EP0878319B1 - Matériau d'enregistrement pour l'impression par jet d'encre - Google Patents

Matériau d'enregistrement pour l'impression par jet d'encre Download PDF

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Publication number
EP0878319B1
EP0878319B1 EP98107696A EP98107696A EP0878319B1 EP 0878319 B1 EP0878319 B1 EP 0878319B1 EP 98107696 A EP98107696 A EP 98107696A EP 98107696 A EP98107696 A EP 98107696A EP 0878319 B1 EP0878319 B1 EP 0878319B1
Authority
EP
European Patent Office
Prior art keywords
ink
recording material
receiving layer
weight
material according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98107696A
Other languages
German (de)
English (en)
Other versions
EP0878319A2 (fr
EP0878319A3 (fr
Inventor
Jürgen Dipl.-Ing. Graumann
Dieter Dr. Dipl.-Chem. Becker
Horst Westfal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP0878319A2 publication Critical patent/EP0878319A2/fr
Publication of EP0878319A3 publication Critical patent/EP0878319A3/fr
Application granted granted Critical
Publication of EP0878319B1 publication Critical patent/EP0878319B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/506—Intermediate layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the invention relates to a recording material for the Ink jet printing process (ink jet process).
  • the ink jet process is one of the electronic ones Printing process. Here it is possible to add pictures, texts and Compose graphics on the computer and as Print out the screen hardcopy directly.
  • droplets of a recording liquid are applied to the surface of the carrier material using various techniques.
  • a permanent stream of droplets is driven out of the nozzle under high pressure.
  • the drops that are not required for image formation are fed back into the ink reservoir by various principles.
  • the ink jet recording process is used to manufacture Color graphics, full color copies and also for text prints used, so it covers a very wide field of application.
  • the recording material is different Requirements such as print gloss, color gradients (bleed), Color density, drying behavior, agitation (mottle), Clapping and shine.
  • the receiving material generally consists of a Carrier material, an ink receiving layer and optionally further auxiliary layers.
  • JP 01-009776 and JP 01-075281 describe one Ink receiving layer with good contrast, good light and Water resistance consisting of a copolymer and a Binder / pigment mixture exists.
  • the copolymer settles together from a dimethyldiallylammonium chloride and a Acrylamide.
  • a pigment content Loss of gloss is not limited.
  • EP 0 627 324 describes a recording material for the Inkjet printing process, in which in the receiving layer Terpolymer of a quaternary ammonium compound used becomes.
  • Terpolymer of a quaternary ammonium compound used becomes.
  • an epoxy or a triazine is considered Crosslinking agent added. This will cause the Color dots and an unevenness of color and Density prevented.
  • the disadvantage is an extension of the Drying time and poorer color absorption. By Polymerizing the quaternary ammonium compound into the Terpolymer reduces the ability to control the Optimization of color fixation.
  • the object of the invention is to provide a recording material for to provide the ink jet printing process that is due to high color density, high gloss, good Drying properties, high color brilliance and low Color gradients with low weight of the Distinguished reception layer.
  • a recording material which a support and an ink-receiving layer disposed thereon contains an uncrosslinked copolymer consisting of a quaternary ammonium compound and vinyl pyrrolidone, one Polyvinyl alcohol and a Contains aminomethacrylate copolymer.
  • PVP Polyvinylpyrrolidone
  • the carrier material varies in gloss values depending on Manufacturing may differ, in some cases necessary to add pigments to the ink-receiving layer, the one Allow adjustment of the gloss.
  • the shine pigments such as calcium carbonate, titanium dioxide, clay, Silicon dioxide, bentonite, aluminum oxide or boehmite added become.
  • the amount of pigments in the ink-receiving layer can be 0 and 5% by weight, based on the dried layer be.
  • the proportion by weight of the copolymer in the ink-receiving layer can be 5 to 80% by weight and, in a more preferred form, 15 to 50% by weight.
  • the proportion of the hydroxy-functional polymer containing amino groups is preferably 5 to 75% by weight and in a more preferred embodiment 15 to 50% by weight.
  • the proportion of the polyvinyl alcohol can be 5 to 80% by weight and, according to an even more preferred embodiment, 30 to 60% by weight.
  • the coating weight of the dried receiving layer may be 2 to 15 g / m 2 and preferably 4 to 10 g / m 2, respectively.
  • the aqueous coating composition can vary in the following amounts by weight: % By weight Vinyl pyrrolidone / methacrylamidopropyl trimethyl ammonium chloride copolymer 2.2 - 60.0 Aminomethacrylate 2.2 - 57.0 Polyvinyl alcohol 3.0 - 80.0 Auxiliaries 0.0 - 20.0 water Rest up to 100.0
  • Ink receiving layer can be used with all common and dosing processes, such as roller application, engraving or nipping processes and air brushes or roller doctor dosage applied become.
  • an intermediate layer is additionally applied between the carrier material and the receiving layer.
  • the intermediate layer preferably contains polyvinyl alcohol; but compounds such as polyvinylpyrrolidone or polyvinyl acetate or mixtures thereof are also suitable.
  • This intermediate layer achieves a high print gloss, since the receiving layer on papers without synthetic resin coating is prevented from sinking. Since the surface of paper always has a certain porosity, parts of the coatings are absorbed by the paper.
  • the print gloss is visible on the printed paper, especially in dark areas and should be uniform over the entire area. High print gloss manifests itself in a smooth, shiny layer.
  • this intermediate layer improves the adhesion of the receiving layer to the carrier material, preventing the receiving layer from being pushed open in the printer.
  • the application weight of the dried intermediate layer can be 0.1 to 4.0 g / m 2 , preferably 0.5 to 2.0 g / m 2 .
  • Suitable carrier materials are preferably papers which are coated on both sides with synthetic resin and so-called cast-coated papers. As particularly important has a very smooth, even surface proven.
  • the surface roughness (Ra) according to DIN 4768 may a value of 0.8 ⁇ m with a measuring distance of 5mm not exceed.
  • the papers coated on both sides with synthetic resin have a basis weight of 50 to 250 g / m 2 .
  • Polyolefins or polyester, for example, are used as the synthetic resin.
  • the application quantity of the synthetic resin coating is at least 5 g / m 2 .
  • Pigments, dyes and other auxiliaries can also be contained in this coating.
  • Cast-coated paper has also proven to be particularly suitable. These papers are coated in the paper machine with a thin coating of binder and pigment and pressed under pressure against a hot high-gloss drum. This gives papers with a good, glossy surface that do not show the disadvantages of highly calendered papers. Compared to synthetic resin coated papers, this has the advantage of very low drying times.
  • the basis weight for this paper is between 50 g / m 2 and 270 g / m 2 .
  • the gloss of the paper with an intermediate layer measured at 60 °, must not be less than 80%, since the gloss of the base paper, due to the low application weight of the ink-receiving layer, has a strong effect on the finished recording material.
  • the print gloss must be at least 65% for papers without an intermediate layer and at least 75% with an intermediate layer.
  • An uncoated material is also suitable as a carrier material or coated base paper.
  • composition B1 B2 B3 B4 B5 B6 Polyvinyl alcohol 15% 26.23 30.77 22.86 57.14 38.4 28.2 VP / MAPTAC copolymer 20% 14.76 11.54 17.15 7.14 11.5 10.1 Aminomethacrylate copolymer 20% 14.75 23.08 8.57 21.42 11.1 9.7 Alumina hydrate hydrate 15% 3.9 16.2 water 44.26 34.61 51.42 14.3 35.1 35.8 Order g / m 2 6.9 10.8 5.2 8.5 7.6 7.8 Solid% 9.8 11.5 8.6 14.3 10.9 10.6
  • the back of the base paper was coated with an LDPE (low density polyethylene).
  • the application weight was 22 g / m 2 .
  • the front was coated with an LDPE with a titanium dioxide content of 10% by weight.
  • the application weight was 19 g / m2.
  • Example 7 a commercially available cast-coated paper was used instead of the polyolefin-coated base paper.
  • the total weight was 215 g / m 2 .
  • Commercial papers are the Cromolux papers from Zanders or the Lustrulux papers from Tullis Russell.
  • the coating composition of Example 1 was used for B7.
  • the coating composition of Example 2 was used for B8.
  • the coating composition of Example 3 was used for B9.
  • the coating composition of Example 4 was used for B10.
  • the coating composition of Example 5 was used for B11.
  • the coating composition of Example 6 was used for B12.
  • a high molecular weight polyvinyl alcohol (Mowiol® 96-98) was applied as an intermediate layer with an application weight of 0.8 g / m 2 .
  • polyvinylpyrrolidone (Luviskol® K90) with an application weight of 1.7 g / m 2 was chosen as the intermediate layer.
  • the recording material was used with a commercially available Ink-jet color printers from Hewlett Packard, Novajet, and the a test pattern is printed on the corresponding inks.
  • This Test image was checked for color density, bleeding, mottle, Color fixation and clapping checked. The results of this Tests are summarized in Tables 3 and 4.
  • the color essence was measured using an X-Rite Desitometer Type 428 measured in the colors cyan, magenta, yellow and black.
  • the print image was checked after 24 Hours of storage at 23 ° C rubbed with a white cloth.
  • the transfer of the ink onto the rag was evaluated for the colors cyan, magenta and yellow.
  • the transfer of black was rated separately (+ no transfer, - transfer).
  • the printed image was after 5 minutes and after 15 minutes covered with a PTS base paper and loaded with a 10 kg weight for 24 hours. Subsequently became the clapping of the ink from the ink receiving layer on the PTS paper visually with the grades 1 to 6 (no Clapping to very heavy clapping).
  • the gloss was measured using a Dr. Lange GmbH according to DIN 67530, measured at an angle of 60 °. The measurement was carried out on the unprinted receiving material.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
  • Ink Jet (AREA)
  • Duplication Or Marking (AREA)

Claims (9)

  1. Matériau d'impression pour impression par jet d'encre, consistant en un support et une couche de fixation des encres disposée sur celui-ci, caractérisé en ce que la couche de fixation des encres contient un copolymère non réticulé, consistant en un composé ammonium quaternaire et une vinylpyrrolidone, un polyvinylalcool et un copolymère aminométhacrylate.
  2. Matériau d'impression suivant la revendication 1, caractérisé en ce que la couche de fixation des encres contient un pigment.
  3. Matériau d'impression suivant les revendications 1 et 2, caractérisé en ce que la quantité de copolymère dans la couche de fixation des encres s'élève de 15 à 50% en poids.
  4. Matériau d'impression suivant les revendications 1 à 3, caractérisé en ce que la quantité d'aminométhacrylate dans la couche de fixation des encres s'élève de 15 à 50% en poids.
  5. Matériau d'impression suivant les revendications 1 à 3, caractérisé en ce que la quantité de polyvinylalcool dans la couche de fixation des encres s'élève de 30 à 60% en poids.
  6. Matériau d'impression suivant les revendications 1 à 5, caractérisé en ce qu'entre le matériau support et la couche de fixation des encres, on dispose une couche intermédiaire.
  7. Matériau d'impression suivant les revendications 1 à 6, caractérisé en ce que la couche intermédiaire contient un polyvinylalcool, une polyvinylpyrrolidone, un poly(acétate de vinyle) ou leurs mélanges.
  8. Matériau d'impression suivant les revendications 1 à 7, caractérisé en ce que le matériau support est un papier revêtu d'une résine synthétique.
  9. Matériau d'impression suivant les revendications 1 à 8, caractérisé en ce que le matériau support est un papier couché par coulée.
EP98107696A 1997-05-17 1998-04-28 Matériau d'enregistrement pour l'impression par jet d'encre Expired - Lifetime EP0878319B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19720833 1997-05-17
DE19720833A DE19720833C1 (de) 1997-05-17 1997-05-17 Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren

Publications (3)

Publication Number Publication Date
EP0878319A2 EP0878319A2 (fr) 1998-11-18
EP0878319A3 EP0878319A3 (fr) 1998-12-02
EP0878319B1 true EP0878319B1 (fr) 2001-10-24

Family

ID=7829835

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98107696A Expired - Lifetime EP0878319B1 (fr) 1997-05-17 1998-04-28 Matériau d'enregistrement pour l'impression par jet d'encre

Country Status (6)

Country Link
EP (1) EP0878319B1 (fr)
AT (1) ATE207417T1 (fr)
DE (2) DE19720833C1 (fr)
DK (1) DK0878319T3 (fr)
ES (1) ES2166576T3 (fr)
PT (1) PT878319E (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6632510B1 (en) 1997-07-14 2003-10-14 3M Innovative Properties Company Microporous inkjet receptors containing both a pigment management system and a fluid management system
US6537650B1 (en) 1998-06-19 2003-03-25 3M Innovative Properties Company Inkjet receptor medium having ink migration inhibitor and method of making and using same
US6383612B1 (en) 1998-06-19 2002-05-07 3M Innovative Properties Company Ink-drying agents for inkjet receptor media
US6703112B1 (en) 1998-06-19 2004-03-09 3M Innovative Properties Company Organometallic salts for inkjet receptor media
EP1152902B1 (fr) 1999-02-12 2003-12-17 3M Innovative Properties Company Support recepteur d'image et procede de production et d'utilisation de ce dernier
ES2282102T3 (es) * 1999-04-16 2007-10-16 3M Innovative Properties Company Medio receptor de chorro de tinta que tiene un inhibidor de migracion de la tinta de multiples etapas.
DE10007484C2 (de) 2000-02-18 2001-12-13 Schoeller Felix Jun Foto Schichtträger für Aufzeichnungsmaterialien
US6685296B2 (en) 2000-06-16 2004-02-03 Canon Kabushiki Kaisha Ink tank and ink jet recording apparatus provided with the same
US20050003113A1 (en) * 2003-07-02 2005-01-06 Tienteh Chen Inkjet recording materials

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2633671B2 (ja) * 1989-01-18 1997-07-23 日本製紙 株式会社 インクジェット記録用シート
US4935307A (en) * 1988-10-21 1990-06-19 Minnesota Mining And Manufacturing Company Transparent coatings for graphics applications
DE4322178C2 (de) * 1993-07-03 1996-11-07 Schoeller Felix Jun Papier Aufzeichnungsmaterial für Ink-Jet-Druckverfahren
US6114047A (en) * 1993-09-30 2000-09-05 Kimoto Co., Ltd. Recording material
JPH08318672A (ja) * 1995-03-23 1996-12-03 Konica Corp インクジェット記録用シート及び記録方法

Also Published As

Publication number Publication date
ATE207417T1 (de) 2001-11-15
PT878319E (pt) 2002-04-29
DE59801835D1 (de) 2001-11-29
EP0878319A2 (fr) 1998-11-18
ES2166576T3 (es) 2002-04-16
DE19720833C1 (de) 1999-04-08
EP0878319A3 (fr) 1998-12-02
DK0878319T3 (da) 2002-02-18

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