EP1237433B1 - HERSTELLUNG EINES INNENFUTTERs FÜR DIE SCHUHINDUSTRIE - Google Patents
HERSTELLUNG EINES INNENFUTTERs FÜR DIE SCHUHINDUSTRIE Download PDFInfo
- Publication number
- EP1237433B1 EP1237433B1 EP00969441A EP00969441A EP1237433B1 EP 1237433 B1 EP1237433 B1 EP 1237433B1 EP 00969441 A EP00969441 A EP 00969441A EP 00969441 A EP00969441 A EP 00969441A EP 1237433 B1 EP1237433 B1 EP 1237433B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- nonwoven fabric
- process according
- multicomponent
- endless
- fabric used
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/016—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the fineness
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/07—Linings therefor
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
- D04H3/011—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
- D04H3/11—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
Definitions
- the invention relates to a method for producing an inner lining for the shoe industry.
- Abrasion-resistant materials are used in the shoe industry for lining the inner part of a shoe, the so-called inner lining. This On the one hand, materials are supposed to transport moisture through perspiration Support from the foot outwards to ensure a dry foot on the other hand, they are supposed to act on the forces occurring during the rolling motion Distribute shoe leather over large areas to prevent wrinkles and the to avoid associated faster wear.
- thermally bonded and embossed calendars have been used for this purpose
- Polyamide nonwovens, roughened or brushed knitted fabrics with a textile look and soft handle, textured fabric, synthetic leather based on Polyurethane coagulates or split leather natural raw materials are used Service.
- the invention has for its object to provide a manufacturing method for an inner lining for the shoe industry, which has basis strengths of 80 to 170 g / m 2 tearing and tear propagation resistance in both the longitudinal and transverse directions> 7 N, and the disadvantages in Avoid prior art.
- an inner lining is produced which has a basis weight of 80 to 170 g / m 2 and tear strength both in the longitudinal and transverse directions> 7 N, the inner lining being made of melt-spun, aerodynamically stretched and immediately deposited into a nonwoven multi-component continuous filament with a There is a titer of 1.5 to 5 dtex and the multicomponent continuous filaments, after pre-consolidation, are split and solidified at least 80% to the micro continuous filaments with a titer of 0.1 to 0.8 dtex.
- These linings have high tensile strengths and abrasion resistance with low basis weights.
- no hemming is required due to the endless filaments and there is no chamfering and thickening in the area of the seams and thus possible pressure points are avoided.
- the inner lining is preferably one in which the nonwoven fabric is made of melt-spun, aerodynamically stretched and instantly one Non-woven deposited multi-component continuous filaments with a titer of 2 to 3 dtex exists and the multi-component continuous filaments if necessary after pre-consolidation at least 80% with micro continuous filaments a titer of 0.1 to 0.5 dtex are split and solidified.
- the inner lining has an isotropic distribution of filaments in the fleece. Hence one Consideration of the machine direction when cutting the inner lining not mandatory.
- the inner lining is preferably one in which the multicomponent continuous filament is a bicomponent continuous filament made of two incompatible polymers, in particular a polyester (PES) and a polyamide (PA).
- the multi-component continuous filament therefore has good splittability and a very favorable ratio of strength to basis weight.
- the inner lining is preferably one in which the multicomponent continuous filaments have a cross section with an orange-like or also called "pie" multi-segment structure, the segments alternately each containing one of the two incompatible polymers.
- a "side-by-side" (s / s) segment arrangement of the incompatible polymers in the multicomponent filament is also possible, which is preferably used to produce crimped filaments.
- Such segment arrangements of the incompatible polymers in the multi-component continuous filament have proven to be very easy to split.
- the inner lining has a very favorable ratio of basis weight to insulation, so that soft and warm inner lining can be produced in particular by subsequent treatment steps such as roughing.
- the inner lining is preferably one in which the from the Multi-component continuous filaments formed nonwoven for pre-consolidation is precalanded.
- the material therefore has a very good quality Thickness uniformity.
- a lining is a material with a textile look and a abrasion-resistant surface preferred, which by treatment with high pressure water jets on a structured and / or open mesh sieve pad was obtained.
- an inner lining is particularly preferred in which at least one the incompatible polymers that form as a multi-component continuous filament an additive, such as color pigments, permanent antistatic agents and / or the additives influencing hydrophilic or hydrophobic properties in Contains amounts up to 15 wt .-%.
- the inner lining can thereby its lightfastness, the tendency to static charge, the Sweat transport or the moisture retention effect can be positively influenced.
- the addition of the color pigments to the dope enables Production of deep and abrasion-resistant colors.
- the inner lining is advantageously one in which one of the sides has a Hot melt adhesive application is provided.
- a material is especially for suitable for further processing on automatic machines.
- the method according to the invention for producing the inner lining consists in the fact that multi-component continuous filaments are spun from the melt, aerodynamically stretched and immediately laid down to form a fleece, if necessary, pre-consolidation by pre-calendering or needling takes place and the nonwoven is solidified by high pressure fluid jets as well simultaneously in micro continuous filaments with a titer of 0.1 to 0.8 dtex, preferably with a titer of 0.1 to 0.5 dtex.
- the so products obtained are very uniform in terms of their Strength stability because a largely isotropic thread distribution in the Product is present.
- the products show no tendency to delamination and have high module values and tear and tear strength.
- Farther have the inner lining according to the invention very good Moisture wicking properties that the comfort of the provided Wet with regard to water vapor transport and drying Favor shoes.
- Another advantageous embodiment of the method is that the Solidification and splitting of the multi-component continuous filaments takes place that the optionally pre-consolidated nonwoven fabric at least once high pressure water jets are applied to each side. That kind of Solidification and splitting of the multi-component continuous filaments leads to very dense nonwovens with smooth surfaces.
- the last high pressure water jet treatment is on one Sieve pad made with mesh sizes from 5 to 50 mesh.
- the inner lining material is additionally solidified, it becomes more abrasion-resistant and receives one textile optics.
- the impregnated material is preferably also post-treatment such as dyeing, tumbling, grinding and / or sanforizing. By these measures can affect the surface finish and the grip of the obtained material can be improved.
- a filament pile with a basis weight of 110 g / m 2 is produced from a PES-PA bicomponent continuous filament and alternately subjected to water jet needling with pressures of up to 280 bar from both sides.
- the water jet needling takes place in a total of four treatment passages, the fourth passage taking place on a 20 mesh sieve pad. This creates a structured and / or perforated surface and gives the inner lining a textile look and a soft feel.
- the water jet needling simultaneously splits the starting filaments to a titer of ⁇ 0.2 dtex.
- the inner lining produced in this way is subjected to jet dyeing and can be used without regard to the machine direction.
- the inner lining obtained has the strength parameters given in the table below and is well suited for the stated purpose.
- characteristics Unit of measurement value
- Weight g / m 2 110 Module 10% lengthways N / 5 cm 60 Module 10% across N / 5 cm 40 Tear force along N 8th Tear strength across N 8th Martindale (abrasion at 12 kPa) Note dry after 51200 tours Touch wet after 12800 tours Good Good
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Woven Fabrics (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paper (AREA)
Description
Vorzugsweise ist das Innenfutter eines, bei dem die Mehrkomponenten-Endlosfilamente einen Querschnitt mit orangenartiger oder auch "Pie" genannten Multisegment-Struktur aufweisen, wobei die Segmente alternierend jeweils eines der beiden inkompatiblen Polymeren enthalten. Neben dieser orangenartigen Multisegment-Struktur der Mehrkomponenten-Endlosfilamente ist auch eine "side-by-side" (s/s) Segment-Anordnung der inkompatiblen Polymeren im Mehrkomponenten-Endlosfilament möglich, die vorzugsweise zur Erzeugung gekräuselter Filamente genutzt wird. Solche Segment-Anordnungen der inkompatiblen Polymeren im Mehrkomponenten-Endlosfilament haben sich als sehr gut splittbar erwiesen. Das Innenfutter besitzt ein sehr günstiges Verhältnis von Flächengewicht zum Isolationsvermögen, so daß sich insbesondere durch nachfolgende Behandlungsschritte wie Rauhen weiche und wärmende Innenfutter herstellen lassen.
Eigenschaften | Maßeinheit | Wert |
Gewicht | g/m2 | 110 |
Modul 10% längs | N/5 cm | 60 |
Modul 10% quer | N/5 cm | 40 |
Weiterreißkraft längs | N | 8 |
Weiterreißkraft quer | N | 8 |
Martindale (Abrieb bei 12 kPa) | Note trocken nach 51200 Touren Note naß nach 12800 Touren | gut gut |
Claims (12)
- Verfahren zur Herstellung eines Schuh-Innenfutters dadurch gekennzeichnet, daß dazu ein ungesäumter, ohne Beachtung der Maschinenlaufrichtung zugeschnittener Vliesstoff bestehend aus einem Mikrofilament-Vliesstoff mit Flächengewichten von 80 bis 170 g/m2 und Weiterreißfestigkeiten sowohl in Längs- als auch in Querrichtung > 7 N, wobei der Vliesstoff aus schmelzgesponnenen, aerodynamisch verstreckten und unmittelbar zu einem Vlies abgelegten Mehrkomponenten-Endlosfilamenten mit einem Titer von 1,5 bis 5 dtex besteht und die Mehrkomponenten-Endlosfilamente nach einer Vorverfestigung zumindest zu 80 % zu Mikro-Endlosfilamenten mit einem Titer von 0,1 bis 0,8 dtex gesplittet und verfestigt sind, verwendet wird.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß der verwendete Vliesstoff aus schmetzgesponnenen, aerodynamisch verstreckten und unmittelbar zu einem Vlies abgelegten Mehrkomponenten-Endlosfilamenten mit einem Titer von 2 bis 3 dtex besteht und die Mehrkomponenten-Endlosfilamente gegebenenfalls nach einer Vorverfestigung zumindest zu 80 % zu Mikro-Endlosfilamenten mit einem Titer von 0,1 bis 0,5 dtex gesplittet und verfestigt sind.
- Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß das Mehrkomponenten-Endlosfilamentdes verwendeten Vliesstoffs ein Bikomponenten-Endlosfilament aus zwei inkompatiblen Polymeren, insbesondere einem Polyester und einem Polyamid, ist.
- Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Mehrkomponenten-Endlosfilamente des verwendeten Vliesstoffs einen Querschnitt mit orangenartiger Multisegment-Struktur oder eine "side-by-side"-Struktur aufweisen, wobei die Segmente alternierend jeweils eines der beiden inkompatiblen Polymeren enthalten.
- Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß der aus dem Mehrkomponenten-Endiosfilamenten gebildete Vliesstoff zur Vorverfestigung prekalandriert ist.
- Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß es der verwendete Vllesstoff eine textile Optik aufweist.
- Verfahren nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß mindestens eines der das Mehrkomponenten-Endlosfilament des verwendeten Vllesstoffs bildenden inkompatiblen Polymere ein Additiv, wie Farbpigmente, permanent wirkende Antistatika und / oder hydrophile, charakterbeeinflussende Zusätze in Mengen bis zu 15 Gew.-%, enthält.
- Verfahren nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, daß das Mehrkomponenten-Endlosfilament des verwendeten Vliesstoffs ungekräuselt ist.
- Verfahren nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß eine der Seiten des verwendeten Vllesstoffs mit einem Schmelzkleberauftrag versehen ist.
- Verfahren nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, daß der gegebenenfalls vorverfestigte Vliesstoff durch Beaufschlagung mindestens einmal von jeder Seite mit Hochdruck-Wasserstrahlen verfestigt und In Mikro-Endlosfilamente gesplittet ist.
- Verfahren nach Anspruch 10 , dadurch gekennzeichnet, daß der verwendete Vliesstoff durch die letzte Hochdruck-Wasserstrahlbehandlung auf einer Siebunterlage mit Maschenweiten von 5 bis 50 mesh strukturiert ist.
- Verfahren nach einem der Ansprüche 1 bis 11, dadurch gekennzeichnet, daß der verwendete Vliesstoff durch Färben, Tumbeln, Schleifen und/oder Sanforisieren nachbehandelt ist.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19960063 | 1999-12-13 | ||
DE19960063A DE19960063C2 (de) | 1999-12-13 | 1999-12-13 | Innenfutter für die Schuhindustrie |
PCT/EP2000/009805 WO2001043575A1 (de) | 1999-12-13 | 2000-10-06 | Innenfutter für die schuhindustrie |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1237433A1 EP1237433A1 (de) | 2002-09-11 |
EP1237433B1 true EP1237433B1 (de) | 2004-07-28 |
Family
ID=7932474
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00969441A Expired - Lifetime EP1237433B1 (de) | 1999-12-13 | 2000-10-06 | HERSTELLUNG EINES INNENFUTTERs FÜR DIE SCHUHINDUSTRIE |
Country Status (23)
Country | Link |
---|---|
EP (1) | EP1237433B1 (de) |
JP (1) | JP2003518965A (de) |
KR (1) | KR20020070315A (de) |
CN (2) | CN1391447A (de) |
AT (1) | ATE271794T1 (de) |
AU (1) | AU7915500A (de) |
BG (1) | BG106820A (de) |
BR (1) | BR0016318A (de) |
CA (1) | CA2394700A1 (de) |
CZ (1) | CZ20021937A3 (de) |
DE (2) | DE19960063C2 (de) |
ES (1) | ES2225234T3 (de) |
HR (1) | HRP20020368A2 (de) |
HU (1) | HUP0203530A2 (de) |
MA (1) | MA25689A1 (de) |
MX (1) | MXPA02004804A (de) |
PL (1) | PL356845A1 (de) |
RU (1) | RU2002119057A (de) |
SK (1) | SK8282002A3 (de) |
TR (1) | TR200201541T2 (de) |
WO (1) | WO2001043575A1 (de) |
YU (1) | YU34502A (de) |
ZA (1) | ZA200204509B (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101686896B1 (ko) * | 2016-08-31 | 2016-12-15 | 허민수 | 양모섬유를 이용한 신발 및 신발의 제조에 이용되는 갑피의 제조방법 |
KR102282838B1 (ko) | 2021-05-17 | 2021-07-29 | (주)마이라텍스 | 울 소재 혼방사를 이용한 산업자재용 내피원단의 제조방법 및 이로부터 제조된 원단 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0090397B1 (de) * | 1982-03-31 | 1990-01-24 | Toray Industries, Inc. | Vlies aus ultra feinen verwirrten Fasern, und Verfahren zur Herstellung desselben |
FR2546536B1 (fr) * | 1983-05-25 | 1985-08-16 | Rhone Poulenc Fibres | Procede pour le traitement de nappes non tissees et produit obtenu |
DE29602475U1 (de) * | 1996-02-13 | 1996-04-18 | Spielau, Paul, Dipl.-Chem. Dr., 53844 Troisdorf | Diffusionsoffene Dachunterspannbahn |
FR2749860B1 (fr) * | 1996-06-17 | 1998-08-28 | Freudenberg Spunweb Sa | Nappe non tissee formee de filaments continus tres fins |
GB9626636D0 (en) * | 1996-12-21 | 1997-02-12 | British United Shoe Machinery | Lining material |
JPH10212624A (ja) * | 1997-01-27 | 1998-08-11 | Nippon Ester Co Ltd | 分割型複合繊維 |
DE19947870C1 (de) * | 1999-10-05 | 2001-05-10 | Freudenberg Carl Fa | Fersenfutter für die Schuhindustrie |
-
1999
- 1999-12-13 DE DE19960063A patent/DE19960063C2/de not_active Expired - Fee Related
-
2000
- 2000-10-06 CN CN00816037A patent/CN1391447A/zh active Pending
- 2000-10-06 BR BR0016318-0A patent/BR0016318A/pt not_active IP Right Cessation
- 2000-10-06 PL PL00356845A patent/PL356845A1/xx unknown
- 2000-10-06 AT AT00969441T patent/ATE271794T1/de not_active IP Right Cessation
- 2000-10-06 SK SK828-2002A patent/SK8282002A3/sk unknown
- 2000-10-06 DE DE50007231T patent/DE50007231D1/de not_active Expired - Fee Related
- 2000-10-06 CA CA002394700A patent/CA2394700A1/en not_active Abandoned
- 2000-10-06 CN CNA2005100920692A patent/CN1803042A/zh active Pending
- 2000-10-06 MX MXPA02004804A patent/MXPA02004804A/es not_active Application Discontinuation
- 2000-10-06 RU RU2002119057/12A patent/RU2002119057A/ru not_active Application Discontinuation
- 2000-10-06 HU HU0203530A patent/HUP0203530A2/hu unknown
- 2000-10-06 AU AU79155/00A patent/AU7915500A/en not_active Abandoned
- 2000-10-06 WO PCT/EP2000/009805 patent/WO2001043575A1/de active IP Right Grant
- 2000-10-06 TR TR2002/01541T patent/TR200201541T2/xx unknown
- 2000-10-06 EP EP00969441A patent/EP1237433B1/de not_active Expired - Lifetime
- 2000-10-06 YU YU34502A patent/YU34502A/sh unknown
- 2000-10-06 KR KR1020027007381A patent/KR20020070315A/ko active IP Right Grant
- 2000-10-06 CZ CZ20021937A patent/CZ20021937A3/cs unknown
- 2000-10-06 JP JP2001544522A patent/JP2003518965A/ja active Pending
- 2000-10-06 ES ES00969441T patent/ES2225234T3/es not_active Expired - Lifetime
-
2002
- 2002-04-26 HR HR20020368A patent/HRP20020368A2/hr not_active Application Discontinuation
- 2002-05-02 MA MA26623A patent/MA25689A1/fr unknown
- 2002-06-05 ZA ZA200204509A patent/ZA200204509B/xx unknown
- 2002-06-13 BG BG106820A patent/BG106820A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
HUP0203530A2 (en) | 2008-01-28 |
CN1803042A (zh) | 2006-07-19 |
AU7915500A (en) | 2001-06-25 |
EP1237433A1 (de) | 2002-09-11 |
DE50007231D1 (de) | 2004-09-02 |
WO2001043575A1 (de) | 2001-06-21 |
DE19960063C2 (de) | 2002-03-14 |
RU2002119057A (ru) | 2004-01-10 |
SK8282002A3 (en) | 2002-11-06 |
JP2003518965A (ja) | 2003-06-17 |
BG106820A (en) | 2003-01-31 |
CA2394700A1 (en) | 2001-06-21 |
CZ20021937A3 (cs) | 2002-08-14 |
TR200201541T2 (tr) | 2002-10-21 |
ES2225234T3 (es) | 2005-03-16 |
MA25689A1 (fr) | 2003-04-01 |
KR20020070315A (ko) | 2002-09-05 |
DE19960063A1 (de) | 2001-06-28 |
ATE271794T1 (de) | 2004-08-15 |
ZA200204509B (en) | 2004-01-28 |
CN1391447A (zh) | 2003-01-15 |
YU34502A (sh) | 2004-12-31 |
HRP20020368A2 (en) | 2004-02-29 |
PL356845A1 (en) | 2004-07-12 |
MXPA02004804A (es) | 2003-10-14 |
BR0016318A (pt) | 2002-08-20 |
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