EP0925351B1 - Agents s'utilisant pour nettoyer des surfaces dures - Google Patents

Agents s'utilisant pour nettoyer des surfaces dures Download PDF

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Publication number
EP0925351B1
EP0925351B1 EP97930422A EP97930422A EP0925351B1 EP 0925351 B1 EP0925351 B1 EP 0925351B1 EP 97930422 A EP97930422 A EP 97930422A EP 97930422 A EP97930422 A EP 97930422A EP 0925351 B1 EP0925351 B1 EP 0925351B1
Authority
EP
European Patent Office
Prior art keywords
alkyl
alkali metal
carbon atoms
independently
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97930422A
Other languages
German (de)
English (en)
Other versions
EP0925351A1 (fr
Inventor
Elisabet Dejorge
Jaume Josa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0925351A1 publication Critical patent/EP0925351A1/fr
Application granted granted Critical
Publication of EP0925351B1 publication Critical patent/EP0925351B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to new agents for cleaning hard surfaces containing alkali metal hypochlorites, Alkali metal hydroxides and selected surfactants and the use of the mixtures for Manufacture of aerosol foam cleaners.
  • EP-A 0 137 551 and EP-A 0 447 261 disclose the use of amine oxides with soap or sarcosinate and other anionic surfactants, for example alkyl sulfates, alkyl ether sulfates, secondary alkane sulfonates or alkyl benzene sulfonates as thickening components.
  • EP-A 0 156 438 reports on the use of alkylarylsulfonates as thickeners in aqueous bleaches which contain certain stilbene dyes as optical brighteners.
  • Potassium hydroxide and in particular sodium hydroxide come into consideration as alkali metal hydroxides, which are preferably used in amounts of 0.05 to 2 and preferably 0.5 to 1.5% by weight and serve to adjust the pH of the agents to an optimal value of 12.5 to 14.
  • the agents can contain active chlorine-stable fragrances, optical brighteners, dyes and pigments in a total of 0.01 to 0.5 wt .-% - based on the agent - included.
  • Active chlorine-resistant fragrances include, for example, monocyclic and bicyclic monoterpene alcohols and their esters with acetic or propionic acid (e.g. isobomeal, dihydroterpene oil, Isobomylacetate, dihydroterpenylacetate).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (5)

  1. Agent pour le nettoyage des surfaces dures, contenant :
    a) un hypochlorite de métal alcalin
    b) un hydroxyde de métal alcalin
    c) un aminoxyde de formule (I)
    Figure 00130001
    dans laquelle R1 représente un reste alkyle linéaire ou ramifié ayant de 12 à 18 atomes de carbone ainsi que R2 et R3 indépendamment l'un de l'autre représentent R1 ou un reste alkyle éventuellement substitué par un hydroxy, ayant de 1 à 4 atomes de carbone :
    d) des (alkyl en C8-C10)sulfates et
    e) des alkylphosphates de formule (III)
    Figure 00130002
    dans laquelle R5 et R6 indépendamment l'un de l'autre représentent un reste alkyle et/ou alkényle ayant de 6 à 22 atomes dé carbone, X représente un groupe R5 (OCH2CH2)n, de l'hydrogène ou un métal alcalin et n et m indépendamment l'un de l'autre représentent O ou des nombres allant de 1 à 10, ainsi qu'éventuellement d'autres adjuvants et additifs usuels.
  2. Agents selon la revendication 1,
    caractérisés en ce qu'
    ils renferment de l'hypochlorite de sodium.
  3. Agents selon l'une quelconque des revendications 1 et 2,
    caractérisés en ce qu'
    ils renferment de l'hydroxyde de sodium.
  4. Agents selon lune des revendications 1 à 3,
    caractérisés en ce qu'
    ils renferment des alkylsulfates de formule (II), R4OSO3X dans laquelle R4 représente un reste alkyle ayant de 8 à 10 atomes de carbone et X représente un métal alcalin et/ou alcalino-terreux, de l'ammonium, un alkylammonium, un hydroxyalkylammonium ou un glucammonium.
  5. Utilisation de mélanges contenant:
    a) un hypochlorite de métal alcalin
    b) un hydroxyde de métal alcalin
    c) un aminoxyde de formule I
    Figure 00140001
    dans laquelle R1 représente un reste alkyle linéaire ou ramifié ayant de 12 à 16 atomes de carbone ainsi que R2 et R3 indépendamment l'un de l'autre représentent R1 ou un reste alkyle éventuellement substitué par un hydroxy, ayant de 1 à 4 atomes de carbone :
    d) des (alkyl en C8-C10)sulfates et
    e) des alkylphosphates de formule (III)
    Figure 00140002
    dans laquelle R5 et R6, indépendamment l'un de l'autre, représentent un reste alkyle et/ou alkényle ayant de 6 à 22 atomes de carbone, X représente un groupe R5 (OCH2CH2)n, de l'hydrogène ou un métal alcalin et n et m indépendamment l'un de l'autre, représentent O ou des nombres allant de 1 à 10, en vue de la préparation d'agents de nettoyage moussants sous forme d'aérosols.
EP97930422A 1996-07-04 1997-06-26 Agents s'utilisant pour nettoyer des surfaces dures Expired - Lifetime EP0925351B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19626906A DE19626906C1 (de) 1996-07-04 1996-07-04 Mittel für die Reinigung harter Oberflächen
DE19626906 1996-07-04
PCT/EP1997/003368 WO1998001528A1 (fr) 1996-07-04 1997-06-26 Agents s'utilisant pour nettoyer des surfaces dures

Publications (2)

Publication Number Publication Date
EP0925351A1 EP0925351A1 (fr) 1999-06-30
EP0925351B1 true EP0925351B1 (fr) 2001-09-05

Family

ID=7798883

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97930422A Expired - Lifetime EP0925351B1 (fr) 1996-07-04 1997-06-26 Agents s'utilisant pour nettoyer des surfaces dures

Country Status (5)

Country Link
EP (1) EP0925351B1 (fr)
AT (1) ATE205249T1 (fr)
DE (2) DE19626906C1 (fr)
ES (1) ES2163787T3 (fr)
WO (1) WO1998001528A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999058635A1 (fr) * 1998-05-08 1999-11-18 Henkel Kommanditgesellschaft Auf Aktien Agents de blanchiment et de desinfection
DE19902904A1 (de) * 1999-01-26 2000-08-03 Henkel Kgaa Bleich- und Desinfektionsmittel
GB0113052D0 (en) * 2001-05-30 2001-07-18 Reckitt Benckiser Inc Improvements in or relating to organic compositions
EP1497404A4 (fr) * 2002-04-01 2005-04-20 Fiber Engineering Inc Elimination de coloration tenace de moisissure
DE102006003336A1 (de) * 2006-01-23 2007-07-26 Henkel Kgaa Sprühbarer Allzweckreiniger

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4352678A (en) * 1978-10-02 1982-10-05 Lever Brothers Company Thickened abrasive bleaching compositions
JPS63165495A (ja) * 1986-12-27 1988-07-08 ライオン株式会社 スプレイヤ−付き容器入り洗浄剤
US4789495A (en) * 1987-05-18 1988-12-06 The Drackett Company Hypochlorite compositions containing a tertiary alcohol
ZA935882B (en) * 1992-10-19 1994-03-11 Clorox Co Composition and method for developing extensional viscosity in cleaning compositions.
JPH08503013A (ja) * 1992-11-03 1996-04-02 ザ、プロクター、エンド、ギャンブル、カンパニー 短鎖界面活性剤によるクリーニング
JP3253035B2 (ja) * 1993-03-09 2002-02-04 大日本除蟲菊株式会社 液体洗浄剤組成物
GB9307804D0 (en) * 1993-04-15 1993-06-02 Unilever Plc Hygienic spray cleaner
AU7366294A (en) * 1993-07-23 1995-02-20 Procter & Gamble Company, The Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants
WO1995008611A1 (fr) * 1993-09-20 1995-03-30 The Procter & Gamble Company Compositions detergentes aqueuses epaissies aux caracteristiques de nettoyage ameliorees

Also Published As

Publication number Publication date
ATE205249T1 (de) 2001-09-15
EP0925351A1 (fr) 1999-06-30
DE19626906C1 (de) 1998-03-12
DE59704548D1 (de) 2001-10-11
WO1998001528A1 (fr) 1998-01-15
ES2163787T3 (es) 2002-02-01

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