EP1051471A2 - Agents de blanchiment et desinfectants - Google Patents

Agents de blanchiment et desinfectants

Info

Publication number
EP1051471A2
EP1051471A2 EP99906173A EP99906173A EP1051471A2 EP 1051471 A2 EP1051471 A2 EP 1051471A2 EP 99906173 A EP99906173 A EP 99906173A EP 99906173 A EP99906173 A EP 99906173A EP 1051471 A2 EP1051471 A2 EP 1051471A2
Authority
EP
European Patent Office
Prior art keywords
weight
composition according
contain
carbon atoms
agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP99906173A
Other languages
German (de)
English (en)
Inventor
Jaume Josa
Maria Teresa Canellas
Lidia Jimenez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1051471A2 publication Critical patent/EP1051471A2/fr
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to new aqueous bleaching and disinfecting agents containing alkali metal hypochlorites, alkylene glycol ethers and selected surfactants in defined proportions.
  • EP-A 0274885 (ICI) recommends the use of mixtures of linear and branched amine oxides. According to the teaching of EP-A 0145084 (Unilever), mixtures of amine oxides with soaps, sarcosinates, thaws or sugar esters can also be used for this purpose.
  • EP-A 0079102, EP-A 0137551 and EP-A 0447261 disclose the use of amine oxides with soap or sarcosinate and other anionic surfactants, for example alkyl sulfates, alkyl ether sulfates, secondary alkane sulfonates or alkylbenzenesulfonates as a thickening component.
  • EP-A 0156438 reports on the use of alkylarylsulfonates as thickeners in aqueous bleaching agents which contain certain stilbene dyes as optical brighteners.
  • ES-A 8801389 (Henkel Iberica) relates to bleaching agents based on aqueous hypochlorite solutions which contain, as the surfactant component, predominantly alkyl ether sulfates and also small amounts of amine oxides. From EP-A1 0447261 aqueous bleaching agent compositions are also tongues containing sodium hypochlorite and anionic surfactants known. However, the hypochlorite concentration of these agents is 0.1 to 8 and preferably 0.5 to 5% by weight of active chlorine.
  • German Patent DE-C1 4333100 the applicant has already proposed stable and sufficiently viscous aqueous bleaching and cleaning agents based on hypochlorites, fatty alcohol ether sulfates and amine oxides, which contain amine oxide phosphonic acids as a mandatory component. Although these contribute significantly to the thickening of the agents, they cannot stabilize the active chlorine content.
  • US Pat. No. 4,588,514 discloses alkaline hypochlorite bleaches which contain amine oxides and small amounts of alkyl ether sulfates and soaps to adjust the viscosity. However, the preparations have a high hypochlorite content of 7% by weight. If the teaching is applied to modern bleaching agents with a low active chlorine content, neither sufficiently thickened nor storage-stable products are obtained.
  • the object of the invention was therefore to provide new aqueous bleaching and disinfecting agents which are characterized by a sufficiently high and stable viscosity at a low active chlorine content and which have excellent cleaning properties on hard surfaces, in particular with regard to greasy soiling.
  • the invention relates to bleaching and disinfecting agents containing - based on the agents -
  • R 1 and R 3 independently of one another represent linear or branched alkyl radicals having 1 to 8 carbon atoms
  • R 2 represents hydrogen or methyl
  • n represents numbers from 1 to 4
  • bleaching agents and disinfectants of the stated composition are not only chlorine-stable and sufficiently viscous, but also have improved cleaning properties, in particular with respect to greasy soiling.
  • Alkali metal hypochlorites are to be understood as meaning lithium, potassium and in particular sodium hypochlorite.
  • the hypochlorites can preferably be used in amounts of 2 to 4% by weight, based on the composition.
  • the alkylene glycol ethers to be used as component (b) in the context of the invention are known sales products. These are Ci-C ⁇ - and preferably C ⁇ -C -alkyl end group-blocked alkylene glycols, such as, for example, the dimethyl, diethyl, diisiopropyl, n -Butyl, tert-butyl, n-octyl and 2-ethylhexyl ether of ethylene glycol, diethylene glycol, triethylene glycols, propylene glycols, dipropylene glycols and tripropylene glycols. Dipropylene glycol dimethyl ether, which is commercially available under the Proglyde® DMM brand, is preferably used.
  • the alkylene glycol ethers can preferably be used in amounts of 1 to 3% by weight.
  • Alkyl ether sulfates are known anionic surfactants which are obtained by sulfation of nonionic surfactants of the alkylpolyglycol ether type and subsequent neutralization.
  • the alkyl ether sulfates which are suitable for the purposes of the agents according to the invention follow the formula (II),
  • R 4 represents an alkyl radical having 12 to 18 carbon atoms
  • n represents numbers 2 to 5
  • X represents sodium or potassium.
  • Typical examples are the sodium salts of sulfates of the Ci2 i4 coco alcohol 2, 2, 3, and 3 EO adduct.
  • the alkyl ether sulfates can have a conventional or narrow homolog distribution.
  • the alkyl ether sulfates are preferably used in amounts of 2 to 4% by weight, based on the composition.
  • Amine oxides are also known substances, which are occasionally attributed to the cationic, but usually the nonionic surfactants. They are prepared from tertiary fatty amines, which usually have either one long and two short or two long and one short alkyl radical, and are oxidized in the presence of hydrogen peroxide.
  • the amine oxides which are suitable for the purposes of the invention follow the formula (III)
  • R 5 represents a linear or branched alkyl radical having 12 to 18 carbon atoms
  • R 6 and R 7 independently of one another represent R 5 or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms.
  • Amine oxides of the formula (III) are preferably used in which R 5 and R 6 are C-12/14 and C-12/18 cocoalkyl radicals and R 7 is a methyl or a hydroxyethyl radical.
  • amine oxides of the formula (III) in which R 5 is a C-12/14 or C1218 cocoalkyl radical and R 6 and R 7 have the meaning of a methyl or hydroxyethyl radical.
  • the amine oxides are preferably used in amounts of 1.5 to 3% by weight, based on the composition.
  • the agents according to the invention may contain fatty acid salts of the formula (IV) as further constituents,
  • R 8 CO represents an acyl radical having 12 to 22 carbon atoms and X represents an alkali metal.
  • Typical examples are the sodium and / or potassium salts of lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their mixtures they occur during the pressure splitting of technical fats and oils. Salts of technical coconut or tallow fatty acids are preferably used.
  • the fatty acids which are neutralized in situ when they are introduced into the mixture can also be used instead of the salts.
  • the fatty acid salts are preferably used in amounts of 1.5 to 2% by weight.
  • Suitable alkali metal hydroxides are potassium hydroxide and in particular sodium hydroxide, which are preferably used in amounts of 1.5 to 2% by weight and are used to adjust the pH of the compositions to an optimal value of 12.5 to 14.
  • the agents according to the invention with a content of cleaning-enhancing alkylene glycol ethers have a viscosity above 1000 mPas - measured at 20 ° C. in a Brookfield viscometer -, are stable in storage, resistant to chlorine consumption and, in addition to high cleaning properties, are also distinguished in particular by greasy soiling due to its excellent dispersibility for dye pigments.
  • Another object of the invention therefore relates to the use of alkylene glycol ethers of the formula (I) as cleaning enhancers for the production of hypochlorite-containing bleaching agents and disinfectants.
  • Auxiliaries and additives which the preparations may further contain include, for example, other chlorine-stable surfactants or hydrotropes, such as alkyl sulfates, alkyl sulfonates, alkyl benzenesulfonates, xylene sulfonates, sarcosinates, taurides, isethionates, sulfosuccinates, betaines, sugar esters, fatty alcohol polyglycol ethers and Alkyl oligoglycosides.
  • the sum of these additional surfactants preferably makes up at most 10% by weight of the total amount of surfactants in the formulation.
  • alkyl sulfates in amounts of 0.5 to 3% by weight is particularly preferred.
  • the agents can contain active chlorine-stable fragrances, optical brighteners, dyes and pigments in a total amount of 0.01 to 0.5% by weight, based on the agents.
  • the fragrances known to be active chlorine-resistant include, for example, monocyclic and bicyclic monoterpene alcohols and their esters with acetic or propionic acid (for example isobomeal, dihydroterpene oil, isobornyl acetate, dihydroterpenyl acetate).
  • the optical brighteners can be, for example, the potassium salt of 4,4'-bis (1, 2,3-triazolyl) - (2 -) - stilbin-2,2-sulfonic acid, which is sold under the Phorwite® BHC brand 766 is distributed.
  • the sequestering agent can furthermore contain electrolyte salts in amounts of 0.1 to 2 and preferably 0.5 to 1% by weight, which can be polyacrylates, carbonates, silicates, phosphates, amine oxide phosphonic acids and lignin sulfonates and mixtures thereof.
  • the agents according to the invention are produced by stirring. If necessary, the product obtained can be decanted or filtered to remove foreign bodies and / or agglomerates. Examples

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne de nouveaux agents de blanchiment et désinfectants, contenant, par rapport auxdits agents, (a) 1 à 6 % en poids d'hypochlorites de métaux alcalins, (b) 0,5 à 5 % en poids d'éther glycolique d'alkylène de formule (I) R<1>O(CHR<2>CH2O)nR<3>, dans laquelle R<1> et R<3> représentent indépendamment l'un de l'autre des radicaux alkyle linéaires ou ramifiés comportant 1 à 8 atomes de carbone, R<2> représente hydrogène ou méthyle et n est compris entre 1 et 4, (c) 0,5 à 5 % en poids de sulfates d'éther d'alkyle et/ou d'aminoxydes, (d) 0 à 4 % en poids de sels d'acides gras et (e) 0 à 2 % en poids d'hydroxydes de métaux alcalins, à condition que la somme des proportions indiquées, ajoutées à de l'eau et éventuellement à d'autres auxiliaires et additifs soit égale à 100 % en poids. Les préparations selon l'invention présentent un excellent pouvoir nettoyant pour les surfaces solides, une viscosité suffisamment élevée et une très bonne stabilité au stockage, une très bonne dispersibilité pour les pigments pour colorants et une très bonne stabilité au chlore.
EP99906173A 1998-01-28 1999-01-20 Agents de blanchiment et desinfectants Ceased EP1051471A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE1998103054 DE19803054A1 (de) 1998-01-28 1998-01-28 Bleich- und Desinfektionsmittel
DE19803054 1998-01-28
PCT/EP1999/000351 WO1999038943A2 (fr) 1998-01-28 1999-01-20 Agents de blanchiment et desinfectants

Publications (1)

Publication Number Publication Date
EP1051471A2 true EP1051471A2 (fr) 2000-11-15

Family

ID=7855792

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99906173A Ceased EP1051471A2 (fr) 1998-01-28 1999-01-20 Agents de blanchiment et desinfectants

Country Status (4)

Country Link
EP (1) EP1051471A2 (fr)
BR (1) BR9908347A (fr)
DE (1) DE19803054A1 (fr)
WO (1) WO1999038943A2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4526023B2 (ja) * 2004-12-24 2010-08-18 信越化学工業株式会社 農業用殺菌剤組成物
DE102005059048A1 (de) * 2005-12-08 2007-06-14 Henkel Kgaa Reinigungsmittel für harte Oberflächen
DE102005062008B3 (de) 2005-12-22 2007-08-30 Henkel Kgaa Geruchsreduktion hypochlorithaltiger Mittel
DE102005063065A1 (de) * 2005-12-29 2007-07-12 Henkel Kgaa Korrosionsinhibierung flüssiger hypochlorithaltiger Reinigungsmittel
DE102005063177A1 (de) 2005-12-30 2007-07-05 Henkel Kgaa Erhöhung der Stabilität hypochlorihaltiger Waschmittel
US20130096045A1 (en) 2011-10-12 2013-04-18 Ecolab Usa Inc. Moderately alkaline cleaning compositions for proteinaceous and fatty soil removal at low temperatures
DE102020215689A1 (de) 2020-12-11 2022-06-15 Henkel Ag & Co. Kgaa Stabile, farbige, viskose Bleichformulierungen

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA722326B (en) * 1971-05-04 1973-11-28 Colgate Palmolive Co Liquid detergent and laundering process
US4329247A (en) * 1980-11-06 1982-05-11 Pdi, Inc. Stain remover for vinyl materials
JPH0649880B2 (ja) * 1986-06-04 1994-06-29 ユニ・チヤ−ム株式会社 起泡性液体洗浄剤組成物
ES2007221A6 (es) * 1988-05-05 1989-06-01 Henkel Iberica Composicion blanqueante a base de hipocloritos alcalinos y procedimiento para su obtencion.
WO1996012787A1 (fr) * 1994-10-21 1996-05-02 Jeyes Group Plc Compositions liquides concentrees comportant des tensioactifs
EP0724011A1 (fr) * 1995-01-24 1996-07-31 The Dow Chemical Company Composition aqueuse de nettoyage
ATE273376T1 (de) * 1996-06-10 2004-08-15 Procter & Gamble Reinigungsmittelzusammensetzungen
US5834414A (en) * 1996-10-17 1998-11-10 Ecolab Inc. Detergent composition having improved chlorine stability characteristics, novel chlorine containing product format and method of making chlorine stable composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9938943A3 *

Also Published As

Publication number Publication date
WO1999038943A3 (fr) 1999-09-23
BR9908347A (pt) 2001-10-16
WO1999038943A2 (fr) 1999-08-05
DE19803054A1 (de) 1999-07-29

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