EP1319394A1 - Zubereitungen mit desodorierender Wirkung, enthaltend das Zinksalz der Ricinolsäure und mindestens eine aminofunktionelle Aminosäure - Google Patents
Zubereitungen mit desodorierender Wirkung, enthaltend das Zinksalz der Ricinolsäure und mindestens eine aminofunktionelle Aminosäure Download PDFInfo
- Publication number
- EP1319394A1 EP1319394A1 EP02026632A EP02026632A EP1319394A1 EP 1319394 A1 EP1319394 A1 EP 1319394A1 EP 02026632 A EP02026632 A EP 02026632A EP 02026632 A EP02026632 A EP 02026632A EP 1319394 A1 EP1319394 A1 EP 1319394A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- preparations
- amino
- deodorant
- acid
- contain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
Definitions
- the present invention relates to preparations with deodorant Effect containing the zinc salt of ricinoleic acid and at least one amino functional amino acid, its salts and / or derivatives.
- Sweating is a normal and healthy body function. Sweat itself is odorless. By breaking down the sweat containing protein compounds through natural, gram-positive Skin bacteria, however, develop body odor, which in the modern society as pushy, repulsive and neglected is felt. A large number were therefore used for personal hygiene cosmetic products developed with the aim of making them unpleasant Eliminate sweat odor. Dosage forms of such Products that contain both odor-inhibiting deodorants and Anti-perspirants include pens and Creams, soaps, roll-ons as well as aerosol and pump sprays.
- deodorants mask the unpleasant smells with the addition of perfumes.
- deodorants also contain antimicrobials Contain active ingredients such as Triclosan®, essential oils or Farnesol®. Such materials act as bactericides or bacteriostatics and reduce the natural bacterial flora on the skin, which prevents the formation of odors.
- active ingredients aluminum and zirconium salts are used, which are due to their protein-precipitating nature constrict the sweat glands and thus the Reduce perspiration.
- enzyme blockers such as triethyl citrate, which are used in the enzymatic Intervene mechanism of bacterial sweat decomposition by inactivating the ester-splitting lipases Prevent the development of unpleasant smelling breakdown products.
- odor absorbers are also known, at which are substances that are the odor-forming compounds through adsorption or absorption chemically or physically can bind.
- a representative of such materials are Zinc salts of ricinoleic acid, the production of which in DE-B-17 92 074 is described.
- Zinc ricinoleate can contain odorous organic substances functional groups containing sulfur or nitrogen, such as Example mercaptans, thioethers, low molecular weight carboxylic acids such as Chemically bind isovaleric acid or amines.
- odorous organic substances functional groups containing sulfur or nitrogen such as Example mercaptans, thioethers, low molecular weight carboxylic acids such as Chemically bind isovaleric acid or amines.
- a special The advantage of this type of odor control is that it is bacterial This does not negatively affect the balance of the skin flora becomes.
- Zinc ricinoleate is, however, due to its polymeric salt structure can only be used directly to a limited extent. It is about a, in common cosmetic solvents, poorly soluble compound. In order to obtain effective preparations, it must therefore be in Combination with solvents and solubilizers used become. Usually monovalent or multivalent are used as solvents Alcohols, optionally with the addition of water, are used. Usually highly ethoxylated solubilizers used are capable the zinc ricinoleate alone, even in high concentrations keep in solution and it doesn't make any flowable Receive products.
- solubilizers for zinc ricinoleate can be found in the patent literature. So in the Patent DE-B-37 26 636 deodorants based on Zinc ricinoleate described with solvents and solubilizers, the hydrolyzed ene adducts as solubilizers of ricen fatty acids and maleic anhydride become.
- deodorants are also based on zinc ricinoleate with solvent and Solution brokers described.
- Tertiary amino alcohols are claimed as tertiary amines, such as triethanolamine or N, N, N ', N'-tetrakis (2-hydroxypropyl) ethylenediamine.
- the contained amino alcohols are used for technical applications, where there is no skin contact, no problem For use in applications with skin contact, such as in particular in cosmetic products, on the other hand, are more and more Alternatives to amino alcohols are asked as these are often contaminants of secondary amines can contain. Moreover are these substances, also because of known sensitizing and allergic reactions when used on the skin, negative headlines.
- Formulations with zinc ricinoleate should therefore preferably be such Contain raw materials as solubilizers that are non-toxic are, preferably of natural origin, very good from that Skin are tolerated, high compatibility with other ingredients and easily incorporate into deodorants to let. It is particularly desirable if these raw materials also perform the function of certain components can be used in deodorant applications, such as pH regulators, skin calming agents or anti-inflammatory agents.
- the zinc salts of ricinoleic acid which can also be used according to the invention are those commercially available under the respective brand names Products such as the TEGO® Sorb, TEGODEO® in particular or ORTEGOL® 2000 from Goldschmidt AG.
- the zinc salt of ricinoleic acid can be used in amounts from 0.01 to 60% by weight, preferably in amounts of 20 to 60% by weight on the active ingredient concentrate.
- preferred amino functional amino acids are preferred Lysine, hydroxylysine and arginine and their derivatives and Salts with organic or inorganic acids alone or in Mix with each other and used together. Low proportions are further natural or synthetic amino acids also possible.
- amino acids as active ingredients in cosmetic Applications have already been described many times. Because of your zwitterionic in nature, amino acids act as buffers and stabilize them the skin's protective acid mantle.
- L-arginine is an endogenous, semi-essential amino acid which are supplemented by food in deficient situations got to. It has a moisturizing effect and is one of the natural ones Skin moisturizing factors (NMF).
- NMF Skin moisturizing factors
- urea is a metabolic product of Is arginine.
- Lysine is part of many proteins and therefore has many Functions in the body. It contributes to growth, tissue repair, for the formation of enzymes, hormones and antibodies as well as for Collagen synthesis and bone health. Lysine may help To absorb and store calcium. Lysine lasts continue to maintain the nitrogen balance in the body and it plays an important role in the immune system. For example, are known antiviral skills.
- Both lysine and arginine can make the skin and mucous membrane compatible greatly improved by irritating substances become.
- the inventive Preparations also derivatives of amino functional amino acids contain.
- These include arginine and lysine salts, especially those with long-chain fatty acids, which due to their surface-active Properties act as mild, skin-friendly surfactants.
- Such materials are e.g. under the trade name "Aminoap" commercially available from Ajinomoto.
- Aminoap commercially available from Ajinomoto.
- N-acyl derivatives of lysine and arginine can be used and cationically modified fat-chemically modified variants hereof.
- the amino functional amino acids can be used in amounts from 0.01 to 40% by weight, preferably in amounts of 0.1 to 30% by weight on the overall formulation.
- Solubilizers in the sense of the present invention are nonionic and ionic surfactants such as alkoxylates, polyglycerols, glycol ethers, Glycols, polyethylene glycols, polypropylene glycols, polybutylene glycols, Glycerol ester ethoxylates, polysorbates, alkyl ether sulfates, Alkyl and / or aryl sulfonates, alkyl sulfates, ester sulfonates (Sulfofatty acid esters), lignin sulfonates, fatty acid cyanamides, anionic sulfosuccinic acid surfactants, fatty acid isethionates, Acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, Ether carboxylic acids and alkyl (ether) phosphates.
- nonionic and ionic surfactants such as alkoxylate
- Preferred nonionic solubilizers are the optionally etherified on one side 6 alkanol with a C 1- C, C 2- C 6 alkylene glycols and poly-C 2 -C 3 -alkylene same with an average of 1 to 9 or different, preferably identical, alkylene glycol per Molecule as well as alcohols and fatty alcohol polyglycol ethers, preferably propylene glycol, dipropylene glycol, trimethylolpropane and lower ethoxylated fatty alcohols having 6 to 22, preferably 8 to 18, in particular 8 to 12 and particularly preferably 8 to 11 carbon atoms.
- Preferred ionic solubilizers are alkyl ether sulfates, Sulfosuccinic acid surfactants, polyacrylates and phosphonic acids, preferably Lauryl sulfate, lauryl ether sulfate, diisooctyl sodium sulfosuccinate, 1-hydroxyethane-1,1-diphosphonic acid and Diacetyl tartaric acid.
- organic and / or inorganic acids HCl, phosphoric acid, acetic acid, lactic acid and / or citric acid used.
- the amount used is essentially dependent on the type and amount of the amino acid used and should be in in any case to adjust a pH value of the overall formulation from approx. 3 to 9 are sufficient. Quantities from 0.01 to 10% by weight are usually sufficient for this.
- Desalted or customary tap water can preferably be used as water those with not too high degrees of hardness can be used.
- the agents according to the invention can be produced by mixing of the components in the usual way such as by simultaneous, portionwise or successive addition of Amino acid and organic acid to the submitted, intense stirred and optionally heated solubilizer and subsequent Dosing of the other co-used if necessary Components.
- the active compound combinations according to the invention can also be used the known zinc ricinoleates on the market in all usual Deformulations can be incorporated. These include pump spray solutions, Liquid soaps, deodorant sprays and deodorant creams. As well it is usually possible to use the corresponding formulations in others used cosmetic products such as hair shampoos or add hair conditioners if known incompatibilities do not exclude this from the outset.
- detergent formulations Find use such as in hand dishwashing detergents, All-purpose cleaners, carpet cleaners, wipes (deowipes) or as a room spray, deodorising household cleaners, Industrial cleaners, adsorbers in filters, deodorising effective formulations for use in private and commercial animal husbandry, deodorising formulations for the treatment of textile fibers and fabrics.
- the processing in cleaning agent concentrates was checked to document the easier incorporation in known surfactant systems.
- the surfactant systems used are concentrates for easy manufacture of the respective fields of application.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
Description
Mit Beispiel K-6 wurde ein Deostick entwickelt. Stick-Formulierung | |
Beispiel A-13 | |
Varonic® APM | 70,5 |
Na-Stearat | 8,0 |
Propylenglykol | 10,0 |
Wasser | 3,0 |
Parfüm | 1,0 |
Beispiel K-6 | 7,5 |
Zn-ricinoleat Gehalt | 1,7 |
Claims (10)
- Zubereitungen mit desodorierender Wirkung, dadurch gekennzeichnet, dass sie enthaltena) das Zinksalz der Ricinolsäure,b) aminofunktionelle Aminosäuren,c) Lösungsvermittler,d) organische und/oder anorganische Säuren und gegebenenfallse) Wasser.
- Zubereitungen mit desodorierender Wirkung gemäß Anspruch 1, dadurch gekennzeichnet, dass sie enthaltena) 0,01 bis 60 Gew.-% Zinksalz der Ricinolsäure,b) 0,01 bis 40 Gew.-% aminofunktionelle Aminosäuren,c) 0,01 bis 40 Gew.-% Lösungsvermittler,d) 0,01 bis 10 Gew.-% organische und/oder anorganische Säuren und gegebenenfallse) ad 100 Gew.-% Wasser.
- Zubereitungen mit desodorierender Wirkung gemäß Ansprüche 1 und 2, dadurch gekennzeichnet, dass sie als aminofunktionelle Aminosäuren mindestens eine der Verbindungen Lysin, Hydroxylysin, Arginin und/oder deren Derivate oder Salze enthalten.
- Zubereitungen mit desodorierender Wirkung gemäß Ansprüche 1 bis 3, dadurch gekennzeichnet, dass sie als Lösungsvermittler ionische Tenside, nichtionische Tenside und/oder Glykole enthalten.
- Zubereitungen mit desodorierender Wirkung gemäß Ansprüche 1 bis 4, dadurch gekennzeichnet, dass sie als organische Säuren Essigsäure, Milchsäure und/oder Citronensäure enthalten.
- Verwendung der Zubereitungen gemäß Anspruch 1 zur Herstellung von desodorierend wirkenden hygienischen und kosmetischen Formulierungen.
- Verwendung der Zubereitungen gemäß Anspruch 1 zur Herstellung von Deodorantien.
- Verwendung der Zubereitungen gemäß Anspruch 1 zur Herstellung desodorierend wirkenden Haushaltsreinigern, Industriereinigern, Adsorbern in Filtern.
- Verwendung der Zubereitungen gemäß Anspruch 1 zur Herstellung von desodorierend wirkenden Formulierungen für die Anwendung in der privaten und gewerblichen Tierhaltung.
- Verwendung der Zubereitungen gemäß Anspruch 1 zur Herstellung desodorierend wirkenden Formulierungen für die Behandlung von textilen Fasern und Geweben.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE10160933 | 2001-12-12 | ||
DE10160933.7A DE10160933B4 (de) | 2001-12-12 | 2001-12-12 | Zubereitungen mit desodorierender Wirkung, enthaltend das Zinksalz der Ricinolsäure und mindestens eine aminofunktionelle Aminosäure |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1319394A1 true EP1319394A1 (de) | 2003-06-18 |
Family
ID=7708872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02026632A Ceased EP1319394A1 (de) | 2001-12-12 | 2002-11-29 | Zubereitungen mit desodorierender Wirkung, enthaltend das Zinksalz der Ricinolsäure und mindestens eine aminofunktionelle Aminosäure |
Country Status (5)
Country | Link |
---|---|
US (2) | US7226584B2 (de) |
EP (1) | EP1319394A1 (de) |
JP (1) | JP2003226630A (de) |
CA (1) | CA2411225C (de) |
DE (1) | DE10160933B4 (de) |
Cited By (25)
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DE102007012743A1 (de) | 2007-03-16 | 2008-09-18 | Neenah Gessner Gmbh | Geruchsabsorbierendes Flächengebilde, Verfahren zu seiner Herstellung und Verwendung von Zink-Ricinoleat in feinverteilter fester Form auf geruchsabsorbierenden Flächengebilden |
WO2008145175A1 (en) * | 2007-05-28 | 2008-12-04 | Nm Tech Nanomaterials Microdevice Technology Ltd. | Breathing means |
DE102008010774A1 (de) | 2007-12-21 | 2009-06-25 | Cam-D Technologies Gmbh | Grenzflächenaktive Metallkomplexe zur Adsorption von Schadstoffen sowie Verfahren zu ihrer Herstellung |
EP2108446A1 (de) | 2008-04-08 | 2009-10-14 | Süd-Chemie Ag | Feste Geruchsadsorber auf der Basis von Zinkricinoleaten und verwandten Verbindungen |
DE102008017796A1 (de) | 2008-04-08 | 2009-10-15 | Süd-Chemie AG | Schichtsilicathaltige Geruchsadsorber auf der Basis von Zinkricinoleaten und verwandten Verbindungen |
WO2012016829A1 (de) * | 2010-08-03 | 2012-02-09 | Henkel Ag & Co. Kgaa | Textilbehandlungsmittel zur entfernung von deodorant-flecken |
US9498421B2 (en) | 2012-12-19 | 2016-11-22 | Colgate-Palmolive Company | Two component compositions containing tetrabasic zinc-amino acid halide complexes and cysteine |
US9504858B2 (en) | 2012-12-19 | 2016-11-29 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
US9572756B2 (en) | 2012-12-19 | 2017-02-21 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor |
US9675823B2 (en) | 2012-12-19 | 2017-06-13 | Colgate-Palmolive Company | Two component compositions containing zinc amino acid halide complexes and cysteine |
US9750670B2 (en) | 2012-12-19 | 2017-09-05 | Colgate-Palmolive Company | Zinc amino acid complex with cysteine |
US9757316B2 (en) | 2012-12-19 | 2017-09-12 | Colgate-Palmolive Company | Zinc-lysine complex |
US9763865B2 (en) | 2012-12-19 | 2017-09-19 | Colgate-Palmolive Company | Oral gel comprising zinc-amino acid complex |
US9775792B2 (en) | 2012-12-19 | 2017-10-03 | Colgate-Palmolive Company | Oral care products comprising a tetrabasic zinc-amino acid-halide complex |
US9827177B2 (en) | 2012-12-19 | 2017-11-28 | Colgate-Palmolive Company | Antiperspirant products with protein and antiperspirant salts |
US9861563B2 (en) | 2012-12-19 | 2018-01-09 | Colgate-Palmolive Company | Oral care products comprising tetrabasic zinc chloride and trimethylglycine |
US9901523B2 (en) | 2012-12-19 | 2018-02-27 | Colgate-Palmolive Company | Oral care products comprising zinc oxide and trimethylglycine |
US9925130B2 (en) | 2012-12-19 | 2018-03-27 | Colgate-Palmolive Company | Composition with zinc amino acid/trimethylglycine halide precursors |
US9943473B2 (en) | 2012-12-19 | 2018-04-17 | Colgate-Palmolive Company | Zinc lysine halide complex |
US9980890B2 (en) | 2012-12-19 | 2018-05-29 | Colgate-Palmolive Company | Zinc amino acid halide mouthwashes |
US10105303B2 (en) | 2012-12-19 | 2018-10-23 | Colgate-Palmolive Company | Oral care composition comprising zinc amino acid halides |
FR3065733A1 (fr) * | 2017-04-28 | 2018-11-02 | Omnium National Industriel Des Peintures | Utilisation d'un sel d'acide ricinoleique comme additif a une peinture pour la destruction des mauvaises odeurs, composition de peinture le contenant, et procede de destruction des mauvaises odeurs dans l'air |
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DE102007045724B4 (de) | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
US8318806B2 (en) | 2007-10-03 | 2012-11-27 | Zorbx Inc. | Deodorizing composition and method of forming thereof |
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US20130139327A1 (en) * | 2010-08-03 | 2013-06-06 | Henkel Ag & Co. Kgaa | Textile treatment composition for removal of deodorant stains |
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US20190365560A1 (en) * | 2016-12-07 | 2019-12-05 | Emory University | Deodorizing Compositions, Ostomy Devices, and Uses Thereof |
US20180161469A1 (en) * | 2016-12-09 | 2018-06-14 | Ningbo Jiangbei Ocean Star Trading Co., Ltd. | Toilet Deodorizer |
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US11905492B2 (en) | 2020-02-21 | 2024-02-20 | Illinois Tool Works Inc. | Odor removing composition comprising zinc ricinoleate and fluorosurfactant and methods of making thereof |
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US20030158079A1 (en) * | 2001-10-19 | 2003-08-21 | The Procter & Gamble Company | Controlled benefit agent delivery system |
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- 2002-11-29 EP EP02026632A patent/EP1319394A1/de not_active Ceased
- 2002-12-04 US US10/309,432 patent/US7226584B2/en not_active Expired - Lifetime
- 2002-12-12 JP JP2002360582A patent/JP2003226630A/ja active Pending
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- 2007-02-15 US US11/675,280 patent/US20070154427A1/en not_active Abandoned
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DE102007012743A1 (de) | 2007-03-16 | 2008-09-18 | Neenah Gessner Gmbh | Geruchsabsorbierendes Flächengebilde, Verfahren zu seiner Herstellung und Verwendung von Zink-Ricinoleat in feinverteilter fester Form auf geruchsabsorbierenden Flächengebilden |
EP1972247A1 (de) | 2007-03-16 | 2008-09-24 | Neenah Gessner GmbH | Geruchsabsorbierendes Flächengebilde, Verfahren zu seiner Herstellung un Verwendung von Zink-Ricinoleat in feinverteilter fester Form auf geruchsabsorbierenden Flächengebilden |
US8715820B2 (en) | 2007-03-16 | 2014-05-06 | Neenah Gessner Gmbh | Odour-absorbing sheet-like structure, method for its production and use of zinc ricinoleate in finely divided solid form on odour-absorbing sheet-like structures |
WO2008145175A1 (en) * | 2007-05-28 | 2008-12-04 | Nm Tech Nanomaterials Microdevice Technology Ltd. | Breathing means |
DE102008010774A1 (de) | 2007-12-21 | 2009-06-25 | Cam-D Technologies Gmbh | Grenzflächenaktive Metallkomplexe zur Adsorption von Schadstoffen sowie Verfahren zu ihrer Herstellung |
WO2009083070A2 (de) | 2007-12-21 | 2009-07-09 | Cam-D Technologies Gmbh | Grenzflächenaktive metallkomplexe zur adsorption von schadstoffen sowie verfahren zu ihrer herstellung |
EP2108446A1 (de) | 2008-04-08 | 2009-10-14 | Süd-Chemie Ag | Feste Geruchsadsorber auf der Basis von Zinkricinoleaten und verwandten Verbindungen |
WO2009124750A1 (de) * | 2008-04-08 | 2009-10-15 | Süd-Chemie AG | Feste geruchsadsorber auf der basis von zinkricinoleaten und verwandten verbindungen |
DE102008017796A1 (de) | 2008-04-08 | 2009-10-15 | Süd-Chemie AG | Schichtsilicathaltige Geruchsadsorber auf der Basis von Zinkricinoleaten und verwandten Verbindungen |
WO2012016829A1 (de) * | 2010-08-03 | 2012-02-09 | Henkel Ag & Co. Kgaa | Textilbehandlungsmittel zur entfernung von deodorant-flecken |
US9827177B2 (en) | 2012-12-19 | 2017-11-28 | Colgate-Palmolive Company | Antiperspirant products with protein and antiperspirant salts |
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US9993407B2 (en) | 2012-12-19 | 2018-06-12 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor |
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US10188112B2 (en) | 2012-12-19 | 2019-01-29 | Colgate-Palmolive Company | Personal cleansing compositions containing zinc amino acid/trimethylglycine halide |
US10195125B2 (en) | 2012-12-19 | 2019-02-05 | Colgate-Palmolive Company | Oral care composition comprising zinc-lysine complex |
US10245222B2 (en) | 2012-12-19 | 2019-04-02 | Colgate-Palmolive Company | Dentifrice comprising zinc-amino acid complex |
US10524995B2 (en) | 2012-12-19 | 2020-01-07 | Colgate-Palmolive Company | Zinc amino acid halide mouthwashes |
US10588841B2 (en) | 2012-12-19 | 2020-03-17 | Colgate-Palmolive Company | Oral care compositions comprising zinc amino acid halides |
US10610470B2 (en) | 2012-12-19 | 2020-04-07 | Colgate-Palmolive Company | Oral care composition zinc-lysine complex |
US10610475B2 (en) | 2012-12-19 | 2020-04-07 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor |
US10792236B2 (en) | 2012-12-19 | 2020-10-06 | Colgate-Palmolive Company | Dentifrice comprising zinc-amino acid complex |
FR3065733A1 (fr) * | 2017-04-28 | 2018-11-02 | Omnium National Industriel Des Peintures | Utilisation d'un sel d'acide ricinoleique comme additif a une peinture pour la destruction des mauvaises odeurs, composition de peinture le contenant, et procede de destruction des mauvaises odeurs dans l'air |
DE102019115279B3 (de) * | 2019-06-06 | 2020-10-15 | Schill + Seilacher Gmbh | Verfahren zur Herstellung eines Zinkderivats einer N-Acylaminosäure und dessen Verwendung |
EP3981888A1 (de) | 2020-08-19 | 2022-04-13 | Schill + Seilacher GmbH | Zurichtmittel für leder |
Also Published As
Publication number | Publication date |
---|---|
US20070154427A1 (en) | 2007-07-05 |
DE10160933A1 (de) | 2003-06-18 |
US7226584B2 (en) | 2007-06-05 |
CA2411225A1 (en) | 2003-06-12 |
JP2003226630A (ja) | 2003-08-12 |
US20030133892A1 (en) | 2003-07-17 |
DE10160933B4 (de) | 2018-06-21 |
CA2411225C (en) | 2009-11-03 |
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