EP0912696B1 - Agents de blanchiment et de desinfection aqueux - Google Patents

Agents de blanchiment et de desinfection aqueux Download PDF

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Publication number
EP0912696B1
EP0912696B1 EP97924946A EP97924946A EP0912696B1 EP 0912696 B1 EP0912696 B1 EP 0912696B1 EP 97924946 A EP97924946 A EP 97924946A EP 97924946 A EP97924946 A EP 97924946A EP 0912696 B1 EP0912696 B1 EP 0912696B1
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EP
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Prior art keywords
weight
preparations
contain
alkali metal
carbon atoms
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Expired - Lifetime
Application number
EP97924946A
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German (de)
English (en)
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EP0912696A1 (fr
Inventor
Mercedes Mendoza
Maite Canellas
Elisabet Dejorge
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to new aqueous bleaching and disinfecting agents containing alkali metal hypochlorites, Alkyl ether sulfates, amine oxides, fatty acid salts and alkali metal hydroxides in selected proportions.
  • EP-A 0 274 885 recommends the use of mixtures of linear and branched amine oxides. According to the teaching of EP-A 0 145 084 (Unilever), mixtures of amine oxides with soaps, sarcosinates, taurides or sugar esters can also be used for this purpose.
  • EP-A 0 137 551 and EP-A 0 447 261 (Unilever) the use of amine oxides with soap or sarcosinate and other anionic surfactants, for example alkyl sulfates, alkyl ether sulfates, secondary alkane sulfonates or alkyl benzene sulfonates as a thickening component, is known.
  • EP-A 0 156 438 reports on the use of alkylarylsulfonates as thickeners in aqueous bleaching agents which contain certain stilbene dyes as optical brighteners.
  • ES-A 8801389 Henkel Ibérica
  • aqueous hypochlorite solutions which predominantly contain alkyl ether sulfates and small amounts of amine oxides as surfactant components.
  • aqueous bleaching agent compositions containing sodium hypochlorite and anionic surfactants are also known.
  • the hypochlorite concentration of these agents is 0.1 to 8 and preferably 0.5 to 5% by weight of active chlorine.
  • Aqueous bleaching and cleaning agents containing alkali metal hypochlorites, Alkyl sulfates, amine oxides, fatty acid and alkali metal hydroxides are known from WO-A-95/08610, WO-A-95/03383 and EP-A-0635568.
  • German patent DE-C1 43 33 100 the applicant has already proposed stable and sufficiently viscous aqueous bleaching and cleaning agents based on hypochlorites, fatty alcohol ether sulfates and amine oxides, which contain amine oxide phosphonic acids as a mandatory component. Even if the preparations are not objectionable from an application point of view, the use of phosphonic acids is not without problems with regard to the introduction of phosphorus compounds into surface waters. Since the amine oxide phosphonic acids are also comparatively expensive ingredients, there continues to be a need on the market for simple, viscous formulations which are characterized by high storage stability, chlorine resistance and good dispersing properties with a low hypochlorite content. The object of the invention was therefore to provide new aqueous bleaching and disinfecting agents which are free from the disadvantages described.
  • Alkali metal hypochlorites are to be understood as meaning lithium, potassium and in particular sodium hypochlorite.
  • the hypochlorites can preferably be used in amounts of 1.5 to 2% by weight, based on the composition become.
  • Alkyl ether sulfates are known anionic surfactants which are obtained by sulfation of nonionic surfactants of the alkyl polyglycol ether type and subsequent neutralization.
  • the alkyl ether sulfates which are suitable for the purposes of the agents according to the invention follow the formula ( I ) R 1 O- (CH 2 CH 2 O) n SO 3 X in which R 1 represents an alkyl radical having 12 to 18 carbon atoms, n represents numbers 2 to 5 and X represents sodium or potassium.
  • Typical examples are the sodium salts of sulfates of the C 12/14 cocoalcohol-2, -2,3- and -3-EO adduct.
  • the alkyl ether sulfates can have a conventional or narrow homolog distribution.
  • the alkyl ether sulfates are preferably used in amounts of 2 to 4% by weight, based on the composition.
  • Amine oxides are also known substances, which are occasionally attributed to the cationic, but usually the nonionic surfactants. They are prepared from tertiary fatty amines, which usually have either one long and two short or two long and one short alkyl radical, and are oxidized in the presence of hydrogen peroxide.
  • the amine oxides which are suitable for the purposes of the invention follow the formula ( II ) in which R 2 represents a linear or branched alkyl radical having 12 to 18 carbon atoms and R 3 and R 4 independently of one another represent R 2 or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms.
  • Amine oxides of the formula ( II ) are preferably used in which R 2 and R 3 are C 12/14 and C 12/18 cocoalkyl radicals and R4 is a methyl or a hydroxyethyl radical. Also preferred are amine oxides of the formula (II) in which R 2 is a C 12/14 or C 12/18 cocoalkyl radical and R 3 and R 4 are methyl or hydroxyethyl. The amine oxides are preferably used in amounts of 1.5 to 3% by weight, based on the composition.
  • the agents according to the invention may contain fatty acid salts of the formula ( III ) as further constituents, R 5 CO-OX in which R 5 CO represents an acyl radical having 12 to 22 carbon atoms and X represents an alkali metal.
  • R 5 CO represents an acyl radical having 12 to 22 carbon atoms
  • X represents an alkali metal.
  • Typical examples are the sodium and / or potassium salts of lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their mixtures, and their mixtures the pressure splitting of technical fats and oils.
  • Salts of technical coconut or tallow fatty acids are preferably used. Since the formulations according to the invention are strongly alkaline, it is also possible to use the fatty acids instead of the salts, which are neutralized in situ when introduced into the mixture.
  • the fatty acid salts are preferably used in amounts of 1.5 to 2% by weight.
  • Potassium hydroxide and in particular sodium hydroxide come into consideration as alkali metal hydroxides. which are preferably used in amounts of 1.5 to 2 wt .-% and serve the pH to set the mean to an optimal value of 12.5 to 14.
  • the agents according to the invention have a viscosity above 100 mPas - measured at 20 ° C. in a Brookfield viscometer - are stable on storage, resistant to chlorine consumption and stand out with an excellent dispersibility for dye pigments.
  • auxiliaries and additives which the preparations may further contain are further chlorine-stable surfactants or hydrotropes, such as alkyl sulfates, alkyl sulfonates, alkylbenzenesulfonates, Xylene sulfonates, sarcosinates, taurides, isethionates, sulfosuccinates, betaines, sugar esters, Fatty alcohol polyglycol ethers and alkyl oligoglycosides.
  • surfactants or hydrotropes such as alkyl sulfates, alkyl sulfonates, alkylbenzenesulfonates, Xylene sulfonates, sarcosinates, taurides, isethionates, sulfosuccinates, betaines, sugar esters, Fatty alcohol polyglycol ethers and alkyl oligoglycosides.
  • the sum of these makes additional
  • alkyl sulfates in amounts of 0.5 to 3% by weight is particularly preferred.
  • agents active chlorine-stable fragrances, optical brighteners, dyes and pigments in a total of 0.01 to 0.5 wt .-% - based on the agent - included.
  • active chlorine resistant Known fragrances include, for example, monocyclic and bicyclic monoterpene alcohols and their esters with acetic or propionic acid (e.g. isoborneal, dihydroterpene oil, Isobomylacetate, dihydroterpenylacetate).
  • the optical brighteners can be, for example the potash salt of 4,4'-bis (1,2,3-triazolyl) - (2-) - stilbin-2,2-sulfonic acid act under the brand name Phorwite® BHC 766 is sold.
  • the color pigments include green chlorophthalocyanines (Pigmosol® Green, Hostaphine® Green) or yellow Solar Yellow® BG 300 (Sandoz) in question.
  • the agents according to the invention are produced by stirring. If necessary, the obtained Decant or filter product to remove foreign bodies and / or agglomerates.
  • the viscosity was determined at 20 ° C. using a Brookfield viscometer (model RCT, spindle No. 1 or No. 2, 200 rpm). To determine the chlorine stability, the test mixtures were stored in a colorless plastic bottle under the influence of daylight and the active chlorine content was determined.
  • the formulas R1 to R3 are according to the invention, the formulas R4 to R7 are used for comparison. The results are summarized in Table 1 (quantitative data as% by weight)
  • the preparations according to the invention are those which are amine oxidephosphonic acids Stabilizers contain not only equivalent in terms of viscosity, storage stability and chlorine consumption, but z. T. are even superior.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (5)

  1. Agents de blanchiment et de désinfection aqueux ayant une viscosité au-dessus de 100 mPas, mesurée à 20°C dans un viscosimètre Brookfield et dépourvus d'acide amino-oxyde phosphonique, contenant rapporté aux compositions :
    (a) de 1 à 3 % en poids d'hypochlortte de métal alcalin,
    (b) de 1 à 5 % en poids de sulfate d'éther alkylique de formule (I) R1O-(CH2CH2O)nSO3X dans laquelle R1 représente un reste alkyle ayant de 12 à 18 atomes de carbone, n représente des nombres 2 à 5 et X représente le sodium ou le potassium,
    (c) de 1 à 4 % en poids d'amino-oxyde
    (d) de 1 à 4 % en poids de sels d'acide gras, et
    (e) de 0,1 à 2 % en poids d'hydroxyde de métal alcalin
    ainsi que le cas échéant d'autres adjuvants et additifs usuels.
  2. Agents selon la revendication 1,
    caractérisés en ce qu'
    ils renferment de l'hypochlorite de sodium.
  3. Agents selon l'une quelconque des revendications 1 ou 2,
    caractérisés en ce qu'
    ils renfermant des amino-oxydes de formule II
    Figure 00110001
    dans laquelle R2 représente un reste alkyle linéaire ou ramifié, ayant de 12 à 18 atomes de carbone ainsi que R3 et R4 indépcndamment l'un de l'autre, représentent R2 ou un reste allyle éventuellement substitué par un hydroxy, ayant dc 1 à 4 atomes de carbone.
  4. Agents selon l'une quelconque des revendications 1 à 3,
    caractérisée en ce qu'
    ils renferment des sels d'acide gras de formule (III) R5CO-OX dans laquelle R5CO représente un reste acyle ayant de 12 à 22 atomes de carbone et X représente un métal alcalin.
  5. Agents selon l'une quelconque des revendications 1 à 4,
    caractérisés en ce qu'
    ils renferment de l'hydroxyde de sodium.
EP97924946A 1996-05-24 1997-05-14 Agents de blanchiment et de desinfection aqueux Expired - Lifetime EP0912696B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19621048 1996-05-24
DE1996121048 DE19621048C2 (de) 1996-05-24 1996-05-24 Wäßrige Bleich- und Desinfektionsmittel
PCT/EP1997/002459 WO1997045520A1 (fr) 1996-05-24 1997-05-14 Agents de blanchiment et de desinfection aqueux

Publications (2)

Publication Number Publication Date
EP0912696A1 EP0912696A1 (fr) 1999-05-06
EP0912696B1 true EP0912696B1 (fr) 2003-04-09

Family

ID=7795282

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97924946A Expired - Lifetime EP0912696B1 (fr) 1996-05-24 1997-05-14 Agents de blanchiment et de desinfection aqueux

Country Status (4)

Country Link
EP (1) EP0912696B1 (fr)
DE (1) DE19621048C2 (fr)
ES (1) ES2196334T3 (fr)
WO (1) WO1997045520A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE297978T1 (de) * 1998-05-08 2005-07-15 Henkel Kgaa Bleich- und desinfektionsmittel
DE19902904A1 (de) * 1999-01-26 2000-08-03 Henkel Kgaa Bleich- und Desinfektionsmittel
DE102005041436A1 (de) * 2005-08-31 2007-03-01 Henkel Kgaa Flüssiges hypohalogenithaltiges Bleichmittel

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474677A (en) * 1981-11-06 1984-10-02 Lever Brothers Company Colored aqueous alkalimetal hypochlorite compositions
GB8325541D0 (en) * 1983-09-23 1983-10-26 Unilever Plc Liquid thickened bleaching composition
GB8332271D0 (en) * 1983-12-02 1984-01-11 Unilever Plc Bleaching composition
EP0635568A1 (fr) * 1993-07-23 1995-01-25 The Procter & Gamble Company Compositions détergentes épassies à base d'hypochlorite, plus performantes pour le nettoyage
HU219162B (hu) * 1993-07-23 2001-02-28 The Procter And Gamble Company Rövid szénláncú felületaktív anyagokat tartalmazó, javított tisztító hatású viszkózus, vizes mosószerkészítmény és alkalmazása
GB9315760D0 (en) * 1993-07-30 1993-09-15 Nat Starch Chem Corp Bleach compositions
WO1995008610A1 (fr) * 1993-09-20 1995-03-30 The Procter & Gamble Company Utilisation de compositions comprenant de l'hypochlorite avec un tensioactif a chaine courte dans l'attenuation d'odeurs
DE4333100C1 (de) * 1993-09-29 1994-10-06 Henkel Kgaa Bleich- und Desinfektionsmittel

Also Published As

Publication number Publication date
DE19621048A1 (de) 1997-11-27
WO1997045520A1 (fr) 1997-12-04
ES2196334T3 (es) 2003-12-16
DE19621048C2 (de) 2000-06-21
EP0912696A1 (fr) 1999-05-06

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