EP1038989A2 - Beschichteter Fräseinsatz - Google Patents

Beschichteter Fräseinsatz Download PDF

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Publication number
EP1038989A2
EP1038989A2 EP00104777A EP00104777A EP1038989A2 EP 1038989 A2 EP1038989 A2 EP 1038989A2 EP 00104777 A EP00104777 A EP 00104777A EP 00104777 A EP00104777 A EP 00104777A EP 1038989 A2 EP1038989 A2 EP 1038989A2
Authority
EP
European Patent Office
Prior art keywords
range
cemented carbide
layer
composition
tin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00104777A
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English (en)
French (fr)
Other versions
EP1038989A3 (de
EP1038989B1 (de
Inventor
Jeanette Persson
Leif Akesson
Rickard Sundtröm
Ake Östlund
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sandvik AB
Original Assignee
Sandvik AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sandvik AB filed Critical Sandvik AB
Publication of EP1038989A2 publication Critical patent/EP1038989A2/de
Publication of EP1038989A3 publication Critical patent/EP1038989A3/de
Application granted granted Critical
Publication of EP1038989B1 publication Critical patent/EP1038989B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F2005/001Cutting tools, earth boring or grinding tool other than table ware
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/26Cutters, for shaping comprising cutting edge bonded to tool shank
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/27Cutters, for shaping comprising tool of specific chemical composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495Thickness [relative or absolute]
    • Y10T428/24967Absolute thicknesses specified
    • Y10T428/24975No layer or component greater than 5 mils thick

Definitions

  • the present invention relates to a coated cemented carbide cutting tool (indexable insert) for the milling, particularly at high cutting speeds, of stainless steels of different composition and microstructure such as austenitic, ferritic, duplex, superaustenitic and precipitation hardened stainless steels but also for the milling of non-stainless steels such as low carbon steels and low and medium alloyed steels.
  • a coated cemented carbide insert when applying a cemented carbide cutting insert in the milling of a workpiece of a non-stainless steel or a stainless steel where the surface of the workpiece is covered by so called cast skin, or when milling under difficult external conditions such as heavy vibrations of the workpiece, a coated cemented carbide insert must be used where the insert includes a substrate of a tough cemented carbide grade and on the surface of the substrate, a hard and wear resistant refractory coating is deposited. The coating should be adherently bonded to the substrate and covering all functional parts of the insert.
  • adhesive wear is active as adhesive wear which is caused by the adhesive force between the stainless steel chip and the cutting edge material. When the adhesive force grows large enough, edge chipping in the vicinity of the above mentioned comb cracks on the cutting edge will occur and, hence, the tool life will be shortened.
  • cemented carbide tools suitable for the machining of stainless steels and, in particular, cemented carbide tools suitable for the milling of stainless steels are usually only optimised with respect to one or two of the required tool properties mentioned above i.e. high resistance to chemical, abrasive, adhesive and plastic deformation wear of a tough cemented carbide substrate coated with a wear resistant and an adherently bonded coating.
  • WO 97/20083 discloses a coated cemented carbide cutting tool particularly designed for the wet and dry milling of workpieces of low and medium alloyed steels or stainless steels, with or without abrasive surface zones, in machining operations requiring a high degree of toughness of the cutting edge.
  • the external cutting conditions are characterized by complex shapes of the workpiece, vibrations, chip hammering, recutting of the chips etc.
  • the described cutting insert comprises a coated cemented carbide substrate containing WC with an average grain size of 1.7 ⁇ m together with cubic carbides and 11-12 wt% Co, a coating including a layer of TiC x N y O z with a columnar grain structure, a second layer of a smooth, finegrained ⁇ -Al 2 O 3 and an outermost third layer of TiN.
  • WO 97/20081 discloses a coated cemented carbide cutting tool particularly designed for the wet and dry milling of low and medium alloyed steels.
  • the described cutting insert comprises a coated cemented carbide substrate containing WC, cubic carbides and Co and a coating including a layer of TiC x N y O z with a columnar grain structure, a second layer of a smooth, finegrained ⁇ -Al 2 O 3 and an outermost third layer of TiN.
  • WO 97/20082 discloses a coated cemented carbide cutting tool particularly designed for the wet turning of stainless steel components in machining operations requiring a high degree of toughness of the carbide cutting edge.
  • the described cutting insert comprises a coated cemented carbide substrate with a cobalt binder phase enriched in W, a coating including a layer of TiC x N y O z with a columnar grain structure, a second layer of ⁇ -Al 2 O 3 , and an outermost third layer of TiN.
  • a very smooth cutting edge surface is optionally obtained by brushing the tool edges with brushes based on e.g. SiC.
  • a coated cemented carbide body comprising a substrate based on WC-Co without any additions of cubic carbides and with a specific grainsize range of the WC grains, a specific composition range of WC-Co and a coating including an innermost, very thin layer of TiN, a second layer of TiAlN with a periodic variation of the Ti/Al ratio along the normal to the substrate/coating interface, and an outermost layer of TiN.
  • Fig. 1 a micrograph of a polished cross section of a coated insert according to the present invention:
  • a coated cutting tool insert for the milling of stainless steels at high cutting speeds comprising a WC-Co based cemented carbide body including a small amount of Cr and with a composition of WC-Co in the range of 10-12 wt% Co, preferably 10-11 wt% Co and most preferably 10.2-10.8 wt% Co, and a Cr concentration in the range of 0.3-0.6 wt%, preferably 0.4-0.5 wt% and the balance is made up by WC.
  • the average WC grainsize is found in the range of 1.0-1.6 ⁇ m, preferably 1.1-1.4 ⁇ m and most preferably 1.15-1.3 ⁇ m.
  • the grainsize of WC is highly affected by the Cr concentration.
  • the saturation magnetization depends on the concentration of W in the binder phase, hence, the CW-value is a function of the W content in the Co binder phase as well. A large CW-value corresponds to a low W-content in the binder phase.
  • the cemented carbide substrate should have a CW-ratio in the range of 0.87-0.96, preferably 0.88-0.95, and most preferably 0.89-0.93.
  • the cemented carbide substrate should not contain any free graphite.
  • the hard and wear resistant refractory coating deposited on the cemented carbide substrate according to the present invention comprises:
  • the total thickness of the coating deposited on the cemented carbide substrate according to the present invention may vary in the range of 1-8 ⁇ m, preferably 2-5 ⁇ m.
  • the layer thickness, the sublayer thickness and the coating thickness quoted above refers to measurements made close to the cutting edge, i . e . the functional part of the cutting tool.
  • the present invention also relates to a method of making a coated cutting tool insert for the milling of stainless steels at high cutting speeds comprising a WC-Co based cemented carbide body including a small amount of Cr and with a composition of WC-Co in the range of 10-12 wt% Co, preferably 10-11 wt% Co and most preferably 10.2-10.8 wt% Co, and a Cr concentration in the range of 0.3-0.6 wt%, preferably 0.4-0.5 wt% and the balance is made up by WC.
  • the average WC grainsize is found in the range of 1.0-1.6 ⁇ m, preferably 1.1-1.4 ⁇ m and most preferably 1.15-1.3 ⁇ m.
  • the hard and wear resistant refractory coating is deposited onto the cemented carbide substrate by applying conventional PVD (Physical Vapor Deposition) or CVD (Chemical Vapor Deposition) methods and according to the present invention said coating comprises:
  • a MTCVD technique Medium Temperature CVD
  • the tool-life criterion was chipping of the cutting edge line with subsequent tool breakage.
  • Tool-life criteria were edge-line chipping and flank wear on the cutting edge. Inserts C and D also suffered from slice fractures on the rake face.
  • Tool-life criterion was chipping of the cutting edge.
  • Tool-life criterion was comb cracks formation with subsequent edge line chipping.
  • Tool-life criterion at the lower cutting speed was build-up edge formation on the tool edge and subsequent edge line chipping and the tool-life criterion at the higher cutting speed was flank wear of the main cutting edge and comb crack formation leading to fracture of the tool edge.
EP00104777A 1999-03-26 2000-03-15 Beschichteter Fräseinsatz Expired - Lifetime EP1038989B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9901149 1999-03-26
SE9901149A SE519005C2 (sv) 1999-03-26 1999-03-26 Belagt hårdmetallskär

Publications (3)

Publication Number Publication Date
EP1038989A2 true EP1038989A2 (de) 2000-09-27
EP1038989A3 EP1038989A3 (de) 2002-06-26
EP1038989B1 EP1038989B1 (de) 2004-06-16

Family

ID=20415051

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00104777A Expired - Lifetime EP1038989B1 (de) 1999-03-26 2000-03-15 Beschichteter Fräseinsatz

Country Status (6)

Country Link
US (1) US6250855B1 (de)
EP (1) EP1038989B1 (de)
JP (1) JP2000308916A (de)
AT (1) ATE269429T1 (de)
DE (1) DE60011494T2 (de)
SE (1) SE519005C2 (de)

Cited By (18)

* Cited by examiner, † Cited by third party
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WO2001016388A1 (en) * 1999-09-01 2001-03-08 Sandvik Ab (Publ) Coated grooving or parting insert
WO2002014569A2 (en) * 2000-08-11 2002-02-21 Kennametal Inc. Chromium-containing cemented tungsten carbide body
US6554548B1 (en) 2000-08-11 2003-04-29 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
US6612787B1 (en) 2000-08-11 2003-09-02 Kennametal Inc. Chromium-containing cemented tungsten carbide coated cutting insert
EP1347076A1 (de) * 2002-03-20 2003-09-24 Seco Tools Ab PVD-beschichteter Werkzeugschneideinsatz
EP1493845A1 (de) * 2003-06-16 2005-01-05 Seco Tools Ab CDV beschichteter Schneidwerkzeugeinsatz
WO2006080888A1 (en) * 2005-01-31 2006-08-03 Sandvik Intellectual Property Ab Cemented carbide insert for toughness demanding short hole drilling operations
EP1803835A1 (de) * 2005-12-30 2007-07-04 Sandvik Intellectual Property AB Beschichteter Schneidwerkzeugeinsatz
EP1944391A1 (de) * 2006-12-27 2008-07-16 Sandvik Intellectual Property AB CVD-beschichtete Hartmetalleinlage für belastbarkeitserfordernde Kleinlochbohrungen
EP2006413A1 (de) * 2007-06-01 2008-12-24 Sandvik Intellectual Property AB Beschichtetes Hartmetall für Stanz- und Formanwendungen
WO2009002266A1 (en) * 2007-06-27 2008-12-31 Sandvik Intellectual Property Ab Coated cemented carbide inserts for milling of especially hard cast steel
EP2008743A1 (de) * 2007-06-01 2008-12-31 Sandvik Intellectual Property Ab Feinkörniges Hartmetall zum Wenden von hitzebeständigen Superlegierungen und rostfreiem Stahl
EP2011894A1 (de) * 2007-06-01 2009-01-07 Sandvik Intellectual Property AB Hartmetallwendeplatten zum Teilen, Rillen und Gewindeschneiden
WO2009070109A1 (en) * 2007-11-28 2009-06-04 Sandvik Intellectual Property Ab Coated cemented carbide inserts for gear milling in cast low carbon steel parts
WO2009070111A1 (en) * 2007-11-28 2009-06-04 Sandvik Intellectual Property Ab Coated cemented carbide inserts for rough milling of gears
US7727621B2 (en) 2005-12-08 2010-06-01 Sandvik Intellectual Property Ab Insert for milling of steel
WO2014019897A1 (de) * 2012-08-03 2014-02-06 Walter Ag Tialn-beschichtetes werkzeug
US9476114B2 (en) 2012-08-03 2016-10-25 Walter Ag TiAlN-coated tool

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SE9903122D0 (sv) 1999-09-06 1999-09-06 Sandvik Ab Coated cemented carbide insert
SE527679C2 (sv) * 2004-01-26 2006-05-09 Sandvik Intellectual Property Hårdmetallkropp, särskilt spiralborr, och användning av denna för verktyg för roterande metallbearbetning
CN100591787C (zh) * 2004-10-29 2010-02-24 山高刀具公司 制造硬质合金的方法
DE102005032860B4 (de) * 2005-07-04 2007-08-09 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Hartstoffbeschichtete Körper und Verfahren zu deren Herstellung
EP1762638B1 (de) * 2005-09-09 2012-01-11 Sandvik Intellectual Property AB PVD-beschichtetes Schneidwerkzeug
SE529015C2 (sv) * 2005-09-09 2007-04-10 Sandvik Intellectual Property PVD-belagt skärverktygsskär tillverkat av hårdmetall
SE529856C2 (sv) 2005-12-16 2007-12-11 Sandvik Intellectual Property Belagt hårdmetallskär, sätt att tillverka detta samt dess användning för fräsning
JP4854359B2 (ja) * 2006-03-29 2012-01-18 京セラ株式会社 表面被覆切削工具
SE530516C2 (sv) * 2006-06-15 2008-06-24 Sandvik Intellectual Property Belagt hårdmetallskär, metod att tillverka detta samt dess användning vid fräsning av gjutjärn
SE0701449L (sv) 2007-06-01 2008-12-02 Sandvik Intellectual Property Finkornig hårdmetall med förfinad struktur
US8455116B2 (en) 2007-06-01 2013-06-04 Sandvik Intellectual Property Ab Coated cemented carbide cutting tool insert
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US8277958B2 (en) 2009-10-02 2012-10-02 Kennametal Inc. Aluminum titanium nitride coating and method of making same
KR101190324B1 (ko) * 2010-02-11 2012-10-11 대구텍 유한회사 절삭공구
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EP2634285A1 (de) * 2012-02-29 2013-09-04 Sandvik Intellectual Property AB Beschichtetes Schneidewerkzeug
CN104994979B (zh) * 2013-02-27 2018-04-17 京瓷株式会社 切削工具
US9103036B2 (en) 2013-03-15 2015-08-11 Kennametal Inc. Hard coatings comprising cubic phase forming compositions
US9168664B2 (en) 2013-08-16 2015-10-27 Kennametal Inc. Low stress hard coatings and applications thereof
US9896767B2 (en) 2013-08-16 2018-02-20 Kennametal Inc Low stress hard coatings and applications thereof
GB2528272B (en) * 2014-07-15 2017-06-21 Tokamak Energy Ltd Shielding materials for fusion reactors
PL3274482T3 (pl) * 2015-03-26 2020-06-15 Sandvik Intellectual Property Ab Słupek do wiercenia w skale
WO2017100734A1 (en) 2015-12-11 2017-06-15 Smith International, Inc. Cutting elements with wear resistant surfaces
JP6638936B2 (ja) * 2016-01-13 2020-02-05 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
JP6044861B1 (ja) * 2016-04-08 2016-12-14 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
JP6045010B1 (ja) * 2016-04-14 2016-12-14 住友電工ハードメタル株式会社 表面被覆切削工具およびその製造方法
EP3263743A1 (de) * 2016-06-29 2018-01-03 Sandvik Intellectual Property AB Cvd-beschichtetes schneidwerkzeug
KR20180065117A (ko) 2016-12-07 2018-06-18 주식회사 세진티앤에스 탄소섬유가 코팅된 고강도 커팅 툴
CN108472739B (zh) * 2016-12-09 2020-11-27 住友电工硬质合金株式会社 表面被覆切削工具
JP7216916B2 (ja) * 2019-03-28 2023-02-02 三菱マテリアル株式会社 ダイヤモンド被覆超硬合金製工具
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US11253929B2 (en) 2019-10-10 2022-02-22 Sumitomo Electric Hardmetal Corp. Cutting tool
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CN114173970A (zh) * 2019-10-10 2022-03-11 住友电工硬质合金株式会社 切削工具

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US6342291B1 (en) 1999-09-01 2002-01-29 Sandvik Ab Coated grooving or parting insert and method of making same
WO2001016388A1 (en) * 1999-09-01 2001-03-08 Sandvik Ab (Publ) Coated grooving or parting insert
US6627049B2 (en) 1999-09-01 2003-09-30 Sandvik Ab Method of making grooving or parting insert
US6612787B1 (en) 2000-08-11 2003-09-02 Kennametal Inc. Chromium-containing cemented tungsten carbide coated cutting insert
US6575671B1 (en) 2000-08-11 2003-06-10 Kennametal Inc. Chromium-containing cemented tungsten carbide body
US6554548B1 (en) 2000-08-11 2003-04-29 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
WO2002014569A3 (en) * 2000-08-11 2002-06-27 Kennametal Inc Chromium-containing cemented tungsten carbide body
US6866921B2 (en) 2000-08-11 2005-03-15 Kennametal Inc. Chromium-containing cemented carbide body having a surface zone of binder enrichment
WO2002014569A2 (en) * 2000-08-11 2002-02-21 Kennametal Inc. Chromium-containing cemented tungsten carbide body
EP1347076A1 (de) * 2002-03-20 2003-09-24 Seco Tools Ab PVD-beschichteter Werkzeugschneideinsatz
US6884497B2 (en) 2002-03-20 2005-04-26 Seco Tools Ab PVD-coated cutting tool insert
EP1493845A1 (de) * 2003-06-16 2005-01-05 Seco Tools Ab CDV beschichteter Schneidwerkzeugeinsatz
WO2006080888A1 (en) * 2005-01-31 2006-08-03 Sandvik Intellectual Property Ab Cemented carbide insert for toughness demanding short hole drilling operations
US7727621B2 (en) 2005-12-08 2010-06-01 Sandvik Intellectual Property Ab Insert for milling of steel
EP1803835A1 (de) * 2005-12-30 2007-07-04 Sandvik Intellectual Property AB Beschichteter Schneidwerkzeugeinsatz
EP1944391A1 (de) * 2006-12-27 2008-07-16 Sandvik Intellectual Property AB CVD-beschichtete Hartmetalleinlage für belastbarkeitserfordernde Kleinlochbohrungen
EP2006413A1 (de) * 2007-06-01 2008-12-24 Sandvik Intellectual Property AB Beschichtetes Hartmetall für Stanz- und Formanwendungen
EP2008743A1 (de) * 2007-06-01 2008-12-31 Sandvik Intellectual Property Ab Feinkörniges Hartmetall zum Wenden von hitzebeständigen Superlegierungen und rostfreiem Stahl
EP2011894A1 (de) * 2007-06-01 2009-01-07 Sandvik Intellectual Property AB Hartmetallwendeplatten zum Teilen, Rillen und Gewindeschneiden
WO2009002266A1 (en) * 2007-06-27 2008-12-31 Sandvik Intellectual Property Ab Coated cemented carbide inserts for milling of especially hard cast steel
WO2009070109A1 (en) * 2007-11-28 2009-06-04 Sandvik Intellectual Property Ab Coated cemented carbide inserts for gear milling in cast low carbon steel parts
WO2009070111A1 (en) * 2007-11-28 2009-06-04 Sandvik Intellectual Property Ab Coated cemented carbide inserts for rough milling of gears
WO2014019897A1 (de) * 2012-08-03 2014-02-06 Walter Ag Tialn-beschichtetes werkzeug
US9476114B2 (en) 2012-08-03 2016-10-25 Walter Ag TiAlN-coated tool

Also Published As

Publication number Publication date
JP2000308916A (ja) 2000-11-07
EP1038989A3 (de) 2002-06-26
DE60011494D1 (de) 2004-07-22
SE9901149L (sv) 2000-09-27
DE60011494T2 (de) 2004-10-28
US6250855B1 (en) 2001-06-26
SE519005C2 (sv) 2002-12-17
SE9901149D0 (sv) 1999-03-26
EP1038989B1 (de) 2004-06-16
ATE269429T1 (de) 2004-07-15

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