CN100424159C - Natural highly effective environmental protection type cleaning agent and its making method - Google Patents

Natural highly effective environmental protection type cleaning agent and its making method Download PDF

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Publication number
CN100424159C
CN100424159C CNB031501532A CN03150153A CN100424159C CN 100424159 C CN100424159 C CN 100424159C CN B031501532 A CNB031501532 A CN B031501532A CN 03150153 A CN03150153 A CN 03150153A CN 100424159 C CN100424159 C CN 100424159C
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Prior art keywords
water
extract
radish
radish seed
composition
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CN1570057A (en
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梁浩东
黄小华
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Huang Xiaohua
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Abstract

The present invention discloses a natural, highly-effective and environment protection type detergent and a production method thereof. The present invention is characterized in that the detergent comprises the components of the following weight percentage: 0.2 to 4% of lucid asparagus extract, 0.5 to 5% of radish seed extract, 8 to 15% of coconut oil, 0.3 to 0.5% of citric acid, 35.9 to 40.5% of sodium carbonate, 4 to 6% of zeolite, 0.3 to 3% of alkali protease, 1 to 5% of plant cellulase, 7 to 10% of cellulose stuffing and water as the rest, wherein the lucid asparagus extract and the radish seed extract are water-soluble substances obtained by adopting a carbon dioxide supercritical extraction method, and the radish seed extract is selected from mixtures of the extract of optional one kind or more kinds of white radish seeds, carrot seeds, green turnip seeds and red radish seeds. The detergent also comprises 0.8 to 7 wt% of sea salt water (containing 7 to 9 wt% of NaCl and 200 to 400 ppm of Cl and O per liter).

Description

Natural environmental-protective cleaning detergent and production method thereof
Technical field
The present invention relates to natural environmental-protective cleaning detergent and production method thereof.
Background technology
In the prior art, people are extensive use of synthetic detergent, although at the aspects such as consumption of washing effect and washing composition, synthetic detergent has certain advantage,, aspects such as security with regard to washing, synthetic detergent but has obvious defects, in recent years, it is found that, the abuse of synthetic detergent causes the hardening of pollution, soil of pollution, farm crop and the vegetables of tap water, some synthetic detergent even have carcinogenic and cause rugged effect.
Summary of the invention
The natural environmental-protective cleaning detergent that the purpose of this invention is to provide a kind of safety performance excellence.
Further purpose of the present invention provides a kind of production method of natural environmental-protective cleaning detergent of safety performance excellence.
Above-mentioned purpose of the present invention adopts following technical scheme to be achieved:
The weight percent of washing composition of the present invention is formed and is comprised:
Radix Asparagi extract 0.2-4%
Radish seed extract 0.5-5%
Oleum Cocois 8-15%
Citric acid 0.3-0.5%
Yellow soda ash 35.9-40.5%
Zeolite 4-6%
Sumizyme MP 0.3-3%
Plant cellulose enzyme 1-5%
Mierocrystalline cellulose stopping composition 7-10%
Surplus is a water.
In the above-mentioned composition, Radix Asparagi extract and Radish seed extract are the water-soluble substances that adopts the carbon dioxide upercritical fluid extraction method to be obtained.
The weight percent of washing composition of the present invention is formed and is also comprised:
Electrolysis sea salt water 0.8-7%, described sea salt water contains sodium chloride 7-9%, every liter 200-400ppmCL and O).
Described Radish seed extract is selected from the mixture of any one or more than one extract in white turnip seed, carrot seed, green turnip seed, the radish seeds.Wherein mix best with carrot seed extract and white turnip seed extract.
Production method of the present invention is:
One, production method of the present invention comprises the steps:
1, raw material extracts, produces solid ingredient, the attached polymer molding, acquisition powder finished product, perhaps;
2, raw material extracts, produces solid ingredient, pre-mixing, the mixing of heating, obtains liquid finished product
Two, natural matter composition extracting method
Natural materials composition extracting method was during prescription was formed:
A) electrolysis sea salt water: purifying from seawater contains the liquid of sodium chloride 7-9% high density, obtains through electrolysis, and every liter contains 200-400ppmCL and O.
B) Radish seed: corresponding Radish seed is removed impurity, with compositions such as the water-soluble high density fatty oil of supercritical carbon dioxide extraction, volatile oil, formic acid, erucic acid, linolic acid, linolenic acid, carotene, the extraction primary condition is: pressure 7-100Mpa, temperature 30-70 ℃, time 0.5-2h, extracted amount are the 3-4% of dry product.
C) Radix Asparagi: the impurity of Radix Asparagi is removed, used compositions such as water-soluble asparagine of supercritical carbon dioxide extraction and phlegmatic temperament, β-Gu Zaichun, saponin, wood sugar, pressure 7-100Mpa, temperature 30-70 ℃, time 2-6h, extracting total amount is 10% of dry product.
Three, mix
Natural extract and Oleum Cocois, yellow soda ash etc. are blended in Forced Mixing produces polymer substances such as strong oxygen activity grease, carbide, muriate in 20 ℃ of-70 ℃ of temperature, the weight percentage scope by prescription gets finished product through the technological process of production.
Because the present invention has adopted technique scheme, is the multifunctional comprehensive cleaning agent thereby make cleaning detergent of the present invention.The raw material abundance of product, cheap.Can make powder shape, liquid state, washing effect is good, the degraded greasy dirt is strong, have high-effective cleansing, deodorize, dust removal, anti-electrostatic, remove functions such as mould, insect protected, sterilization, softness, do not contain white dyes, without phosphorus, heavy metal free, nuisanceless, pollution-free, harmless, can replace petrochemicals to use.Use range is wide, can be used for washing clothes, wash water fruit vegetable, the chopsticks of washing the dishes, wash floor tile, timber floor, wash carpet (wash or dry-clean), bathroom, lavatory decontamination and deodorant, clean smoke extractor, clean jewellery, wrist-watch, gold and silver, bronze, brass or copper ware, glasswork and industrial machine greasy dirt and clean, and can be used for automobile clean, derust, antirust, be used to improve soil property, livestock industry raising place cleaning, deodorizing on household mosquito repellent, insect protected, the agricultural, water flowers and plants, farm crop, fruit tree, potted landscape etc., the using method of its all purposes is with reference to " sort product specification sheets ".
Embodiment
Embodiment 1
The weight percent of liquid washing agent of the present invention consists of: (by producing 100 kilograms of products)
Radix Asparagi extract 0.2%
Radish seed extract 0.5% (wherein the part by weight from Radish seed extract and carrot seed extract is 6: 4)
Electrolysis sea salt water 0.8%
Oleum Cocois 8%
Citric acid 0.3%
Yellow soda ash 35.9%
4A zeolite 4%
Sumizyme MP 0.3%
Plant cellulose enzyme 1%
Mierocrystalline cellulose stopping composition 7%
Surplus is a water.
In the above-mentioned composition, Radix Asparagi extract and Radish seed extract are the water-soluble substances that adopts the carbon dioxide upercritical fluid extraction method to be obtained, electrolysis sea salt water contains the liquid of sodium chloride 7-9% high density for purifying from seawater, obtain through electrolysis, every liter contains 200-400ppmCL and O, and the Mierocrystalline cellulose stopping composition is starch or dextrin or carboxymethyl cellulose or Natvosol.
Production method of the present invention is:
1, natural materials composition extracting method
Natural materials composition extracting method was during prescription was formed:
Electrolysis sea salt water: purifying from seawater contains the liquid of sodium chloride 7-9% high density, obtains through electrolysis, and every liter contains 200-400ppmCL and O.
Radish seed: corresponding Radish seed is removed impurity, with compositions such as the water-soluble high density fatty oil of supercritical carbon dioxide extraction, volatile oil, formic acid, erucic acid, linolic acid, linolenic acid, carotene, the extraction primary condition is: pressure 7-100Mpa, temperature 30-70 ℃, time 0.5-2h, extracted amount are the 3-4% of dry product.Radix Asparagi: the impurity of Radix Asparagi is removed, used compositions such as water-soluble asparagine of supercritical carbon dioxide extraction and phlegmatic temperament, β-Gu Zaichun, saponin, wood sugar, pressure 7-100Mpa, temperature 30-70 ℃, time 2-6h, extracting total amount is 10% of dry product.
Mix
Natural extract is mixed with Oleum Cocois, yellow soda ash etc., at 20 ℃---Forced Mixing produces polymer substances such as strong oxygen activity grease, carbide, muriate in 70 ℃ of temperature, and the weight percentage scope by prescription gets finished product through the technological process of production.
Embodiment 2
The weight percent of washing composition of the present invention consists of:
Radix Asparagi extract 0.8%
Carrot seed extract 2%
Electrolysis sea salt water 3%
Oleum Cocois 10%
Citric acid 0.4%
Yellow soda ash 40%
Zeolite 5%
Sumizyme MP 2%
Plant cellulose enzyme 5%
Mierocrystalline cellulose stopping composition 9%
Surplus is a water.
Its production method is with embodiment 1.
Embodiment 3
The weight percent of solid detergent of the present invention consists of:
Radix Asparagi extract 4%
Carrot seed extract 5%
Electrolysis sea salt water 7%
Oleum Cocois 15%
Citric acid 0.5%
Yellow soda ash 40.5%
Zeolite 6%
Sumizyme MP 3%
Plant cellulose enzyme 5%
Mierocrystalline cellulose stopping composition 10%
Surplus is a water.
The production method of solid powder/particle of the present invention comprises the steps:
Raw material extracts, produces solid ingredient, the attached polymer molding, acquisition powder finished product,
Other production methods are with embodiment 1.
Embodiment 4
Other are with embodiment 1, but do not contain the seawater extract, and the white turnip seed is substituted by green turnip seed or radish seeds.
Embodiment 5
Other are with embodiment 3, but do not contain the seawater extract.
Embodiment 6
Adopt embodiment 3 natural environmental-protective cleaning detergent solid powder that obtains and commercially available washing composition consumption contrast (classification of washing clothes)
Commercially available famous brand washing powder has following kind
Lion king, flower king, Tide, green wave, Wei Wei, white cat, upright white, color strange, dab hand, prestige are clean 33, fragrant ten thousand families, profoundness, the despot that lives, carving board.
Common consumption: hand washing: 10 grams---25 grams do not wait.
Machine washing: 20 grams---50 grams do not wait.
Washing effect is good, contains white dyes, without phosphorus, low-phosphorous or phosphorous, and the heavy metal composition is arranged, and need add softening agent after the washing in addition and just can reach soft.
The natural environmental-protective cleaning detergent
Common consumption is hand-washed 5 premium on currency, 5 grams
General type washing machine
Low-water level median water level high-water
30 liters 40 liters 50 liters of the water yields
Washing loads 4kg 5kg 6kg
Washing composition consumption 20 grams 25 grams 30 grams
Washing effect: splendid, do not contain white dyes, without phosphorus, heavy metal free, need not add softening agent, gentle silk essence or cold wash essence, can wash out nature.Keep clothing primary colors, bulk, soft.Washing clothes, soaked for a long time can be not smelly yet, keeps the nature smell.Washing foam few, easy flushing, degraded greasy dirt are strong especially, water-saving, power saving.
Embodiment 7
The comparison sheet of natural environmental-protective cleaning detergent and commercially available petrochemical industry sanitising agent
Numbering Relatively The natural environmental-protective cleaning detergent Commercially available petrochemical industry sanitising agent
1 Petrifaction (toxic) Do not have Have
2 Fluorescent agent (toxic) Do not have Have
3 Phosphorus Do not have The overwhelming majority has
4 Main raw material Herbal medicine, seawater, coconut wet goods natural goods Petroleum chemistry raw materials such as LAS
5 Environmental pollution The reduction of tool water quality, purification river, effects such as activating soil Cause the excellent oxidation in heavy metal pollution of soil and river ... public hazards
6 Physical effects Can improve skin, not injure human body Cause allergicly, cytopathy is as acute eczema etc.
7 Solvency power 100% is dissolved in water, is transparence Can't be dissolved in water fully, be muddy shape
8 The dirt clearing power Splendid Good (white dyes visual process)
9 The purposes function Multi-functional Simple function can't replace other functions
10 Attachment Do not have The residue that petrochemical industry toxin and heavy metal are arranged
11 The clothing material Keep primary colors Can variable color, bleach, increase gorgeous
12 The energy uses But easily flushing power saving, water-saving, save time, human-saving Be difficult for flushing, need a large amount of water flushings, so take electricity, water wasting, time-consuming, expense manpower
13 Economic benefit The comprehensive use only needs half following expense of general cleaning agent Kind is many, expense is high
Embodiment 8
The natural environmental-protective cleaning detergent can according to the use range situation do following dilution (embodiment 1 liquid that obtains or embodiment 3 powdery solid that obtains are example:
1: 5,1: 10,1: 20,1: 30,1: 40,1: 50......1: 500 times
Above-mentioned ratio is the ratio of stoste or powdery solid and water.This standard meets the safety standards of the relevant product of country fully, does not contain to cause to lose efficacy or to the injury of human body.

Claims (4)

1. natural environmental-protective cleaning detergent is characterized in that: the weight percent of described washing composition is formed and is comprised:
Radix Asparagi extract 0.2-4%
Radish seed extract 0.5-5%
Oleum Cocois 8-15%
Citric acid 0.3-0.5%
Yellow soda ash 35.9-40.5%
Zeolite 4-6%
Sumizyme MP 0.3-3%
Plant cellulose enzyme 1-5%
Mierocrystalline cellulose stopping composition 7-10%
Surplus is a water,
In the above-mentioned composition, Radix Asparagi extract and carrot seed extract are the water-soluble substances that adopts the carbon dioxide upercritical fluid extraction method to be obtained, and described Radish seed extract is selected from the mixture of any one or more than one extract in white turnip seed, carrot seed, green turnip seed, the radish seeds.
2. natural environmental-protective cleaning detergent according to claim 1 is characterized in that: the weight percent of described washing composition is formed and is also comprised:
Sea salt water 0.8-7%, described sea salt water contains sodium chloride 7-9%, every liter 200-400ppmCL and O.
3. the production method of natural environmental-protective cleaning detergent according to claim 1 and 2 is characterized in that: the production method of described solid detergent comprises the steps:
Raw material extracts, produces solid ingredient, the attached polymer molding, acquisition powder finished product, and wherein, natural materials composition extracting method was during prescription was formed:
Electrolysis sea salt water: purifying from seawater contains the liquid of sodium chloride 7-9% high density, obtains through electrolysis, and every liter contains 200-400ppmCL and O,
Radish seed: corresponding Radish seed is removed impurity, with the water-soluble high density fatty oil of supercritical carbon dioxide extraction, volatile oil, formic acid, erucic acid, linolic acid, linolenic acid, and carotene, the extraction primary condition is: pressure 7-100Mpa, temperature 30-70 ℃, time 0.5-2h, extracted amount is the 3-4% of dry product, Radix Asparagi: the impurity of Radix Asparagi is removed, with supercritical carbon dioxide extraction water-soluble asparagine and phlegmatic temperament, β-Gu Zaichun, saponin, wood sugar, pressure 7-100Mpa, temperature 30-70 ℃, time 2-6h, extracting total amount is 10% of dry product.
4. the production method of natural environmental-protective cleaning detergent according to claim 1 and 2 is characterized in that: the production method of described liquid washing agent comprises the steps:
Raw material extracts, produces solid ingredient, pre-mixing, mixings of heating, activation mix, obtain liquid finished product, and natural materials composition extracting method is in the prescription composition:
Electrolysis sea salt water: the liquid that contains sodium chloride 7-9% high density of purifying from seawater is obtained through electrolysis, and every liter contains 200-400ppmCL and O,
Radish seed: corresponding Radish seed is removed impurity, with supercritical carbon dioxide extraction water-soluble high density fatty oil, volatile oil, formic acid, erucic acid, linolic acid, linolenic acid, carotene, the extraction primary condition is: pressure 7-100Mpa, temperature 30-70 ℃, time 05-2h, extracted amount is the 3-4% of dry product, Radix Asparagi: the impurity of Radix Asparagi is removed, with the water-soluble asparagine of supercritical carbon dioxide extraction and phlegmatic temperament, β-Gu Zaichun, saponin, wood sugar, pressure 7-100Mpa, temperature 30-70 ℃, time 2-6h, extracting total amount is 10% of dry product.
CNB031501532A 2003-07-21 2003-07-21 Natural highly effective environmental protection type cleaning agent and its making method Expired - Fee Related CN100424159C (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660530A (en) * 2012-05-16 2012-09-12 苏州先阔生物科技有限公司 Alkali protease composition with enhanced activity, and application thereof
CN103589520B (en) * 2013-10-15 2015-01-21 常州思宇环保材料科技有限公司 Automobile cleaning solution and cleaning method
CN105176709A (en) * 2015-07-19 2015-12-23 中盐榆林盐化有限公司 Preparation method of plant washing salt powder
CN106281784A (en) * 2016-08-25 2017-01-04 仇颖超 A kind of preparation method of efficient detergent for toilet
CN108034526A (en) * 2017-12-05 2018-05-15 北京军秀咨询有限公司 A kind of biological green environment protection multifunctional special efficacy liquid detergent and preparation method thereof
CN109370813B (en) * 2018-11-16 2020-11-10 欧新永 Raw material of washing and caring product and preparation method thereof
CN110452788B (en) * 2019-09-03 2021-08-27 北京汇真源科技有限公司 Fruit and vegetable cleaning agent and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1169466A (en) * 1996-06-22 1998-01-07 云南省药物研究所制药厂 Agent for bath in tub with functions of skin-beautifying, stimulating blood-circulation and causing muscles and joints to relax and sterilizing
CN1205358A (en) * 1998-03-19 1999-01-20 易群芳 Natural plant washing powder having environmental protection and energy saving functions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1169466A (en) * 1996-06-22 1998-01-07 云南省药物研究所制药厂 Agent for bath in tub with functions of skin-beautifying, stimulating blood-circulation and causing muscles and joints to relax and sterilizing
CN1205358A (en) * 1998-03-19 1999-01-20 易群芳 Natural plant washing powder having environmental protection and energy saving functions

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
洗涤化妆品. 李龙章.化学研究与应用,第6卷第1期. 1994
洗涤化妆品. 李龙章.化学研究与应用,第6卷第1期. 1994 *

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Effective date of registration: 20161123

Address after: 519000 Guangdong Province, Zhuhai city Xiangzhou District Jida Bailian Road No. 113 building 24 unit 2 Room 202

Patentee after: Huang Xiaohua

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Patentee before: Huang Xiaohua

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