EP1409632A1 - Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment - Google Patents
Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environmentInfo
- Publication number
- EP1409632A1 EP1409632A1 EP01961943A EP01961943A EP1409632A1 EP 1409632 A1 EP1409632 A1 EP 1409632A1 EP 01961943 A EP01961943 A EP 01961943A EP 01961943 A EP01961943 A EP 01961943A EP 1409632 A1 EP1409632 A1 EP 1409632A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hydrogen peroxide
- glycolic acid
- water
- weight percent
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
Definitions
- the invention relates to a method of making a composition and a product from such
- rollers apparatus to contain and move fluids (such as hoses and trays), and other moving
- pesticide systems meat processing systems, poultry processing systems, dairy processing
- the contaminants can foul such water-containing systems to such an extent that such water-
- compositions that can be used for reducing the concentration of,
- compositions can be difficult to use due to the difficulty in determining how much of each component of the composition should be added.
- An object of the present invention is to provide a process for preparing a composition
- Another object of the present invention is to provide
- composition having desirable properties such as enhanced capabilities for reducing
- a further object of the present invention is to provide an improved process of
- glycolic acid also referred to as hydroxy acetic
- Another embodiment of the present invention is a process of preparing a novel
- composition comprising contacting hydrogen peroxide, glycolic acid, and water.
- a novel composition of the present invention can be used for reducing the
- Such contaminants can include Groups II- VIII of the Periodic
- Such environments can include water-
- Such water-containing systems can include
- swimming pools water treating systems, drainage systems, boiler systems, chiller systems,
- a process of preparing a composition of the present invention comprises
- the hydrogen peroxide is generally
- hydrogen peroxide solution generally comprises at least about 0.1 weight percent hydrogen
- invention can be prepared by adding a stabilizing amount of water to a commercially
- the water suitable for use in a process of the present invention is preferably a low
- solids water generally comprising less than about 10 parts per million (ppm) dissolved solids
- dissolved solids and most preferably about 0 ppm dissolved solids.
- the water preferably low solids water, can be prepared by any suitable means known
- the low solids water can be prepared by subjecting a high solids water to a treating
- the high solids water generally comprises more dissolved solids than
- the low solids water Generally, the high solids water comprises more than about 200 ppm of
- water is present in a stabilizing amount which allows for the contacting of
- stabilizing amount of water as described herein should be large enough to prevent an
- composition from being so dilute that such resulting composition no longer has the ability to
- composition so that such composition is effective in reducing the concentration of, preferably
- a stabilizing amount of water preferably low solids water, is present in an
- a stabilizing amount of water is present in an amount of at least about 60 percent by weight water based on
- glycolic acid is preferably a glycolic acid solution comprising glycolic acid and
- Such glycolic acid solution generally comprises at least about 1 weight percent
- glycolic acid and at most about 15 weight percent glycolic acid, preferably at least about 1
- weight percent glycolic acid and at most about 10 weight percent glycolic acid, and more
- glycolic acid solution which can be used in a process of
- the present invention can be obtained by adding low solids water as described herein to a
- the hydrogen peroxide, glycolic acid, and water can be contacted by any suitable
- such contacting comprises mixing utilizing any suitable
- mixing means known in the art for mixing an aqueous solution with another aqueous solution.
- a hydrogen peroxide solution as described herein is mixed with a glycolic
- glycolic acid is generally at least about 1 :1 and at most about 30:1, preferably at least about 2:1 and at most about 20:1, more preferably at least about 2:1 and at most about 10:1, and
- the temperature during contacting is at least about 0°F and at most about
- 100°F preferably at least about 10°F and at most about 90°F, and more preferably at least
- the pressure during contacting can be any pressure
- the pressure is generally at least about
- the time period of contacting can be any time period capable of providing for a
- the time period of contacting is generally at least about 0.1
- a process of providing a composition of the present invention can further comprise
- isopropyl alcohol has a purity of at least about 95 percent, preferably at least about 98 percent,
- invention can further comprise contacting with one or more components selected from the
- esters include, but are not limited to, ethoxylated esters and the like and combinations thereof.
- Suitable acids include, but are not limited to, acetic, sulfuric, formic, peroxyacetic, and the like and combinations thereof.
- beta hydroxy acids include, but are not limited to, citric, lactic, maleic, and the like and
- Such additional component(s) can be added in any amount(s) as long as such
- amount(s) provides a composition effective in reducing the concentration of, preferably
- composition and more preferably in an amount of at least about 0.1 weight percent based on
- a preferred method of preparing a composition of the present invention comprises
- glycolic acid solution prepared by contacting a 70 weight percent glycolic acid
- composition having a pH of about 1.9 to about 3.5. Such composition is particularly suitable
- glycolic acid solution prepared by contacting a 70 weight percent
- glycolic acid solution with low solids water comprising less than about 1 ppm dissolved
- composition is particularly suitable for use in reducing the concentration of, preferably
- An additional preferred process of preparing such composition is to further contact the
- composition with isopropyl alcohol having a purity of about 99 percent in an amount
- a composition of the present invention generally has a pH of at least about 1.5 and at
- a composition of the present invention generally has a specific gravity of at least
- present invention comprises a molecule containing two carbon atoms, four hydrogen atoms,
- a composition of the present invention prepared by a process of the present invention
- contaminant(s) from such environment examples include, but are
- Group II elements Group II elements, Group III elements, Group IV elements, Group V elements, Group
- surfactants natural gums, synthetic gums, organic compounds, paper fibers, paper filters,
- clays such as clays, sulfites, sulfates, oxides, adhesives, starches, and the like and combinations thereof.
- Examples of a suitable environment include, but are not limited to, water-containing
- system refers to any method, process,
- water-containing systems refers to any water-containing systems.
- water-containing systems refers to any water-containing systems.
- food processing systems refers to any method, process, apparatus, components, and
- printing systems refers to any method, process, apparatus, components, and the like and combinations thereof known in the art related in any
- suitable water-containing systems include, but are not limited to,
- swimming pools water treating systems, drainage systems, boiler systems, chiller systems,
- composition of the present invention can be contacted with one or more
- the contacting condition also referred to as the
- contaminant contacting condition which comprises a concentration of a composition as
- period can be any contacting condition effective in reducing the concentration of, preferably
- contacting condition will generally depend on the type and concentration of contaminant and
- the contacting condition will generally have an increased
- one or more contaminants is increased compared to the contacting condition necessary when
- composition of the present invention is used to maintain the reduction in concentration of
- liquid medium such as the water-containing
- the concentration of composition is generally at least about 0.1 part
- composition by volume per million parts environment (ppmv) and at most about 25 volume
- the concentration of composition is generally at least about 0.1 part
- composition by weight per million parts environment (ppm) and at most about 20 weight
- the contacting temperature also referred to as the contaminant contacting
- temperature is at least about 50°F and at most about 200°F, preferably at least about 70°F
- the contacting pressure also referred to as the contaminant
- contacting pressure is generally at least about atmospheric and at most about 100 pounds per
- the contacting time also referred to as psia
- the contaminant contacting time is generally at least about 0.1 minute and at most about
- composition of the present invention examples include, but are
- a composition of the present invention can be used as a descalant, biocide, slimicide,
- flocculant, and the like and combinations thereof to reduce the concentration of, preferably remove or dissolve, scale, algae, and the like and combinations thereof from machinery and
- composition of the present invention can be used as a descalant, biocide and/or
- algaecide to reduce the concentration of, preferably remove or dissolve, various contaminants
- the present invention can be used as a calcium and surfactant remover to reduce the
- composition of the present invention can be used to reduce the
- composition of the present invention can also be used as a
- mbber roller rinse to reduce the concentration of, preferably remove or dissolve, organic
- a composition of the present invention can be used for reducing the concentration of,
- a contaminant such as scale, algae, fungi, bacteria,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be any composition of the present invention.
- adhesives can thus provide for easy removal of such glues and adhesives.
- a composition of the present invention can be used to treat anilox rolls, particularly
- composition of the present invention provides
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used in waste sludge treatment
- a composition of the present invention can be used as an industrial biocide treatment
- a composition of the present invention can be used to enhance the bleaching
- a composition of the present invention can be used in fish farming and agricultural
- Such agricultural processes include, but are not
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used to reduce the concentration of,
- a composition of the present invention can be used as an additive in various products
- a composition of the present invention can be used to reduce the concentration of,
- composition of the present invention is used to reduce the concentration
- a composition of the invention preferably remove or dissolve, contaminants from printing systems.
- present invention can be used in addition to, or preferably as an alternative to, various
- composition ofthe present invention is used as a sanitizer, fungicide,
- algaecide and the like and combinations thereof to reduce the concentration of, preferably
- compositions ofthe present invention are used as a sanitizer, fungicide, and
- algaecide and the like and combinations thereof to reduce the concentration of, preferably
- composition ofthe present invention can be used in addition to, or preferably as an alternative
- This example illustrates a preparation of a composition ofthe present invention.
- a 55-gallon quantity of a composition of the present invention was prepared by
- glycolic acid solution which had been prepared by contacting 0.825 gallons of approximately
- glycolic acid solution obtained from DuPont Chemical, Wilmington,
- composition A having a pH
- composition A as described herein to reduce the concentration of, preferably remove or
- composition A was then applied directly to the glue residue using a trigger sprayer
- composition A as described herein to remove organic substances and mineral residue from
- PCA located in Waco, Texas. Such equipment had been used for several years.
- composition A was sprayed directly onto the surface of the anilox
- anilox roll cells having a concentration of 145 cells per linear inch of anilox roll.
- Composition A appeared to decompose the bonded minerals and deposits, allowing such bonded minerals and deposits to be removed by washing with normal
- composition A allowed for the anilox equipment to be cleaned on
- the second method of applying Composition A was by adding Composition A to the
- composition A A is a mixture of ingredients that were utilized, but had only cleaned the surface ofthe anilox cells.
- This example illustrates another preparation of a composition ofthe present invention.
- a 55-gallon quantity of a composition of the present invention was prepared by
- glycolic acid solution which had been prepared by contacting 1.65 gallons of 70 weight
- glycolic acid solution obtained from DuPont Chemical, Wilmington, Delaware, as a
- composition B having a pH of
- composition of the present invention illustrates a use of a composition of the present invention (Composition 1)
- a printing press was obtained from Rock Tenn Company, Waxahachie, Texas, and
- a Man Roland fountain solution recirculating system also referred to as a
- dampening system which comprised a blender, chiller, and recirculating unit containing an
- mineral substance residue such as mineral deposits consisting of calcium and lime deposits
- hair algae which were white, green,
- press recirculating systems included products comprising a mixture of sodium hydroxide,
- glycol ethers and various biocides, such as those sold by various chemical manufacturers,
- composition B was poured directly, in one-pint quantities, into each of
- composition B contains
- Composition B The recirculating system was then recharged with a standard fountain solution having
- startup recovery time was about 2 to 3 sheets. It is believed that the better
- hydroxide hydroxide, glycol ethers and biocides, with some of these products containing foaming agents
- Composition B has a similar residual pH, use of Composition B provides a direct benefit to
- composition of the present invention illustrates a use of a composition of the present invention (Composition 1)
- the test site consisted of a swimming pool which contained 25,000 gallons of water
- the swimming pool which was substantially free of chlorine and other chemical substances.
- the surface areas of the pool under water were covered with a green algae
- the filter media contained in the swimming pool filtration system was diametaceous earth.
- the pH ofthe water was 7.2 and the temperature ofthe water was about 78°F.
- Composition B by pouring Composition B at a steady rate into the pool from a plastic bucket while walking
- the pool water remained uncovered, dormant, and was not circulated for two weeks.
- the dissolved oxygen (DO) was 106 parts per million (ppm)
- composition ofthe present invention is a composition ofthe present invention.
- Test site 1 consisted of an outdoor water garden comprising a circular-
- the tank also contained soil, rock, several bricks, and 36
- Composition B added to the tank by pouring Composition B directly from a plastic bottle into the water at
- the temperature of the water during addition was about 78°F.
- Test site 2 consisted of a standard 29-gallon aquarium containing six gallons of
- the pH was 8.0.
- the growth medium used in the tank included a General Electric
- Composition B was added in an amount of 100 parts Composition B by weight per
- oxygen level was 106 ppm.
- the dissolved oxygen level was about 44 ppm and an
- the dissolved oxygen was 44 ppm.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CY20071101329T CY1107765T1 (en) | 2000-08-04 | 2007-10-15 | A METHOD FOR CREATING A COMPOSITION, A PRODUCT FROM A COMPLETE METHOD, AND ITS USE FOR REMOVING OR SOLVING A SINGLE SOLUTION |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US22306400P | 2000-08-04 | 2000-08-04 | |
US223064P | 2000-08-04 | ||
PCT/US2001/024775 WO2002012428A1 (en) | 2000-08-04 | 2001-08-03 | Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06025103 Division | 2006-12-05 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1409632A1 true EP1409632A1 (en) | 2004-04-21 |
EP1409632A4 EP1409632A4 (en) | 2004-08-25 |
EP1409632B1 EP1409632B1 (en) | 2007-07-18 |
Family
ID=22834863
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01961943A Expired - Lifetime EP1409632B1 (en) | 2000-08-04 | 2001-08-03 | Method of making a composition, a product from such method, and the use thereof in removing or dissolving a contaminant from an environment |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP1409632B1 (en) |
JP (2) | JP5614912B2 (en) |
CN (1) | CN1261555C (en) |
AT (1) | ATE367431T1 (en) |
AU (1) | AU8316501A (en) |
BR (1) | BR0113031B1 (en) |
CA (1) | CA2417927C (en) |
CY (1) | CY1107765T1 (en) |
DE (1) | DE60129477T2 (en) |
DK (1) | DK1409632T3 (en) |
ES (1) | ES2288980T3 (en) |
IL (2) | IL154269A0 (en) |
MX (1) | MXPA03001038A (en) |
NZ (2) | NZ545460A (en) |
PL (1) | PL199174B1 (en) |
PT (1) | PT1409632E (en) |
WO (1) | WO2002012428A1 (en) |
ZA (1) | ZA200300973B (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7029588B2 (en) * | 2003-03-19 | 2006-04-18 | Samuel Rupert Owens | Oxidizing solution and process for contaminants |
US8398781B2 (en) * | 2004-08-27 | 2013-03-19 | Ecolab Usa Inc. | Methods for cleaning industrial equipment with pre-treatment |
GEP20237469B (en) * | 2020-11-10 | 2023-02-10 | Dzala Llc | Novel compositions for neutralizing toxic effects of hydrogen peroxide in living cells or tissues |
DE102021129678A1 (en) | 2021-11-15 | 2023-05-17 | Knieler & Team Gmbh | Ready-to-use aqueous disinfectant composition |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2720441A (en) * | 1953-09-21 | 1955-10-11 | Du Pont | Peroxygen bleaching of nylon |
US4609475A (en) * | 1984-02-24 | 1986-09-02 | Halliburton Company | Method of improving the permeability of a subterranean formation by removal of polymeric materials therefrom |
DE4026806A1 (en) * | 1990-08-24 | 1992-02-27 | Henkel Kgaa | Cleaning carpet by impregnation with aq. soln. - contg. solid inorganic peroxide, activator for peroxide, and surfactant |
EP0540515B1 (en) * | 1990-07-23 | 1995-02-01 | Ecolab Inc. | Peroxy acid generator |
EP0659876A2 (en) * | 1993-12-24 | 1995-06-28 | The Procter & Gamble Company | Detergent additive composition. |
US5567444A (en) * | 1993-08-30 | 1996-10-22 | Ecolab Inc. | Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface |
US5674538A (en) * | 1993-03-17 | 1997-10-07 | Ecolab Inc. | Process for inhibition of microbial growth in aqueous food transport or process streams |
US5958984A (en) * | 1996-10-10 | 1999-09-28 | Devillez; Richard L. | Method and composition for skin treatment |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3397383B2 (en) * | 1992-10-28 | 2003-04-14 | 花王株式会社 | Liquid bleaching detergent composition |
GB9302441D0 (en) * | 1993-02-08 | 1993-03-24 | Warwick Int Group | Oxidising agents |
US5961736A (en) * | 1993-04-05 | 1999-10-05 | Active Environmental Technologies, Inc. | Method for removal of contaminants from surfaces |
AU671895B2 (en) * | 1993-04-12 | 1996-09-12 | Colgate-Palmolive Company, The | Tricritical point composition |
US5759975A (en) * | 1996-08-26 | 1998-06-02 | Gage Products Company | Paint line cleaner |
JPH115995A (en) * | 1997-04-21 | 1999-01-12 | Lion Corp | Liquid oxygenic bleaching agent composition |
JP3370571B2 (en) * | 1997-09-03 | 2003-01-27 | クリーンケミカル株式会社 | Disinfectant cleaning agents for medical equipment and disinfecting cleaning methods |
JPH1180794A (en) * | 1997-09-08 | 1999-03-26 | Kao Corp | Liquid bleaching composition |
JP3766746B2 (en) * | 1997-12-24 | 2006-04-19 | ライオン株式会社 | Liquid bleach composition |
-
2001
- 2001-08-03 NZ NZ545460A patent/NZ545460A/en not_active IP Right Cessation
- 2001-08-03 AU AU8316501A patent/AU8316501A/en active Pending
- 2001-08-03 PT PT01961943T patent/PT1409632E/en unknown
- 2001-08-03 EP EP01961943A patent/EP1409632B1/en not_active Expired - Lifetime
- 2001-08-03 MX MXPA03001038A patent/MXPA03001038A/en active IP Right Grant
- 2001-08-03 DE DE60129477T patent/DE60129477T2/en not_active Expired - Lifetime
- 2001-08-03 CA CA2417927A patent/CA2417927C/en not_active Expired - Fee Related
- 2001-08-03 DK DK01961943T patent/DK1409632T3/en active
- 2001-08-03 WO PCT/US2001/024775 patent/WO2002012428A1/en active IP Right Grant
- 2001-08-03 PL PL366164A patent/PL199174B1/en unknown
- 2001-08-03 ES ES01961943T patent/ES2288980T3/en not_active Expired - Lifetime
- 2001-08-03 NZ NZ524399A patent/NZ524399A/en not_active IP Right Cessation
- 2001-08-03 JP JP2002517719A patent/JP5614912B2/en not_active Expired - Fee Related
- 2001-08-03 CN CN01813465.3A patent/CN1261555C/en not_active Expired - Fee Related
- 2001-08-03 IL IL15426901A patent/IL154269A0/en active IP Right Grant
- 2001-08-03 BR BRPI0113031-5A patent/BR0113031B1/en not_active IP Right Cessation
- 2001-08-03 AT AT01961943T patent/ATE367431T1/en active
-
2003
- 2003-02-03 IL IL154269A patent/IL154269A/en not_active IP Right Cessation
- 2003-02-04 ZA ZA200300973A patent/ZA200300973B/en unknown
-
2007
- 2007-10-15 CY CY20071101329T patent/CY1107765T1/en unknown
-
2014
- 2014-07-24 JP JP2014150725A patent/JP5976731B2/en not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2720441A (en) * | 1953-09-21 | 1955-10-11 | Du Pont | Peroxygen bleaching of nylon |
US4609475A (en) * | 1984-02-24 | 1986-09-02 | Halliburton Company | Method of improving the permeability of a subterranean formation by removal of polymeric materials therefrom |
EP0540515B1 (en) * | 1990-07-23 | 1995-02-01 | Ecolab Inc. | Peroxy acid generator |
DE4026806A1 (en) * | 1990-08-24 | 1992-02-27 | Henkel Kgaa | Cleaning carpet by impregnation with aq. soln. - contg. solid inorganic peroxide, activator for peroxide, and surfactant |
US5674538A (en) * | 1993-03-17 | 1997-10-07 | Ecolab Inc. | Process for inhibition of microbial growth in aqueous food transport or process streams |
US5567444A (en) * | 1993-08-30 | 1996-10-22 | Ecolab Inc. | Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface |
EP0659876A2 (en) * | 1993-12-24 | 1995-06-28 | The Procter & Gamble Company | Detergent additive composition. |
US5958984A (en) * | 1996-10-10 | 1999-09-28 | Devillez; Richard L. | Method and composition for skin treatment |
Non-Patent Citations (2)
Title |
---|
KIRK OTHMER: "ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY 4.TH ED VOL.18" 1996, WILEY INTERSCIENCE , NEW YORK * page 268 - page 272 * * |
See also references of WO0212428A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1261555C (en) | 2006-06-28 |
DE60129477D1 (en) | 2007-08-30 |
DE60129477T2 (en) | 2008-02-14 |
PL199174B1 (en) | 2008-08-29 |
PL366164A1 (en) | 2005-01-24 |
WO2002012428A1 (en) | 2002-02-14 |
JP5976731B2 (en) | 2016-08-24 |
MXPA03001038A (en) | 2004-09-10 |
JP2004519529A (en) | 2004-07-02 |
EP1409632B1 (en) | 2007-07-18 |
ATE367431T1 (en) | 2007-08-15 |
JP5614912B2 (en) | 2014-10-29 |
JP2014224265A (en) | 2014-12-04 |
NZ524399A (en) | 2006-03-31 |
IL154269A0 (en) | 2003-09-17 |
CA2417927A1 (en) | 2002-02-14 |
NZ545460A (en) | 2008-07-31 |
DK1409632T3 (en) | 2007-11-12 |
ES2288980T3 (en) | 2008-02-01 |
EP1409632A4 (en) | 2004-08-25 |
IL154269A (en) | 2007-03-08 |
CA2417927C (en) | 2012-05-22 |
BR0113031B1 (en) | 2012-01-24 |
BR0113031A (en) | 2004-11-09 |
CY1107765T1 (en) | 2013-04-18 |
ZA200300973B (en) | 2004-07-28 |
CN1447852A (en) | 2003-10-08 |
AU2001283165B2 (en) | 2006-10-26 |
AU8316501A (en) | 2002-02-18 |
PT1409632E (en) | 2007-10-11 |
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