EP1226958A1 - Matériau récepteur d'images ayant une couche adhésive, méthode pour sa fabrication, et son utilisation - Google Patents

Matériau récepteur d'images ayant une couche adhésive, méthode pour sa fabrication, et son utilisation Download PDF

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Publication number
EP1226958A1
EP1226958A1 EP01101603A EP01101603A EP1226958A1 EP 1226958 A1 EP1226958 A1 EP 1226958A1 EP 01101603 A EP01101603 A EP 01101603A EP 01101603 A EP01101603 A EP 01101603A EP 1226958 A1 EP1226958 A1 EP 1226958A1
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EP
European Patent Office
Prior art keywords
layer
image recording
recording system
ink
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01101603A
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German (de)
English (en)
Inventor
Toni Bunschi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celfa AG
Original Assignee
Celfa AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celfa AG filed Critical Celfa AG
Priority to EP01101603A priority Critical patent/EP1226958A1/fr
Publication of EP1226958A1 publication Critical patent/EP1226958A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays

Definitions

  • the present invention relates to a material hereinafter referred to as the image recording system, the especially by means of transfer procedures.
  • transfer technologies for digital data, especially pictures and Texts such as laser lettering and especially inkjet printers, is inscribable and printable.
  • imaging systems can either be firmly attached to a carrier available or for transfer to substrates, especially dark textile substrates. Imaging systems, which are suitable for transfer to substrates are referred to below as transfer systems.
  • Transfer procedures or transfer technologies for digital data are subsequently called digital Image transfer process or digital image transfer technologies designated.
  • Imaging systems using transfer processes can be printed or labeled for digital data, are already known.
  • imaging systems of the State of the art include a carrier, optionally can be provided with a layer which the Adhesion to a layer applied over it is reduced, an ink receptive layer and, if applicable, one arranged between the support and the ink-receiving layer, effecting the separation from the carrier or at least promoting layer.
  • a carrier optionally can be provided with a layer which the Adhesion to a layer applied over it is reduced, an ink receptive layer and, if applicable, one arranged between the support and the ink-receiving layer, effecting the separation from the carrier or at least promoting layer.
  • Such systems are described for example in US 5 501 901, US 5 242 739, EP-A-0 825 031, WO 98/30749 and EP-A-0 850 786.
  • Such prior art systems will be applied in such a way that they are on the ink-receptive layer side a substrate, especially a textile substrate, e.g. put on a t-shirt and warm it up with an iron be that between the substrate and the ink receptive layer better liability is developed than this between the ink-receiving layer and the carrier, such that that the carrier after the heat treatment and optionally at least partial cooling, removed by stripping can be.
  • the aim of the present invention was therefore to provide an imaging system that a improved color fastness, even after repeated washing, guaranteed and especially on dark substrates, gives good images, especially dark textile substrates.
  • This goal was achieved through the provision of an image recording system that a carrier, at least one ink receptive layer and at least one Includes adhesive layer, the ink-receiving layer a thermoplastic binder and one under the influence of heat reactive polymer system and / or a thermoplastic, crosslinking under the influence of heat Binder and / or a thermoplastic system and Contains nanoparticles.
  • Figure 1 shows the structure of an inventive Imaging system with an adhesive layer, in particular an elastic adhesive layer and a removable carrier.
  • Figure 2 shows the structure of an inventive Image acquisition system with two layers of adhesion and removable carrier.
  • FIG. 3 shows an embodiment of the image recording system with a non-elastic resp. Not flexible intermediate layer and a non-removable Carrier.
  • the penetration of the ink receptive layer 1 is greatly reduced in the substrate is between the Carrier 3 and the ink-receiving layer 1 at least one another layer that improves adhesion (adhesion layer) 2, 5 available.
  • the adhesive layer is common an intermediate layer 5 and / or an elastic Layer 2.
  • an elastic intermediate layer 2 proved to be extremely advantageous because one such a layer is the transferred ink receiving layer 1 always back to the original dimensions brings and thus the appearance resp. the becoming visible unwanted cracks reduced or even completely prevented.
  • the ink receptive layer 1 and / or at least one, preferably all, adhesion layers 2, 5 to pigment are preferred 1 as well as the adhesive layers 2, 5 pigmented, to keep the pigment content in a range in which he does not have the desired properties of the layer impaired.
  • pigments e.g. various colors, fluorescent Pigments etc. are white pigments, phosphorescent Pigments and effect pigments (e.g. mica pigments) prefers.
  • the ink receiving layer 1 can be a homogeneous Layer or from layers lying on top of each other be built up, possibly only a sub-layer Contains pigment, or being different sub-layers contain various pigments, e.g. one closer to the carrier partial layer lying one white pigment and another a sublayer removed from the support is a phosphorescent Pigment.
  • the ink receptive layer comprises 1 in addition to a thermoplastic binder a reactive polymer system that can be activated under the influence of heat.
  • a thermoplastic binder in Combination with an activatable reactive polymer system can also be a thermoplastic under the influence of heat crosslinkable binder can be used.
  • Reactive polymer systems respectively.
  • thermoplastic crosslinkable under the influence of heat Binder resp. Binder systems are known to the person skilled in the art and include prepolymers and hardeners, wherein the hardener and / or any catalysts present can be thermally activated. Because the imaging systems of the present invention usually are to be applicable without safety precautions are reactive polymer systems preferred that are not harmful to health Fabrics and preferably none uncomfortable smelling substances contain resp. in the reaction release.
  • Suitable systems include aminoplasts, in particular Melamine resins, such as melamine-formaldehyde resins, respectively.
  • modified melamine resins such as etherified melamine resins, Melamine-urea-formaldehyde resins resp. Melamine-phenol-formaldehyde resins. All of these resins have the advantage in the hardened state very stable and such translucent to be good image quality available is.
  • their reaction by acid e.g. diluted organic or inorganic acids or salts such acids, which become a volatile base only when heated (e.g. ammonia) split off, accelerated and the reaction can be controlled by the pH in this way.
  • preferred Acids are p-toluenesulfonic acid, acetic acid and hydrochloric acid.
  • thermoplastic binders are known from the prior art (see US 5 501 901, US 5,242,739, EP-A-0 825 031, WO 98/30749 and EP-A-0 850 786).
  • Preferred binders, especially for Transfer systems include polyvinyl alcohols, polyvinyl acetates, Polyvinyl pyrrolidones, polyurethanes and specially preferably polyamides, for transfer to e.g. Cotton T-Shirts especially thermoplastics with melting point ⁇ 200 ° C, especially ⁇ 140 ° C.
  • thermoplastic crosslinking binder the above-mentioned come into question, with a corresponding one System one or more under the influence of heat for networking includes leading components.
  • the ink-receiving layer comprises porous solid particles in a binder.
  • porous particles are, for example, ceramic parts such as zeolites, silicates and aluminum hydroxides, or plastic particles, such particles being able to be obtained directly by a special production process or by subsequent treatment (mechanical or chemical) or agglomeration.
  • Preferred porous particles are porous, solid thermoplastics.
  • Such particles preferably have a specific surface area of> 6 m 2 / g, in particular 20 20 m 2 / g, a particle size of 0.1-40 ⁇ m, in particular 5-15 ⁇ m, and a melting temperature of ⁇ 200 ° C.
  • Thermoplastics such as the products known under the name Orgasol, in particular Orgasol® 3501 from, for example, Elf Atochem, Pouteaux, France, with a particle diameter of approximately 10 ⁇ m and a surface area of approximately 25 m 2 / g are particularly preferred.
  • Ceramic particles used like Zeolite these are preferably in combination with porous solid thermoplastics such as Orgasol® 3501.
  • the ink-receiving layer contains nanoparticles in addition to or as an alternative to reactive polymer components.
  • Preferred nanoparticles have a specific surface area of 50 to 300 m 2 / g and a dispersed particle size of 10 to 300 nm.
  • Aluminum hydroxide for example Dispersal from Condea Chemie GmbH, Fritz-Staigerstrasse 15, D-25541 Brünsbüttel
  • silicates e.g. CAB-O-Sperse from Cabot Corporation, Cab-O-Sil Division, 700 EUS Highway 36, Tuscola, IL 61953-96-43
  • Such nanoparticles serve on the one hand as a pigment, on the other hand at the same time as porous particles for ink absorption. Surprisingly, it has been shown that such small particles remain in the layer even after repeated washing.
  • porous particles can either only in one partial layer, preferably the sublayer without phosphorescent Pigment, or present in both sub-layers his.
  • the presence is for quick color absorption porous particles in the layer facing away from the support, the ink receptive layer 1, preferred.
  • thermoplastic binder are porous.
  • a process for making a porous Binder layer is e.g. known from EP 0 850 786.
  • the ink-receiving layer 1 usually has a proportion of thermoplastic binder of 5 to 40% by weight, preferably approximately 20% by weight, reactive polymer system of 8 to 20% by weight, preferably approximately 15% by weight, of porous particles from 5 to 80% by weight, preferably approximately 50% by weight, pigments from 5 to 80% by weight, in particular white pigment (TiO 2 ) in quantities of 5 to 15% by weight, preferably approximately 10% by weight .-%, and / or phosphorescent pigment in amounts of 5 to 80 wt .-%, preferably about 65 wt .-%, based on the dried ink-receiving layer.
  • thermoplastic binder of 5 to 40% by weight, preferably approximately 20% by weight, reactive polymer system of 8 to 20% by weight, preferably approximately 15% by weight, of porous particles from 5 to 80% by weight, preferably approximately 50% by weight, pigments from 5 to 80% by weight, in particular white pigment (TiO 2 ) in quantities of 5 to 15% by weight, preferably approximately 10% by weight
  • a dispersing additive in an amount of about 0.2% by weight, for example "Coadis 123 K”. Manufacturer Coatex, 35, rue Ampere-BP 8-ZI Lyon-Nord 69727 Genay Cedex-France.
  • crosslinkable Systems When using a thermoplastic, crosslinkable Systems is usually in quantities of 10 to 60 wt .-% present, preferably in amounts of approx. 30 to 40% by weight.
  • a layer containing nanoparticles exhibits these usually in amounts of 40 to 80 wt .-%, preferably in amounts of approximately 60% by weight and the binder in amounts of 15 to 35% by weight, preferably in Amounts of approx. 25% by weight.
  • other components can be present like porous particles, e.g. Orgasol 3501 in amounts of 5 to 25% by weight, preferably in an amount of about 15% by weight.
  • the ink-receiving layer is applied in amounts of (in the dried state) 5 to 80 g / m 2 on the support provided with an adhesive layer.
  • the adhesion layer 2, 5 has a polymer matrix on, especially an elastic matrix. Suitable are all materials that have adequate adhesion between Ensure substrate and ink receptive layer and if necessary, additionally the desired elasticity respectively. Have flexibility. Such materials are e.g. Polyurethanes, such as polyester polyurethanes with a deep Melting range and high "Melt Flow Index".
  • the intermediate layer is preferably pigmented.
  • An elastic adhesive layer usually has a thickness of 20-100 ⁇ m, in particular about 50 ⁇ m.
  • the ink absorption layer and / or the intermediate layer contain various, identical or different pigments are white pigments and phosphorescent pigments and optionally effect pigments are highly preferred.
  • Suitable white pigments are widely used.
  • the preferred white pigment is titanium dioxide, particularly preferably TiO 2 with high relative scattering power, such as Kronos 1002, available from Kronos, International Inc., D-51373 Leverkusen.
  • the materials according to the invention include Transfer systems, e.g. for the transmission of images, i.e. at least the ink receptive layer, on a substrate.
  • Such substrates are e.g. Fabrics, knitted fabrics, fleeces, especially textiles like T-shirts, but also others, especially "porous" substrates such as leather, wood etc., especially preferred dark substrates.
  • the preferred transfer layers include the materials according to the invention also "fixed" materials, i.e. Materials where the ink-receptive layer 1 remains on the carrier 3.
  • Fixed materials are relatively uncritical and can be a variety of different substrates , provided that their flexibility and the Liability of the ink absorption layer for the implementation of the Printing process is sufficient.
  • To increase liability can optionally be a surface treatment of the carrier or an adhesion promoter layer between the carrier and the ink receptive layer can be provided.
  • an intermediate layer in particular an elastic intermediate layer to apply, namely for example with a very flexible Carrier, such as a plastic or paper carrier, e.g. only bent when inserted into a holder and then stretched again. Due to the elastic intermediate layer any damage to the picture "healed" again by bending.
  • the ink absorption layer is also used for fixed materials 1 not further critical as long as it is sufficient Color recording, e.g. sufficient access to the porous solid particles, allowed and the ink after Warming well fixed.
  • the printed resp. labeled ink absorption layer by applying a later Cover, e.g. a film, against mechanical damage secure, e.g. when used as signs, such as floor labels, Valve or keyboard names etc.
  • a later Cover e.g. a film
  • the carrier 3 on the one facing away from the ink-receiving layer Side with an adhesive layer 7, z.
  • an adhesive layer to be provided with a removable, optionally printed protective layer 8, like one-sided siliconized paper against pollution can be protected.
  • transfer materials advance, with at least the ink receptive layer and an adhesive layer on a substrate, e.g. a textile, is transmitted.
  • Such transfer materials must be in addition to the sufficient flexibility and sufficient liability the ink receptive layer 1 and the adhesive layer 2, 5 the carrier layer 3 during printing, respectively. inscribing also have good transfer properties, i.e. e.g. good strippability of the backing layer 3 before heat treatment.
  • This separation of carrier and ink-receptive layer can e.g. through a release layer 4 between Backing layer 3 and adhesive layer 2, 5, e.g. a Silicone layer, caused or at least favored.
  • This release layer can also be a pretreatment of the wearer.
  • the layers removed from the support become then with the one originally on the carrier or the release layer adhering layer applied to a substrate and afterwards, if necessary after covering the Surface (ink absorption layer) to protect against contamination by e.g. Iron on or hot laminate a substrate, e.g. a textile, fixed.
  • a carrier material 3, 4, 6 preferred for the transfer system is a siliconized paper on one side with a basis weight in the range of 50-150 g / m 2 , which can be provided with a print 6 on the non-siliconized side.
  • a pigmented ink-receiving layer 1 can be produced simply by mixing powdered pigment with the other components of the ink-receiving layer or a partial layer of the ink-receiving layer 1 and solvent and the resulting mixture on an optionally pretreated or. pre-coated carrier is applied by conventional methods.
  • Preferred solvents are water and alcohols, especially C 1 -C 3 alcohols.
  • Example 1 Preparation of a Binder Solution for the Production of an Intake Layer (Reactive)
  • Polyamide e.g. Elvamide 8023 (available from Du Pont de Nemours, International SA, 2, Chemin du Pavillon, CH-1218 Le Grand-Saconnex / Geneva), is dissolved in a mixture of water / methanol and microporous pigments (e.g. polyamide pigments such as Orgasol , with a grain size of approximately 10 ⁇ m and a specific surface area of approximately 25 m 2 / g) are dispersed therein together with typical dispersing additives.
  • a white pigment e.g. white pigment with a high relative scattering power of approx. 70, preferably titanium dioxide
  • a phosphorescent pigment e.g. a non-radioactive, phosphorescent pigment in powder form, e.g. Luminova G 300
  • a white pigment e.g. white pigment with a high relative scattering power of approx. 70, preferably titanium dioxide
  • a phosphorescent pigment e.g. a non-radioactive,
  • a reactive polymer system e.g. based on a melamine resin such as Maprenal MF 927) and a catalyst (e.g. an acid such as p-Toluenesulfonic acid (PTS)) added with stirring.
  • a catalyst e.g. an acid such as p-Toluenesulfonic acid (PTS)
  • the concentration of the polyamide in the solution should be 10 to 90 wt .-% and the mixing ratio Water / alcohol is adjusted so that the Spreading the binder solution on a carrier and then drying at approx. 60 to 110 ° C a porous Layer arises.
  • Aluminum hydroxide eg Dispersal 14/2 with a specific surface area of approx. 170 m 2 / g and a particle size of 13 nm
  • microporous pigments eg Orgasol
  • a binder for example polyvinyl acetate such as Mowilite DM from Hoechst Aktiengesellschaft, Kennedyallee 76, D 6000 Frankfurt (Main) 70
  • Mowilite DM from Hoechst Aktiengesellschaft, Kennedyallee 76, D 6000 Frankfurt (Main) 70
  • an additional White pigment or a phosphorescent pigment added and dispersed again for perfect wetting to obtain the pigments with the binder.
  • the solids concentration of the pigments (including the nanoparticle) to the binder approx. 2: 1.
  • thermoplastic, opaque layer with a basis weight of approx. 50 g / m 2 is applied by means of an extrusion process or an ethylene-acrylic acid copolymer, for example an Enorex VN, by means of wet coating 375 (trade name of Collano Ebnöther AG, Rank industrial area, in CH-6203 Sempach station), with a solids content of approx. 40% by weight, such that the dry application is approx. 30 g / m 2 .
  • the coating solution prepared for the ink absorption layer (see Examples 1 and 2).
  • the viscosity is adjusted by dilution with water / alcohol so that the formulation, for example using a reverse roll coating process, is applied to the carrier film provided with an elastic layer (see Example 3 or available from Sarna Xirio AG, CH-3185 in Schmitten, under the trade name " PURO-X ”) and can be dried at a temperature of 60 to 110 ° C.
  • the dry application is approx. 30 g / m 2 .
  • Such a layer has a good mechanical Stability and porosity and can be done with digital Image transfer processes, such as laser marking and especially ink-jet printers but also using CLP (Color Laser Printer) or CLC (Color Laser Copier), good print and label, but it can also be used with usual Paint aids such as aqueous and solvent-based Similar to crayons, water colors and wax crayons are painted like ordinary paper, and it leaves deal with common printing processes such as offset printing or print on screen printing.
  • digital Image transfer processes such as laser marking and especially ink-jet printers but also using CLP (Color Laser Printer) or CLC (Color Laser Copier), good print and label, but it can also be used with usual Paint aids such as aqueous and solvent-based Similar to crayons, water colors and wax crayons are painted like ordinary paper, and it leaves deal with common printing processes such as offset printing or print on screen printing.
  • the reactive hot melt material is removed from the wearer, placed on the T-shirt and positioned at the desired location.
  • the one from the substrate averted printed layer can e.g. by hanging up a non-stick film, such as a siliconized one Paper to be protected against pollution, before ironing under strong pressure is fixed on the substrate. Then several can Washing processes in a washing machine with common Detergents are carried out. The pigment and the Colors showed good fastness to washing.
  • the transfer can also be carried out using a hot laminator on e.g. a large-area textile, e.g. on Banner, done.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
EP01101603A 2001-01-25 2001-01-25 Matériau récepteur d'images ayant une couche adhésive, méthode pour sa fabrication, et son utilisation Withdrawn EP1226958A1 (fr)

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EP01101603A EP1226958A1 (fr) 2001-01-25 2001-01-25 Matériau récepteur d'images ayant une couche adhésive, méthode pour sa fabrication, et son utilisation

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EP01101603A EP1226958A1 (fr) 2001-01-25 2001-01-25 Matériau récepteur d'images ayant une couche adhésive, méthode pour sa fabrication, et son utilisation

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EP1356953A1 (fr) * 2002-04-24 2003-10-29 Daicel Chemical Industries, Ltd. Feuilles de transfert
WO2005087492A1 (fr) * 2004-02-13 2005-09-22 The Procter & Gamble Company Articles resistants a la decoloration et permettant d'appliquer une couleur sur des surfaces et procedes de reduction de la decoloration d'articles pour l'application de couleurs sur des surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7722938B2 (en) 2003-02-14 2010-05-25 The Procter & Gamble Company Dry paint transfer laminate
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7842363B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
CN102114737A (zh) * 2009-12-31 2011-07-06 鸿富锦精密工业（深圳）有限公司 转印膜及转印膜的制造方法
CN105603778A (zh) * 2016-02-19 2016-05-25 太仓市鑫泰针织有限公司 一种真丝面料刺绣用活性墨水
CN112176747A (zh) * 2020-09-23 2021-01-05 江西瑞臻科技有限公司 一种用于pe新型塑料制品外部上色的生产工艺

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EP0805049A1 (fr) * 1996-04-30 1997-11-05 Canon Kabushiki Kaisha Matériau de transfert d'image pour l'impression au jet d'encre, procédé d'impression par transfert utilisant ce matériau, et tissu imprimé par ce procédé
JPH10151845A (ja) * 1996-11-22 1998-06-09 Toyobo Co Ltd 画像記録体および電飾用画像記録体
EP0933226A2 (fr) * 1998-01-28 1999-08-04 Canon Kabushiki Kaisha Matériau pour le transfert thermique et imprimable par jet d'encre, procédé pour le transfert d'images, et tissu ainsi imprimé
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EP1031432A1 (fr) * 1998-09-04 2000-08-30 Somar Corporation Feuille d'enregistrement phosphorescente, et panneau

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JPH01258994A (ja) * 1988-04-09 1989-10-16 Ozu:Kk 昇華染料による転写方法とその転写方法に用いる転写用基材
EP0805049A1 (fr) * 1996-04-30 1997-11-05 Canon Kabushiki Kaisha Matériau de transfert d'image pour l'impression au jet d'encre, procédé d'impression par transfert utilisant ce matériau, et tissu imprimé par ce procédé
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EP0933226A2 (fr) * 1998-01-28 1999-08-04 Canon Kabushiki Kaisha Matériau pour le transfert thermique et imprimable par jet d'encre, procédé pour le transfert d'images, et tissu ainsi imprimé
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US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
EP1356953A1 (fr) * 2002-04-24 2003-10-29 Daicel Chemical Industries, Ltd. Feuilles de transfert
US7722938B2 (en) 2003-02-14 2010-05-25 The Procter & Gamble Company Dry paint transfer laminate
US7807246B2 (en) 2003-02-14 2010-10-05 The Procter & Gamble Company Dry paint transfer laminate
US7842363B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7842364B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7846522B2 (en) 2003-02-14 2010-12-07 The Procter & Gamble Company Discoloration-resistant articles for applying color on surfaces and methods of reducing discoloration in articles for applying color on surfaces
US7905981B2 (en) 2003-02-14 2011-03-15 The Procter & Gamble Company Method of making a dry paint transfer laminate
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
WO2005087492A1 (fr) * 2004-02-13 2005-09-22 The Procter & Gamble Company Articles resistants a la decoloration et permettant d'appliquer une couleur sur des surfaces et procedes de reduction de la decoloration d'articles pour l'application de couleurs sur des surfaces
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CN105603778A (zh) * 2016-02-19 2016-05-25 太仓市鑫泰针织有限公司 一种真丝面料刺绣用活性墨水
CN112176747A (zh) * 2020-09-23 2021-01-05 江西瑞臻科技有限公司 一种用于pe新型塑料制品外部上色的生产工艺

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