine ou au fluor et l'oxyde d'indium dopé à l'étain.
- Dispositif selon la revendication 4 ou n'importe quelle revendication dépendant de celle-ci, dans lequel la matière électrochromique est sélectionnée parmi les viologènes et polymères et mélanges de ceux-ci.
- Dispositif selon l'une quelconque des revendications précédentes, comprenant en outre un milieu de conduction ionique.
- Dispositif selon l'une quelconque des revendications précédentes, dans lequel la couche électriquement isolante comprend un milieu de conduction ionique.
- Dispositif selon l'une quelconque des revendications 1 à 17, dans lequel la matière électriquement isolante est poreuse et chacune des couches poreuses est au moins partiellement scellée, et le milieu de conduction ionique comprend un électrolyte liquide qui remplit au moins partiellement les pores des électrodes et la matière isolante.
- Dispositif selon l'une quelconque des revendications précédentes, comprenant en outre un couvercle transparent qui expose au moins partiellement ladite matière électrochromique et une matière d'étanchéité qui scelle le couvercle sur ledit dispositif électrochromique.
- Dispositif selon la revendication 20, dans lequel ladite matière d'étanchéité scelle ledit couvercle sur ledit substrat de support.
- Dispositif selon l'une quelconque des revendications 19 à 21, dans lequel la matière électriquement isolante comprend un oxyde métallique sélectionné parmi les SiO2, Al2O3, ZrO et MgO, ou TiO2 sous la forme rutile passivée au SiO2.
- Dispositif selon l'une quelconque des revendications précédentes, comprenant en outre une couche de support de courant électrique interposée entre l'électrode de travail et les couches électriquement isolantes.
- Dispositif selon la revendication 23, dans lequel la couche de support de courant électrique comprend de l'oxyde d'indium dopé à l'étain ou de l'oxyde d'étain dopé au fluor, ou un polymère conducteur sélectionné parmi les polythiophènes, les polypyrroles et les polyviologènes.
- Afficheur comprenant un ou plusieurs dispositifs selon l'une quelconque des revendications précédentes.
- Afficheur selon la revendication 25, comprenant une pluralité de dispositifs connectés en série.
- Utilisation d'un dispositif selon l'une quelconque des revendications 1 à 24 dans une matrice active ou une matrice passive ou en configurations de commande directe.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04706771A EP1593000B1 (fr) | 2003-01-31 | 2004-01-30 | Afficheur electrochrome |
| EP06014423A EP1708016B1 (fr) | 2003-01-31 | 2004-01-30 | Dispositif d'affichage électrochromique et procédé pour sa production |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03394011 | 2003-01-31 | ||
| EP03394011 | 2003-01-31 | ||
| PCT/IE2004/000014 WO2004068231A1 (fr) | 2003-01-31 | 2004-01-30 | Afficheur electrochrome |
| EP04706771A EP1593000B1 (fr) | 2003-01-31 | 2004-01-30 | Afficheur electrochrome |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06014423A Division EP1708016B1 (fr) | 2003-01-31 | 2004-01-30 | Dispositif d'affichage électrochromique et procédé pour sa production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1593000A1 EP1593000A1 (fr) | 2005-11-09 |
| EP1593000B1 true EP1593000B1 (fr) | 2006-07-12 |
Family
ID=32799176
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04706771A Expired - Lifetime EP1593000B1 (fr) | 2003-01-31 | 2004-01-30 | Afficheur electrochrome |
| EP06014423A Expired - Lifetime EP1708016B1 (fr) | 2003-01-31 | 2004-01-30 | Dispositif d'affichage électrochromique et procédé pour sa production |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06014423A Expired - Lifetime EP1708016B1 (fr) | 2003-01-31 | 2004-01-30 | Dispositif d'affichage électrochromique et procédé pour sa production |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7460289B2 (fr) |
| EP (2) | EP1593000B1 (fr) |
| JP (1) | JP4589915B2 (fr) |
| KR (1) | KR100980796B1 (fr) |
| CN (1) | CN100462830C (fr) |
| AT (2) | ATE333108T1 (fr) |
| AU (1) | AU2004208241B2 (fr) |
| CA (1) | CA2509771A1 (fr) |
| DE (2) | DE602004001508T2 (fr) |
| DK (1) | DK1593000T3 (fr) |
| HK (1) | HK1085274A1 (fr) |
| TW (1) | TW200417280A (fr) |
| WO (1) | WO2004068231A1 (fr) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1271227A1 (fr) * | 2001-06-26 | 2003-01-02 | Nanomat Limited | Dispositif d'affichage électrochromique à haute resolution et procédé pour sa production |
| WO2005012993A1 (fr) * | 2003-07-31 | 2005-02-10 | Sanyo Electric Co., Ltd. | Affichage electrochimique |
| US7864398B2 (en) * | 2004-06-08 | 2011-01-04 | Gentex Corporation | Electro-optical element including metallic films and methods for applying the same |
| KR101136398B1 (ko) * | 2004-10-23 | 2012-04-18 | 엘지디스플레이 주식회사 | 입체영상 표시장치 및 그 제조방법 |
| KR100870613B1 (ko) * | 2005-11-02 | 2008-11-25 | 주식회사 엘지화학 | 전기변색소자의 전극구조 |
| US7420727B2 (en) | 2006-01-13 | 2008-09-02 | Ntera Limited | Active matrix electrochromic display |
| WO2007082067A2 (fr) | 2006-01-13 | 2007-07-19 | Ntera, Limited | Dispositif électrochromique employant un gel ou des polymères solides présentant une direction de canal spécifique pour la conduction d'ions |
| US20070188841A1 (en) * | 2006-02-10 | 2007-08-16 | Ntera, Inc. | Method and system for lowering the drive potential of an electrochromic device |
| EP2040115A1 (fr) | 2006-07-12 | 2009-03-25 | Konica Minolta Holdings, Inc. | Dispositif d'affichage electrochromique |
| JP5040218B2 (ja) * | 2006-08-28 | 2012-10-03 | コニカミノルタホールディングス株式会社 | 表示素子 |
| WO2008083861A1 (fr) * | 2007-01-11 | 2008-07-17 | Siemens Aktiengesellschaft | Formulation électrochrome transparente à base organique, préparation d'un composant électrochrome transparent et utilisations de ce composant |
| WO2008115598A1 (fr) * | 2007-03-21 | 2008-09-25 | Ntera, Inc. | Affichage couleur imprimé mince |
| WO2008150851A1 (fr) * | 2007-06-01 | 2008-12-11 | Ntera, Inc. | Architecture monolithique et électrolyte pour dispositifs électrochromiques |
| WO2008149811A1 (fr) * | 2007-06-06 | 2008-12-11 | Fujikura Ltd. | Module de batterie solaire sensibilisée par un colorant et son procédé de fabrication |
| WO2008149850A1 (fr) | 2007-06-08 | 2008-12-11 | Konica Minolta Holdings, Inc. | Processus de production d'un élément d'affichage électrochimique et élément d'affichage électrochimique |
| WO2009101851A1 (fr) | 2008-02-13 | 2009-08-20 | Konica Minolta Holdings, Inc. | Dispositif d'affichage |
| JP5177219B2 (ja) | 2008-03-18 | 2013-04-03 | コニカミノルタホールディングス株式会社 | 電気化学的表示素子 |
| JPWO2010010814A1 (ja) * | 2008-07-24 | 2012-01-05 | コニカミノルタホールディングス株式会社 | 表示素子及び表示素子の多孔質層の形成方法 |
| WO2010099147A1 (fr) * | 2009-02-24 | 2010-09-02 | Ntera Inc. | Structures d'électrode avancées et dispositifs électrochromiques |
| US8582193B2 (en) | 2010-04-30 | 2013-11-12 | View, Inc. | Electrochromic devices |
| US9007674B2 (en) | 2011-09-30 | 2015-04-14 | View, Inc. | Defect-mitigation layers in electrochromic devices |
| US10591795B2 (en) | 2009-03-31 | 2020-03-17 | View, Inc. | Counter electrode for electrochromic devices |
| US10261381B2 (en) | 2009-03-31 | 2019-04-16 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| WO2016085764A1 (fr) | 2014-11-26 | 2016-06-02 | View, Inc. | Contre-électrode pour dispositifs électrochromiques |
| US9261751B2 (en) | 2010-04-30 | 2016-02-16 | View, Inc. | Electrochromic devices |
| US10852613B2 (en) | 2009-03-31 | 2020-12-01 | View, Inc. | Counter electrode material for electrochromic devices |
| US10156762B2 (en) | 2009-03-31 | 2018-12-18 | View, Inc. | Counter electrode for electrochromic devices |
| US11599003B2 (en) | 2011-09-30 | 2023-03-07 | View, Inc. | Fabrication of electrochromic devices |
| US11187954B2 (en) | 2009-03-31 | 2021-11-30 | View, Inc. | Electrochromic cathode materials |
| US9664974B2 (en) | 2009-03-31 | 2017-05-30 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| PT104482A (pt) * | 2009-04-01 | 2010-10-01 | Univ Nova De Lisboa | Método de fabrico e criação de transístores de filme fino electrocrómicos de estrutura lateral ou vertical utilizando substratos vitrocerâmicos, poliméricos, metálicos ou de papel celulósico natural, sintético ou misto funcionalizados ou não funciona |
| KR101655245B1 (ko) * | 2010-03-23 | 2016-09-07 | 삼성전자 주식회사 | 전기 변색 물질 및 이를 포함하는 전기 변색 소자 |
| WO2011137104A1 (fr) * | 2010-04-30 | 2011-11-03 | Soladigm, Inc. | Dispositifs électro-chromatiques |
| KR102014040B1 (ko) * | 2010-04-30 | 2019-08-23 | 뷰, 인크. | 전기변색 디바이스 |
| US9759975B2 (en) | 2010-04-30 | 2017-09-12 | View, Inc. | Electrochromic devices |
| DE102011102235B4 (de) * | 2010-05-24 | 2015-06-18 | Industrial Technology Research Institute | Steuerbare fotovoltaische elektrochrome Vorrichtung und Modul |
| DE102010027070A1 (de) | 2010-07-13 | 2012-01-19 | Eberhard-Karls-Universität Tübingen | Gas-Sensor und Verfahren zu seiner Herstellung |
| US10802371B2 (en) | 2011-12-12 | 2020-10-13 | View, Inc. | Thin-film devices and fabrication |
| US20150168796A1 (en) * | 2012-07-23 | 2015-06-18 | Ricoh Company, Ltd. | Electrochromic device and a method for manufacturing an electrochromic device |
| CN102965096B (zh) * | 2012-11-21 | 2015-03-04 | 中国科学技术大学 | 一种紫精化合物电致变色材料及其电致变色器件 |
| KR102063776B1 (ko) * | 2012-12-17 | 2020-01-09 | 엘지이노텍 주식회사 | 전기변색 디스플레이 장치 및 그 제조 방법 |
| US9013778B2 (en) | 2013-03-06 | 2015-04-21 | Sage Electrochromics, Inc. | Laser cuts to reduce electrical leakage |
| JP6171637B2 (ja) * | 2013-07-08 | 2017-08-02 | 株式会社リコー | エレクトロクロミック調光レンズ、エレクトロクロミック調光眼鏡、及びそれらの製造方法 |
| US9152001B2 (en) * | 2013-07-25 | 2015-10-06 | Sage Electrochromics, Inc. | Electrochromic devices having improved structure for reducing current leakage across lower transparent conductor layers |
| US20150153622A1 (en) | 2013-12-03 | 2015-06-04 | Sage Electrochromics, Inc. | Methods for producing lower electrical isolation in electrochromic films |
| KR102208249B1 (ko) * | 2013-12-27 | 2021-01-26 | 엘지디스플레이 주식회사 | 유기전계발광 표시장치 및 그 제조 방법 |
| US9297998B2 (en) * | 2014-03-28 | 2016-03-29 | Amazon Technologies, Inc. | Electrode of an electrowetting device |
| US11891327B2 (en) | 2014-05-02 | 2024-02-06 | View, Inc. | Fabrication of low defectivity electrochromic devices |
| US10345671B2 (en) | 2014-09-05 | 2019-07-09 | View, Inc. | Counter electrode for electrochromic devices |
| WO2016077005A1 (fr) * | 2014-11-14 | 2016-05-19 | Heliotrope Technologies, Inc. | Dispositifs électrochromiques à nano-cristaux post-trempage |
| US9726594B2 (en) * | 2014-11-18 | 2017-08-08 | Baker Hughes Incorporated | Electrochemical sensor for monitoring under-deposit corrosion |
| CN107533267A (zh) | 2015-03-20 | 2018-01-02 | 唯景公司 | 更快速地切换低缺陷电致变色窗 |
| JP7122965B2 (ja) * | 2015-09-02 | 2022-08-22 | コンコード （エイチケー） インターナショナル エデュケーション リミテッド | 内部全反射型画像ディスプレイにおける双安定性強化 |
| CN105093770A (zh) * | 2015-09-28 | 2015-11-25 | 张健敏 | 能调节透光率的显示屏外壳及其制作方法 |
| EP3500891A4 (fr) | 2016-08-22 | 2020-03-25 | View, Inc. | Fenêtres électrochromiques à blindage électromagnétique |
| US10509291B2 (en) | 2017-02-27 | 2019-12-17 | Sage Electrochromics, Inc. | Electrical device including a substrate and a transparent conductive layer and a process of forming the same |
| KR102078403B1 (ko) * | 2017-04-27 | 2020-04-07 | 주식회사 엘지화학 | 전기변색소자 |
| US11608428B2 (en) * | 2017-06-28 | 2023-03-21 | The Texas A&M University System | Thermochromic compositions, thermochromic substrates, and related methods of making |
| US10732476B2 (en) | 2018-05-14 | 2020-08-04 | Nokia Solutions And Networks Oy | Electrochromic cell |
| CN109881198B (zh) * | 2019-04-10 | 2020-04-17 | 浙江大学 | 二氧化锡/五氧化二钒核壳结构的多色电致变色薄膜的制备方法 |
| CN110669076B (zh) * | 2019-09-27 | 2020-07-07 | 中国科学院化学研究所 | 一种双钌金属配合物及其在近红外电致变色薄膜中的应用 |
| WO2021154971A1 (fr) | 2020-01-31 | 2021-08-05 | Microchip Technology Incorporated | Affichage tête haute utilisant des éléments électrochromes |
| CN112909194B (zh) * | 2021-01-29 | 2023-02-28 | Tcl华星光电技术有限公司 | 透明显示面板 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4193670A (en) * | 1977-11-08 | 1980-03-18 | American Cyanamid Company | Electrochromic devices having protective interlayers |
| JPS6320976Y2 (fr) * | 1978-07-07 | 1988-06-10 | ||
| JPS6084531A (ja) * | 1983-10-17 | 1985-05-13 | Hitachi Maxell Ltd | エレクトロクロミツク表示素子 |
| US4645308A (en) * | 1984-12-21 | 1987-02-24 | The United States Of America As Represented By The Department Of Energy | Low voltage solid-state lateral coloration electrochromic device |
| CN1007815B (zh) * | 1985-08-07 | 1990-05-02 | 加利福尼亚大学 | 具有异硫茚结构和电致变色显示的聚合物的制备方法 |
| JP2704887B2 (ja) * | 1988-08-22 | 1998-01-26 | キヤノン株式会社 | エレクトロクロミック素子 |
| US5189549A (en) | 1990-02-26 | 1993-02-23 | Molecular Displays, Inc. | Electrochromic, electroluminescent and electrochemiluminescent displays |
| JPH04318525A (ja) * | 1991-04-17 | 1992-11-10 | Nikon Corp | 反射型エレクトロクロミック素子 |
| JPH07133341A (ja) * | 1993-11-09 | 1995-05-23 | Ykk Kk | 電解重合膜の製造方法 |
| ATE209366T1 (de) * | 1996-03-15 | 2001-12-15 | Ecole Polytech | Elektrochrome oder photoelektrochrome vorrichtung |
| DE19622600C2 (de) * | 1996-06-05 | 2001-08-02 | Fraunhofer Ges Forschung | Elektrochrome Einheit |
| US5923457A (en) * | 1997-04-02 | 1999-07-13 | Gentex Corporation | Electro-optic device including a low sheet resistance, high transmission transparent electrode |
| US6094292A (en) * | 1997-10-15 | 2000-07-25 | Trustees Of Tufts College | Electrochromic window with high reflectivity modulation |
| EP1154311A4 (fr) * | 1999-02-18 | 2007-03-28 | Nippon Mitsubishi Oil Corp | Element electrochromique |
| US7012600B2 (en) * | 1999-04-30 | 2006-03-14 | E Ink Corporation | Methods for driving bistable electro-optic displays, and apparatus for use therein |
| EP1079397A1 (fr) * | 1999-08-23 | 2001-02-28 | Agfa-Gevaert N.V. | Méthode de formation d'un motif conducteur sur un substrat |
| US20020017108A1 (en) | 1999-11-30 | 2002-02-14 | Schooley Frank W. | Portable marine air conditioner and dehumidifier |
| JP2001209078A (ja) * | 2000-01-26 | 2001-08-03 | Nippon Mitsubishi Oil Corp | エレクトロクロミック素子 |
| JP2001264823A (ja) * | 2000-03-21 | 2001-09-26 | Sharp Corp | エレクトロクロミック表示装置 |
| JPWO2002039180A1 (ja) * | 2000-11-10 | 2004-03-18 | 株式会社村上開明堂 | 固体型エレクトロクロミック素子及びその素子を用いたミラー装置並びにｃｒｔディスプレイ |
| US7030854B2 (en) * | 2001-03-13 | 2006-04-18 | E Ink Corporation | Apparatus for displaying drawings |
| CA2441172A1 (fr) | 2001-03-19 | 2002-09-26 | Dow Global Technologies Inc. | Dispositif d'affichage electrochromique a adressage matriciel |
| EP1244168A1 (fr) * | 2001-03-20 | 2002-09-25 | Francois Sugnaux | Electrode à réseau mésoporeux pour batterie |
| US7230597B2 (en) * | 2001-07-13 | 2007-06-12 | Tpo Hong Kong Holding Limited | Active matrix array devices |
-
2004
- 2004-01-30 JP JP2006502614A patent/JP4589915B2/ja not_active Expired - Fee Related
- 2004-01-30 AT AT04706771T patent/ATE333108T1/de active
- 2004-01-30 TW TW093102165A patent/TW200417280A/zh unknown
- 2004-01-30 EP EP04706771A patent/EP1593000B1/fr not_active Expired - Lifetime
- 2004-01-30 CN CNB2004800023031A patent/CN100462830C/zh not_active Expired - Fee Related
- 2004-01-30 AU AU2004208241A patent/AU2004208241B2/en not_active Ceased
- 2004-01-30 DE DE602004001508T patent/DE602004001508T2/de not_active Expired - Lifetime
- 2004-01-30 CA CA002509771A patent/CA2509771A1/fr not_active Abandoned
- 2004-01-30 EP EP06014423A patent/EP1708016B1/fr not_active Expired - Lifetime
- 2004-01-30 WO PCT/IE2004/000014 patent/WO2004068231A1/fr active IP Right Grant
- 2004-01-30 AT AT06014423T patent/ATE426187T1/de active
- 2004-01-30 US US10/543,527 patent/US7460289B2/en not_active Expired - Fee Related
- 2004-01-30 DE DE602004020114T patent/DE602004020114D1/de not_active Expired - Lifetime
- 2004-01-30 KR KR1020057013562A patent/KR100980796B1/ko not_active IP Right Cessation
- 2004-01-30 DK DK04706771T patent/DK1593000T3/da active
-
2006
- 2006-05-03 HK HK06105223A patent/HK1085274A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE333108T1 (de) | 2006-08-15 |
| CN100462830C (zh) | 2009-02-18 |
| EP1708016A2 (fr) | 2006-10-04 |
| KR100980796B1 (ko) | 2010-09-10 |
| JP2006520481A (ja) | 2006-09-07 |
| DK1593000T3 (da) | 2006-10-30 |
| DE602004001508D1 (de) | 2006-08-24 |
| KR20050105178A (ko) | 2005-11-03 |
| EP1593000A1 (fr) | 2005-11-09 |
| HK1085274A1 (en) | 2006-08-18 |
| US7460289B2 (en) | 2008-12-02 |
| US20060132885A1 (en) | 2006-06-22 |
| ATE426187T1 (de) | 2009-04-15 |
| DE602004001508T2 (de) | 2007-02-15 |
| EP1708016B1 (fr) | 2009-03-18 |
| CN1739057A (zh) | 2006-02-22 |
| AU2004208241B2 (en) | 2009-06-11 |
| DE602004020114D1 (de) | 2009-04-30 |
| WO2004068231A1 (fr) | 2004-08-12 |
| JP4589915B2 (ja) | 2010-12-01 |
| CA2509771A1 (fr) | 2004-08-12 |
| AU2004208241A1 (en) | 2004-08-12 |
| EP1708016A3 (fr) | 2007-10-31 |
| TW200417280A (en) | 2004-09-01 |
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