EP1123263A1 - Aufarbeitung verunreinigter fettalkohol-gemische - Google Patents

Aufarbeitung verunreinigter fettalkohol-gemische

Info

Publication number
EP1123263A1
EP1123263A1 EP99953786A EP99953786A EP1123263A1 EP 1123263 A1 EP1123263 A1 EP 1123263A1 EP 99953786 A EP99953786 A EP 99953786A EP 99953786 A EP99953786 A EP 99953786A EP 1123263 A1 EP1123263 A1 EP 1123263A1
Authority
EP
European Patent Office
Prior art keywords
fatty alcohol
alcohol
fatty
alcohol mixtures
contaminated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99953786A
Other languages
German (de)
English (en)
French (fr)
Inventor
Werner Leinemann
Michael KÖHLER
Ulrich Nitsche
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Personal Care and Nutrition GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1123263A1 publication Critical patent/EP1123263A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/94Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07HSUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H15/00Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
    • C07H15/02Acyclic radicals, not substituted by cyclic structures
    • C07H15/04Acyclic radicals, not substituted by cyclic structures attached to an oxygen atom of the saccharide radical

Definitions

  • the invention relates to a process for working up contaminated fatty alcohol mixtures, in which
  • the invention relates to a process for working up contaminated fatty alcohol mixtures, in which
  • Fatty alcohols which serve as a further feed component, are to be understood as primary aliphatic alcohols of the formula (I)
  • R 1 represents an aliphatic, linear or branched hydrocarbon radical having 6 to 22 carbon atoms and 0 and / or 1, 2 or 3 double bonds.
  • Typical examples are capronic alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolenyl alcohol, linolyl alcohol, linoleyl alcohol, linoleyl alcohol Technical mixtures which are obtained, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxosynthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols.
  • acids are used in amounts of 0.1 to 10, preferably 0.5 to 5 and in particular 1% by weight, based on the fatty alcohol.
  • Organic acids such as, for example, sulfosuccinic acid or alkylbenzenesulfonic acids are preferably used, the alkyl radical representing 1 to 14, preferably 1 or 12, carbon atoms.
  • the use of dodecylbenzenesulfonic acid or p-toluenesulfonic acid is preferred.
  • the acid treatment is usually carried out with stirring at pressures from 1 to 200, preferably 20 to 30 mbar and at temperatures from 50 to 120, preferably around 105 ° C.
  • the reaction time is usually 30 minutes to 2 hours.
  • Existing or formed water is distilled off under the conditions mentioned above.
  • the purified fatty alcohol is generally distilled from the residue at a pressure of 1 to 50 mbar, preferably 10 mbar and in a temperature range of 50 to 250, preferably 150 ° C. A residue of 1 to 10% remains in the bladder.
  • Glucose was acetalized with technical C. 4 4 coconut fatty alcohol in a molar ratio of 1: 4 and with the addition of 1% by weight of dodecylbenzenesulfonic acid at 112 ° C. and 20 mbar to the alkyl oligoglycocoside.
  • the water of condensation was continuously removed from the equilibrium.
  • the reaction was complete and the excess fatty alcohol was separated from the reaction product in a combination of a falling film and a thin film evaporator. The fatty alcohol was worked up separately.
  • the alcohol separated from the acetalization was, as described in EP 0387912 B1, washed with an aqueous solution of 42% by weight NaOH and 12% by weight sodium borohydride, distilled and then returned to the reaction mixture. When returned to the acetalization, the reaction time increased from 6.5 to 7.5 hours.
  • the fatty alcohol separated from the reaction mixture was mixed with 1% by weight of dodecylbenzenesulfonic acid and stirred at 105 ° C. and 30 mbar for 1 hour. The pressure was then reduced to 1 mbar and the temperature increased to 150 ° C., so that the fatty alcohol distilled over into the receiver. A 5% residue remained in the bladder. When returned to the acetalization, the reaction time was reduced from 6.5 to 5.1 hours.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP99953786A 1998-10-21 1999-10-12 Aufarbeitung verunreinigter fettalkohol-gemische Withdrawn EP1123263A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19848548 1998-10-21
DE19848548A DE19848548C2 (de) 1998-10-21 1998-10-21 Verfahren zur Aufarbeitung verunreinigter Fettalkohol-Gemische
PCT/EP1999/007657 WO2000023406A1 (de) 1998-10-21 1999-10-12 Aufarbeitung verunreinigter fettalkohol-gemische

Publications (1)

Publication Number Publication Date
EP1123263A1 true EP1123263A1 (de) 2001-08-16

Family

ID=7885205

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99953786A Withdrawn EP1123263A1 (de) 1998-10-21 1999-10-12 Aufarbeitung verunreinigter fettalkohol-gemische

Country Status (7)

Country Link
EP (1) EP1123263A1 (ja)
JP (1) JP2002527495A (ja)
KR (1) KR20010080232A (ja)
CN (1) CN1324339A (ja)
AU (1) AU1035800A (ja)
DE (1) DE19848548C2 (ja)
WO (1) WO2000023406A1 (ja)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6335934B2 (ja) * 2013-03-07 2018-05-30 アールイージー ライフ サイエンシズ リミテッド ライアビリティ カンパニー 組み換え宿主細胞により産生された脂肪族アルコール組成物の下流処理
KR102691177B1 (ko) 2018-01-25 2024-08-01 메르크 파텐트 게엠베하 포토레지스트 리무버 조성물
CN111690021B (zh) * 2020-06-24 2023-03-14 江苏万淇生物科技股份有限公司 脱除烷基糖苷中脂肪醇的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1113449B (de) * 1958-05-13 1961-09-07 Union Carbide Corp Verfahren zur Reinigung synthetisch hergestellter Alkohole
DE3010510A1 (de) * 1979-03-23 1980-10-02 Basf Wyandotte Corp Verfahren zur reinigung zweiwertiger alkohole
JPH0684390B2 (ja) * 1989-03-17 1994-10-26 花王株式会社 アルキルグリコシドの製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0023406A1 *

Also Published As

Publication number Publication date
DE19848548C2 (de) 2001-06-13
CN1324339A (zh) 2001-11-28
WO2000023406A1 (de) 2000-04-27
AU1035800A (en) 2000-05-08
KR20010080232A (ko) 2001-08-22
JP2002527495A (ja) 2002-08-27
DE19848548A1 (de) 2000-04-27

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