EP1272602B2 - Wasserenthärter in form eines brausepulvers - Google Patents

Wasserenthärter in form eines brausepulvers Download PDF

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Publication number
EP1272602B2
EP1272602B2 EP01921578A EP01921578A EP1272602B2 EP 1272602 B2 EP1272602 B2 EP 1272602B2 EP 01921578 A EP01921578 A EP 01921578A EP 01921578 A EP01921578 A EP 01921578A EP 1272602 B2 EP1272602 B2 EP 1272602B2
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EP
European Patent Office
Prior art keywords
water
acid
perfume
effervescent system
softener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01921578A
Other languages
English (en)
French (fr)
Other versions
EP1272602A1 (de
EP1272602B1 (de
Inventor
Paul Robinson
Manuela Bosco
Fabio Amiconi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser NV
Original Assignee
Reckitt Benckiser NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the invention relates to a perfumed water-softener composition in powdered form which contains an effervescent system.
  • Cleaning agents and water-softener compositions often contain a perfume or perfume mixture, intended to impart a pleasant fragrance to items to be cleaned, such as laundry, and/or intended to release a fragrance that is pleasant to the user during the washing process, for example, when washing laundry by hand.
  • effervescent systems in detergent compositions - particularly these are in a tablet form - in order to accelerate dissolution in the washing water is known. Examples of this are described in WO98/46714 , WO98/45283 or WO98/04667 which compositions contain surfactants and/or bleaching agents.
  • the underlying objective of the invention is to improve water-softener compositions, preferably in powdered form (powder water softener compositions), so that they produce a perfume effect sustained for a long period during its use.
  • a water-softener composition preferably in powdered form, containing at least one perfume, the composition also containing an effervescent system.
  • the water-softening composition should be essentially free of any surfactant and bleaching agent.
  • the effervescent system contains at least one alkali metal carbonate and/or alkali hydrogen carbonate and at least one acidifying agent, the acidifying agent preferably containing at least one acid, most preferably an organic carboxylic acid.
  • the organic carboxylic acid is a fruit acid, preferably citric acid or malic acid.
  • the invention also relates to the use of an effervescent system, preferably one as described above, used in water-softener compositions, preferably in the form of a powder, containing at least one perfume, to improve the durability of the fragrance given off by this perfume.
  • the invention relates to the use of water-softener compositions, preferably in the form of a powder for applications involving manual laundering.
  • This effect can be regarded as positive with all conceivable water-softener compositions, it is of particular advantage for those in which the duration of the fragrancing effect of the perfume or the perfume mixture is particularly perceptible, i.e. in cases where the composition is deployed in such a way that the user is immediately aware of the perfume effect, such as when used for manual laundering, for example.
  • One particularly preferred application is the addition of an effervescent system to a water-softener composition in a powder form displaced with a fragrance for use in manual laundering, which is preferably added to the washing liquid prior to adding the actual washing agent, in order to enhance the cleansing effect. Tests to date have therefore mainly been conducted on compositions of this type.
  • the system comprising sodium hydrogen carbonate and citric acid
  • the effervescent system in the example described below, it would, of course, also be possible to consider other effervescent systems, in particular those containing other acids, such as polymeric acids or glycolic acid, lactic acid, etc. Tests have shown that the effervescent system as such is not critical to the described effect. On the contrary, there is considerable flexibility, which means that a selection can be made to suit specific circumstances for the use of the water-softening composition.
  • Preferred amounts of acidifying agent are present in the composition in the range of 0.51% w/w to 25% w/w, ideally 1% w/w to 20% w/w, preferably 2% w/w to 10% w/w and especially 2% w/w to 6% w/w.
  • a preferred acidifying agent is citric acid.
  • alkali metal carbonate and/or hydrogen carbonate are present in the composition in the range of 4% w/w to 70% w/w, ideally 15% w/w to 65% w/w, preferably 25% w/w to 60% w/w and especially 40% w/w to 58% w/w.
  • the water softening component of the composition may contain any known water softening compound or mixture, such as water soluble water-softening agent or a water-insoluble water-softening agent, notably alkali-metal aluminosilicate.
  • Water soluble water-softening agent may be organic or inorganic.
  • Inorganic may be present include alkali metal (generally sodium) carbonate; while organic include polycarboxylate polymers, such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates, monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono- di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates and hydroxyethyliminodiacetates.
  • polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphonates
  • monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono- di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates and hydroxyethyliminodiacetates.
  • composition contains only soluble water-softening agent, this may well be a salt of tripolyphosphate and/or ditric acid, such as the sodium salt, and/or a condensed phosphate.
  • Suitable crystalline sodium aluminosilicate ion-exchange detergency builders are described, for example, in GB 1429143 (Procter & Gamble).
  • the preferred sodium aluminosilicates of this type are the well known commercially available zeolites A and X, and mixtures thereof.
  • Also of interest is the novel zeolite P described and claimed in EP 384070 (Unilever).
  • water-insoluble material which can function as a water-softening agent is the layered sodium silicate builders disclosed in US-A-4464839 and US-A-4820439 and also referred to in EP-A-551375 .
  • water-soluble water-softening agent as described above, jointly with aluminosilicate, to enhance water-softening efficacy.
  • Such water-soluble soluble water-softening agent are generally used in an amount which is not greater than the amount of aluminosilicate, often less than half the amount of aluminosilicate.
  • Preferred amounts of the water-softening component are present in the composition in the range of 4% w/w to 65% w/w, ideally 15% w/w to 60% w/w, preferably 25% to 55% w/w and especially 35% w/w to 48% w/w.
  • the amount of perfume added to the composition is dependent upon the desired effect wanted to be achieved. Typical amounts may be from 0.05% w/w to 2% w/w.
  • composition is preferbly in the form of a powder, however other solid formulations are contemplated such as tablets, either made by compaction or by extruding.
  • Liquid formulations may also be used in which the ingredients may be suspended or dissolved in a nonaqueous liquid carrier medium, such liquid media include;
  • composition of samples I to IV is set out more specifically in Table I below.
  • Table I Sodium tripolyphosphate Sodium hydrogen carbonate Citric acid Fragrance I 42.53 44.88 12.00 0.12 II 42.53 50.88 6.00 0.12 III 42.53 53.88 3.00 0.12 IV 42.54 56.88 - 0.12

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Paints Or Removers (AREA)
  • Fats And Perfumes (AREA)

Claims (6)

  1. Verwendung eines Sprudelsystems in Wasserenthärterzusammensetzungen, enthaltend mindestens ein Parfum zum Verbessern der Dauer der Duftwirkung dieses Parfums, wobei die Wasserenthärterzusammensetzung in Pulverform vorliegt und im Wesentlichen frei von jeglichem oberflächenaktiven Mittel und Bleichmittel ist, für Anwendungen unter Beteiligung von Handwäsche.
  2. Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass das Sprudelsystem mindestens ein Alkalimetallcarbonat und/oder - hydrogencarbonat und mindestens ein Säuerungsmittel enthält.
  3. Verwendung nach Anspruch 2, dadurch gekennzeichnet, dass das Säuerungsmittel mindestens eine Säure enthält.
  4. Verwendung nach Anspruch 3, dadurch gekennzeichnet, dass die Säure eine Carbonsäure ist.
  5. Verwendung nach Anspruch 4, dadurch gekennzeichnet, dass die Fruchtsäure Zitronensäure oder Äpfelsäure ist.
  6. Verwendung nach Anspruch 1, wobei die Wasserenthärterzusammensetzung Folgendes umfasst:
    1) 4 Gew.-% bis 65 Gew.-% einer Wasserenthärterverbindung oder eines Gemischs davon;
    2) 4 Gew.-% bis 70 Gew.-% eines Alkalimetallcarbonats und/oder -hydrogencarbonats;
    3) 0,51 Gew.-% bis 25 Gew.-% eines Säuerungsmittels;
    4) und ein Parfum.
EP01921578A 2000-04-14 2001-04-12 Wasserenthärter in form eines brausepulvers Expired - Lifetime EP1272602B2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10018570 2000-04-14
DE10018570 2000-04-14
PCT/GB2001/001679 WO2001079411A1 (en) 2000-04-14 2001-04-12 Water-softener in powdered form with an effervescent system

Publications (3)

Publication Number Publication Date
EP1272602A1 EP1272602A1 (de) 2003-01-08
EP1272602B1 EP1272602B1 (de) 2006-06-14
EP1272602B2 true EP1272602B2 (de) 2009-10-28

Family

ID=7638775

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01921578A Expired - Lifetime EP1272602B2 (de) 2000-04-14 2001-04-12 Wasserenthärter in form eines brausepulvers

Country Status (7)

Country Link
EP (1) EP1272602B2 (de)
AT (1) ATE329996T1 (de)
AU (1) AU2001248552A1 (de)
DE (1) DE60120668T3 (de)
ES (1) ES2264977T5 (de)
GB (1) GB2364302B (de)
WO (1) WO2001079411A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2666260A1 (en) * 2006-10-14 2008-04-17 Reckitt Benckiser N.V. Composition

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3512717A1 (de) † 1984-04-12 1985-10-31 Kao Corp., Tokio/Tokyo Schwach saure badesalz-zusammensetzung
US4650667A (en) † 1982-10-15 1987-03-17 Kao Corporation Gas-emitting bath additive composition
EP0229616A2 (de) † 1986-01-08 1987-07-22 Kao Corporation Badezusatz
EP0456315A2 (de) † 1990-05-08 1991-11-13 The Procter & Gamble Company Niedrig-pH-Waschmittelgranulate enthaltend Aluminiumsilikat, Zitronensäure und Carbonatbuilder
WO1992018596A1 (en) † 1991-04-19 1992-10-29 The Procter & Gamble Company Granular laundry detergent compositions having improved solubility
EP0537584A1 (de) † 1991-10-12 1993-04-21 Henkel KGaA Duftstoffe enthaltende Tablette
DE4420735A1 (de) † 1994-06-15 1995-12-21 Allphamed Arzneimittel Gmbh Verfahren zur Herstellung mechanisch stabiler, sich mit hoher Auflösegeschwindigkeit auszeichnender Brausetabletten
WO1998035011A1 (de) † 1997-02-06 1998-08-13 Henkel Kommanditgesellschaft Auf Aktien Verwendung von cobuilder-haltigen additiven in wasch- oder reinigungsmitteln
EP0922450A1 (de) † 1997-12-01 1999-06-16 Gerhard Dr. Gergely Brausezubereitung enthaltend ein Pflanzenextrakt
US5955057A (en) † 1998-06-12 1999-09-21 Biotech Holdings Ltd. Effervescing or foaming bath shape or solid
US5993854A (en) † 1997-09-17 1999-11-30 Phyzz, Inc. Exothermic effervescent composition for improved fragrance dispersion
WO2000075079A1 (de) † 1999-06-05 2000-12-14 Herbst Juergen Verfahren zum dispergieren von unlöslichen mineralischen sedimenten sowie additive zur durchführung des verfahrens
WO2000077150A1 (de) † 1999-06-10 2000-12-21 Henkel Kommanditgesellschaft Auf Aktien Lagerstabile brausetabletten
EP1082957A1 (de) † 1999-09-09 2001-03-14 Gergely, Gerhard Brausegranulat mit verzögerter Brausewirkung

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477174A1 (fr) * 1980-02-28 1981-09-04 Lichtenberg Jean Paul Detergent en comprime
JPS56164110A (en) * 1980-05-20 1981-12-17 Mitsubishi Chem Ind Ltd Foaming bath liquid
JPS60146821A (ja) * 1983-12-29 1985-08-02 Sansho Seiyaku Kk 浴剤
JPH0660320B2 (ja) * 1985-09-25 1994-08-10 花王株式会社 香料造粒物
US5476607A (en) * 1993-12-01 1995-12-19 Warner-Lambert Company Perborate:persulfate:protease denture cleanser powder composition
GB2315762A (en) * 1996-07-31 1998-02-11 Procter & Gamble Detergent composition comprising a dicarboxylic acid source and an alkaline source
DE19745964A1 (de) * 1996-12-24 1998-06-25 Wella Ag Selbstschäumende Instantshampoo-Zubereitung
MA24525A1 (fr) * 1997-04-14 1998-12-31 Procter & Gamble Particule detergente

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4650667A (en) † 1982-10-15 1987-03-17 Kao Corporation Gas-emitting bath additive composition
DE3512717A1 (de) † 1984-04-12 1985-10-31 Kao Corp., Tokio/Tokyo Schwach saure badesalz-zusammensetzung
EP0229616A2 (de) † 1986-01-08 1987-07-22 Kao Corporation Badezusatz
EP0456315A2 (de) † 1990-05-08 1991-11-13 The Procter & Gamble Company Niedrig-pH-Waschmittelgranulate enthaltend Aluminiumsilikat, Zitronensäure und Carbonatbuilder
WO1992018596A1 (en) † 1991-04-19 1992-10-29 The Procter & Gamble Company Granular laundry detergent compositions having improved solubility
EP0537584A1 (de) † 1991-10-12 1993-04-21 Henkel KGaA Duftstoffe enthaltende Tablette
DE4420735A1 (de) † 1994-06-15 1995-12-21 Allphamed Arzneimittel Gmbh Verfahren zur Herstellung mechanisch stabiler, sich mit hoher Auflösegeschwindigkeit auszeichnender Brausetabletten
WO1998035011A1 (de) † 1997-02-06 1998-08-13 Henkel Kommanditgesellschaft Auf Aktien Verwendung von cobuilder-haltigen additiven in wasch- oder reinigungsmitteln
US5993854A (en) † 1997-09-17 1999-11-30 Phyzz, Inc. Exothermic effervescent composition for improved fragrance dispersion
EP0922450A1 (de) † 1997-12-01 1999-06-16 Gerhard Dr. Gergely Brausezubereitung enthaltend ein Pflanzenextrakt
US5955057A (en) † 1998-06-12 1999-09-21 Biotech Holdings Ltd. Effervescing or foaming bath shape or solid
WO2000075079A1 (de) † 1999-06-05 2000-12-14 Herbst Juergen Verfahren zum dispergieren von unlöslichen mineralischen sedimenten sowie additive zur durchführung des verfahrens
WO2000077150A1 (de) † 1999-06-10 2000-12-21 Henkel Kommanditgesellschaft Auf Aktien Lagerstabile brausetabletten
EP1082957A1 (de) † 1999-09-09 2001-03-14 Gergely, Gerhard Brausegranulat mit verzögerter Brausewirkung

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"Enzyklopädie Naturwissenschaft und Technik", vol. 1, part A-D 1979, VERLAG MODERNE INDUSTRIE, MÜNCHEN, article "Aromastoffe", pages: 268 †
"Römpp-Chemie-Lexikon", vol. 4, part M-PK 1991, GEORG THIEME VERLAG, STUTTGART, article "Natriumaluminate", pages: 2917 †
Priorutätsdokument DE 100 18 570 †

Also Published As

Publication number Publication date
EP1272602A1 (de) 2003-01-08
EP1272602B1 (de) 2006-06-14
DE60120668T2 (de) 2007-06-06
GB2364302A (en) 2002-01-23
WO2001079411A8 (en) 2002-02-14
ATE329996T1 (de) 2006-07-15
GB2364302B (en) 2002-06-26
WO2001079411A1 (en) 2001-10-25
DE60120668D1 (de) 2006-07-27
DE60120668T3 (de) 2010-05-20
ES2264977T5 (es) 2010-04-06
ES2264977T3 (es) 2007-02-01
AU2001248552A1 (en) 2001-10-30
GB0109194D0 (en) 2001-05-30

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