EP1055450A2 - Agitateur - Google Patents
Agitateur Download PDFInfo
- Publication number
- EP1055450A2 EP1055450A2 EP00111186A EP00111186A EP1055450A2 EP 1055450 A2 EP1055450 A2 EP 1055450A2 EP 00111186 A EP00111186 A EP 00111186A EP 00111186 A EP00111186 A EP 00111186A EP 1055450 A2 EP1055450 A2 EP 1055450A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- agitator
- gas
- shaft
- hollow
- hub
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/20—Mixing gases with liquids
- B01F23/23—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
- B01F23/233—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements
- B01F23/2332—Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids using driven stirrers with completely immersed stirring elements the stirrer rotating about a horizontal axis; Stirrers therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
- B01F27/71—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with propellers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
Definitions
- the invention relates to an agitator for stirring liquids in a stirred container, a gas being supplied to the liquid, in particular for suspending of solids and gas dispersion in the liquid in flue gas desulfurization plants, with a stirring shaft and a stirring propeller sitting on it.
- fumigation pipes or fumigation lances For the fumigation of absorbers from flue gas desulphurization plants previously used fumigation pipes or fumigation lances. It refers to simple, horizontal pipes with holes or around vertical pipes through which the gas, usually air, is blown in. High gas rates can with such Pipes or lances can no longer be distributed efficiently.
- the invention is therefore based on the object of a stirrer of the abovementioned Kind in such a way that even higher gas rates efficiently in the liquid in the Stirring tanks can be distributed, and the gas introduced through the agitator can be predispersed.
- this is achieved in that the agitator shaft is hollow and the gas can be supplied through the hollow stirring shaft and into the stirring container can be introduced.
- the agitator is rotatably connected to the Stirring shaft connected, hollow hub through which the gas is feasible and insertable into the stirred tank.
- the hollow stirrer shaft and the hollow hub are expediently in the region of their ends on the container side with cross bores for introducing the gas into the stirred container Mistake.
- a gassing device in the region of the container is advantageous Arranged end of the agitator shaft or the hub.
- the gassing device is preferably in the form of a plurality of in particular tubes running radially to the longitudinal axis of the agitator shaft or the hub, with the interior of the agitator shaft or the hub or with the agitator shaft connected pipes is connected.
- the gassing device is in the form of a Chamber formed which surrounds the agitator shaft or the hub and with the Interior of the agitator shaft or the hub is connected.
- the outlet openings of the tubes and the chamber preferably lie through which flows the gas into the stirred tank, on a diameter that is about 35 is up to 75% of the diameter of the stirring propeller.
- the axial distance between the gassing device and the propeller is appropriate 25% to 75% of the stirring propeller.
- the outlet openings of the gassing device for introducing the gas into the Stirring tanks are preferably arranged on the pressure side of the stirring propeller
- a stationary distributor head is advantageously used to supply the gas intended.
- the hub can advantageously only in the region of the inner end of the massive stirrer shaft, the gas of the hollow hub via a pipe carried out through the wall of the stirred tank can be fed directly.
- FIG. 1 schematically shows an agitator 10 which is located in the interior of an agitator 12 is installed.
- the stirred tank 12 can be the absorber of a flue gas desulfurization system.
- the agitator 10 comprises an agitator shaft 14, which from the outside through the wall of the Stirring container 12 protrudes into the interior of the latter.
- the longitudinal axis of the In the installed position, the agitator shaft 14 runs essentially horizontally or up to approximately 15 ° down.
- the agitator shaft 14 can by a not shown external drive can be rotated.
- An axial conveyor in shape sits on the agitator shaft 14 inside the agitator container 12 a propeller 16, which is rotatably connected to the agitator shaft 14 and the material to be stirred promotes in the direction of arrow P.
- the agitator shaft 14, as the figure shows, is hollow and outside the agitator tank 12 coupled to a fixed distribution head 18, which the gas to Example air, via a pipe feed 20 and by means of a not shown Fan can be fed.
- the agitator shaft 14 has radial bores 22 in the area of the distributor head 18 which enter the gas from the distributor head 18 into the interior of the agitator shaft 14 can.
- seals 24 are between the stationary distributor head 18 and the rotatable agitator shaft 14 suitable seals 24 (for example lip seals, labyrinth seals or Gap seals) installed, also between the agitator shaft 14 and the wall of the Stirring tank 12.
- the inner end 36 of the agitator shaft 14 is closed at the end, but it is in the Area of this inner end with transverse to its longitudinal axis in the Cylinder wall formed through openings 26.
- This gassing device 28 is, for example, as shown schematically in Figure 4 shows, from four radially extending tubes 30, each at its outer ends Have outlet opening 32 for the gas.
- the pipes are 30 sloping at their outer ends, for example at an angle of 45 ° to her Longitudinal axis, cut off, whereby the outlet openings 32 are formed.
- the tubes 30 can also be closed on their end faces and Outlet openings 30 can be formed in the cylinder wall of the respective tube be, wherein only one, but also several, outlet openings are provided per tube can.
- the outlet openings 32 of the tubes 30 are based on the direction of rotation R Fumigation device 28, on the back of the tubes 30, that is, on the vacuum side of the gas channels or the pipes 30, whereby a back pressure before the Pipes corresponding negative pressure is generated, which in a possible pressure loss the gas supply is reduced or that with small liquid coverages of the outlet opening 32 can also be used for self-priming (without an external fan).
- the axial distance A between the center plane of the propeller 16 and the center plane the gassing device 28 is expediently about 25 to 75% of the propeller diameter, so that any gas kick back has an effect the axial conveyor, that is, the propeller 16, can not affect.
- the outlet openings 32 lie on a diameter which is larger than that Diameter of the agitator shaft 14 or the hub 34 ( Figure 2), preferably the Diameter of the circle on which the centers of the outlet openings 32 lie, approximately 35% to 75% of the propeller diameter.
- FIG. 5 shows a further embodiment of the gassing device 28.
- This gassing device has the shape of a triangular, for example Chamber 48 which, as Figure 5 shows, the container end of the hollow agitator shaft 14 or the hollow hub 34 and which rotatably with the shaft 14 or Hub 34 is connected.
- the axial width of the chamber 48 in the direction of the longitudinal axis of the agitator shaft 14 or the hub 34 is selected so that the chamber 48 at least the radial bores 26 in the agitator shaft 14 or the radial bores 38 in the hub 34 covered.
- the width of the chamber 48 is somewhat larger than that Diameter of these bores 22 and 38.
- the chamber 48 has three outlet openings 32, through which the supplied via the shaft 14 or the hub 34 and by the Bores 26 and 38 gas entering the chamber 48 into the stirred tank 12 is blown in.
- the outlet openings can extend over the entire axial width the chamber 48 extend.
- the chamber 48 according to FIG. 5 also lies the outlet openings 32 based on the direction of rotation R of the gassing device 28 on the back of the chamber 48, whereby the one already described above Negative pressure is generated.
- the axial distance lies between the center plane of the propeller 16 and the axial center plane of the chamber 48 at about 25% to 75% of the propeller diameter. Also the middle of the Outlet openings 32 of the chamber 48 on a diameter that is about 35% to 75% of the propeller diameter.
- FIG. 2 shows a further embodiment of the agitator 10 according to the invention.
- the stationary one is outside of the stirring container 12 arranged distributor head 18 coupled to the massive stirrer shaft 15, wherein the agitator shaft 15 is passed through the distributor head 18 and between the the latter and the agitator shaft 15 seals 24 are installed.
- the agitator shaft 15 sits the axial conveyor in the form of the propeller 16.
- the agitator shaft 15 and the propeller 16 in this embodiment is a hollow hub 34 non-rotatably connected, from which in the pipe feed 20 and via an annular space 40 between the stirrer shaft 15 and the distributor head 18, the gas can be introduced is.
- the hub 34 runs concentrically to the agitator shaft 15 and overlaps its outer end 42 the inner end 44 of the distribution head 18, which in this embodiment something protrudes into the latter through the wall of the stirred tank 12.
- the inner end 46 of the hub 34 is closed at the end, but in the area of this inner end 46 is the hollow hub 34 with radial, in its cylindrical wall trained holes 38 equipped.
- the propeller 16 conveys the liquid Direction of arrow P.
- the gassing device 28 is non-rotatable with the Stirring shaft 14 or the hub 34 connected and thus rotates together with the Stirrer shaft 14 or the hub 34 and the propeller 16 as a unit.
- the gas is thus not shown Blower via the pipe feed 20, the distributor head 18, the radial bores 22, the hollow agitator shaft 14, and the radial bores 26 in the latter in the Tubes 30 or the chamber 48 of the gassing device 28 and fed through whose outlet openings 32 are blown into the liquid in the stirred tank 12.
- the gas is by means of a not shown Blower via the pipe feed 20, the annular space 40 between the agitator shaft 15 and the distributor head 18, the hollow hub 34 and the radial bores 38 in the the latter, introduced into the tubes 30 or the chamber 43 of the gassing device 28 and through their outlet openings 32 into the liquid in the stirred tank 12 blown in.
- the gassing device 28 which has the axial distance A from the propeller 16, is located based on the peripheral wall of the stirred tank inwards from the propeller 16 and the pressure side of the latter.
- the gas is thus from the outside through the hollow stirring shaft 14 or the hollow Hub 34 is introduced into the stirring container 12 and by means of the gassing device 28 on the pressure side of the propeller 16 of the liquid in the stirred tank 12 fed.
- the propeller 16 generates a sufficiently strong jet of liquid to simultaneously Suspend solids in the liquid and the gas in the liquid too disperse.
- Figure 3 schematically shows a side view of an embodiment of the invention Agitator.
- the agitator shaft 15 is solid in the embodiment of Figure 2.
- the inner end face of the distributor head 18 is closed by a wall 58, which axially engages over the inner end 44 of the distributor head 18, with between the wall 58 and the inner end 44 of the distributor head 18 a suitable Seal 24 is installed.
- the end wall 58 is rotatably connected to the agitator shaft 15.
- agitator shaft 15 On the outer circumference of the agitator shaft 15 there are several, for example four, tubes 52 arranged and firmly connected to the agitator shaft 15, which is practically parallel to Stirrer shaft 15 extend and the outer end 60 thereof through the wall 58 in the annular space 40 of the fixed distributor head 18 protrude. (Between the the latter and the shaft 15, a suitable seal 24 is also arranged.)
- the tubes 52 are in the region of the inner, container-side end 54 of the agitator shaft 15 radially outwards (essentially perpendicular to the longitudinal axis of the shaft 15) bent and thus form radial pipe sections 56, at the free ends of the Outlet openings 32 are formed for the introduction of the gas into the stirred tank 12 are.
- the pipe sections 56 form the gassing device 28
- Figure 6 shows another embodiment of the agitator according to the invention.
- the hub 34 is only in the area of the inner end 54 of FIG massive stirrer shaft 15 and it is suitable for example by welding or by means of screws with this inner end 54 of the agitator shaft 15 connected.
- the container end 46 of the hollow hub 34 is open and into this end 46 opens the pipe feed 20, between the rotating hub 34 and the stationary pipe feed 20 a suitable seal 24, for example a lip seal or a labyrinth seal or the like is installed.
- sealing can also be achieved by means of a defined gap, whereby a special seal can be omitted.
- the embodiment is different from the above-described embodiments 6, the tube 20 from the outside through the wall of the stirred tank 12 passed through.
- the tube 20 then expediently runs radially into the stirred tank 12 in, is then bent over so that its end portion 21 again is directed outwards to the wall of the stirred tank and thus from the inside opens into the hollow hub 34.
- the hub 34 according to FIG. 6 is equipped with the gassing device 28 already described provided, which in turn from the tubes 30 ( Figure 4) or from the chamber 48 ( Figure 5) can be formed.
- the tubes 30, 52 and 56 can have a circular cross-section, rectangular cross-section or have any other suitable cross-section.
- the chamber 48 according to FIG 5 can also be rectangular in cross section or another have a suitable cross-section.
- the gassing device 28 can be dispensed with and that Gas is blown directly into the stirred tank.
- the distributor head 18 can also be integrated into the wall of the agitator 12 or entirely be installed inside the stirred tank 12. In this case the pipe feed 20 passed through the wall of the stirred tank 12 and to the distributor head 18 connected.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Accessories For Mixers (AREA)
- Treating Waste Gases (AREA)
- Cleaning In General (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE29909312U DE29909312U1 (de) | 1999-05-27 | 1999-05-27 | Rührwerk |
DE29909312U | 1999-05-27 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1055450A2 true EP1055450A2 (fr) | 2000-11-29 |
EP1055450A3 EP1055450A3 (fr) | 2002-06-19 |
EP1055450B1 EP1055450B1 (fr) | 2005-07-27 |
Family
ID=8074047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00111186A Expired - Lifetime EP1055450B1 (fr) | 1999-05-27 | 2000-05-24 | Agitateur |
Country Status (6)
Country | Link |
---|---|
US (1) | US6439756B1 (fr) |
EP (1) | EP1055450B1 (fr) |
JP (1) | JP4828013B2 (fr) |
KR (1) | KR100472620B1 (fr) |
AT (1) | ATE300350T1 (fr) |
DE (2) | DE29909312U1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010142406A1 (fr) * | 2009-06-08 | 2010-12-16 | EKATO Rühr- und Mischtechnik GmbH | Ensemble agitateur |
CN104046562A (zh) * | 2014-06-11 | 2014-09-17 | 苏州市金翔钛设备有限公司 | 一种搅拌反应器 |
DE102015108260A1 (de) * | 2015-05-26 | 2016-12-01 | EKATO Rühr- und Mischtechnik GmbH | Rührwerkvorrichtung |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4596658B2 (ja) * | 2000-03-10 | 2010-12-08 | 佐竹化学機械工業株式会社 | 通気撹拌用撹拌装置 |
JP4802393B2 (ja) * | 2001-05-23 | 2011-10-26 | 株式会社Ihi | 気体吹込式撹拌機 |
US6860474B2 (en) * | 2003-01-06 | 2005-03-01 | Spx Corporation | Agitator and drive apparatus and method |
DE20307458U1 (de) * | 2003-05-13 | 2003-09-25 | Ekato Ruehr Mischtechnik | Vorrichtung zur Behandlung von Feststoffen |
EP2813281B1 (fr) * | 2004-01-07 | 2016-08-17 | Pall Technology UK limited | Récipient pour le traitement biologique |
US7028992B2 (en) * | 2004-05-28 | 2006-04-18 | American Aerators, Inc. | Aerator with intermediate bearing |
DE102004039960A1 (de) * | 2004-08-18 | 2006-02-23 | Bayer Materialscience Ag | Rührvorrichtung und Verfahren zur Durchführung einer Gas-Flüssig-Reaktion |
US8603805B2 (en) | 2005-04-22 | 2013-12-10 | Hyclone Laboratories, Inc. | Gas spargers and related container systems |
US7377497B2 (en) * | 2005-09-16 | 2008-05-27 | Philadelphia Gear Corporation | Aeration system and method |
US20080261299A1 (en) * | 2007-04-23 | 2008-10-23 | Zeikus J Gregory | Pneumatic Bioreactor |
US7628528B2 (en) * | 2005-10-26 | 2009-12-08 | PRS Biotech, Inc. | Pneumatic bioreactor |
US8790913B2 (en) * | 2005-10-26 | 2014-07-29 | Pbs Biotech, Inc. | Methods of using pneumatic bioreactors |
WO2007134267A2 (fr) * | 2006-05-13 | 2007-11-22 | Advanced Technology Materials, Inc. | Bioréacteur jetable |
US7713730B2 (en) * | 2007-04-24 | 2010-05-11 | Pbs Biotech, Inc. | Pneumatic bioreactor |
EP2279240A2 (fr) * | 2008-04-25 | 2011-02-02 | PBS Biotech, Inc | Appareil de bioréacteur |
DE102008061258A1 (de) * | 2008-12-10 | 2010-06-24 | Hitachi Power Europe Gmbh | Verfahren zur CO2-Abtrennung aus Rauchgas und Absorber |
KR200454154Y1 (ko) * | 2009-10-12 | 2011-06-17 | 한국서부발전 주식회사 | 탈황 흡수탑용 교반기 |
IT1402807B1 (it) * | 2010-10-14 | 2013-09-18 | Butussi | "agitatore per prodotti alimentari" |
EP2486975B1 (fr) * | 2010-12-29 | 2015-09-23 | Wanhua Chemical Group Co., Ltd. | Réacteur à mélange rapide et son utilisation |
US9376655B2 (en) | 2011-09-29 | 2016-06-28 | Life Technologies Corporation | Filter systems for separating microcarriers from cell culture solutions |
EP2760571B1 (fr) | 2011-09-30 | 2015-12-30 | Life Technologies Corporation | Récipient à aérateur sous forme de film |
CA2866951A1 (fr) * | 2012-03-23 | 2013-09-26 | Ekato Ruhr- Und Mischtechnik Gmbh | Systeme et procede de demarrage d'agitateurs dans un sediment |
US9339026B2 (en) * | 2012-06-14 | 2016-05-17 | Therapeutic Proteins International, LLC | Pneumatically agitated and aerated single-use bioreactor |
JP6143039B2 (ja) * | 2013-07-18 | 2017-06-07 | ウォン ジャン,スン | 曝気装置 |
KR101394728B1 (ko) * | 2013-12-18 | 2014-05-15 | 엔시스 주식회사 | 압축 공기 방식의 교반과 폭기를 겸용하는 장치 및 이에 의한 교반과 폭기 방법 |
US9079690B1 (en) | 2014-06-26 | 2015-07-14 | Advanced Scientifics, Inc. | Freezer bag, storage system, and method of freezing |
US10589197B2 (en) | 2016-12-01 | 2020-03-17 | Life Technologies Corporation | Microcarrier filter bag assemblies and methods of use |
EP3749895A4 (fr) * | 2018-02-09 | 2021-11-10 | Nano Silver Manufacturing SDN BHD | Appareil de nettoyage de fumée d'échappement |
CN109200714B (zh) * | 2018-06-29 | 2020-12-22 | 广西康纳环保有限公司 | 一种隔声屏除尘发电装置 |
KR102366372B1 (ko) * | 2020-06-30 | 2022-02-23 | 주식회사 한테크 | 파우더 플라즈마 처리장치 |
CN114042580B (zh) * | 2022-01-11 | 2022-04-08 | 云奕智创航空科技(南通)有限公司 | 一种无人机外壳加工用喷涂装置 |
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DE7411389U (fr) * | 1974-07-04 | Mueller H | ||
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JPS61120623A (ja) * | 1984-11-16 | 1986-06-07 | Babcock Hitachi Kk | 気液接触機能を有する撹拌装置 |
DE9201820U1 (fr) * | 1992-02-13 | 1992-04-09 | Kirschenmann, Guenter, Dipl.-Ing., 7507 Pfinztal, De | |
EP0711590A2 (fr) * | 1994-11-08 | 1996-05-15 | Mitsubishi Jukogyo Kabushiki Kaisha | Contacteur gaz-liquide et système de désulfuration de gaz de fumée par voie humide |
EP0754489A1 (fr) * | 1995-07-20 | 1997-01-22 | Air Products And Chemicals, Inc. | Méthode et appareil pour améliorer la dispersion de gaz et le transfert de masse de gaz dans un réacteur agité |
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1999
- 1999-05-27 DE DE29909312U patent/DE29909312U1/de not_active Expired - Lifetime
-
2000
- 2000-05-01 US US09/561,722 patent/US6439756B1/en not_active Expired - Fee Related
- 2000-05-24 DE DE50010802T patent/DE50010802D1/de not_active Expired - Lifetime
- 2000-05-24 AT AT00111186T patent/ATE300350T1/de active
- 2000-05-24 EP EP00111186A patent/EP1055450B1/fr not_active Expired - Lifetime
- 2000-05-26 KR KR10-2000-0028571A patent/KR100472620B1/ko not_active IP Right Cessation
- 2000-05-26 JP JP2000155929A patent/JP4828013B2/ja not_active Expired - Fee Related
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE7411389U (fr) * | 1974-07-04 | Mueller H | ||
DE879081C (de) * | 1951-02-23 | 1953-06-11 | Michael Philosophow | Ruehrwerk mit Luftzufuehrung |
US3400918A (en) * | 1967-03-08 | 1968-09-10 | David S. Maclaren | Sewage aerator |
GB2052278A (en) * | 1978-11-11 | 1981-01-28 | Streicher M | Fluid flow apparatus |
JPS61120623A (ja) * | 1984-11-16 | 1986-06-07 | Babcock Hitachi Kk | 気液接触機能を有する撹拌装置 |
DE9201820U1 (fr) * | 1992-02-13 | 1992-04-09 | Kirschenmann, Guenter, Dipl.-Ing., 7507 Pfinztal, De | |
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Cited By (7)
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WO2010142406A1 (fr) * | 2009-06-08 | 2010-12-16 | EKATO Rühr- und Mischtechnik GmbH | Ensemble agitateur |
AU2010257782B2 (en) * | 2009-06-08 | 2014-01-09 | Ekato Ruhr- Und Mischtechnik Gmbh | Stirring device |
US8894047B2 (en) | 2009-06-08 | 2014-11-25 | Ekato Ruehr- und Mischtechnek GmbH | Stirring arrangement |
RU2542258C2 (ru) * | 2009-06-08 | 2015-02-20 | Экато Рюр-Унд Миштехник Гмбх | Перемешивающая установка |
CN104046562A (zh) * | 2014-06-11 | 2014-09-17 | 苏州市金翔钛设备有限公司 | 一种搅拌反应器 |
CN104046562B (zh) * | 2014-06-11 | 2016-05-25 | 苏州市金翔钛设备有限公司 | 一种搅拌反应器 |
DE102015108260A1 (de) * | 2015-05-26 | 2016-12-01 | EKATO Rühr- und Mischtechnik GmbH | Rührwerkvorrichtung |
Also Published As
Publication number | Publication date |
---|---|
EP1055450A3 (fr) | 2002-06-19 |
DE29909312U1 (de) | 1999-08-12 |
US6439756B1 (en) | 2002-08-27 |
JP2001000851A (ja) | 2001-01-09 |
DE50010802D1 (de) | 2005-09-01 |
KR100472620B1 (ko) | 2005-03-08 |
JP4828013B2 (ja) | 2011-11-30 |
EP1055450B1 (fr) | 2005-07-27 |
KR20010049418A (ko) | 2001-06-15 |
ATE300350T1 (de) | 2005-08-15 |
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