EP1468739A1 - Broyeur agitateur à billes - Google Patents

Broyeur agitateur à billes Download PDF

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Publication number
EP1468739A1
EP1468739A1 EP04405182A EP04405182A EP1468739A1 EP 1468739 A1 EP1468739 A1 EP 1468739A1 EP 04405182 A EP04405182 A EP 04405182A EP 04405182 A EP04405182 A EP 04405182A EP 1468739 A1 EP1468739 A1 EP 1468739A1
Authority
EP
European Patent Office
Prior art keywords
ball mill
grinding
agitator ball
good
mill according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04405182A
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German (de)
English (en)
Other versions
EP1468739B1 (fr
Inventor
Martin Heinzelmann
Stefan Spornberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Willy A Bachofen AG
Original Assignee
Willy A Bachofen AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32873502&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1468739(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Willy A Bachofen AG filed Critical Willy A Bachofen AG
Priority to PL04405182T priority Critical patent/PL1468739T3/pl
Publication of EP1468739A1 publication Critical patent/EP1468739A1/fr
Application granted granted Critical
Publication of EP1468739B1 publication Critical patent/EP1468739B1/fr
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/16Mills in which a fixed container houses stirring means tumbling the charge
    • B02C17/163Stirring means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/16Mills in which a fixed container houses stirring means tumbling the charge
    • B02C17/161Arrangements for separating milling media and ground material

Definitions

  • the invention relates to a stirred ball mill with a Separator for separation of KleinstmahlMechn with a Diameter D ⁇ 0,1mm from the product.
  • Agitator ball mills for example, for crushing and dispersing solids in a liquid phase or used for the digestion of microorganisms.
  • agitator ball mills have a cylindrical, horizontal or vertical axis grinding chamber with various types Separators for separating the grinding media from Product in the product outlet area.
  • the housing of the grinding chamber of a stirred ball mill consists from one longitudinal wall and two at the two ends of the Longitudinal wall arranged end walls. It has a Feeding the ground good serving inlet and a for Discharge of the good serving good outlet.
  • In the Milling chamber is also a rotatable about the chamber axis Agitator arranged to be located in the mill To convey grinding media radially to the stirring shaft and thereby the continuously passed through the grinding chamber Good crushed by impact and shear forces or zu disperse.
  • a blockage of the outlet possibly caused Due to the tight tolerances at the good outlet, can be a striking Increase in pressure and the actual grinding and Prevent dispersing process.
  • grinding media will come out of the mill and the grinding agent Dispersion process increasingly deteriorates. moreover In this case, the millbase is contaminated with grinding media.
  • the invention is based on the object, a horizontal axis Agitator ball mill with a novel Separating member to create, not the aforementioned disadvantages and with which a good gently and evenly can be ground with KleinstmahlMechn, the one Have diameter D ⁇ 0.1 mm, without this the grinding chamber leave.
  • FIG. 1 shows a longitudinal section through a part of a horizontal grinding chamber with a separating element of the inventive type
  • FIG. 2 a shows a cross section through the separating element shown in FIG. 1
  • FIG. 2b shows a section along the line IIb of FIG. 2a
  • 3 shows a longitudinal section through a second embodiment of the invention
  • Figure 4 is a plan view of an alternative embodiment of a separating member of the inventive type.
  • the only partially shown in Figure 1 and as a whole designated 50 grinding chamber of a stirred ball mill has a housing 40 with a horizontal axis 60.
  • the Housing 40 has an elongated, substantially cylindrical Longitudinal wall 30 and two at both ends of the longitudinal wall 30 arranged end walls 35 and 36, of which the End wall 36 serving for feeding the ground material Good inlet 37 and the end wall 35 a for discharging the good serving outlet 38 has.
  • a stirrer 1 is arranged, the several, for example two, distributed along the axis 60, Paddle wheel-like impellers 2 has.
  • the axis 60th Coaxial shaft 4 of the agitator 1 is with her the end wall 36 piercing end to one in the drawing not shown drive device connected.
  • separating member 80 In the end wall 35 of the grinding chamber 50 is located a coaxial with the axis 60 arranged separating member 80, which with an external drive 18 is connected. This external Drive 18 displaces the separating member 80 in one of the agitator. 1 independent rotary motion.
  • the regrind outlet 38 leads coaxial with the axis 60 from the separator 80 for rotary feedthrough 17th
  • a seal 45 is provided in the end wall 35, which ensures that no regrind with grinding media the annular gap between separating device 80 and End wall 35 penetrates through to the outside. This seal 45 complies with the requirements for grinding media size ⁇ 0.1mm.
  • the two disks 5 arranged parallel to one another and 7 of the separating member 80 are at a predetermined distance from each other. This is done by several, around the disk center symmetrically distributed, from the disk edge inwards leading, in plan view arcuate conveyor or Wing elements 12 determined.
  • the circular disc 7 sits on the wing elements 12 and is about this with the disc. 5 detachably or permanently connected.
  • a circular cavity 8 between the discs. 5 and Figure 7 may further include a ring cage 10 with one at its end Be located outer surface mesh screen ring 6 inserted.
  • the Ring cage 10 is preferably with O-rings 11th pressed and sealed and can be either with or without Screen plate ring 6 to be mounted. The choice of the use of the Siebblechringes 6 can on the respective Product properties are adjusted.
  • This can be for example primarily products from nanotechnology, but also um Dye suspension, enamel paints, printing inks, Agrochemicals, filler suspension, video tape Coating, cosmetics, food, pharmaceutical or Act microorganisms.
  • the use of Smaller grinding media D ⁇ 0.1 mm is mainly used to Break up agglomerates and aggregates without the Primary particles are destroyed.
  • rotating separator 80 is now formed and measure that from the grinding media and the ground and / or dispersed Good formed mixture in the interspace between the two disks 5 and 7 flows, whereupon due to the centrifugal force and the different specific Density the grinding media serving for grinding the conveying elements 12 separated from the material to be ground and back into the Interior 3 of the grinding chamber 50 are conveyed.
  • the regrind itself passes through the circular cavity 8 of the Separator 80 through the Gutauslauf 38 where it Grinding chamber 50 leaves. By the rotation of the separating member 80th the product must pass through this separator overcome relative to the centrifugal force a relative pressure.
  • the peripheral speed of the separating member 80th and the radial flow velocity in the Flow channels are the determining Operating variables, the peripheral speed of the separating member 80th and the radial flow velocity in the Flow channels.
  • the peripheral speed is determined by the Speed determined.
  • the radial flow velocity results from the free cross section and the volume flow of the product through the pump.
  • the grinding chamber 51 shown in FIG. 3 corresponds essentially the grinding chamber according to FIG. 1. That is,
  • the separating element designated here by 82 is located opposite the agitator 22 on a separate drive shaft and it carries the regrind outlet 39 coaxial with the axis 61 of Separator 82 for rotary feedthrough 17.
  • the drive 28 is in arranged in this case parallel to the axis 61 and offset the the separating member 83 bearing shaft via a sub / translation in a direction independent of the agitator 22 rotational movement.
  • a sieve scraper 65 which serves, if necessary, stuck on the sieve 6 Strip off grinding media, so that no adverse Pressure increase takes place and all grinding media through the Rotational movement of the separating member 82 of the grinding chamber returned can be.
  • FIG. 4 in the form of a paddle wheel-like Separator 85 differs from the above described separating members 80 and 82 in that between the arcuate wing elements 12 additionally straight or slightly curved conveying elements 86 are provided, the extend inwards from the edge of the disc. This forms inside a secondary flow.
  • the separating members 80 and 82 optionally provided with or without straight conveying elements 86 be the conveying elements 12 and 86 either to the Slices 5 or 7 may be attached and it may be the parting organs optionally equipped with or without screen plate ring 6 his.
  • stirring elements described above numerically arbitrary with each other and / or with others Known stirrers are combined and it can the grinding chamber additionally with pressure relief valves or the like be designed to withstand any pressure fluctuations, especially to compensate for pressure increases.
  • longitudinal wall of the grinding chamber in addition of a cylindrical Sheath be wrapped, which together with her in the Cross-section circular, space bounded in the to Cooling or heating of the existing in the interior of a good Cooling or heating fluid can be introduced.

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  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Crushing And Grinding (AREA)
  • Powder Metallurgy (AREA)
EP04405182A 2003-04-15 2004-03-24 Broyeur agitateur à billes Revoked EP1468739B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL04405182T PL1468739T3 (pl) 2003-04-15 2004-03-24 Młyn kulowy z mieszadłem

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH6782003 2003-04-15
CH6782003 2003-04-15

Publications (2)

Publication Number Publication Date
EP1468739A1 true EP1468739A1 (fr) 2004-10-20
EP1468739B1 EP1468739B1 (fr) 2008-03-19

Family

ID=32873502

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04405182A Revoked EP1468739B1 (fr) 2003-04-15 2004-03-24 Broyeur agitateur à billes

Country Status (8)

Country Link
US (1) US7014134B2 (fr)
EP (1) EP1468739B1 (fr)
JP (1) JP4205620B2 (fr)
AT (1) ATE389456T1 (fr)
DE (1) DE502004006541D1 (fr)
DK (1) DK1468739T3 (fr)
ES (1) ES2304157T3 (fr)
PL (1) PL1468739T3 (fr)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2036613A2 (fr) 2007-09-13 2009-03-18 Netzsch-Feinmahltechnik GmbH Broyeur à billes à agitateur
CN102069025A (zh) * 2009-11-25 2011-05-25 威利A.巴霍芬股份公司 搅拌球磨机
US8118247B2 (en) 2009-07-06 2012-02-21 Willy A. Bachofen Ag Agitator ball mill
DE102010053484A1 (de) 2010-12-04 2012-06-06 Netzsch-Feinmahltechnik Gmbh Dynamisches Element für die Trenneinrichtung einer Rührwerkskugelmühle
WO2012055388A3 (fr) * 2010-10-27 2012-06-28 Netzsch-Feinmahltechnik Gmbh Broyeur à boulets avec agitateur
CN102794215A (zh) * 2012-08-21 2012-11-28 向小月 一种多环流研磨系统
CN102814216A (zh) * 2012-08-26 2012-12-12 向小月 双轴研磨系统
CN103056011A (zh) * 2013-01-24 2013-04-24 陈波 一种强制双向垂直环流研磨系统
CN103657801A (zh) * 2013-12-19 2014-03-26 占天义 搅拌式研磨分离器及研磨装置
EP2106859A3 (fr) * 2008-03-31 2014-05-07 Ashizawa Finetech Ltd Broyeur-mélangeur à charges broyantes
CN101869863B (zh) * 2009-04-22 2014-08-13 芦泽精美技术股份有限公司 介质搅拌式粉碎机
DE102013111762A1 (de) 2013-07-08 2015-01-08 Netzsch-Feinmahltechnik Gmbh Rührwerkskugelmühle mit Axialkanälen
EP2886198A1 (fr) * 2013-12-20 2015-06-24 NETZSCH Trockenmahltechnik GmbH Procédé de fonctionnement pour un broyeur à billes et broyeur à billes associé
FR3018807A1 (fr) * 2014-03-20 2015-09-25 Herakles Procede d'obtention de charges de cristaux d'hexanitrohexaazaisowurtzitane (cl20) de granulometrie monomodale submicronique, lesdites charges et leur utilisation comme charges d'ensemencement
WO2017000757A1 (fr) * 2015-06-29 2017-01-05 广东派勒智能纳米科技股份有限公司 Broyeur à boulets avancé à double système de séparation
CN108435341A (zh) * 2018-04-26 2018-08-24 苏州世名科技股份有限公司 用于制备颗粒分散体的研磨设备
CN110328021A (zh) * 2019-07-17 2019-10-15 北矿机电科技有限责任公司 超细磨用搅拌盘及立式搅拌装置及立式超细搅拌磨机
WO2020016363A1 (fr) 2018-07-20 2020-01-23 Total Raffinage Chimie Procédé par voie humide de récupération d'une huile produite par des microorganismes
CN111185282A (zh) * 2019-07-26 2020-05-22 湖北迈兆机械有限公司 一种球磨系统

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KR101104779B1 (ko) * 2004-03-22 2012-01-12 니폰 가야꾸 가부시끼가이샤 액정 씰 재료 및 그의 제조방법
JP4741931B2 (ja) * 2005-05-17 2011-08-10 アシザワ・ファインテック株式会社 循環型メディア撹拌ミル
WO2006131698A2 (fr) * 2005-06-08 2006-12-14 Cheshire Dispersion Company Limited Appareil de broyage
US20070040055A1 (en) * 2005-08-17 2007-02-22 Riendeau Robert D Method and apparatus for pulverizing solid materials
JP4918272B2 (ja) * 2006-04-11 2012-04-18 アシザワ・ファインテック株式会社 循環型メディア撹拌ミル
JP5046546B2 (ja) * 2006-04-24 2012-10-10 日本コークス工業株式会社 メディア攪拌型湿式分散機及び微粒子の分散方法
JP5046557B2 (ja) * 2006-05-22 2012-10-10 日本コークス工業株式会社 メディア攪拌型湿式分散機及び微粒子の分散方法
JP5159102B2 (ja) * 2006-12-14 2013-03-06 アシザワ・ファインテック株式会社 竪型のメディア攪拌ミル
JP5026819B2 (ja) * 2007-03-02 2012-09-19 日本コークス工業株式会社 メディア攪拌型湿式粉砕機及び粉砕処理方法
JP5203776B2 (ja) * 2008-03-31 2013-06-05 日本製紙株式会社 苛性化工程で製造された軽質炭酸カルシウムのスラリーの製造方法及び前記スラリーを含有する塗工液を塗工した紙
US8246831B2 (en) * 2009-02-05 2012-08-21 Mcfarland Martin Allen Digesting and continuously self-cleaning aquarium filter
CH700446A1 (de) * 2009-02-24 2010-08-31 Bachofen Willy A Ag Rührwerkskugelmühle.
DE102011010527A1 (de) 2011-02-07 2012-08-09 Lipp Mischtechnik Gmbh Rührwerkskugelmühle
WO2013015237A1 (fr) * 2011-07-28 2013-01-31 アシザワ・ファインテック株式会社 Pulvérisateur à agitation d'agent
CN102553687B (zh) * 2012-01-09 2013-08-28 山东理工大学 球石群动态分布检测系统及方法
DE102012013279A1 (de) * 2012-07-05 2014-01-09 Roland Nied Verfahren zum Betrieb einer Rührwerkskugelmühle sowie Rührwerkskugelmühle dafür
CN102921512B (zh) * 2012-11-16 2015-06-03 广西大学 卧式强化多糖高聚物改性搅拌球磨反应器
CN102974432B (zh) * 2012-12-26 2015-12-02 广州派勒机械设备有限公司 一种动态分离出料式研磨机
DE102015105103A1 (de) * 2015-04-02 2016-10-06 Netzsch-Feinmahltechnik Gmbh Verschlusssystem für den Mahlbehälter einer Zerkleinerungseinrichtung und Mahlbehälter mit einem derartigen Verschlusssystem und Zerkleinerungseinrichtung mit einem Mahlbehälter
CN105214790B (zh) * 2015-09-22 2018-06-08 广东派勒智能纳米科技股份有限公司 智能纳米动态离心旋转分离装置
EP3311922B1 (fr) * 2016-10-18 2018-12-05 Willy A. Bachofen AG Broyeur à billes à agitateur
EP3311921B1 (fr) * 2016-10-18 2018-09-26 Willy A. Bachofen AG Broyeur à billes à agitateur
DE102017201418B3 (de) * 2017-01-30 2018-06-28 Netzsch-Feinmahltechnik Gmbh Rührwerksmühle
FR3081732B1 (fr) * 2018-05-29 2020-09-11 Deasyl Sa Broyeur tridimensionnel, son procede de mise en œuvre et ses utilisations
AU2021262226A1 (en) * 2020-04-30 2022-11-10 Vectis Pty Ltd A grinding mill rotor
US11691155B2 (en) 2020-09-17 2023-07-04 U.S. Silica Company Methods and apparatus for producing nanometer scale particles utilizing an electrosterically stabilized slurry in a media mill
CN115364976B (zh) * 2022-04-19 2024-03-12 鄂尔多斯应用技术学院 一种超高压陶瓷介质材料生产系统及生产方法

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DE19510807A1 (de) * 1994-03-24 1995-09-28 Netzsch Erich Holding Rührwerksmühle
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Cited By (42)

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Publication number Priority date Publication date Assignee Title
EP2036613A2 (fr) 2007-09-13 2009-03-18 Netzsch-Feinmahltechnik GmbH Broyeur à billes à agitateur
DE102007043670A1 (de) 2007-09-13 2009-04-02 Netzsch-Feinmahltechnik Gmbh Rührwerkskugelmühle
EP2036613A3 (fr) * 2007-09-13 2009-11-25 Netzsch-Feinmahltechnik GmbH Broyeur à billes à agitateur
US7845589B2 (en) 2007-09-13 2010-12-07 Netzsch-Feinmahltechnik Gmbh Agitating ball mill
TWI410281B (zh) * 2007-09-13 2013-10-01 Netzsch Feinmahltechnik 攪拌式球磨機
EP2106859A3 (fr) * 2008-03-31 2014-05-07 Ashizawa Finetech Ltd Broyeur-mélangeur à charges broyantes
CN101869863B (zh) * 2009-04-22 2014-08-13 芦泽精美技术股份有限公司 介质搅拌式粉碎机
US8118247B2 (en) 2009-07-06 2012-02-21 Willy A. Bachofen Ag Agitator ball mill
EP2327480A1 (fr) 2009-11-25 2011-06-01 Willy A. Bachofen AG Broyeur à billes à agitateur
CN102069025B (zh) * 2009-11-25 2014-08-20 威利A.巴霍芬股份公司 搅拌球磨机
EP2327479A1 (fr) 2009-11-25 2011-06-01 Willy A. Bachofen AG Broyeur à billes à agitateur
CN102069025A (zh) * 2009-11-25 2011-05-25 威利A.巴霍芬股份公司 搅拌球磨机
WO2012055388A3 (fr) * 2010-10-27 2012-06-28 Netzsch-Feinmahltechnik Gmbh Broyeur à boulets avec agitateur
US8702023B2 (en) 2010-10-27 2014-04-22 Netzch-Feinmahltechnik GmbH Stirring ball mill
WO2012083915A2 (fr) 2010-12-04 2012-06-28 Netzsch-Feinmahltechnik Gmbh Élément dynamique conçu pour le dispositif de séparation d'un broyeur à boulets
RU2555915C2 (ru) * 2010-12-04 2015-07-10 Неч-Файнмальтехник Гмбх Динамический элемент для разделительного узла шаровой мельницы с мешалкой
US8794558B2 (en) 2010-12-04 2014-08-05 Netzsch-Feinmahltechnik Gmbh Dynamic element for the separating device of a stirring ball mill
WO2012083915A3 (fr) * 2010-12-04 2012-08-23 Netzsch-Feinmahltechnik Gmbh Élément dynamique conçu pour le dispositif de séparation d'un broyeur à boulets
DE102010053484A1 (de) 2010-12-04 2012-06-06 Netzsch-Feinmahltechnik Gmbh Dynamisches Element für die Trenneinrichtung einer Rührwerkskugelmühle
US8876028B2 (en) 2010-12-04 2014-11-04 Netzsch-Feinmahltechnik Gmbh Method for operating an agitator ball mill
CN102794215B (zh) * 2012-08-21 2016-05-11 向小月 一种多环流研磨系统
CN102794215A (zh) * 2012-08-21 2012-11-28 向小月 一种多环流研磨系统
CN102814216A (zh) * 2012-08-26 2012-12-12 向小月 双轴研磨系统
CN103056011A (zh) * 2013-01-24 2013-04-24 陈波 一种强制双向垂直环流研磨系统
CN103056011B (zh) * 2013-01-24 2016-05-11 陈波 一种强制双向垂直环流研磨系统
WO2015003676A1 (fr) 2013-07-08 2015-01-15 Netzsch-Feinmahltechnik Gmbh Broyeur à boulets à agitateur, muni de canaux axiaux
US11141737B2 (en) 2013-07-08 2021-10-12 Netzsch-Feinmahltechnik Gmbh Agitator ball mill with axial channels
DE102013111762A1 (de) 2013-07-08 2015-01-08 Netzsch-Feinmahltechnik Gmbh Rührwerkskugelmühle mit Axialkanälen
US10610871B2 (en) 2013-07-08 2020-04-07 Netzsch-Feinmahltechnik Gmbh Agitator ball mill with axial channels
CN103657801B (zh) * 2013-12-19 2016-11-23 占天义 搅拌式研磨分离器及研磨装置
CN103657801A (zh) * 2013-12-19 2014-03-26 占天义 搅拌式研磨分离器及研磨装置
CN104815726A (zh) * 2013-12-20 2015-08-05 耐驰干法研磨技术有限公司 研磨机及其研磨方法
CN104815726B (zh) * 2013-12-20 2017-05-31 耐驰干法研磨技术有限公司 研磨机及其研磨方法
EP2886198A1 (fr) * 2013-12-20 2015-06-24 NETZSCH Trockenmahltechnik GmbH Procédé de fonctionnement pour un broyeur à billes et broyeur à billes associé
FR3018807A1 (fr) * 2014-03-20 2015-09-25 Herakles Procede d'obtention de charges de cristaux d'hexanitrohexaazaisowurtzitane (cl20) de granulometrie monomodale submicronique, lesdites charges et leur utilisation comme charges d'ensemencement
WO2017000757A1 (fr) * 2015-06-29 2017-01-05 广东派勒智能纳米科技股份有限公司 Broyeur à boulets avancé à double système de séparation
CN108435341A (zh) * 2018-04-26 2018-08-24 苏州世名科技股份有限公司 用于制备颗粒分散体的研磨设备
CN108435341B (zh) * 2018-04-26 2023-11-14 苏州世名科技股份有限公司 用于制备颗粒分散体的研磨设备
WO2020016363A1 (fr) 2018-07-20 2020-01-23 Total Raffinage Chimie Procédé par voie humide de récupération d'une huile produite par des microorganismes
CN110328021A (zh) * 2019-07-17 2019-10-15 北矿机电科技有限责任公司 超细磨用搅拌盘及立式搅拌装置及立式超细搅拌磨机
CN111185282A (zh) * 2019-07-26 2020-05-22 湖北迈兆机械有限公司 一种球磨系统
CN111185282B (zh) * 2019-07-26 2023-10-27 湖北迈兆机械有限公司 一种球磨系统

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DE502004006541D1 (de) 2008-04-30
JP2004314066A (ja) 2004-11-11
US7014134B2 (en) 2006-03-21
ATE389456T1 (de) 2008-04-15
PL1468739T3 (pl) 2008-10-31
EP1468739B1 (fr) 2008-03-19
ES2304157T3 (es) 2008-09-16
DK1468739T3 (da) 2008-07-21
US20050224612A1 (en) 2005-10-13

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