EP1481998A3 - Wässrige PUR-Dispersionen zur Herstellung von Beschichtungen mit Softfeel-Effekt - Google Patents

Wässrige PUR-Dispersionen zur Herstellung von Beschichtungen mit Softfeel-Effekt Download PDF

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Publication number
EP1481998A3
EP1481998A3 EP04011891A EP04011891A EP1481998A3 EP 1481998 A3 EP1481998 A3 EP 1481998A3 EP 04011891 A EP04011891 A EP 04011891A EP 04011891 A EP04011891 A EP 04011891A EP 1481998 A3 EP1481998 A3 EP 1481998A3
Authority
EP
European Patent Office
Prior art keywords
polyurethane
daltons
number average
optionally
urea resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04011891A
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English (en)
French (fr)
Other versions
EP1481998A2 (de
EP1481998B1 (de
Inventor
Thomas Dr. Münzmay
Martin Dr. Melchiors
Jürgen Dr. Meixner
Reinhard Dr. Halpaap
Torsten Dr. Pohl
Uwe Klippert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
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Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of EP1481998A2 publication Critical patent/EP1481998A2/de
Publication of EP1481998A3 publication Critical patent/EP1481998A3/de
Application granted granted Critical
Publication of EP1481998B1 publication Critical patent/EP1481998B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/283Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4202Two or more polyesters of different physical or chemical nature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6659Compounds of group C08G18/42 with compounds of group C08G18/34
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/73Polyisocyanates or polyisothiocyanates acyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2290/00Compositions for creating anti-fogging

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Die Erfindung betrifft neue Überzugsmittel auf Basis wässriger, wasserverdünnbarer Polyurethan-Dispersionen, ein Verfahren zu ihrer Herstellung und deren Verwendung zur Herstellung von Softfeel Beschichtungen mit geringen Fog- und VOC-Werten.
EP04011891A 2003-05-30 2004-05-19 Wässrige PUR-Dispersionen zur Herstellung von Beschichtungen mit Softfeel-Effekt Expired - Lifetime EP1481998B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10324306A DE10324306A1 (de) 2003-05-30 2003-05-30 Wässrige PUR-Dispersionen zur Herstellung von Beschichtungen mit Softfeel-Effekt
DE10324306 2003-05-30

Publications (3)

Publication Number Publication Date
EP1481998A2 EP1481998A2 (de) 2004-12-01
EP1481998A3 true EP1481998A3 (de) 2006-03-08
EP1481998B1 EP1481998B1 (de) 2009-09-02

Family

ID=33103627

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04011891A Expired - Lifetime EP1481998B1 (de) 2003-05-30 2004-05-19 Wässrige PUR-Dispersionen zur Herstellung von Beschichtungen mit Softfeel-Effekt

Country Status (9)

Country Link
US (1) US20040242765A1 (de)
EP (1) EP1481998B1 (de)
JP (1) JP5191624B2 (de)
KR (1) KR101045702B1 (de)
CN (1) CN100554350C (de)
AT (1) ATE441681T1 (de)
CA (1) CA2468603A1 (de)
DE (2) DE10324306A1 (de)
ES (1) ES2330329T3 (de)

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DE102004049591A1 (de) * 2004-10-12 2006-04-13 Bayer Materialscience Ag Wässrige Schaumbeschichtung mit Softfeel-Effekt
US20060100308A1 (en) * 2004-11-09 2006-05-11 Eastman Kodak Company Overcoat composition for printed images
DE102005006551A1 (de) * 2005-02-11 2006-08-24 Basf Ag Wässrige Polyurethan-Dispersionen mit geringem Gehalt an cyclischen Verbindungen
DE102005043173A1 (de) * 2005-09-09 2007-03-15 Basf Ag Polyurethandispersion, enthaltend Alkanolamine
PT2230068E (pt) * 2006-05-30 2016-06-16 Recticel Automobilsysteme Gmbh Método para a produção de um revestimento flexível e elastomérico de poliuretano
CN102558477B (zh) * 2006-05-30 2014-09-10 雷克蒂塞尔汽车配件有限公司 柔韧性弹性聚氨酯表皮层的制备方法
KR100828789B1 (ko) * 2006-07-05 2008-05-09 현대자동차주식회사 박막형 수성 소프트 질감도료
WO2008018616A1 (fr) * 2006-08-09 2008-02-14 Kansai Paint Co., Ltd. Composition de revêtement aqueuse et article revêtu
US20080108773A1 (en) * 2006-11-06 2008-05-08 Wicks Douglas A Polyurethane dispersions containing POSS nanoparticles
MX2009009346A (es) * 2007-03-02 2009-09-21 Akzo Nobel Coatings Int Bv Composicion de recubrimiento de sensacion suave transmitida por agua.
US7741402B2 (en) * 2007-03-21 2010-06-22 Rohm And Haas Company Thickener composition and method for thickening aqueous systems
DE102009033194A1 (de) * 2009-07-14 2011-01-20 Mankiewicz Gebr. & Co. (Gmbh & Co. Kg) Beschichtungsstoffzusammensetzung und deren Verwendung
US20120178825A1 (en) * 2009-09-17 2012-07-12 Bayer Materialscience Ag Cyclohexanedimethanol-based hydrophilic polyurethane urea
BR112012006812A2 (pt) * 2009-09-29 2020-08-18 Dow Global Technologies Llc mistura de polióis, processo para preparar um poliuretano, processo para preparar uma espuma rígida de poliuretano e espuma rígida de poliuretano
US20120259063A1 (en) * 2009-10-15 2012-10-11 Benecke-Kaliko Ag Use of nmp-free coatings for automotive interiors
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CN102532463B (zh) * 2011-12-26 2014-01-01 四川达威科技股份有限公司 一种皮革涂饰用水性聚氨酯及其制备方法
CN103589319B (zh) * 2013-11-08 2015-11-04 株洲市九华新材料涂装实业有限公司 一种机车内饰用聚氨酯柔感涂料及制备方法
US10822520B1 (en) * 2014-06-05 2020-11-03 The Sherwin-Williams Company Radiation polymerizable waterborne soft-feel coatings
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JP6648369B2 (ja) 2015-03-02 2020-02-14 エボニック オペレーションズ ゲーエムベーハー Vocおよびフォギング値の低い接着剤
WO2016139144A1 (de) 2015-03-02 2016-09-09 Evonik Degussa Gmbh Klebstoffe mit geringen voc und fogging-werten
CN105131805B (zh) * 2015-09-30 2018-06-08 芜湖春风新材料有限公司 一种汽车内饰水性热固型pc专用涂料及其制备方法
CN106916273B (zh) * 2015-12-28 2021-06-15 科思创德国股份有限公司 聚氨酯脲水性分散体
JP7084911B2 (ja) * 2016-07-28 2022-06-15 コベストロ、ドイチュラント、アクチエンゲゼルシャフト 低硬度のポリウレタン分散体
WO2019061019A1 (en) 2017-09-26 2019-04-04 Covestro Deutschland Ag TWO-COMPONENT SYSTEM FOR ELASTIC COATINGS
JP2021508753A (ja) * 2017-12-28 2021-03-11 コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag 水性分散液
CN111655805B (zh) 2018-01-23 2023-01-10 斯蒂潘公司 用于低voc聚氨酯应用的多元醇
CN110724448B (zh) * 2019-10-24 2022-04-05 芜湖春风新材料有限公司 一种水性双组份安全气囊盖装饰用弹性手感涂料及其制备方法及其形成的涂层
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DE2221751A1 (de) * 1972-05-04 1973-11-15 Bayer Ag Polyurethanharnstoffelastomere
EP0282072A2 (de) * 1987-03-13 1988-09-14 Kuraray Co., Ltd. Stabilisierte Poly(beta-methyl-delta-valerolacton)
DE4406159A1 (de) * 1994-02-25 1995-08-31 Bayer Ag Wäßrige Polyester-Polyurethan-Dispersionen und ihre Verwendung in Beschichtungsmitteln
EP0978549A1 (de) * 1998-08-04 2000-02-09 Vianova Resins AG Wasserverdünnbare Bindemittel für "Soft-Feel"-Lacke

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DE2314513C3 (de) * 1973-03-23 1980-08-28 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von wäßrigen Polyurethandispersionen
DE2651506C2 (de) * 1976-11-11 1986-04-30 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von in Wasser dispergierbaren Polyurethanen
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KR20040103459A (ko) 2004-12-08
EP1481998A2 (de) 2004-12-01
ES2330329T3 (es) 2009-12-09
US20040242765A1 (en) 2004-12-02
ATE441681T1 (de) 2009-09-15
EP1481998B1 (de) 2009-09-02
JP5191624B2 (ja) 2013-05-08
KR101045702B1 (ko) 2011-06-30
DE10324306A1 (de) 2004-12-16
CN1572849A (zh) 2005-02-02
CN100554350C (zh) 2009-10-28
DE502004009991D1 (de) 2009-10-15
CA2468603A1 (en) 2004-11-30
JP2004359952A (ja) 2004-12-24

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