EP1409632A1 - Verfahren zur herstellung einer zusammensetzung sowie diese zusammensetzung, als auch die verwendung dieser zur entfernung oder aufloesung einer verunreinigung aus einer umgebung - Google Patents

Verfahren zur herstellung einer zusammensetzung sowie diese zusammensetzung, als auch die verwendung dieser zur entfernung oder aufloesung einer verunreinigung aus einer umgebung

Info

Publication number
EP1409632A1
EP1409632A1 EP01961943A EP01961943A EP1409632A1 EP 1409632 A1 EP1409632 A1 EP 1409632A1 EP 01961943 A EP01961943 A EP 01961943A EP 01961943 A EP01961943 A EP 01961943A EP 1409632 A1 EP1409632 A1 EP 1409632A1
Authority
EP
European Patent Office
Prior art keywords
hydrogen peroxide
glycolic acid
water
weight percent
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01961943A
Other languages
English (en)
French (fr)
Other versions
EP1409632A4 (de
EP1409632B1 (de
Inventor
James E. Mcclung
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
McClung James E
Original Assignee
McClung James E
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by McClung James E filed Critical McClung James E
Publication of EP1409632A1 publication Critical patent/EP1409632A1/de
Publication of EP1409632A4 publication Critical patent/EP1409632A4/de
Application granted granted Critical
Publication of EP1409632B1 publication Critical patent/EP1409632B1/de
Priority to CY20071101329T priority Critical patent/CY1107765T1/el
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/261—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof

Definitions

  • the invention relates to a method of making a composition and a product from such
  • rollers apparatus to contain and move fluids (such as hoses and trays), and other moving
  • pesticide systems meat processing systems, poultry processing systems, dairy processing
  • the contaminants can foul such water-containing systems to such an extent that such water-
  • compositions that can be used for reducing the concentration of,
  • compositions can be difficult to use due to the difficulty in determining how much of each component of the composition should be added.
  • An object of the present invention is to provide a process for preparing a composition
  • Another object of the present invention is to provide
  • composition having desirable properties such as enhanced capabilities for reducing
  • a further object of the present invention is to provide an improved process of
  • glycolic acid also referred to as hydroxy acetic
  • Another embodiment of the present invention is a process of preparing a novel
  • composition comprising contacting hydrogen peroxide, glycolic acid, and water.
  • a novel composition of the present invention can be used for reducing the
  • Such contaminants can include Groups II- VIII of the Periodic
  • Such environments can include water-
  • Such water-containing systems can include
  • swimming pools water treating systems, drainage systems, boiler systems, chiller systems,
  • a process of preparing a composition of the present invention comprises
  • the hydrogen peroxide is generally
  • hydrogen peroxide solution generally comprises at least about 0.1 weight percent hydrogen
  • invention can be prepared by adding a stabilizing amount of water to a commercially
  • the water suitable for use in a process of the present invention is preferably a low
  • solids water generally comprising less than about 10 parts per million (ppm) dissolved solids
  • dissolved solids and most preferably about 0 ppm dissolved solids.
  • the water preferably low solids water, can be prepared by any suitable means known
  • the low solids water can be prepared by subjecting a high solids water to a treating
  • the high solids water generally comprises more dissolved solids than
  • the low solids water Generally, the high solids water comprises more than about 200 ppm of
  • water is present in a stabilizing amount which allows for the contacting of
  • stabilizing amount of water as described herein should be large enough to prevent an
  • composition from being so dilute that such resulting composition no longer has the ability to
  • composition so that such composition is effective in reducing the concentration of, preferably
  • a stabilizing amount of water preferably low solids water, is present in an
  • a stabilizing amount of water is present in an amount of at least about 60 percent by weight water based on
  • glycolic acid is preferably a glycolic acid solution comprising glycolic acid and
  • Such glycolic acid solution generally comprises at least about 1 weight percent
  • glycolic acid and at most about 15 weight percent glycolic acid, preferably at least about 1
  • weight percent glycolic acid and at most about 10 weight percent glycolic acid, and more
  • glycolic acid solution which can be used in a process of
  • the present invention can be obtained by adding low solids water as described herein to a
  • the hydrogen peroxide, glycolic acid, and water can be contacted by any suitable
  • such contacting comprises mixing utilizing any suitable
  • mixing means known in the art for mixing an aqueous solution with another aqueous solution.
  • a hydrogen peroxide solution as described herein is mixed with a glycolic
  • glycolic acid is generally at least about 1 :1 and at most about 30:1, preferably at least about 2:1 and at most about 20:1, more preferably at least about 2:1 and at most about 10:1, and
  • the temperature during contacting is at least about 0°F and at most about
  • 100°F preferably at least about 10°F and at most about 90°F, and more preferably at least
  • the pressure during contacting can be any pressure
  • the pressure is generally at least about
  • the time period of contacting can be any time period capable of providing for a
  • the time period of contacting is generally at least about 0.1
  • a process of providing a composition of the present invention can further comprise
  • isopropyl alcohol has a purity of at least about 95 percent, preferably at least about 98 percent,
  • invention can further comprise contacting with one or more components selected from the
  • esters include, but are not limited to, ethoxylated esters and the like and combinations thereof.
  • Suitable acids include, but are not limited to, acetic, sulfuric, formic, peroxyacetic, and the like and combinations thereof.
  • beta hydroxy acids include, but are not limited to, citric, lactic, maleic, and the like and
  • Such additional component(s) can be added in any amount(s) as long as such
  • amount(s) provides a composition effective in reducing the concentration of, preferably
  • composition and more preferably in an amount of at least about 0.1 weight percent based on
  • a preferred method of preparing a composition of the present invention comprises
  • glycolic acid solution prepared by contacting a 70 weight percent glycolic acid
  • composition having a pH of about 1.9 to about 3.5. Such composition is particularly suitable
  • glycolic acid solution prepared by contacting a 70 weight percent
  • glycolic acid solution with low solids water comprising less than about 1 ppm dissolved
  • composition is particularly suitable for use in reducing the concentration of, preferably
  • An additional preferred process of preparing such composition is to further contact the
  • composition with isopropyl alcohol having a purity of about 99 percent in an amount
  • a composition of the present invention generally has a pH of at least about 1.5 and at
  • a composition of the present invention generally has a specific gravity of at least
  • present invention comprises a molecule containing two carbon atoms, four hydrogen atoms,
  • a composition of the present invention prepared by a process of the present invention
  • contaminant(s) from such environment examples include, but are
  • Group II elements Group II elements, Group III elements, Group IV elements, Group V elements, Group
  • surfactants natural gums, synthetic gums, organic compounds, paper fibers, paper filters,
  • clays such as clays, sulfites, sulfates, oxides, adhesives, starches, and the like and combinations thereof.
  • Examples of a suitable environment include, but are not limited to, water-containing
  • system refers to any method, process,
  • water-containing systems refers to any water-containing systems.
  • water-containing systems refers to any water-containing systems.
  • food processing systems refers to any method, process, apparatus, components, and
  • printing systems refers to any method, process, apparatus, components, and the like and combinations thereof known in the art related in any
  • suitable water-containing systems include, but are not limited to,
  • swimming pools water treating systems, drainage systems, boiler systems, chiller systems,
  • composition of the present invention can be contacted with one or more
  • the contacting condition also referred to as the
  • contaminant contacting condition which comprises a concentration of a composition as
  • period can be any contacting condition effective in reducing the concentration of, preferably
  • contacting condition will generally depend on the type and concentration of contaminant and
  • the contacting condition will generally have an increased
  • one or more contaminants is increased compared to the contacting condition necessary when
  • composition of the present invention is used to maintain the reduction in concentration of
  • liquid medium such as the water-containing
  • the concentration of composition is generally at least about 0.1 part
  • composition by volume per million parts environment (ppmv) and at most about 25 volume
  • the concentration of composition is generally at least about 0.1 part
  • composition by weight per million parts environment (ppm) and at most about 20 weight
  • the contacting temperature also referred to as the contaminant contacting
  • temperature is at least about 50°F and at most about 200°F, preferably at least about 70°F
  • the contacting pressure also referred to as the contaminant
  • contacting pressure is generally at least about atmospheric and at most about 100 pounds per
  • the contacting time also referred to as psia
  • the contaminant contacting time is generally at least about 0.1 minute and at most about
  • composition of the present invention examples include, but are
  • a composition of the present invention can be used as a descalant, biocide, slimicide,
  • flocculant, and the like and combinations thereof to reduce the concentration of, preferably remove or dissolve, scale, algae, and the like and combinations thereof from machinery and
  • composition of the present invention can be used as a descalant, biocide and/or
  • algaecide to reduce the concentration of, preferably remove or dissolve, various contaminants
  • the present invention can be used as a calcium and surfactant remover to reduce the
  • composition of the present invention can be used to reduce the
  • composition of the present invention can also be used as a
  • mbber roller rinse to reduce the concentration of, preferably remove or dissolve, organic
  • a composition of the present invention can be used for reducing the concentration of,
  • a contaminant such as scale, algae, fungi, bacteria,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be any composition of the present invention.
  • adhesives can thus provide for easy removal of such glues and adhesives.
  • a composition of the present invention can be used to treat anilox rolls, particularly
  • composition of the present invention provides
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used in waste sludge treatment
  • a composition of the present invention can be used as an industrial biocide treatment
  • a composition of the present invention can be used to enhance the bleaching
  • a composition of the present invention can be used in fish farming and agricultural
  • Such agricultural processes include, but are not
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used to reduce the concentration of,
  • a composition of the present invention can be used as an additive in various products
  • a composition of the present invention can be used to reduce the concentration of,
  • composition of the present invention is used to reduce the concentration
  • a composition of the invention preferably remove or dissolve, contaminants from printing systems.
  • present invention can be used in addition to, or preferably as an alternative to, various
  • composition ofthe present invention is used as a sanitizer, fungicide,
  • algaecide and the like and combinations thereof to reduce the concentration of, preferably
  • compositions ofthe present invention are used as a sanitizer, fungicide, and
  • algaecide and the like and combinations thereof to reduce the concentration of, preferably
  • composition ofthe present invention can be used in addition to, or preferably as an alternative
  • This example illustrates a preparation of a composition ofthe present invention.
  • a 55-gallon quantity of a composition of the present invention was prepared by
  • glycolic acid solution which had been prepared by contacting 0.825 gallons of approximately
  • glycolic acid solution obtained from DuPont Chemical, Wilmington,
  • composition A having a pH
  • composition A as described herein to reduce the concentration of, preferably remove or
  • composition A was then applied directly to the glue residue using a trigger sprayer
  • composition A as described herein to remove organic substances and mineral residue from
  • PCA located in Waco, Texas. Such equipment had been used for several years.
  • composition A was sprayed directly onto the surface of the anilox
  • anilox roll cells having a concentration of 145 cells per linear inch of anilox roll.
  • Composition A appeared to decompose the bonded minerals and deposits, allowing such bonded minerals and deposits to be removed by washing with normal
  • composition A allowed for the anilox equipment to be cleaned on
  • the second method of applying Composition A was by adding Composition A to the
  • composition A A is a mixture of ingredients that were utilized, but had only cleaned the surface ofthe anilox cells.
  • This example illustrates another preparation of a composition ofthe present invention.
  • a 55-gallon quantity of a composition of the present invention was prepared by
  • glycolic acid solution which had been prepared by contacting 1.65 gallons of 70 weight
  • glycolic acid solution obtained from DuPont Chemical, Wilmington, Delaware, as a
  • composition B having a pH of
  • composition of the present invention illustrates a use of a composition of the present invention (Composition 1)
  • a printing press was obtained from Rock Tenn Company, Waxahachie, Texas, and
  • a Man Roland fountain solution recirculating system also referred to as a
  • dampening system which comprised a blender, chiller, and recirculating unit containing an
  • mineral substance residue such as mineral deposits consisting of calcium and lime deposits
  • hair algae which were white, green,
  • press recirculating systems included products comprising a mixture of sodium hydroxide,
  • glycol ethers and various biocides, such as those sold by various chemical manufacturers,
  • composition B was poured directly, in one-pint quantities, into each of
  • composition B contains
  • Composition B The recirculating system was then recharged with a standard fountain solution having
  • startup recovery time was about 2 to 3 sheets. It is believed that the better
  • hydroxide hydroxide, glycol ethers and biocides, with some of these products containing foaming agents
  • Composition B has a similar residual pH, use of Composition B provides a direct benefit to
  • composition of the present invention illustrates a use of a composition of the present invention (Composition 1)
  • the test site consisted of a swimming pool which contained 25,000 gallons of water
  • the swimming pool which was substantially free of chlorine and other chemical substances.
  • the surface areas of the pool under water were covered with a green algae
  • the filter media contained in the swimming pool filtration system was diametaceous earth.
  • the pH ofthe water was 7.2 and the temperature ofthe water was about 78°F.
  • Composition B by pouring Composition B at a steady rate into the pool from a plastic bucket while walking
  • the pool water remained uncovered, dormant, and was not circulated for two weeks.
  • the dissolved oxygen (DO) was 106 parts per million (ppm)
  • composition ofthe present invention is a composition ofthe present invention.
  • Test site 1 consisted of an outdoor water garden comprising a circular-
  • the tank also contained soil, rock, several bricks, and 36
  • Composition B added to the tank by pouring Composition B directly from a plastic bottle into the water at
  • the temperature of the water during addition was about 78°F.
  • Test site 2 consisted of a standard 29-gallon aquarium containing six gallons of
  • the pH was 8.0.
  • the growth medium used in the tank included a General Electric
  • Composition B was added in an amount of 100 parts Composition B by weight per
  • oxygen level was 106 ppm.
  • the dissolved oxygen level was about 44 ppm and an
  • the dissolved oxygen was 44 ppm.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paper (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Cleaning Or Drying Semiconductors (AREA)
EP01961943A 2000-08-04 2001-08-03 Verfahren zur herstellung einer zusammensetzung sowie diese zusammensetzung, als auch die verwendung dieser zur entfernung oder aufloesung einer verunreinigung aus einer umgebung Expired - Lifetime EP1409632B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CY20071101329T CY1107765T1 (el) 2000-08-04 2007-10-15 Μεθοδος για τη δημιουργια μιας συνθεσης, ενα προϊον απο μια τετοια μεθοδο, και η χρηση αυτου στην αφαιρεση ή τη διαλυση ενος μολυσματος απο ενα περιβαλλον

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22306400P 2000-08-04 2000-08-04
US223064P 2000-08-04
PCT/US2001/024775 WO2002012428A1 (en) 2000-08-04 2001-08-03 Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP06025103 Division 2006-12-05

Publications (3)

Publication Number Publication Date
EP1409632A1 true EP1409632A1 (de) 2004-04-21
EP1409632A4 EP1409632A4 (de) 2004-08-25
EP1409632B1 EP1409632B1 (de) 2007-07-18

Family

ID=22834863

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01961943A Expired - Lifetime EP1409632B1 (de) 2000-08-04 2001-08-03 Verfahren zur herstellung einer zusammensetzung sowie diese zusammensetzung, als auch die verwendung dieser zur entfernung oder aufloesung einer verunreinigung aus einer umgebung

Country Status (18)

Country Link
EP (1) EP1409632B1 (de)
JP (2) JP5614912B2 (de)
CN (1) CN1261555C (de)
AT (1) ATE367431T1 (de)
AU (1) AU8316501A (de)
BR (1) BR0113031B1 (de)
CA (1) CA2417927C (de)
CY (1) CY1107765T1 (de)
DE (1) DE60129477T2 (de)
DK (1) DK1409632T3 (de)
ES (1) ES2288980T3 (de)
IL (2) IL154269A0 (de)
MX (1) MXPA03001038A (de)
NZ (2) NZ545460A (de)
PL (1) PL199174B1 (de)
PT (1) PT1409632E (de)
WO (1) WO2002012428A1 (de)
ZA (1) ZA200300973B (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7029588B2 (en) * 2003-03-19 2006-04-18 Samuel Rupert Owens Oxidizing solution and process for contaminants
US8398781B2 (en) * 2004-08-27 2013-03-19 Ecolab Usa Inc. Methods for cleaning industrial equipment with pre-treatment
GEP20237469B (en) * 2020-11-10 2023-02-10 Dzala Llc Novel compositions for neutralizing toxic effects of hydrogen peroxide in living cells or tissues
DE102021129678A1 (de) 2021-11-15 2023-05-17 Knieler & Team Gmbh Gebrauchsfertige Wässrige Desinfektionsmittelzusammensetzung

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2720441A (en) * 1953-09-21 1955-10-11 Du Pont Peroxygen bleaching of nylon
US4609475A (en) * 1984-02-24 1986-09-02 Halliburton Company Method of improving the permeability of a subterranean formation by removal of polymeric materials therefrom
DE4026806A1 (de) * 1990-08-24 1992-02-27 Henkel Kgaa Verfahren zum reinigen von teppichen
EP0540515B1 (de) * 1990-07-23 1995-02-01 Ecolab Inc. Peroxycarbonsäuregenerator
EP0659876A2 (de) * 1993-12-24 1995-06-28 The Procter & Gamble Company Reinigungszusatzmittel
US5567444A (en) * 1993-08-30 1996-10-22 Ecolab Inc. Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface
US5674538A (en) * 1993-03-17 1997-10-07 Ecolab Inc. Process for inhibition of microbial growth in aqueous food transport or process streams
US5958984A (en) * 1996-10-10 1999-09-28 Devillez; Richard L. Method and composition for skin treatment

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3397383B2 (ja) * 1992-10-28 2003-04-14 花王株式会社 液体漂白洗浄剤組成物
GB9302441D0 (en) * 1993-02-08 1993-03-24 Warwick Int Group Oxidising agents
US5961736A (en) * 1993-04-05 1999-10-05 Active Environmental Technologies, Inc. Method for removal of contaminants from surfaces
NZ260144A (en) * 1993-04-12 1995-10-26 Colgate Palmolive Co Cleaning composition; contains three liquid phases which merge at a tricritical point; use for removing tar or grease from articles
US5759975A (en) * 1996-08-26 1998-06-02 Gage Products Company Paint line cleaner
JPH115995A (ja) * 1997-04-21 1999-01-12 Lion Corp 液体酸素系漂白剤組成物
JP3370571B2 (ja) * 1997-09-03 2003-01-27 クリーンケミカル株式会社 医療機器用消毒洗浄剤と消毒洗浄方法
JPH1180794A (ja) * 1997-09-08 1999-03-26 Kao Corp 液体漂白剤組成物
JP3766746B2 (ja) * 1997-12-24 2006-04-19 ライオン株式会社 液体漂白剤組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2720441A (en) * 1953-09-21 1955-10-11 Du Pont Peroxygen bleaching of nylon
US4609475A (en) * 1984-02-24 1986-09-02 Halliburton Company Method of improving the permeability of a subterranean formation by removal of polymeric materials therefrom
EP0540515B1 (de) * 1990-07-23 1995-02-01 Ecolab Inc. Peroxycarbonsäuregenerator
DE4026806A1 (de) * 1990-08-24 1992-02-27 Henkel Kgaa Verfahren zum reinigen von teppichen
US5674538A (en) * 1993-03-17 1997-10-07 Ecolab Inc. Process for inhibition of microbial growth in aqueous food transport or process streams
US5567444A (en) * 1993-08-30 1996-10-22 Ecolab Inc. Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface
EP0659876A2 (de) * 1993-12-24 1995-06-28 The Procter & Gamble Company Reinigungszusatzmittel
US5958984A (en) * 1996-10-10 1999-09-28 Devillez; Richard L. Method and composition for skin treatment

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KIRK OTHMER: "ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY 4.TH ED VOL.18" 1996, WILEY INTERSCIENCE , NEW YORK * page 268 - page 272 * *
See also references of WO0212428A1 *

Also Published As

Publication number Publication date
JP5614912B2 (ja) 2014-10-29
CN1447852A (zh) 2003-10-08
DE60129477T2 (de) 2008-02-14
CA2417927C (en) 2012-05-22
EP1409632A4 (de) 2004-08-25
JP5976731B2 (ja) 2016-08-24
CN1261555C (zh) 2006-06-28
CA2417927A1 (en) 2002-02-14
NZ545460A (en) 2008-07-31
PL366164A1 (en) 2005-01-24
ATE367431T1 (de) 2007-08-15
JP2014224265A (ja) 2014-12-04
BR0113031A (pt) 2004-11-09
AU2001283165B2 (en) 2006-10-26
WO2002012428A1 (en) 2002-02-14
CY1107765T1 (el) 2013-04-18
MXPA03001038A (es) 2004-09-10
BR0113031B1 (pt) 2012-01-24
ZA200300973B (en) 2004-07-28
PL199174B1 (pl) 2008-08-29
EP1409632B1 (de) 2007-07-18
JP2004519529A (ja) 2004-07-02
IL154269A0 (en) 2003-09-17
AU8316501A (en) 2002-02-18
ES2288980T3 (es) 2008-02-01
NZ524399A (en) 2006-03-31
DK1409632T3 (da) 2007-11-12
DE60129477D1 (de) 2007-08-30
IL154269A (en) 2007-03-08
PT1409632E (pt) 2007-10-11

Similar Documents

Publication Publication Date Title
US8524647B2 (en) Method of making a composition and the uses thereof in removing or dissolving a contaminant from an environment
US7501388B2 (en) Method of using a composition for disinfection and/or sterilization
CA2321752C (en) Solid tcmtb formulations
JP5976731B2 (ja) 組成物の製造方法、該方法による製造物、および環境からの汚染物質の除去または分解におけるその使用
CA2642512A1 (en) Method and composition for removing biological fouling from surfaces in contact with water
CA2705589A1 (en) Method and composition for removing contamination from surfaces in contact with water
AU741710B2 (en) Methods and compositions for controlling biofouling using sulfamic acids
AU2001283165B8 (en) Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment
AU2001283165A1 (en) Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment
CN101096828B (zh) 树脂粘稠物控制剂以及树脂粘稠物控制方法
JP4692788B2 (ja) オフセット印刷で使用する湿し水にナノバブルを含ませる印刷方法
US5542981A (en) Process for removing mineral deposits from lagoon recycle lines
US20060000495A1 (en) Novel methods and compositions for remediating submerged deposits
AU2003204716B2 (en) Solid TCMTB Formulations
Singh et al. Cleaning and disinfection in the brewing industry
JP2010095694A (ja) 洗浄剤
BRPI1102485A2 (pt) Composição e processo de higienização de reservatório de água
CZ1682U1 (cs) Alkalický čisticí a dezinfekční prostředek

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20030225

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

A4 Supplementary search report drawn up and despatched

Effective date: 20040708

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 60129477

Country of ref document: DE

Date of ref document: 20070830

Kind code of ref document: P

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20070928

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: BRAUNPAT BRAUN EDER AG

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: GR

Ref legal event code: EP

Ref document number: 20070403085

Country of ref document: GR

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2288980

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20080421

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 60129477

Country of ref document: DE

Representative=s name: SSM SANDMAIR PATENTANWAELTE RECHTSANWALT PARTN, DE

Ref country code: DE

Ref legal event code: R082

Ref document number: 60129477

Country of ref document: DE

Representative=s name: SCHWABE SANDMAIR MARX PATENTANWAELTE RECHTSANW, DE

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 16

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 17

REG Reference to a national code

Ref country code: CH

Ref legal event code: PCAR

Free format text: NEW ADDRESS: HOLEESTRASSE 87, 4054 BASEL (CH)

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 20180821

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20180823

Year of fee payment: 18

Ref country code: IE

Payment date: 20180828

Year of fee payment: 18

Ref country code: IT

Payment date: 20180830

Year of fee payment: 18

Ref country code: FR

Payment date: 20180827

Year of fee payment: 18

Ref country code: ES

Payment date: 20180921

Year of fee payment: 18

Ref country code: NL

Payment date: 20180821

Year of fee payment: 18

Ref country code: MC

Payment date: 20180814

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20180821

Year of fee payment: 18

Ref country code: FI

Payment date: 20180822

Year of fee payment: 18

Ref country code: SE

Payment date: 20180823

Year of fee payment: 18

Ref country code: DK

Payment date: 20180823

Year of fee payment: 18

Ref country code: AT

Payment date: 20180822

Year of fee payment: 18

Ref country code: TR

Payment date: 20180801

Year of fee payment: 18

Ref country code: CH

Payment date: 20180822

Year of fee payment: 18

Ref country code: GB

Payment date: 20180822

Year of fee payment: 18

Ref country code: GR

Payment date: 20180813

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20180720

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CY

Payment date: 20180723

Year of fee payment: 18

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 60129477

Country of ref document: DE

REG Reference to a national code

Ref country code: FI

Ref legal event code: MAE

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20190831

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20190901

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 367431

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190803

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20190803

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190804

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200305

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200203

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190902

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20190831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200303

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190901

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190831

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20210105

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190804

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190803