EP1185605A1 - Produits de blanchiment et de desinfection - Google Patents

Produits de blanchiment et de desinfection

Info

Publication number
EP1185605A1
EP1185605A1 EP00938729A EP00938729A EP1185605A1 EP 1185605 A1 EP1185605 A1 EP 1185605A1 EP 00938729 A EP00938729 A EP 00938729A EP 00938729 A EP00938729 A EP 00938729A EP 1185605 A1 EP1185605 A1 EP 1185605A1
Authority
EP
European Patent Office
Prior art keywords
composition according
sodium
alkali
agents
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00938729A
Other languages
German (de)
English (en)
Inventor
Lidia Jimenez
Teresa Canellas
Miguel Osset
Pilar Ibanez
Elisabet De Jorge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1185605A1 publication Critical patent/EP1185605A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to new aqueous bleaching and disinfecting agents containing hypochlones, ether carboxylates and hydroxides in defined proportions
  • EP 0 274 885 A recommends the use of mixtures of linear and branched amine oxides.
  • EP 0 340 371 A (Henkel Ibe ⁇ ca) relates to bleaching agents based on aqueous hypochlorite solutions, the surfactant component being predominantly alkyl ether sulfates and small proportions Contain amine oxides.
  • German patent DE 43 33 100 C1 the applicant has already proposed stable and sufficiently viscous aqueous bleaching and cleaning agents based on hypochlones, fatty alcohol ether sulfates and amine oxides, which contain, as a mandatory component, amine oxide phosphonic acids, which make a decisive contribution to the thickening of the agents.
  • EP 0 812 908 A discloses cleaning agents which contain alkali metal hypochlone, a hypochlorite-compatible surfactant, for example an alkyl ether carboxylate, and, to reduce foam formation, contain an end-capped alkoxylated nonionic surfactant.
  • aqueous bleaches with increased viscosity which comprise an alkali metal hypochlorite from an alkyl ether carboxylate, a surfactant composition or their salt, a fatty acid or their salt and an alkyl ether sulfate and / or an alkyl sulfobetaine and an alkali metal hydroxide, the alkyl ether carboxylic acid or its salt making up up to 75% by weight of the surfactant composition.
  • hypochlorite liquors known from the literature often have too high a viscosity for cleaning hard surfaces (viscosities> 130 mPas measured in a Brookfield viscometer at 20 ° C, spindle 1, 60 rpm).
  • viscosities> 130 mPas measured in a Brookfield viscometer at 20 ° C, spindle 1, 60 rpm the excessive foam development (foam heights> 100 ml measured in the Ross-Miles test at 20 ° C) is often regarded as disturbing. In comparison to previous products, less expensive bleach and disinfectants would also be desirable.
  • the object of the invention was therefore to provide new aqueous bleaching and disinfecting agents which are characterized by less foaming than the agents available hitherto and are less viscous than these.
  • the invention relates to a bleaching and disinfecting agent containing - based on the agents -
  • R is a hydrocarbon radical having 6 to 28 carbon atoms
  • the weight ratio of the ether carboxylates (b) to these further surfactants is at least 4 to 1. In a further embodiment of the invention, this weight ratio is at least 9 to 1. In a further embodiment of the invention, the agent contains ether carboxylates (b ) as the only surfactants.
  • ether carboxylates as the sole or predominant surfactants in bleaching and disinfecting agents, not only cause a low viscosity but also a low level of foaming. Viscosities (measurement: Brookfield viscometer, 20 ° C., spindle 1, 60 rpm) below 130 mPas and foam heights (measurement: Ross-Miles test, 20 ° C.) below 100 ml could be measured for the agents according to the invention.
  • Alkali and alkaline earth metal hypochlorites are to be understood in particular as lithium, sodium, potassium, magnesium and calcium hypochlorite, preferably potassium and particularly preferably sodium hypochlorite.
  • the hypochlorites can preferably be used in amounts of 1.0 to 6.0 and in particular 3.0 to 5.0% by weight, based on the composition.
  • Ether carboxylates of the formula (I) can be obtained by alkoxylating alcohols ROH with ethylene oxide as the only alkoxide or with several alkoxides and subsequent oxidation.
  • the sum u + v + w represents the total degree of alkoxylation of the ether carboxylate. While the numbers u, v and w and the total degree of alkoxylation at the molecular level can only be integers including zero, at the macroscopic level they are mean values in the form of fractional numbers.
  • formula (I) is R straight-chain or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, preferably a straight-chain or branched, acyclic Ce-22 alkyl or alkenyl residue or a C 22 alkyl phenyl residue, in particular a C ⁇ -i ⁇ -alkyl residue or alkenyl or a C -i6-alkyl-phenyl radical, particularly preferably a C ⁇ o-16-alkyl radical, u, v, w in total u + v + w, preferably a number from 2 to 20, in particular 3 to 17 and particularly preferably 5 to 15, x, y, z in the sum x + y + z preferably not greater than 2, in particular not greater than 1 and particularly preferably equal to 0,
  • M in particular lithium, sodium, potassium, calcium or magnesium, of which potassium and particularly sodium are preferred.
  • Suitable ether carboxylates or ether carboxylic acids are accordingly, for example, the following representatives designated by their INCI name (INCI: nomenclature for raw materials according to the International Cosmetic Ingredient Dictionary 7th Edition published by The Cosmetic, Toiletry and Fragrance Association Inc.
  • R, w and M have the same meaning as in formula (I) and preferably R is a C ⁇ o-16-alkyl radical, w is from 3 to 17 and M is sodium.
  • R is a C ⁇ o-16-alkyl radical
  • w is from 3 to 17
  • M is sodium.
  • the ether carboxylates can have a conventional or narrow homolog distribution.
  • the ether carboxylates are preferably used in amounts of 0.1 to 5.0% by weight and in particular 0.2 to 1.5% by weight, based on the composition.
  • alkali and alkaline earth metal hydroxides come in particular lithium, sodium, potassium Magnesium and calcium hydroxide, of which potassium hydroxide and especially sodium hydroxide are preferred, are considered, which are preferably used in amounts of 0.5 to 2.0 and in particular 0.7 to 1.0% by weight, based on the composition and serve to adjust the pH of the agents to an optimal value of 10 to 14, preferably 12.5 to 13.5.
  • the agents according to the invention can include further surfactants, auxiliaries and additives, etc. Alkyl ether sulfates, amine oxides, electrolyte salts and fatty acid salts.
  • Alkyl ether sulfates are known anionic surfactants which are obtained by sulfation of nonionic surfactants of the alkylpolyglycol ether type and subsequent neutralization.
  • Preferred alkyl ether sulfates in the context of the teaching according to the invention follow the formula (II),
  • R 1 represents an alkyl radical having 12 to 18 carbon atoms
  • n represents numbers 2 to 5
  • X represents sodium or potassium.
  • Typical examples are the sodium salts of sulfates of the C12 / 14 coconut fatty alcohol-2, -2,3- and -3-EO adduct.
  • the alkyl ether sulfates can have a conventional or narrow homolog distribution.
  • the alkyl ether sulfates are preferably used in amounts of 0.1 to 3.3% by weight and in particular 0.2 to 1.5% by weight, based on the.
  • amidoamine oxides are also known substances, which are occasionally attributed to the cationic, but usually the nonionic surfactants.
  • the amidoamine oxides preferred in the context of the invention can be prepared starting from tertiary fatty acid amidoamines by oxidation with hydrogen peroxide. Particularly preferred amidoamine oxides follow the formula (III) R3
  • R 2 CO represents a linear or branched acyl radical having 12 to 18 carbon atoms
  • R 3 and R 4 independently of one another an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms and m represents numbers from 1 to 3.
  • the amidoamine oxides are preferably used in amounts of 0.5 to 3.3% by weight and in particular of 1 , 0 to 3% by weight, based on the composition
  • Suitable electrolyte salts are the alkali and alkaline earth metal carbonates, chlorides, silicates, phosphates and phosphonates and mixtures thereof.
  • Sodium or potassium carbonate or chloride are preferably used, which not only effect the desired buffering of the preparation, but also one Perform sequestration of metal ions, in particular heavy metal ions.
  • An additional advantage is their low price and ease of incorporation.
  • the electrolyte salts are preferably used in quantities of 1.0 to 2.0% by weight, based on the composition
  • agents according to the invention can furthermore contain fatty acid salts of the formula (IV)
  • R 5 CO stands for an acyl residue with 12 to 22 carbon atoms and X for an alkali metal.
  • Typical examples are the sodium and / or potassium salts of lau ⁇ nsaure, mynstinsaure, palmitinsaure, palmoleinklare, stearinklare, isostea ⁇ nsaure, oleic acid, elaidic acid, Petroselinic acid, linoleic acid, linoienic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid as well as their technical mixtures as they occur in the pressure splitting of technical fats and oils.
  • Salts of technical coconut or tallow fatty acids are preferably used. Since the recipes according to the invention are strongly alkaline, the fatty acids which are neutralized in situ when they are introduced into the mixture can also be used instead of the salts.
  • the fatty acid salts are preferably used in amounts of 0.5 to 2.0% by weight, based on the composition.
  • auxiliaries and additives include, for example, other chlorine-stable surfactants or hydrotropes, such as, for example, alkyl sulfates, alkyl sulfonates, alkylbenzenesulfonates, xylene sulfonates, sarcosinates, taurides, isethionates, sulfosuccinates, betaines, sugar esters, fatty alcohol polyglycol ethers, alkyl oligoglycosides and fatty acid amide glucosacids.
  • alkyl sulfates in amounts of 0.5 to 3% by weight is particularly preferred.
  • the agents can contain further active chlorine-stable fragrances, optical brighteners, sequestering agents, dyes and pigments in amounts of in total from 0.001 to 10% by weight, preferably 0.01 to 5% by weight, based on the agents.
  • Suitable optical brighteners are derivatives of diaminostilbenedisulfonic acid or its alkali metal salts.
  • derivatives of 4,4'-diamino-2,2'-stilbenedisulfonic acid (flavonic acid) are suitable, such as, in particular, the salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl- 6-amino) -stilbene-2,2'-disulfonic acid or compounds of the same structure which carry a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group instead of the morpholino group.
  • the potassium salt of 4,4'-bis (1,3,3-triazolyl) - (2-) - stilbin-2,2-sulfonic acid which is sold under the brand name Phorwite® BHC 766, is particularly preferred.
  • the agents contain the optical brighteners in amounts of 1 and 5% by weight, preferably between 2 and 3% by weight.
  • a particularly preferred dye is Tinolux® (Ciba-Geigy).
  • Suitable active chlorine-stable fragrances are citronellol (3,7-dimethyl-6-octen-1-ol), dimethyloctanol (3,7-dimethyloctanol-1), hydroxycitronellol (3,7-dimethyloctane-1, 7-diol), Mugol (3J-dimethyl-4,6-octatrien-3-ol), mirsenol (2-methyl-6-methylene-7-octen-2-ol), terpinolene (p-mentho-1, 4 (8) -diene ), Ethyl 2-methylbutyrate, phenylpropyl alcohol, galaxolide (1, 3,4,6,7,8-hexahydro-4,6,6,7,8,8, -hexamethylcyclopental-2-benzopyran), tonalide (7- Acetyl-1, 1, 3,4,4,6-hexamethyltetrahydronaphthalene), rose oxide, linalol oxide
  • Polyacrylates, amine oxide phosphonic acids and lignin sulfonates and mixtures thereof can also be present as sequestering agents in amounts of 0.1 to 2.0 and preferably 0.5 to 1.0% by weight, based on the agent.
  • the color pigments include green chlorophthalocyanines [Pigmosol® Green, Hostaphine® Green) or yellow Solar Yellow BG 300 (thiazole dye C.I. Disperse Yellow 28, Clariant) in question.
  • the agents according to the invention are produced by stirring. If necessary, the product obtained can be decanted or filtered to remove foreign bodies and / or agglomerates. Immediately after production, the agents have a viscosity - measured at 20 ° C. using a Brookfield viscometer (model RVT, spindle 1, 60 rpm) - below 130, preferably below 100, in particular below 50 mPas and a foam height below from 100, preferably below 80, in particular not more than 60 ml - measured at 20 ° C. in a Ross-Miles test. Examples
  • Recipes 1 and 2 are according to the invention, recipe V1 is used for comparison. Immediately after production, the viscosity was determined at 20 ° C. using a Brookfield viscometer (model RVT, spindle 1, 60 rpm) and the foaming power in the Ross-Miles test. The results are summarized in Table 1 (quantitative data as% by weight).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Nouveaux produits de blanchiment et de désinfection qui contiennent, par rapport au produit total, (a) 1,0 à 6,0 % en poids d'hypochlorite de métal alcalin et/ou alcalino-terreux, (b) de 0,1 à 10,0 % en poids d'éthercarboxylates de formule R[OCH2CH2]u[O(CH2)xCH(R')(CH2)yCH(R'')(CH2)z]v[OCH2CH2]wOCH2COOM dans laquelle R représente un reste hydrocarbure ayant 6 à 28 atomes de carbone, u et v sont des nombres identiques ou différents de 0 à 30, u étant égal à 0 lorsque v est égal à 0, w est un nombre de 0 à 30, la somme u + v + w étant inférieure ou égale à 30, x, y et z sont indépendamment l'un de l'autre les chiffres 0 ou 1, R' et R'' représentent indépendamment l'un de l'autre hydrogène, méthyle ou éthyle, la somme x + y + z étant supérieure à 0 lorsque R' = R'' = H, M représente un métal alcalin ou alcalino-terreux et (c) de 0,5 à 2,0 % en poids d'hydroxyde de métal alcalin et/ou alcalino-terreux, à condition que les quantités des constituants (a) à (c) soient complétées avec de l'eau et éventuellement avec d'autres tensio-actifs, adjuvants et additifs jusqu'à 100 % en poids, le rapport pondéral des éthercarboxylates (b) à ces autres tensio-actifs étant de plus de 3 à 1. Lesdites compositions abaissent la viscosité et réduisent l'effet moussant de solutions d'hypochlorite.
EP00938729A 1999-06-11 2000-06-02 Produits de blanchiment et de desinfection Withdrawn EP1185605A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19926627 1999-06-11
DE19926627A DE19926627A1 (de) 1999-06-11 1999-06-11 Bleich- und Desinfektionsmittel
PCT/EP2000/005042 WO2000077145A1 (fr) 1999-06-11 2000-06-02 Produits de blanchiment et de desinfection

Publications (1)

Publication Number Publication Date
EP1185605A1 true EP1185605A1 (fr) 2002-03-13

Family

ID=7910905

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00938729A Withdrawn EP1185605A1 (fr) 1999-06-11 2000-06-02 Produits de blanchiment et de desinfection

Country Status (9)

Country Link
EP (1) EP1185605A1 (fr)
JP (1) JP2003502481A (fr)
CN (1) CN1354781A (fr)
AR (1) AR024305A1 (fr)
AU (1) AU5400200A (fr)
CA (1) CA2311485A1 (fr)
DE (1) DE19926627A1 (fr)
HU (1) HUP0201960A3 (fr)
WO (1) WO2000077145A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102234597B (zh) * 2010-04-26 2015-05-27 东友精细化工有限公司 清洗组合物
US20130146098A1 (en) * 2011-12-09 2013-06-13 Clariant International Ltd. Automatic Dishwashing Detergent Compositions Comprising Ethercarboxylic Acids Or Their Salts, Which Are Free Of Nonionic Surfactants
EP2892348A4 (fr) 2012-09-07 2016-05-11 Marcus E Martin Formulation désinfectante comprenant de l'hydroxyde de calcium et de l'hypochlorite de sodium
EP2970822A2 (fr) * 2013-03-14 2016-01-20 Clariant International Ltd. Compositions détergentes de lavage de vaisselle automatique exemptes de tensioactifs non ioniques et comprenant des acides carboxyliques d'éther ou leurs sels

Family Cites Families (10)

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Publication number Priority date Publication date Assignee Title
JPS4926688B1 (fr) * 1970-12-09 1974-07-11
JPS565800B2 (fr) * 1973-12-11 1981-02-06
CH647543A5 (de) * 1980-05-13 1985-01-31 Sandoz Ag Reinigungsmittel auf hypochlorit-basis mit verdickungsmitteln.
GB2076010B (en) * 1980-05-13 1984-05-16 Sandoz Products Ltd Bleach composition
NL8103829A (nl) * 1981-08-15 1983-03-01 Chem Y Waterig bleekmiddel met reinigende werking.
NL8301168A (nl) * 1983-03-31 1984-10-16 Chem Y Reinigingsmiddel op basis van actief chloor en alkali.
EP0256638B1 (fr) * 1986-08-07 1991-01-23 The Clorox Company Composition d'hypochlorite épaississante et son utilisation
DE4333100C1 (de) * 1993-09-29 1994-10-06 Henkel Kgaa Bleich- und Desinfektionsmittel
NL9401510A (nl) * 1994-09-16 1996-05-01 Chem Y Surfactantsamenstelling, surfactantconcentraat in vloeibare vorm en waterig bleekmiddel met verhoogde viscositeit en reinigende werking.
EP0812904A3 (fr) * 1996-06-10 1999-05-26 The Procter & Gamble Company Compositions nettoyantes

Non-Patent Citations (1)

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Title
See references of WO0077145A1 *

Also Published As

Publication number Publication date
HUP0201960A3 (en) 2004-03-01
DE19926627A1 (de) 2000-12-14
WO2000077145A1 (fr) 2000-12-21
AR024305A1 (es) 2002-09-25
CN1354781A (zh) 2002-06-19
AU5400200A (en) 2001-01-02
HUP0201960A2 (en) 2002-09-28
CA2311485A1 (fr) 2000-12-11
JP2003502481A (ja) 2003-01-21

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