CA2417927A1 - Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment - Google Patents

Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment Download PDF

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Publication number
CA2417927A1
CA2417927A1 CA002417927A CA2417927A CA2417927A1 CA 2417927 A1 CA2417927 A1 CA 2417927A1 CA 002417927 A CA002417927 A CA 002417927A CA 2417927 A CA2417927 A CA 2417927A CA 2417927 A1 CA2417927 A1 CA 2417927A1
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Canada
Prior art keywords
hydrogen peroxide
glycolic acid
water
weight percent
systems
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002417927A
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French (fr)
Other versions
CA2417927C (en
Inventor
James E. Mcclung
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MCCLUNG JAMES
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MCCLUNG JAMES
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Publication date
Application filed by MCCLUNG JAMES filed Critical MCCLUNG JAMES
Publication of CA2417927A1 publication Critical patent/CA2417927A1/en
Application granted granted Critical
Publication of CA2417927C publication Critical patent/CA2417927C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paper (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Cleaning Or Drying Semiconductors (AREA)

Abstract

A composition which is effective in removing a wide variety of contaminants, such as organic compounds, from a wide variety of environments, such as printing systems, is provided. A process of preparing such composition includes contacting hydrogen peroxide, glycolic acid, and water. The process can additionally include contacting with one or more additional components such as isopropyl alcohol.

Claims (44)

1. A process of producing a composition comprising contacting hydrogen peroxide, glycolic acid, and water wherein said water is present in an amount of least about 50 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water and at most about 99.9 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water.
2. The process according to claim 1 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 1:1 and at most about 30:1.
3. The process according to claim 1 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 2:1 and at most about 20:1.
4. The process according to claim 1 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 2:1 and at most about 10:1.
5. The process according to claim 1 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 0.1 weight percent said hydrogen peroxide and at most about 20 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water and wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 15 weight percent said glycolic acid.
6. The process according to claim 1 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 0.5 weight percent said hydrogen peroxide and at most about 15 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 10 weight percent said glycolic acid.
7. The process according to claim 1 further comprising contacting with isopropyl alcohol.
8. The process according to claim 7 wherein said isopropyl alcohol has a purity of at least about 99 percent.
9. The process according to claim 2 wherein said water is present in an amount of least about 60 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water and at most about 97 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water.
10. The process according to claim 1 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 1 weight percent said hydrogen peroxide and at most about 15 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water and wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 5 weight percent said glycolic acid.
11. The process according to claim 1 wherein said water is present in an amount of least about 70 weight percent based on the total weight of said hydrogen peroxide, glycolic acid and water and at most about 95 weight percent based on the total weight of said hydrogen peroxide, glycolic acid and water.
12. The process according to claim 1 further comprising contacting with a component selected from the group consisting of potassium monopersulfate, silver, acids, esters, alcohols, alpha hydroxy acids, beta hydroxy acids, and combinations thereof.
13. The process according to claim 12 wherein said acids are selected from the group consisting of acetic, sulfuric, formic, peroxyacetic, and combinations thereof.
14. The process according to claim 12 wherein said alpha hydroxy and beta hydroxy acids are selected from the group consisting of citric, lactic, maleic, and combinations thereof.
15. The process according to claim 1 wherein said composition has a pH of at least about 1.5 and at most about 4.5.
16. The process according to claim 1 wherein said composition has a specific gravity of at least about 1.0 and at most about 1.5.
17. A composition prepared by the process of contacting hydrogen peroxide, glycolic acid, and water wherein said water is present in an amount of least about 50 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water and at most about 99.9 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water.
18. The composition according to claim 17 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 1:1 and at most about 30:1.
19. The composition according to claim 17 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 2:1 and at most about 20:1.
20. The composition according to claim 17 wherein the weight ratio of said hydrogen peroxide to said glycolic acid is at least about 2:1 and at most about 10:1.
21. The composition according to claim 17 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 0.1 weight percent said hydrogen peroxide and at most about 20 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water and wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 15 weight percent said glycolic acid.
22. The composition according to claim 17 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 0.5 weight percent said hydrogen peroxide and at most about 15 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 10 weight percent said glycolic acid.
23. The composition according to claim 17 wherein the process further comprises contacting with isopropyl alcohol.
24. The composition according to claim 23 wherein said isopropyl alcohol has a purity of at least about 99 percent.
25. The composition according to claim 18 wherein said water is present in an amount of least about 60 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water and at most about 97 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water.
26. The composition according to claim 17 wherein said hydrogen peroxide is present as a hydrogen peroxide solution of said hydrogen peroxide and said water and wherein said hydrogen peroxide solution comprises at least about 1 weight percent said hydrogen peroxide and at most about 15 weight percent said hydrogen peroxide, and further wherein said glycolic acid is present as a glycolic acid solution of said glycolic acid and said water and wherein said glycolic acid solution comprises at least about 1 weight percent said glycolic acid and at most about 5 weight percent said glycolic acid.
27. The composition according to claim 17 wherein said water is present in an amount of least about 70 weight percent based on the total weight of said hydrogen peroxide, glycolic acid and water and at most about 95 weight percent based on the total weight of said hydrogen peroxide, glycolic acid and water.
28. The composition according to claim 17 wherein the process further comprises contacting with a component selected from the group consisting of potassium monopersulfate, silver, acids, esters, alcohols, alpha hydroxy acids, beta hydroxy acids, and combinations thereof.
29. The composition according to claim 28 wherein said acids are selected from the group consisting of acetic, sulfuric, formic, peroxyacetic, and combinations thereof.
30. The composition according to claim 28 wherein said alpha hydroxy and beta hydroxy acids are selected from the group consisting of citric, lactic, maleic, and combinations thereof.
31. The composition according to claim 17 wherein said composition has a pH of at least about 1.5 and at most about 4.5.
32. The composition according to claim 17 wherein said composition has a specific gravity of at least about 1.0 and at most about 1.5.
33. A composition comprising a molecule consisting of two carbon atoms, four hydrogen atoms, and four oxygen atoms.
34. A composition according to claim 33 wherein two of said four hydrogen atoms and two of said four oxygen atoms are present as hydroxyl groups.
35. A process of removing or dissolving a contaminant from an environment comprising:
selecting a composition of hydrogen peroxide, glycolic acid, and water, wherein said water is present in an amount of least about 50 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water and at most about 99.9 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water to provide a composition and contacting said contaminant with a concentration of said composition, wherein said concentration is effective in removing at some of said contaminant from said environment.
36. A process according to claim 35 wherein said contaminant is selected from the group consisting of Group II elements, Group III elements, Group IV elements, Group V
elements, Group VI elements, Group VII elements, Group VIII elements, algae, fungi, bacteria, surfactants, natural gums, synthetic gums, organic compounds, paper fibers, paper filters, clays, sulfites, sulfates, oxides, adhesives, starches, and combinations thereof.
37. A process according to claim 35 wherein said environment is selected from the group consisting of water-containing systems, paper producing systems, pulp producing systems, printing systems, packaging systems, flexographic systems, food processing systems, bleaching systems, metallurgy systems, acid washing systems, veterinary product systems, pesticide systems, meat processing systems, poultry processing systems, dairy processing systems, sanitizing systems, and combinations thereof.
38. A process according to claim 37 wherein said water-containing systems are selected from the group consisting of swimming pools, water treating systems, drainage systems, boiler systems, chiller systems, sewage treating systems, irrigation systems, agricultural systems, cooling tower systems, and combinations thereof.
39. A process according to claim 35 wherein said contaminant comprises algae and said environment comprises a water-containing system.
40. A process according to claim 39 wherein said water-containing system comprises a swimming pool.
41. A process according to claim 35 wherein said contaminant comprises a Group II element and said environment comprises a printing system.
42. A process according to claim 35 wherein said contaminant comprises a Group II element and said environment comprises a packaging system.
43. A process according to claim 35 wherein said contaminant comprises a starch and said environment comprises a packaging system.
44. A process of producing a composition comprising contacting hydrogen peroxide, glycolic acid, and water wherein said water is present in an amount of least about 50 weight percent based on the total weight of said hydrogen peroxide, glycolic acid, and water.
CA2417927A 2000-08-04 2001-08-03 Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment Expired - Fee Related CA2417927C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22306400P 2000-08-04 2000-08-04
US60/223,064 2000-08-04
PCT/US2001/024775 WO2002012428A1 (en) 2000-08-04 2001-08-03 Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment

Publications (2)

Publication Number Publication Date
CA2417927A1 true CA2417927A1 (en) 2002-02-14
CA2417927C CA2417927C (en) 2012-05-22

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Family Applications (1)

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CA2417927A Expired - Fee Related CA2417927C (en) 2000-08-04 2001-08-03 Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment

Country Status (18)

Country Link
EP (1) EP1409632B1 (en)
JP (2) JP5614912B2 (en)
CN (1) CN1261555C (en)
AT (1) ATE367431T1 (en)
AU (1) AU8316501A (en)
BR (1) BR0113031B1 (en)
CA (1) CA2417927C (en)
CY (1) CY1107765T1 (en)
DE (1) DE60129477T2 (en)
DK (1) DK1409632T3 (en)
ES (1) ES2288980T3 (en)
IL (2) IL154269A0 (en)
MX (1) MXPA03001038A (en)
NZ (2) NZ524399A (en)
PL (1) PL199174B1 (en)
PT (1) PT1409632E (en)
WO (1) WO2002012428A1 (en)
ZA (1) ZA200300973B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7029588B2 (en) * 2003-03-19 2006-04-18 Samuel Rupert Owens Oxidizing solution and process for contaminants
US8398781B2 (en) * 2004-08-27 2013-03-19 Ecolab Usa Inc. Methods for cleaning industrial equipment with pre-treatment
GEP20237469B (en) * 2020-11-10 2023-02-10 Dzala Llc Novel compositions for neutralizing toxic effects of hydrogen peroxide in living cells or tissues
DE102021129678A1 (en) 2021-11-15 2023-05-17 Knieler & Team Gmbh Ready-to-use aqueous disinfectant composition

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US2720441A (en) * 1953-09-21 1955-10-11 Du Pont Peroxygen bleaching of nylon
US4609475A (en) * 1984-02-24 1986-09-02 Halliburton Company Method of improving the permeability of a subterranean formation by removal of polymeric materials therefrom
US5122538A (en) * 1990-07-23 1992-06-16 Ecolab Inc. Peroxy acid generator
DE4026806A1 (en) * 1990-08-24 1992-02-27 Henkel Kgaa Cleaning carpet by impregnation with aq. soln. - contg. solid inorganic peroxide, activator for peroxide, and surfactant
JP3397383B2 (en) * 1992-10-28 2003-04-14 花王株式会社 Liquid bleaching detergent composition
GB9302441D0 (en) * 1993-02-08 1993-03-24 Warwick Int Group Oxidising agents
US5409713A (en) * 1993-03-17 1995-04-25 Ecolab Inc. Process for inhibition of microbial growth in aqueous transport streams
US5961736A (en) * 1993-04-05 1999-10-05 Active Environmental Technologies, Inc. Method for removal of contaminants from surfaces
NZ260144A (en) * 1993-04-12 1995-10-26 Colgate Palmolive Co Cleaning composition; contains three liquid phases which merge at a tricritical point; use for removing tar or grease from articles
US5567444A (en) * 1993-08-30 1996-10-22 Ecolab Inc. Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface
EP0659876A3 (en) * 1993-12-24 1996-12-04 Procter & Gamble Detergent additive composition.
US5759975A (en) * 1996-08-26 1998-06-02 Gage Products Company Paint line cleaner
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JPH115995A (en) * 1997-04-21 1999-01-12 Lion Corp Liquid oxygenic bleaching agent composition
JP3370571B2 (en) * 1997-09-03 2003-01-27 クリーンケミカル株式会社 Disinfectant cleaning agents for medical equipment and disinfecting cleaning methods
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JP3766746B2 (en) * 1997-12-24 2006-04-19 ライオン株式会社 Liquid bleach composition

Also Published As

Publication number Publication date
JP2004519529A (en) 2004-07-02
NZ524399A (en) 2006-03-31
AU2001283165B2 (en) 2006-10-26
CA2417927C (en) 2012-05-22
JP2014224265A (en) 2014-12-04
AU8316501A (en) 2002-02-18
EP1409632A1 (en) 2004-04-21
BR0113031A (en) 2004-11-09
NZ545460A (en) 2008-07-31
DK1409632T3 (en) 2007-11-12
CY1107765T1 (en) 2013-04-18
ZA200300973B (en) 2004-07-28
MXPA03001038A (en) 2004-09-10
BR0113031B1 (en) 2012-01-24
IL154269A0 (en) 2003-09-17
JP5614912B2 (en) 2014-10-29
ATE367431T1 (en) 2007-08-15
JP5976731B2 (en) 2016-08-24
PT1409632E (en) 2007-10-11
PL366164A1 (en) 2005-01-24
EP1409632B1 (en) 2007-07-18
DE60129477T2 (en) 2008-02-14
WO2002012428A1 (en) 2002-02-14
ES2288980T3 (en) 2008-02-01
PL199174B1 (en) 2008-08-29
IL154269A (en) 2007-03-08
CN1261555C (en) 2006-06-28
EP1409632A4 (en) 2004-08-25
DE60129477D1 (en) 2007-08-30
CN1447852A (en) 2003-10-08

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FZDC Discontinued application reinstated

Effective date: 20110517

MKLA Lapsed

Effective date: 20200831