EP1024028A1 - Procede pour transferer des articles a afficher y compris dessins, motifs et caracteres - Google Patents

Procede pour transferer des articles a afficher y compris dessins, motifs et caracteres Download PDF

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Publication number
EP1024028A1
EP1024028A1 EP98935328A EP98935328A EP1024028A1 EP 1024028 A1 EP1024028 A1 EP 1024028A1 EP 98935328 A EP98935328 A EP 98935328A EP 98935328 A EP98935328 A EP 98935328A EP 1024028 A1 EP1024028 A1 EP 1024028A1
Authority
EP
European Patent Office
Prior art keywords
patterns
designs
representation
letters
object surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98935328A
Other languages
German (de)
English (en)
Other versions
EP1024028A4 (fr
Inventor
Takehiko Ogi
Sadao Tanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP1024028A1 publication Critical patent/EP1024028A1/fr
Publication of EP1024028A4 publication Critical patent/EP1024028A4/fr
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1704—Decalcomanias provided with a particular decorative layer, e.g. specially adapted to allow the formation of a metallic or dyestuff layer on a substrate unsuitable for direct deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
    • E01F9/512—Preformed road surface markings, e.g. of sheet material; Methods of applying preformed markings

Definitions

  • the present invention relates to a method of transferring a representation such as designs, patterns and letters on various object surfaces such as existing road, sidewalk, floor and wall surfaces.
  • the present invention has been made to solve those problems. It is an object of the present invention to achieve clear display of designs, patterns, letters and the like, easy operation and prevention of the occurrence of the air layer between the transfer sheet and the base layer on the object surface.
  • the present invention has been conceived to achieve the above objects.
  • the method for achieving the objects is characterized by the steps of bonding a transfer sheet, including a sheet substrate 4 with a surface thereof provided with a display member 5 displaying the representation such as designs, patterns and letters, on a base member 2 which has been applied on the object surface; and releasing the sheet substrate 4 to transfer the display member 5 on the surface of the base member 2, so that the representation such as designs, patterns and letters are transferred on the object surface.
  • a further method is characterized by the steps of bonding a transfer sheet 3 including a sheet substrate 4 with a surface thereof provided with a display member 5 displaying the representation such as designs, patterns and letters, and a cover member 6 located on the opposite surface of the display member 5 to the surface contacting the sheet substrate 4, on a base member 2 which has been applied on the object surface; and releasing the sheet substrate 4 to transfer the display member 5 on the surface of the base member 2 via the cover member 6, so that the representation such as designs, patterns and letters are transferred on the object surface.
  • a still further method is characterized by the steps of bonding a transfer sheet 3, including a sheet substrate 4 with a surface thereof provided with a display member 5 displaying the representation such as designs, patterns and letters, on a transferring medium sheet 8; releasing the sheet substrate 4 to transfer the display member 5 to the transferring medium sheet 8; and bonding the transferring medium sheet 8 on the surface of the base member 2 which has been applied on the object surface to transfer the display member 5 to the base member 2 via the transferring medium sheet 8, so that the representation such as designs, patterns and letters are transferred on the object surface.
  • the base member 2 is made of, for example, a methacrylate resin.
  • the cover member 6 is made of, for example, titanium oxide.
  • Ink paint pigment or the like is used as the display member 5.
  • a protection layer 7 may be located on the transferred representation.
  • Using the transfer method of the present invention achieves clear display of designs, patterns, letters and the like, so that even printed designs, patterns can also be displayed in a state as close as the actual ones.
  • the transferring can be advantageously accomplished in easy manner and in a short period of time.
  • the method also prevents the occurrence of an air layer between the transfer sheet and the base layer on the object surface.
  • patterns can be repeatedly overlappingly transferred to the transferred designs, patterns.
  • the surface of a road repaired by roadwork or the like can be partially renovated in easy manner without the necessity of a special equipment.
  • given designs patterns can be displayed on new car parking spaces, old corsos, car parking spaces for vanous facilities such as a super market, and any other large spaces or narrow spaces in a short period of time, and can have an excellent durability.
  • a base member 2 made of a methacrylate resin is applied on an object surface 1 such as a road, sidewalk, floor and wall surface, as illustrated in FIG. 1.
  • the methacrylate resin used for the base member 2 is made by removing wax, paraffin and the like from a methacrylate resin liquid (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.).
  • the methacrylate resin liquid (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.) is of a fast cure type, which can be cured in 30 to 60 minutes, and therefore can be used in one to two hours after the application. This liquid is cured even at a low temperature of -30°C and exhibits excellent chemical resistance to organic acids, inorganic acids, alkali and the like, impact resistance, wear resistance, slip resistance and the like.
  • the methacrylate resin liquid (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.) is a reactive resin liquid containing methylmethacrylate as a main component.
  • a curing agent in the methacrylate resin liquid By adding a curing agent in the methacrylate resin liquid, it reacts with an accelerating agent in the methacrylate resin liquid to generate radicals. Wax, paraffin or the like contained in the methacrylate resin liquid move toward the surface of the methacrylate resin liquid and block the air so that radicals are developed, and hence radical polymerization are generated, resulting in the curing of the methacrylate resin liquid.
  • the aforementioned wax, paraffin or the like is removed from the methacrylate resin making up the base member 2, since a display member 5 and a cover member 6 (both will be described hereinafter) have air blocking capability like the wax, paraffin or the like.
  • the curing agent is, for example, benzoyl peroxide, which reacts to amines in the resin solution to generate radicals immediately after the benzoyl peroxide is added to the resin solution.
  • the methacrylate resin liquid of this type is basically an anaerobic resin liquid and therefore paraffin is added thereto for blocking the air.
  • a transfer sheet 3 for being bonded to the surface of the base member 2 is separately prepared.
  • the transfer sheet 3 includes a sheet substrate 4 made of a polyethylene terephthalate film with its surface provided with the display member 5 such as ink, paint and pigment displaying a representation such as designs and patterns, and the cover member 6 made of titanium oxide and provided on the surface of the display member 5 opposite to the surface contacting the sheet substrate 4.
  • the display member 5 such as ink, paint and pigment displaying a representation such as designs and patterns
  • the cover member 6 made of titanium oxide and provided on the surface of the display member 5 opposite to the surface contacting the sheet substrate 4.
  • titanium oxide of a solvent type When the titanium oxide of a solvent type is directly applied on the display member 5, the display member 5 is likely to be damaged.
  • titanium is applied on a different film and left thereon until it is dried, and then is thermally transferred to the sheet substrate 4 provided thereon with the display member 5 so as to be unified with the designs, patterns and the like.
  • the thicker application of the titanium oxide causes the hardening of the film, so that cracks or the like may occur in the film when it is bent. This may prevent the rolling up of the film. Therefore, the titanium oxide is preferably applied by a suitable thickness.
  • the transfer sheet 3 is bonded on the base member 2 before the base member 2 is dried, as illustrated in FIG. 3.
  • the bonding of the transfer sheet 3 on the methacrylate resin via the surface thereof, in which such a curing delay occurs, allows the transfer sheet 3 to be favorably bonded on the upper surface of the base member 2, even if an bonding agent is not interposed therebetween.
  • the cover member 6, the display member 5 and the like act as wax, paraffin or the like, as described above, thereby initiating the curing of the anaerobic methacrylate resin liquid. Consequently, the base member 2 and the transfer sheet 3 are tightly bonded together so as not to be separated from each other.
  • an ink layer, a titanium oxide layer or the like remains on the surface of the base member 2 so as to block the air at the surface thereof.
  • radicals are generated in the same manner as paraffin, and hence the curing occurs.
  • the sheet substrate 4 is released from the dried base member 2, as illustrated in FIG. 4.
  • the cover member 6 is transferred onto the upper surface of the base member 2 and the display member 5 is transferred on the upper surface of the cover member 6.
  • the representation such as designs and patterns displayed on the display member 5 is thus transferred on the object surface 1 such as a road, sidewalk, floor and wall surface.
  • the methacrylate resin liquid (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.), from which wax, paraffin or the like has not been removed, is applied on the upper surface of the display member 5 to form a top coat.
  • the reason for using the methacrylate resin without removal of wax, paraffin or the like therefrom is that the display member 5, the cover member 6 and the like are not transferred on the methacrylate resin forming the top coat.
  • the methacrylate resin making up the top coat has wax, paraffin or the like exuding on the surface so as to be cured in a short period of time.
  • a protection layer 7 is formed on the upper surface of the display member 5.
  • the transfer sheet 3 of this embodiment is bonded on the undried base member 2 without the necessity of applying a bonding agent on the base member 2. Therefore, the air does not exist between the base member 2 and the transfer sheet 3, and the bonding agent is not used, so that the operation can be easily accomplished.
  • the base member 2 made of the methacrylate resin can smoothen such an irregular surface to achieve smooth transference of designs, patterns and the like thereon.
  • the base member 2 is made of the methacrylate resin, it acts as an alkali block and water block for the concrete/asphalt, enhances adhesion power between the object surface, and the display member 5 or the cover member 6, as well as becomes tolerable against shrinkage, cracking and releasing forces.
  • the cover member 6 made of the titanium oxide is located between the base member 2 and the display member 5, the transferred designs, patterns and the like are hardly lost to sight, even if the base member 2 has stains, blackish portions and the like.
  • the transferred designs, patterns and the like can remarkably clearly be displayed on the surface side with a white background of the titanium oxide, while the stains and the blackish portions are favorably concealed.
  • the film made of the polyethylene terephthalate is used for the film making up the sheet substrate 4 in the above-mentioned embodiment, it is not necessary to limit the material of the film to this. It is possible to use, for example, polyvinyl chloride resin, polyamide resin and the like for the film, and therefore various kinds of synthetic resins can be used for making up the film.
  • water soluble paper For paper, it is also possible to use water soluble paper (wet transfer paper).
  • the display member displaying designs, patterns and the like is printed on the sheet substrate made of the water soluble paper, and then the synthetic resin layer made of the methacrylate resin and the like is provided on the upper surface of the printed designs, patterns and the like.
  • the rear surface of the paper the surface opposite to the surface with a layer of the printed designs, patterns and the like
  • the display member and the synthetic resin layer can be transferred on the object surface.
  • the base member of the methacrylate resin and the like is previously provided on the object surface in the same manner as the above-mentioned embodiment.
  • a top coat layer made of the methacrylate resin and the like can be provided on the upper surface of the synthetic resin layer after the transfer.
  • the transfer can be made even on the three-dimensional object surface such as a helmet, frame of TV set and eggshell, without occurrence of wrinkles by conforming around such an object surface.
  • the transfer is made by directly bonding the sheet substrate on the object surface.
  • the display member 5 can be bonded on the object surface 1, for example, by bonding the sheet substrate 4 with the display member 5 thereon to a transferring medium sheet 8 made of glass fibers, polyester or the like via a bonding agent 9 of an acrylate resin, methacrylate resin or the like as illustrated in FIG. 6, then releasing the sheet substrate 4 from the display member 5, as illustrated in FIG. 7, and then bonding the transferring medium sheet 8 on the object surface 1, as illustrated in FIG. 8.
  • the base member 2 made of the methacrylate resin and the like is also previously provided on the object surface 1 in this case.
  • the transferring medium sheet 8 is located on the object surface 1 via the base member 2
  • the display member 5 is located on the upper surface of the transferring medium sheet 8 via the bonding agent 9, as illustrated in FIG. 8.
  • a protection layer can also be located on the display member 5.
  • the methacrylate resin can be used as a material of the transferring medium sheet.
  • the base member, the transferring medium sheet and the protection layer can be integrated together by melting respective methacrylate resins thereof
  • the display member 5 displaying the representation such as designs, patterns and letters was directly provided on a surface of the sheet substrate 4.
  • a cellulose fiber layer can be provided on the sheet substrate 4 via wax, paraffin, silicone or the like applied on the surface of the sheet substrate 4.
  • the application of wax, paraffin, silicone or the like is advantageous in the fact that the display member 5 displaying designs, patterns and the like can be securely released from the sheet substrate 4 made of the film.
  • providing the cellulose fiber layer on the surface of the sheet substrate 4 is advantageous in the fact that various kinds of ink, pigment, paint and the like, which make up the display member 5, can be well absorbed in the sheet substrate 4 made of the film.
  • a large number of notches or small apertures can also be formed in the film making up the sheet substrate 4.
  • the formation of the notches and the like achieves a favorable air-ventilation so that the sheet substrate 4 can be released, without problems, from the cured resin, even if the methacrylate resin liquid making up the base member 2 exudes through the notches or the like and sticks on peripheral portions of the notches of the film.
  • each notch is preferably of a size of about 1.0 to 2.0 mm.
  • the length between the adjacent notches is preferably in the range of 5 to 10cm.
  • protection layer 7 is formed as the top coat in the above-mentioned embodiment, the formation of the protection layer 7 is not essential in the present invention.
  • the protection layer 7 is required to protect the display member 5 for use in such an actual site.
  • the protection layer When the above-mentioned methacrylate resin is used as the protection layer in this case, it produces effects of easily washing out stains and the like on road surfaces by water, and hence maintaining an aesthetical appearance for a prolonged period of time, as well as exhibiting excellent wear resistance and weather resistance.
  • an embossing substrate made of a film or the like having a predetermined concave or convex pattern is placed on the thus applied synthetic resin to let the air, an excessive synthetic resin and the like out of this portion, and then the embossing substrate is released from the cured synthetic resin, so that various kinds of concave or convex patterns are formed in the protection layer.
  • slip resistance capability can be impaired to the protection layer by mixing deformed beads or grained ceramics, sands or the like having a particle size of about 0.5 to 0.7 mm, into the protection layer, or spreading them over the protection layer to such an extent as not to damage the appearance of designs, patterns and the like.
  • the beads and the like spread over the protection layer cause irregular reflection of lights of cars or street lights, thereby enhancing a visual recognition characteristic. This contributes to traffic safety.
  • a rolled film having endless designs and patterns is preferable for the operation in view of shortening a period of time for the execution and cost effectiveness.
  • the transfer can easily be carried out by using a film cut into pieces each having a length of about 10 cm to 1 m.
  • the cut pieces of the film each can be shaped into an angular, rounded, triangular or other graphic forms, a letter, mark or the like.
  • the thus transferred cut pieces of the film are slightly higher than the remaining portions of the object surface to which the cut pieces have not been transferred, thus improving drainage of water and facilitating a one person operation.
  • a two component epoxy resin or a two component urethane resin which is generally used as the base member and the like, tends to be slow to react and is therefore difficult to be cured, when it drops to around 10°C. If the film is directly transferred on the base member made of such a material, the operation may not be carried out during not only the winter and rain but also wet weather.
  • the titanium oxide is used to form the cover member 6 in the above embodiment, it is not necessary to limit the material of the cover member 6 to that of the above embodiment.
  • the display member 5 can also be made by various kinds of materials such as ink, pigment and paint.
  • the display member 5 can also display various kinds of representations such as designs, patterns and letters.
  • the designs, patterns and other representations can also be transferred on various surfaces such as road, sidewalk, floor and wall surfaces.
  • the transfer can be made on a fire hydrant, a manhole and the like.
  • the methacrylate resin (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.), without the inclusion of wax, paraffin or the like, is applied to a car parking space of 100 m 2 to form the base member.
  • the sheet substrate made of the polyethylene terephthalate film with a thickness of about 50 ⁇ and with a printed picture of a marbled pattern having a width of 60 cm and a length of 100m, is then bonded on the base member to transfer designs, patterns and the like thereon. The film is then released in about 10 minutes.
  • a coating liquid made of the methacrylate resin liquid (Acrysirup manufactured by Mitsubishi Rayon Co., Ltd.), with the inclusion of wax, paraffin or the like, is applied on the transferred designs by a roller to form a top coat having a thickness of about 0.6 to 0.8 mm.
  • Spherical glass beads having a diameter of about 1mm were then spread over the coating liquid before it is dried
  • the object surface with the picture transferred thereon was cured in about ten minutes, thus enabling a person to walk thereon.
  • a flower picture of cosmoses placed at the center of a marbled background is divided into four, and printed out on electrostatic recording papers, by a large-scaled copying machine (manufactured by Sumitomo 3M Ltd.) with a total enlarged size of 2400 mm wide by 4000 mm long. Then, they are again transferred on the polyethylene terephthalate film, and the titanium oxide as a white paint is applied on a lower surface of the polyethylene terephthalate film, and the resultant film was transferred on the marbled road surface.
  • a visually excellent car parking space with an image of cosmoses in bloom in very beautiful marbles has been emerged.
  • grained alumina powders having a particle size of 0.5 to 0.7 mm were prepared and mixed into a resin forming the top coat, and the resultant resin forming the top coat was applied on the upper surface of the display member of designs, patterns and the like. Whereby, a more enhanced slip resistance could be obtained and maintained even during rain.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)
EP98935328A 1998-08-03 1998-08-03 Procede pour transferer des articles a afficher y compris dessins, motifs et caracteres Withdrawn EP1024028A4 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1998/003444 WO2000007831A1 (fr) 1998-08-03 1998-08-03 Procede pour transferer des articles a afficher y compris dessins, motifs et caracteres

Publications (2)

Publication Number Publication Date
EP1024028A1 true EP1024028A1 (fr) 2000-08-02
EP1024028A4 EP1024028A4 (fr) 2002-02-06

Family

ID=14208728

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98935328A Withdrawn EP1024028A4 (fr) 1998-08-03 1998-08-03 Procede pour transferer des articles a afficher y compris dessins, motifs et caracteres

Country Status (4)

Country Link
EP (1) EP1024028A4 (fr)
JP (1) JP4218859B2 (fr)
AU (1) AU8462698A (fr)
WO (1) WO2000007831A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003054840A2 (fr) * 2001-12-10 2003-07-03 Sales Activation Solutions Group Limited Ameliorations apportees a des affiches de plancher

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008299075A (ja) * 2007-05-31 2008-12-11 Tatsuo Tani 路面用シート、及び、広告用シートの施工方法
JP4981752B2 (ja) * 2008-06-10 2012-07-25 積水樹脂株式会社 視覚障害者誘導用突起フィルム及びその敷設方法
JP5205682B2 (ja) * 2012-04-09 2013-06-05 龍男 谷 路面用シート、及び、路面用シートの施工方法
JP2014211014A (ja) * 2013-04-17 2014-11-13 Ｎｐｏ法人日本防災環境 標示材の敷設方法
CN110431022A (zh) * 2017-03-13 2019-11-08 富士胶片株式会社 转印薄膜及图像形成方法
JP6993275B2 (ja) * 2018-03-27 2022-01-13 リンテック株式会社 路面用蓋材化粧シートおよび路面用蓋材化粧方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4515849A (en) * 1983-06-01 1985-05-07 Matsui Shikiso Chemical Co. Ltd. Transfer printing sheet, printing method and printed article

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58188687A (ja) * 1982-04-30 1983-11-04 Toppan Printing Co Ltd 化粧板の製造方法
JPH0478598A (ja) * 1990-07-20 1992-03-12 Dainippon Printing Co Ltd カセット用転写シートおよびカセット

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4515849A (en) * 1983-06-01 1985-05-07 Matsui Shikiso Chemical Co. Ltd. Transfer printing sheet, printing method and printed article

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO0007831A1 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003054840A2 (fr) * 2001-12-10 2003-07-03 Sales Activation Solutions Group Limited Ameliorations apportees a des affiches de plancher
WO2003054840A3 (fr) * 2001-12-10 2003-10-02 Floor Image Holdings Pty Ltd Ameliorations apportees a des affiches de plancher
GB2398917A (en) * 2001-12-10 2004-09-01 Sales Activation Solutions Gro Improvements to floor posters
GB2398917B (en) * 2001-12-10 2006-03-01 Sales Activation Solutions Gro Improvements to floor posters
CN1326099C (zh) * 2001-12-10 2007-07-11 销售活性溶液集团有限公司 对场地招贴的改进

Also Published As

Publication number Publication date
EP1024028A4 (fr) 2002-02-06
WO2000007831A1 (fr) 2000-02-17
AU8462698A (en) 2000-02-28
JP4218859B2 (ja) 2009-02-04

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