EP0953079B1 - Systemes de transfert a jet d'encre, leur procede de fabrication et leur utilisation dans un procede d'impression - Google Patents

Systemes de transfert a jet d'encre, leur procede de fabrication et leur utilisation dans un procede d'impression Download PDF

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Publication number
EP0953079B1
EP0953079B1 EP98900003A EP98900003A EP0953079B1 EP 0953079 B1 EP0953079 B1 EP 0953079B1 EP 98900003 A EP98900003 A EP 98900003A EP 98900003 A EP98900003 A EP 98900003A EP 0953079 B1 EP0953079 B1 EP 0953079B1
Authority
EP
European Patent Office
Prior art keywords
ink
transfer system
jet printable
hot
printable transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98900003A
Other languages
German (de)
English (en)
Other versions
EP0953079A1 (fr
Inventor
Ulf Bamberg
Peter Kummer
Ilona Stiburek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkwright Inc
Original Assignee
Arkwright Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkwright Inc filed Critical Arkwright Inc
Publication of EP0953079A1 publication Critical patent/EP0953079A1/fr
Application granted granted Critical
Publication of EP0953079B1 publication Critical patent/EP0953079B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254—Polymeric or resinous material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide

Definitions

  • the present invention relates to an ink jet transfer system or inkjet transfer printing according to the preamble of claim 1, and method according to independent claims 11 and 13 and Use according to claim 15 in the version for Contracting states DE, FR, GB and IT or procedures according to independent claims 12 and 14 and use according to claim 16 in the version for the contracting states AT, BE, CH, DK, ES, FI, GR, IE, LU, MC, NL, PT, SE.
  • Transfer prints enjoy a big one Popularity because of the application of any graphic Representations, patterns, images or typefaces especially on items of clothing such as T-shirts, Sweatshirts, shirts or other textile substrates such as enable, for example, mouse pads.
  • inkjet transfer systems inkjet transfer prints
  • a computer In a first step by the user of the transfer print using a computer generates the desired, electronically processed image, which from the computer to a suitable printer, for example an ink jet printer, which is again the desired image on the transfer system, printed out.
  • the transfer print produced in this way must have a quality have, which the further use for Printing on, for example, a textile substrate allowed.
  • a suitable transfer print the desired one graphic representation on the desired textile substrate applied for liability.
  • US 5,242,739 describes image-sensitive, heat-sensitive transfer paper which comprises the following components: (a) a flexible cellulosic, non-woven, tissue-like paper, which has an upper and a lower surface and (b) an image-receptive melt transfer film layer, which is on the top surface of the Sheet support is located, c) and, if applicable, a Hotmelt sulfur harsh.
  • the film layer is about 15 to 80% by weight from a film-forming binder and from about 85 to about 20% by weight of a powder thermoplastic polymer, the film-forming Binder and the thermoplastic polymer Has melting point of between about 65 ° C and 180 ° C.
  • US-5,501,902 represents a further development from US-5,242,739, which also consists of a two-layer system exists, but for improvement of the printed image is still an ink viscosity agent is included. Also in transfer printing is US-5,501,902 to improve ink absorption preferably another cationic, thermoplastic Polymer included.
  • pigments for the absorption of the ink dye are usually polyester in the prior art, Polyethylene wax, ethylene-vinyl acetate copolymers and as binders polyacrylates, styrene-vinyl acetate copolymers, Nitrile rubbers, polyvinyl chloride, polyvinyl acetate, Ethylene acrylate copolymers and melamine resins called.
  • Another transfer system is disclosed in EP-A-850,786. In this published publication, a hot melt transfer material with highly porous polyamide pigments is proposed for painting with colored pencils and water colors.
  • the inkjet transfer systems comprise a carrier material, a hotmelt layer applied to the carrier material and at least one ink receiving layer applied to the hot melt layer, wherein the at least one ink receiving layer a mixture of a highly porous pigment and of a binder and wherein the molecules of the highly porous pigments and optionally the binder and optionally the hot melt layer to form essentially chemical bonds with the dye molecules the ink are capable.
  • the conventional Inkjet transfer systems the corresponding Dyes after printing on the textile substrate, for example by ironing, mainly mechanically are bound
  • the dye molecules are the Ink according to the present invention by means of chemical Bonds to the molecules of the pigment and the Binder and optionally the hot melt. This is achieved according to the invention in that the Molecules of the pigment and optionally the binder and optionally the hot melt via reactive groups have which for the formation of chemical bonds with also reactive groups of the dye molecules Ink are capable.
  • the hot melt layer which is directly on is a waxy polymer, easy to melt and can therefore, for example by ironing together with the printed ink receiving layer transferred to the textile substrate in order to then peel off the backing. It is the Hot melt layer, which, thanks to its waxy properties, primarily strengthens the adhesion to the textile substrate.
  • the ink absorption layer (ink layer) is located on the hot melt layer and primarily includes a highly porous pigment and a binder.
  • the highly porous Pigment is used to initially absorb the ink mechanically when printing out the desired graphic representation, with maximum porosity being particularly high Absorbency guaranteed.
  • Binders are necessary around the highly porous pigments on the product surface to bind in order to process (print) of the inkjet transfer system.
  • the chemical bonds between the dye molecules the ink and the molecules of the pigment as well as the binder are among other things under supply trained by energy, for example when ironing on of the ink jet transfer system according to the invention the textile substrate.
  • acid dyes for example azo dyes according to formula I
  • azo dyes are usually used on the market.
  • the molecules of the ink dyes are predominantly in solution as anions and also have reactive groups which allow the formation of chemical bonds with the reactive groups of the pigment molecules and, if appropriate, of the binder molecules.
  • the reactive groups are usually one or more sulfonate groups or carboxylate groups per dye molecule.
  • poly [1,2-bis (aminomethylcyclohexyl) ethane adipic acid amide] of the formula (II) which, with its terminal amino groups, produces the chemical bonds according to the invention (suifonamide groups or acid amide groups) when reacted with the acid groups of an azo dye.
  • the ink receiving layer of the ink jet transfer system from a highly porous pigment and a binder, at least one of the two components, especially the one that is available in large quantities Pigment, has reactive amino groups that are used for training from chemical bonds to the dye molecules the ink liquid are capable.
  • the present invention comprises the ink-receiving layer a highly porous polyamide pigment and a binder consisting of a soluble polyamide, the terminal, free amino groups of the polyamide pigment and of the polyamide binder for fixing reactive Groups, for example sulfonate groups or carboxylate groups, the dye molecules are capable.
  • a chemical fixation of the dye molecules can be achieved.
  • the inkjet transfer system in addition to the inventive requirement of Ability to form chemical bonds between the dye molecules of the ink and the molecules of the pigment as well as the binder, a high absorbency or absorption capacity of ink to ensure a clear print image.
  • a pigment preferably a polyamide pigment, with high porosity.
  • the choice of the preferred polyamide pigment is extremely critical because it has been shown that about the degree of porosity of the polyamide pigment Ink absorption capacity of the inkjet transfer system is decisively influenced.
  • the polyamide pigments which are used for the inkjet transfer systems according to the present invention preferably have a spherical, for example a spherical, geometry and the highest possible inner surface.
  • the grain sizes of the polyamide pigments used according to the invention are in a range from approximately 5 ⁇ m and approximately 45 ⁇ m, a range from 5 to 20 ⁇ m being particularly preferred.
  • the inner surface of the highly porous pigment is at least about 15 m 2 / g, preferably it is between about 20-30 m 2 / g.
  • a highly porous polyamide pigment with an inner surface of at least about 15 m 2 / g and grain sizes of about 5 ⁇ m and about 45 ⁇ m is obtained by means of anionic polyaddition and a subsequent controlled precipitation process.
  • the polyamide pigments according to the invention are literally grown and the growth of the pigments is stopped when the desired grain size is reached. 85-95% of the polyamide pigment thus obtained have the desired shape and grain size, while only a maximum of 15% have a smaller or larger grain size.
  • the binder preferably also from a Polyamide.
  • the polyamide used as a binder is in its nature differs from the polyamide pigment in that when it is used as a solution and therefore does not have to meet any special formal requirements.
  • the usage of polyamide as a binder is therefore less critical. It just has to be in a suitable solvent, for example alcohol or an alcohol-water mixture, be soluble and preferably via free terminals Have amino groups, with the help of dye molecules, for example sulfone groups of azo dyes, or ester groups can be fixed.
  • the ratio of highly porous pigment and the binder in the ink-receiving layer of the inventive Inkjet transfer system is between about 5: 1 and 1: 1, preferably 3: 1 and 2: 1, and very particularly preferably 2.4: 1.
  • the hot melt layer in the inkjet transfer system is located directly on the removable carrier material and is used by the inkjet printer printed graphic representation on the textile substrate transferred to. This transfer is, for example by a cold trigger, i.e. by ironing, cooling and peeling off the carrier layer.
  • a cold trigger i.e. by ironing, cooling and peeling off the carrier layer.
  • the hot-melt layer is first ironed on Melt brought, which is then that of the inkjet printer ink-receiving layer printed on the transfer system transfers to the textile substrate. there become spaces between the pigment and binder particles filled up by the first melted hot melt, before the pigments are largely melted or melted.
  • the hot melt is in contrast to the highly porous Pigment and to the binder wax-like, i.e. he can do it easier be melted.
  • hot melts melt in a range of about 100-120 ° C, while the highly porous pigments preferably in a range of melt about 120-180 ° C, preferably 140-160 ° C.
  • the usual hot melt is, for example, an ethylene acrylic acid copolymer dispersion.
  • hot melts are particularly preferred, which in turn also via reactive groups for fixation of ink dye molecules. This can bind even more dye, which improves the washing properties, i.e. the wash resistance and color fastness the printed graphic representation is particularly high can be adjusted.
  • a hot melt is therefore preferred consisting of a polyethylene copolymer with a polyamide content used.
  • the one to be applied to the textile substrate graphic representation is initially based on the so obtained Inkjet transfer system via a common printer, for example an ink jet printer (ink jet plotter), printed mirror-inverted and then on the desired textile substrate, for example a t-shirt at a temperature of between about 150 and 220 ° C, preferably at 190 ° C for at least 10 seconds ironed.
  • the top layer is the backing material, which after applying the graphical representation and preferably stripped and discarded after cooling will (cold deduction).
  • the preferred carrier layer is a heat-resistant silicone paper is used.
  • the on printed graphics obtained in this way (cold print) Presentation is smooth and shiny.
  • a hot fume cupboard is preferred carried out to the washability, the breathability of the cold-drawn and sealed textile substrate to improve.
  • the hot deduction eliminates still an undesirable shine and prevents bleeding of the dyes during the washing process. Therefore becomes plain white paper or siliconized on one side Paper with the silicone side on the cold-stripped textile substrate with the graphic already printed Representation at a temperature at which the hot melt ironed and melted for about 10 seconds quickly pulled off.
  • the one that is printed in the cold trigger is printed Layer microscopically roughened and the textile fibers are made up of the waxy mix consisting of printed hot melt and ink absorption layer better penetrated, while after the cold deduction primarily only one film-like surface adhesion is achieved.
  • the hot melt layer applied to the carrier material on silicone paper with a layer thickness of 0.1 mm with an ethylene copolymer, which is related to polyamide cut from 60:40 to a layer thickness of 30 ⁇ m coated.
  • the ink-receiving layer is produced in parallel: an ethanol / water mixture in the ratio of 3: 1 is introduced and a soluble polymamide binder is dissolved therein with heating to 45 ° C.
  • the highly porous polyamide pigment "Orgasol 3501 EX D NAT1" with a particle size of 10 ⁇ m and an inner surface of about 25 m 2 / g pigment is then dispersed into the solution.
  • a for organic pigments sold by Coatex provided, dispersing additive with the product name COADIS 123K introduced and the dispersion stirred for 10 minutes at room temperature.
  • the desired slides can be used for the necessary needs are tailored.
  • the ink jet transfer system made in Example 1 is used to display a graph to be printed on a t-shirt. It is in first step the desired electronically processable and stored graphical representation from the computer reversed by means of an inkjet printer printed out the sheet, which in Example 1 as an inkjet transfer system was obtained.
  • the next step is now a normal one white sheet of paper applied to the print and again for 10 seconds at a temperature of about Ironed on at 190 ° C. Without letting it cool down the paper smoothly and quickly without tearing deducted. With the hot fume cupboard there is flexibility reinforced, better washability and full breathability as well as a comfortable grip.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)

Claims (16)

  1. Système de transfert imprimable par jet d'encre comprenant un matériau de support, une couche thermofusible, étant appliquée sur ledit matériau de support, et au moins une couche réceptrice d'encre, selon lequel la couche réceptrice d'encre, au nombre d'au moins un, contient un mélange d'un pigment fortement poreux ayant une surface d'au moins 15 m2/g et une granulométrie moyenne de 5-25 µm et un liant, selon lequel les molécules de pigment disposent de groupes amino qui, lorsqu'on les chauffe, sont capables de former des liaisons chimiques avec les molécules de colorant de l'encre.
  2. Système de transfert imprimable par jet d'encre selon la revendication 1, caractérisé en ce que les molécules du liant disposent par ailleurs de groupes amino qui sont capables de former des liaisons chimiques avec les molécules de colorant de l'encre.
  3. Système de transfert imprimable par jet d'encre selon les revendications 1 à 2, caractérisé en ce que les molécules thermofusibles disposent par ailleurs de groupes amino qui sont capables de former des liaisons chimiques avec les molécules de colorant de l'encre.
  4. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 3, caractérisé en ce que le pigment fortement poreux contient ou est constitué d'un pigment polyamide fortement poreux, et en ce que le liant contient ou est constitué d'un alcool ou d'un mélange d'alcool et de polyamide soluble dans l'eau et en ce que le thermofusible contient éventuellement ou est éventuellement constitué d'un polyamide.
  5. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 4, caractérisé en ce que le pigment fortement poreux a une surface de 20-30 m2/g.
  6. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 5, caractérisé en ce que le pigment fortement poreux a une granulométrie moyenne de 5-15 µm.
  7. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 6, caractérisé en ce que le rapport entre le pigment fortement poreux et le liant, sur une base pondérale, a une valeur comprise entre 5:1 et 1:1, de préférence 3:1 et 2:1 et en particulier de 2,4:1.
  8. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 7, caractérisé en ce que la couche thermofusible contient ou est constituée d'un mélange d'un ensemble comprenant un copolymère éthylène-acide acrylique et un polyamide comportant des groupes terminaux amino réactifs.
  9. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 8, caractérisé en ce que la couche de support est constituée d'un papier de séparation résistant à la chaleur à une température comprise entre 150°C et 220°C, de préférence de 190°C, pendant au moins 10 secondes, de préférence de papier siliconé.
  10. Système de transfert imprimable par jet d'encre selon la revendication 9, caractérisé en ce que la couche de support est constituée, seulement sur une face, sur la face thermofusible, de papier siliconé résistant à la chaleur.
  11. Système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 10, caractérisé en ce que, en outre, un additif dispersant pour pigments organiques est contenu dans la couche réceptrice d'encre.
  12. Procédé de préparation d'un système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 11, comprenant les étapes suivantes :
    a) application d'une couche thermofusible sur un matériau de support, en ajustant l'épaisseur à 30 à 40 µm, et
    b) application d'au moins une dispersion formant une couche réceptrice d'encre sur ladite couche thermofusible, de manière à obtenir une épaisseur totale de la couche réceptrice d'encre de 20-35 µm, et
    c) évaporation des solvants.
  13. Procédé selon la revendication 12, caractérisé en ce que l'on applique deux couches réceptrices d'encre.
  14. Procédé d'impression sur des substrats textiles, caractérisé en ce qu'une présentation graphique est imprimée à partir de l'ordinateur, via une table traçante, au système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 11, au moyen de la page inverse, puis est transférée au fer à repasser sur le substrat textile, selon lequel le matériau de support est retiré après le refroidissement.
  15. Procédé selon la revendication 14, caractérisé en ce que, en plus de l'impression à froid, une impression à chaud est réalisée, selon laquelle un papier blanc normal ou un papier ayant été siliconé sur une face, la face siliconée étant placée sur le substrat textile imprimé à froid, est repassé au fer et retiré sans refroidissement.
  16. Utilisation d'un système de transfert imprimable par jet d'encre selon l'une quelconque des revendications 1 à 11 pour imprimer avec une présentation graphique au moyen d'une table traçante à jet d'encre.
EP98900003A 1997-01-10 1998-01-06 Systemes de transfert a jet d'encre, leur procede de fabrication et leur utilisation dans un procede d'impression Expired - Lifetime EP0953079B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH4997 1997-01-10
CH4997 1997-01-10
PCT/IB1998/000004 WO1998030749A1 (fr) 1997-01-10 1998-01-06 Systemes de transfert a jet d'encre, leur procede de fabrication et leur utilisation dans un procede d'impression

Publications (2)

Publication Number Publication Date
EP0953079A1 EP0953079A1 (fr) 1999-11-03
EP0953079B1 true EP0953079B1 (fr) 2003-07-02

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EP98900003A Expired - Lifetime EP0953079B1 (fr) 1997-01-10 1998-01-06 Systemes de transfert a jet d'encre, leur procede de fabrication et leur utilisation dans un procede d'impression

Country Status (11)

Country Link
US (1) US6638604B1 (fr)
EP (1) EP0953079B1 (fr)
JP (1) JP2001508138A (fr)
AT (1) ATE244332T1 (fr)
AU (1) AU737516B2 (fr)
CA (1) CA2277232C (fr)
CZ (1) CZ239299A3 (fr)
DE (1) DE59808907D1 (fr)
HU (1) HUP0000831A3 (fr)
PL (1) PL334490A1 (fr)
WO (1) WO1998030749A1 (fr)

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HUP0000831A3 (en) 2001-10-29
JP2001508138A (ja) 2001-06-19
DE59808907D1 (de) 2003-08-07
AU737516B2 (en) 2001-08-23
US6638604B1 (en) 2003-10-28
HUP0000831A2 (hu) 2001-06-28
PL334490A1 (en) 2000-02-28
CA2277232A1 (fr) 1998-07-16
EP0953079A1 (fr) 1999-11-03
CZ239299A3 (cs) 1999-11-17
AU5407198A (en) 1998-08-03
CA2277232C (fr) 2005-11-01
WO1998030749A1 (fr) 1998-07-16
ATE244332T1 (de) 2003-07-15

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